• Title/Summary/Keyword: PbI2

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Effect of Ohjeoksan-Decoction on Brain Metal Level in Rats (오적산을 투여한 흰쥐의 뇌중 금속농도변화에 관한 연구)

  • Min Dae Ki;Han Seong Nim;Ko Seong Gyu
    • Journal of Physiology & Pathology in Korean Medicine
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    • v.16 no.5
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    • pp.967-975
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    • 2002
  • This study was to investigate the metal accumulation from Ohjeoksan-Decoction to rat brain(Sprague Dawley). 1. In Control group, each metal concentration was within 26.65mg/kg, and in each experimental groups, was within 28.39mg/kg. And, there were no significant metal concentration between control and experimental groups. Exceptionally, Cr and Ni level of control group was lower than experimental groups significantly. (p<0.05) and Cr and Ni level of experimental I group was lower than other experimental groups too.(p<0.05). But, Pb level of control group was higher than experimental groups significantly.(p<0.05) Pb level of experimental I group was higher than other experimental groups(p<0.01). 2. In non-hazardous, hazardous and total metal concentration, there was no increase tendency in brain according to the high dose of OD(Ohjeoksan-Decoction) intake. Reversely, in experimental groups, hazardous metal concentration was decrease by high OD intake.(p<0.05). 3. Correlation among each metal in brain was various in each groups. Briefly under the intake of Ohjeoksan-Decoction, that is very busy herb prescription, this study was defined within safety in brain metal level by P.O. during 10 days. But, there should be a more research about Pb increase by high dose OD intake

Study on Determination of Permissible Soil Concentrations for Explosives and Heavy Metals (화약류 및 중금속의 인체위해성평가 및 생태독성에 기반한 토양허용농도도출에 관한 연구)

  • Kim, Moonkyung;Jung, Jae-Woong;Nam, Kyoungphile;Jeong, Seulki
    • Journal of Soil and Groundwater Environment
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    • v.20 no.6
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    • pp.19-27
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    • 2015
  • Permissible soil concentrations for explosives (i.e., TNT and RDX) and heavy metals (i.e., Cu, Zn, Pb, and As) heve been derived from human risk and ecotoxicity, respectively. For TNT and RDX, human risk based-permissible soil concentrations were determined as 460 mg-TNT/kg-soil and 260 mg-RDX/kg-soil. Ecotoxicity based-permissible soil concentrations for Cu and Zn were determined from species sensitivity distribution (SSD) and uncertainty factor of 1 to 5, yielding 18.0-40.0 mg-Cu/kg-soil and 46.0-100 mg-Zn/kg-soil. For Pb and As, ecotoxicity data were not enough to establish SSD so that a deterministic method was used, generating 13.8-30.8 mg-Pb/kg-soil and 2.10-4.60 mg-As/kg-soil. It is worth noting that the methodology used to derive permissible concentrations in soil can differ depending on ecotoxicity data availability and socio-economic situations, which results in different permissible concentrations. The permissible concentrations presented in this study have been derived from conservative assumptions for exposure parameters, and thus should be considered as soil standards. In the light of remediation and pollution management of a site of interest, the site-specific and receptor-specific permissible soil concentrations should be derived considering potential receptors, current and future land use, background concentrations, and socio-economic consultation.

Contamination Assessment of Surface Sediments in Urban Rivers, Busan (부산지역 도시하천 표층 퇴적물 오염도 평가에 관한 연구)

