• Proceedings of the Korean Magnestics Society Conference
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• 1999.04a
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• pp.100-101
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• 1999

• Proceedings of the Korean Magnestics Society Conference
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• 2005.06a
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• pp.170-171
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• 2005

• Journal of the Korean Magnetics Society
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• v.4 no.4
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• pp.307-312
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• 1994

The magneto-optical Kerr effect due to the (Fe,Co)/(Pd,Pt,Cu,Ag) multilayer film is calculated considering of multiple reflection effect, and the calculated Kerr spectrum is compared to the reported experimental value. In case of Co/Pd, the reliance of composition and the variable tendency of magneto-optical Kerr rotation angle for Co thickness fully coresponds to experimantal and theoretical value. The theoretical Kerr spectrum of Fe/Cu and Fe/Ag multilayer films show the peaks near the Cu and Ag optical ansorption band in accordance with the experiment. But in case of Co/Pt, the increase tendency of Kerr rofation with decreasing wavelength reported by experiments could not be explained by the optical multiple interference. This difference of theoretical and experimental Kerr spectrum of Co/Pt film might be related with the change of electronic structure of Co and/or Pt from their bulk state.

• Journal of the Korean Magnetics Society
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• v.20 no.3
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• pp.89-93
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• 2010

We study the giant magneto-resistance (GMR), coercivity and their dependence on the ferromagnetic layers adjacent to the nonmagnetic layer in a spin-valve structure, [Pd/ferromagnetic] multilayers with perpendicular anisotropy. We fabricated a basic spinvalve structure of $[Pd/Co]_2$/ferro-magnetic layer/nonmagnet/ferro-magnetic layer/$[Pd/Co]_2$/FeMn and investigated the dependence of its GMR and magnetic properties such ad coercivity on the ferromagnetic material to reduce the coercivity of the free layer. We try to reduce the freelayer coercivity by controlled the anisotropy, we insert the material NiFe, $Co_8Fe_2$, $Co_9Fe_1$ to ferromagnetic layers adjacent to the Cu layer. Then, we have been able to reduce the coercivity as low as 100 Oe, and also achieved 6.7% of magneto-resistance ratio when the ferromagnetic layer thickness was 0,7 nm.

• Journal of Magnetics
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• v.10 no.1
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• pp.33-35
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• 2005

Perpendicular magnetization curves and crystal textures of $[Pd(0.8 nm)/Co(0.8 nm)]_5/FeMn$ multilayers having an exchange-biased perpendicular magnetic anisotropy as a function of FeMn thickness and annealing temperature were measured. As FeMn thickness increases from 0 to 21 nm, the perpendicular exchange biasing field ($H_{ex}$) obtained the maximum value of 130 Oe at FeMn thickness 12 nm. As the annealing temperature increases to $240^{\circ}C$, the H_ex increased from 115 Oe to 190 Oe and the exchange-biased perpendicular magnetic anisotropy disappeared at $330^{\circ}C$.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2003.05a
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• pp.13-16
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• 2003

Magnetic and magneto-optical properties of Fe/Pt/Fe, Co/Pd/Co trilayers and also the sandwiches with wedge-shaped magnetic (Fe, Co) and nonmagnetic (Pt, Pd) layers were investigated. The oscillatory behavior of the saturation field $H_{s}$ of the studied trilayers with changing the thickness of the nonmagnetic layer (NML) $t_{NML}$ was revealed. That was explained by the exchange coupling between ferromagnetic layers (FML) through the nonmagnetic spacer. For the first time, oscillations of the transverse Kerr effect (TKE) with changing the Pt- and Pd-wedge thickness were discovered. Period of these oscillations was found to depend on the FML thickness and the photon energy of the incident light. TKE spectra of the examined samples were discovered to modify very strongly with increasing $t_{NML}$. The discovered peculiarities of magneto-optical properties of thin-film systems were explained by a concept of the spin-polarized quantum well states in the pt and Pd layers.

• Journal of Electrochemical Science and Technology
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• v.9 no.3
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• pp.202-211
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• 2018

In this work, Fe-Pd alloy films have been electrodeposited on different substrates using an electrolyte containing $[Pd(NH_3)_4]^{2+}$ (0.02 M) and $[Fe-Citrate]^{2+}$ (0.2 M). The influences of substrate and overpotential on chemical composition, nucleation and growth kinetics as well as the electrodeposited films morphology have been investigated using energy dispersive X-ray spectroscopy (EDS), current-time transients, scanning electron microscopy (SEM), atomic force microscopy (AFM) and X-ray diffraction (XRD) patterns. In all substrates - brass, copper and sputtered fluorine doped tin oxide on glass (FTO/glass) - Fe content of the electrodeposited alloys increases by increasing the overpotential. Also the cathodic current efficiency is low due to high rate of $H_2$ co-reduction. Regarding the chronoamperometry current-time transients, it has been demonstrated that the nucleation mechanism is instantaneous with a typical three dimensional (3D) diffusion-controlled growth in the case of brass and copper substrates; while for FTO, the growth mode changes to 3D progressive. At a constant overpotential, the calculated number of active nucleation sites for metallic substrates is much higher than that of FTO/glass; however by increasing the overpotential, the number of active nucleation sites increases. The SEM micrographs as well as the XRD patterns reveal the formation of Fe-Pd alloy thin films with nanostructure arrangement and ultra-fine grains.

• Korean Chemical Engineering Research
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• v.57 no.6
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• pp.774-780
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• 2019

An efficient Pd-coated $La_{0.1}Sr_{0.9}Co_{0.2}Fe_{0.8}O_{3-{\delta}}$ (LSCF-1928) catalyst for total oxidation of methane under landfill gas at low tmeperature has been developed. Synergism was observed between Pd coating and LSCF-1928 substrate. When Pd coating on LSCF-1928, we used electroless plating method and conformed characteristic of catalyst through TPR(Temperature Programmed Reduction) analysis, XRD(X-ray Diffraction) analysis, SEM(Scanning Electron Microscope). The results demonstrated that the Pd coated LSCF-1928 catalysts showed higher performance than non-Pd LSCF-1928. Pd coated LSCF-1928 had low total oxidation temperature of methane (< $475^{\circ}C$) which is lower than total oxidation temperature of methane about non-Pd LSCF-1928 catalysts (= $475^{\circ}C$). Also, $O_2$ conversion rate was higher than non-Pd LSCF-1928 at same temperature.

• Applied Chemistry for Engineering
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• v.9 no.2
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• pp.243-248
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• 1998

This study investigated the separation and the property of palladium precipitate formed by ascorbic acid in a simulated radioactive liquid waste, which was composed of 10 elements((Pd, Ru, Rh, Nd, Cs, Sr, Fe, Ni, Zr, Mo). Pd was separated selectively by using reduction characteristics of metal ions contained in the simulated waste with ascorbic acid. When the nitric acid concentration was 0.5 M, the Pd over 99.5% was precipitated by adding 0.04 M ascorbic acid. Nitric acid concentration is important at the reduction reaction of Pd ion. The precipitation yield of Pd was decreased as the concentration of nitric acid was increased. The Pd precipitate was re-dissolved in reaching at an equilibrium when the concentration of nitric acid was high and ascorbic acid was added with a small amount. The Pd precipitate formed by ascorbic acid was Pd metal and was aggregated by particles less than $1.0{\mu}m$.

• Proceedings of the Korean Magnestics Society Conference
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• 2008.12a
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• pp.78.2-78.2
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• 2008