• 제목/요약/키워드: Pd complex

검색결과 179건 처리시간 0.025초

오차적분 적용계수를 이용한 PD+I 퍼지제어기 (PD+I Fuzzy Controller Using Error-Accumulating Applying Factor)

  • 전경한;이연정;최봉열
    • 제어로봇시스템학회논문지
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    • 제8권3호
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    • pp.193-198
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    • 2002
  • In this paper, we Propose a PD+I fuzzy controller using an error-accumulating applying factor. In fuzzy control, analytical study was done formerly, in which fuzzy control can be classified by PD type and PI type, and also the study for getting merits of both types was done, too. But the mixed type has a complex structure and many parameters. The proposed fuzzy controller is 2-input 2-out-put and PD type fuzzy control is used as a basic structure. And the proposed controller annihilates a steady-state error and improves transient responses because of using the error-accumulating applying factor which is determined in the real time along the current state of controlled process. Futhermore it is easy to tune the system because of decreasing the number of scaling factors and the I type controller with resetting resolves the integral wind-up problem. Finally we apply the proposed scheme to various plants and show the performance betterment.

Gingival crevicular fluid CSF-1 and IL-34 levels in patients with stage III grade C periodontitis and uncontrolled type 2 diabetes mellitus

  • Ahu Dikilitas;Fatih Karaaslan;Sehrazat Evirgen;Abdullah Seckin Ertugrul
    • Journal of Periodontal and Implant Science
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    • 제52권6호
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    • pp.455-465
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    • 2022
  • Purpose: Periodontal diseases are inflammatory conditions that alter the host's response to microbial pathogens. Type 2 diabetes mellitus (T2DM) is a complex disease that affects the incidence and severity of periodontal diseases. This study investigated the gingival crevicular fluid (GCF) levels of colony-stimulating factor-1 (CSF-1) and interleukin-34 (IL-34) in patients with stage III grade C periodontitis (SIII-GC-P) and stage III grade C periodontitis with uncontrolled type 2 diabetes (SIII-GC-PD). Methods: In total, 72 individuals, including 24 periodontally healthy (PH), 24 SIII-GC-P, and 24 SIII-GC-PD patients, were recruited for this study. Periodontitis patients (stage III) had interdental attachment loss (AL) of 5 mm or more, probing depth (PD) of 6 mm or more, radiographic bone loss advancing to the middle or apical part of the root, and tooth loss (<5) due to periodontal disease. Radiographic bone loss in the teeth was also evaluated; grade C periodontitis was defined as a ratio of the percentage of root bone loss to age greater than 1.0. The plaque index (PI), gingival index (GI), presence of bleeding on probing (BOP), PD, and clinical AL were used for clinical periodontal assessments. GCF samples were obtained and analyzed using an enzyme-linked immunosorbent assay. Results: All clinical parameters-PD, AL, GI, BOP, and PI-were significantly higher in the SIII-GC-PD group than in the PH and SIII-GC-P groups for both the full mouth and each sampling site (P<0.05). The total IL-34 and CSF-1 levels were significantly higher in the SIII-GC-PD group than in the PH and SIII-GC-P groups (P<0.05), and there were significant differences between the periodontitis groups (P<0.05). Conclusions: These findings suggest that IL-34 and CSF-1 expression increases in patients with SIII-GC-PD. CSF-1 was associated with the inflammatory status of periodontal tissues and T2DM, while IL-34 was associated only with T2DM.

가압 수소가 발전기 고정자 권선 절연 열화와 부분 방전 특성에 미치는 영향 (The Effect of Pressurized Hydrogen on the Aging and Partial Discharge Activity in Generator Winding Insulations)

  • 김진봉
    • 한국안전학회지
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    • 제14권4호
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    • pp.100-107
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    • 1999
  • The purpose of the study is to investigate the effect of H$_2$ pressure on partial discharge (PD) activity and aging rate in turbine generator winding insulations. A series of field tests and laboratory tests were peformed to investigate the effect of $H_2$ pressure on PD activity. Field tests were conducted at two unit turbine generators in two conditions, in $H_2$ pressure and in air atmosphere. Obtained results are as follows ; 1) ${\Delta}tan{\delta}$ and maximum partial discharge are reduced with increase of $H_2$ pressure and partial discharge inception voltage. 2) The reduction ratio of ${\Delta}tan{\delta}$ due to $H_2$ pressure is higher than one of PD magnitude. 3) Partial discharge pulses suffer from attenuation and distortion when transmitted along windings, because of the complex L-C network between windings. From the result, partial discharge pulses are subjected to resonance phenomena in a generator winding.