  • Kwag, Jin-Suk;Son, Jung-Won;Kim, Chu-In;Song, Bok-Joo
    • Journal of Korean Society on Water Environment
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    • v.37 no.4
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    • pp.296-305
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    • 2021
  • This work investigated heavy metal pollution in surface sediments of rivers in Busan, Korea. Surface sediments were analyzed in order to conduct contamination assessment of organic matter, nutrients, and heavy metal concentrations. Contamination assessment of heavy metals was conducted using geoaccumulation index (Igeo), pollution load index (PLI), and potential ecological risk index (RI). Accumulation of organic matter and nutrients were affected by water discharged from sewage treatment plant. The concentrations of organic matter and nutrients were found to be greater in points which were close to the sewage treatment plant more than points furthest. The concentrations of Pb, Zn, Cu, Cd, Hg, As, Cr, and Ni were found to be greater in surface sediment more than in the background. The mean concentrations of heavy metals were in the order of Zn (323.5 mg/kg) > Cu (70.5 mg/kg) > Pb (39.8 mg/kg) > Cr (33.4 mg/kg) > Ni (13.5 mg/kg) > As (9.4 mg/kg) > Cd (0.84 mg/kg) > Hg (0.092 mg/kg). The result of geoaccumulation indices indicated that Hg > Cr > Cu > Ni > Zn > As > Pb > Cd were found in order of severe contamination by heavy metals. From PLI and RI analysis, it was evident that the Suyeonggang 2 was the most contaminated river.

Study on 1,200 N-class bipropellant rocket engine using decomposed $H_2O_2$ and kerosene (분해된 과산화수소와 케로신을 이용한 1,200 N 급 이원추진제 로켓 엔진의 연구)

  • Jo, Sung-Kwon;An, Sung-Yong;Kim, Jong-Hak;Yoon, Ho-Sung;Kwon, Se-Jin
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2010.05a
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    • pp.156-164
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    • 2010
  • As part of preliminary study for development of 1,200 N-class bipropellant rocket engine with the concentrated hydrogen peroxide, bipropellant engine elements were designed and experimentally tested. The catalysts of $MnO_2$ and $MnO_2$ added Pb as an addictive were compared to achieve high decomposition performance and the catalytic reactor with $MnO_2$ added Pb was designed and its decomposition efficiency of 97.2% was achieved. The autoignition tests of kerosene by decomposed hydrogen peroxide were carried out under various equivalence ratios to ignite without additional ignition sources. Autoignition were achieved in all experimental conditions and $C^*$ efficiencies at each condition were at or above 90%. From the measured thrust results, the highest value was 830 N which is in corresponds with 1,035 N at vacuum level using 94.1% theoretical $I_{sp}$.

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Chemical Compositions of Glass Beads from Tombs of Hakso-ri Site, O'chang (오창 학소리유적 토광묘내 유리구슬의 화학적 특성 - 37호 및 40호 -)

  • Chung, Kwang Yong;Kang, Hyung Tae;Koh, Min Jeong;Kim, Hwa Jung
    • 보존과학연구
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    • s.32
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    • pp.113-121
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    • 2011
  • Four glass beads from Hakso-ri site, O'chang were analyzed for thirteen oxides with SEM/EDS and lead isotope ratios with TIMS respectively. These samples were classified to potash glass system($K_2O-CaO-SiO_2$) with HCLA(High CaO, Low $Al_2O_3$). However three samples with above 4% for lead could be classified to potash-lead ($K_2O-PbO-CaO-SiO_2$)glass system and it seemed that coloring agent for greenish blue was Cu. Lead isotope ratio data for four samples did not make a group but scattered to the space respectively. It needs more study for compositions and lead iosotope data of potash-lead glasses with regions and ages.

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A Study on Structural Shielding Design of Afterloading Therapy Room (강내치료실 차폐에 대한 고찰)

  • Yun, Suk-Rok;Kim, Myung-Ho;Shin, Dong-Oh
    • The Journal of Korean Society for Radiation Therapy
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    • v.2 no.1
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    • pp.31-40
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    • 1987
  • In the case of designing a high dose rate remote controlled afterloading treatment room with existing hospital facilities. We must construct the effective protective barriers so as to reduce the primary and scattered radiation up to the maximum permissible dose level. It is difficult to reinforce the barrier thickness of the shielding requirements because of the limited space and the problem of the existing building structure at the surrounding area. Therefore we can reduce the intensity of primary radiation to the required degree at the location of interest with installing the appropriate I shaped Pb barriers between the radiation source and the shielding wall of the concrete. As a result, it was possible to reduce the intensity of the primary radiation below the M.P.D level by using additional Pb barriers instead of increasing thickness of concrete wall.