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PD 측정과 HFPD의 감도특성에 관한 연구 (A Study on the Sensitivities Characteristics in a PD and a HFPD)

  • 임장섭;김덕근
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2000년도 춘계학술대회 논문집 유기절연재료 방전 플라즈마
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    • pp.29-32
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    • 2000
  • The partial discharge testing is widely used in insulation property measurement because it gives low stress to high voltage equipment which is undertaken tests. Therefore it is very useful method compare to previous destructive methods and effective diagnosis method in power transformer that requires on-line & on-site diagnosis. But partial discharges have very complex characteristics of discharge pattern so it is required continuous research to development of precise analysis method. In recent, the study of partial discharge is carrying out discover of initial defect of power equipment through condition diagnosis and system development of degradation diagnosis using HFPD(High Frequency Partial Discharge) detection. In this study, simulated transformer is manufactured and PD/HFPD occurred from transformer is measured with broad band antenna in real time, the degradation grade of transformer is analyzed through produced patterns in simulated transformer according to applied voltages.

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Formation and Properties of Dimethylamine Complexes of Palladium(II) Having trans Phosphorus Spanning Terdentate Ligands

  • 류상열;양웅강;김훈식;박순흠
    • Bulletin of the Korean Chemical Society
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    • 제18권11호
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    • pp.1183-1185
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    • 1997
  • Dimethylamine complexes of palladium(Ⅱ) [(PCP)Pd(NHMe2)](OTf) (PCP = 2,6-(R2PCH2)2C6H3); R = Ph (1), R = Cy (2)), have been prepared from the reaction of (PCP)Pd(OTf) and dimethylamine. The complex 1 is stable both in solution and in the solid state, while 2 is stable only in solution in the presence of dimethylamine although the formation of 2 in solution is quantitative by NMR Spectroscopy. A solution NMR spectroscopic study shows that dimethylamine favors over carbon monoxide in the coordination sphere of palladium(Ⅱ) having rigid terdentate ligands. The complexes 1 and 2 in chlorinated solvents undergo a chlorine abstract reaction yielding Pd(2,6-(R2PCH2)2C6H3)Cl in the presence of a base such as dimethylamine and DABCO (diazabicyclooctane), in which a transient dimethylamido palladium(Ⅱ) species likely involves.

염산용액(鹽酸溶液)에서 白金(IV), 팔라듐(II)과 로듐(III)의 이온평형(平衡) (Ionic Equilibria of Pt(IV), Pd(II) and Rh(III) in Hydrochloric Acid Solution)

  • 이만승;이진영
    • 자원리싸이클링
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    • 제18권1호
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    • pp.30-37
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    • 2009
  • 염산농도 0.001에서 10 M사이의 범위에서 백금(IV)과 팔라듐(II) 및 로듐(III)의 착물형성반응과 물질수지를 고려하여 각 금속의 분배곡선을 구했다. 염산농도가 0.1 M이상인 조건에서는 백금과 팔라듐의 대부분은 $PtCl_6^{2-}$$PdCl_2^{2-}$로 존재하였다. 로듐의 농도분포는 염산농도에 큰 영향을 받는다. 염산농도가 0.1에서 10 M로 증가함에 따라 로듐의 주 화학종이 $PhCl_5^{2-}$에서 $PhCl_6^{3-}$로 변했다. 문헌에 발표된 백금과 팔라듐의 용매추출자료로부터 $PtCl_6^{2-}$$PtCl_4^{2-}$와 수소이온간의 매개변수를 추산했다.

지속가능한 공동주택단지 커뮤니티 가든 조성 및 운영방안 연구 - 민간분양단지 및 공공임대단지의 비교분석을 중심으로 - (Research of Management Plan for Sustainable Community Garden in Apartment Complex - Focused on Comparison General Apartment Complex and Public Lease Apartment Complex -)

  • 오주석;민병학;최정민;김세용
    • 대한건축학회논문집:계획계
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    • 제34권4호
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    • pp.57-67
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    • 2018
  • The Purpose of this study was to enhancing sustainable participation of community gardeners by comparing general apartment complex with public lease apartment complex by drawing indices for quantitative research. This research carried out interviews and statistical research with 319. The results revealed statistically difference between 2 types of apartment, and satisfactions and intention of continuous participation is also different from each sustainable in participating in community garden are also different from each type. Overall, however, participation of female citizens, public assistance, area of plot, and effectiveness of exchange can enhance participants' continuous participation.

국내 범죄예방 환경설계 인증제도의 효과성에 관한 연구 (A Study on the Effectiveness of an Authorization System for Domestic Crime Prevention Through Environmental Design)

  • 임동현;이경훈
    • 대한건축학회논문집:계획계
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    • 제34권6호
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    • pp.85-92
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    • 2018
  • This study was to confirm the effectiveness of crime prevention in an apartment complex environmentally designed for domestic crime prevention. The researchers surveyed 267 residents on the community, fear of crime, and crime victimization. They arrived at the following conclusions. The authorization complex received higher security satisfaction results than the unauthorized complex; residents were less afraid of crime and more active in the apartment complex community. These results differ from previous studies in that the fear of crime is not related to a crime victim experience and that the fear of crime is low when there are less households in the apartment complex. Therefore, effectiveness of crime prevention abroad should not be accepted in a domestic residential environment.

Palladium(II) Schiff Base Complexes Derived from Allylamine and Vinylaniline

  • Uh, Yoon-Seo;Zhang, Hai-Wen;Vogels, Christopher M.;Decken, Andreae;Westcott, Stephen A.
    • Bulletin of the Korean Chemical Society
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    • 제25권7호
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    • pp.986-990
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    • 2004
  • Condensation of salicylaldehyde $(2-HOC_6H_4C(O)H)$ with allylamine afforded the unsaturated salicylaldimine, $2-HOC_6H_4C(H)=NCH_2CH=CH_2$. Similar reactivity was observed with substituted salicylaldehydes. Further reaction of these Schiff bases with palladium acetate or $Na_2PdCl_4$ afforded complexes of the type $PdL_2$, where L = deprotonated Schiff base. The molecular structure of the parent salicylaldimine palladium complex $[trans-(2-OC_6H_4C(H)=NCH_2CH=CH_2)_2Pd]$ (1) was characterized by an X-ray diffraction study. Crystals of 1 were monoclinic, space group $P2_1/n,\;a\;=\;14.0005(9)\;{\AA},\;b\;=7.2964(5)\;{\AA},\;c\;=\;17.5103(12)\;{\AA},\;{\beta}\;=\;100.189(1)^{\circ}$, Z = 4. Analogous chemistry with 4-vinylaniline also gave novel palladium complexes containing a pendant styryl group. Crystals of $[trans-(2-HOC_6H_4C(H)=N-4-C_6H_4CH=CH_2)_2Pd]$ (4) were monoclinic, space group $P2_1/c$, a = 13.7710(14) ${\AA}$, b = 11.0348(11) ${\AA}$, c = 7.8192(8) ${\AA}$, ${\beta}\;=\;98.817(2)^{\circ}$, Z = 2.

양친매성 다중층막의 전기적 도전성 및 전기적 특성 (The Electrical Conductivity and Electrochemical Characteristics of Amphiphilic Milecules Multilayer Film confined with Hetero Type)

  • 최인희;박수길;임기조;이주성
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1996년도 춘계학술대회 논문집
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    • pp.269-272
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    • 1996
  • The electrochemical behavior of Ru complex and PD complex monolayer, deposited on conductive substrate by the Langmuir-Blodgett(LB) technique as monolayer and multilayer, has been studied by cyclic voltammetry. Monolayer films show stable reversible state. Atomic resolution imaging of LB highly-conductive, environmently stable organic films has been obtained by atomic force microscopy (AFM) showing their closely packed structure,

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