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고온초전도 BSCCO 2223상 형성시 나타나는 여러 가지 이차상들이 선재의 임계전류에 미치는 영향(토요일)

  • 박성창;김철진;유재무;고재웅;김영국
    • Proceedings of the Korea Crystallographic Association Conference
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    • 2003.05a
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    • pp.24-24
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    • 2003
  • 고온초전도 BSCCO 2223 ((Bi, Pb)₂Sr₂Ca₂Cu₃O/sub x/) 선재의 특성을 향상시키기 위해서는 반복적인 인발 및 압연과정을 통한 texturing향상, BSCCO 2223입자의 배향성 증대, 피복재내 초전도체의 충진율(밀도)향상, 이차상의 부피분율 감소등이 이루어져야 한다. 최적 열처리 조건을 통하여 열처리 시에 형성되는 이차상인 (Bi,Pb)₂Sr₂CuO/sub y/ (2201, amorphous phase)를 조절하면서, (Ca,Sr)₂CuO₃ (2/1 AEC), (Ca,Sr)/sub 14/Cu/sub 24/O/sub 41/ (14/24 AEC)와 같은 이차상들의 부피분율 및 크기를 감소시켜야만 한다. 본 실험에서는 BSCCO 2223 선재의 특성을 향상시킬수 있는 최적의 열처리 조건 확립 및 기계적 공정시 나타나는 여러 가지 문제점을 개선하여 높은 임계전류를 가지는 선재의 특성을 분석하고자 하였다. 최종적으로 제조된 선재는 2223상 결정이 피복재(Ag)와 평행하게 길게 성장하며, AEC상의 크기와 부피분율이 감소할수록 더 높은 임계전류특성을 나타내었다(I/sub c/~70A, J/sub c/~42,000 A/㎠). 또한 이 선재에서 나타나는 여러 가지 이차상들을 분석하기 위하여 XRD, SEM, EDS 분석을 행하였다.

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Recycling of Acidic Etching Waste Solution Containing Heavy Metals by Nanofiltration (I): Evaluation of Acid Stability of Commercial Nanofiltration Membranes (나노여과에 의한 중금속 함유 산성 폐에칭액의 재생(I): 상용 나노여과 막의 산 안정성 평가)

  • Youm, Kyung-Ho;Shin, Hwa-Sup;Jin, Cheon-Deok
    • Membrane Journal
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    • v.19 no.4
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    • pp.317-323
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    • 2009
  • In this study the nanofiltration (NF) membrane treatment of a nitric acid waste solutions containing $Pb^{+2}$ heavy metal ion discharging from the etching processes of an electronics and semiconductors industry has been studied for the purpose of recycling of nitric acid etching solutions. Three kinds of NF membranes (General Electric Co. Duraslick NF-4040 membrane, Dow Co. Filmtec LP-4040 membrane and Koch Co. SelRO MPS-34 4040 membrane) were tested for their separation efficiency (total rejection) of $Pb^{+2}$ ion and membrane stability in nitric acid solution. NF experiments were carried out with a dead-end membrane filtration laboratory system. The membrane permeate flux was increased with the increasing storage time in nitric acid solution and lowering pH of acid solution because of the enhancing of NF membrane damage by nitric acid. The membrane stability in nitric acid solution was more superior in the order of Filmtec LP-4040 < Duraslick NF-4040 < SelRO MPS-34 4040 membrane. The total rejection of Pb+2 ion was decreased with the increasing storage time in nitric acid solution and lowering the pH of acid solution. The total rejection of $Pb^{+2}$ ion after 4 months NF treatment was decreased from 95% initial value to 20% in the case of Duraslick NF-4040 membrane, from 85% initial value to 65% in the case of SelRO MPS-34 4040 membrane and from 90% initial value to 10% in the case of Filmtec LP-4040 membrane. These results showed that SelRO MPS-34 4040 NF membrane was more suitable for the treatment of an acidic etching waste solutions containing heavy metal ions.

Comparison of microstructures in T1-1223/Ag tapes with different chemical compositions and J$_c$'s

  • Jeong, D.Y.;Kim, H.K.;Lee, H.Y.;Cha, M.K.;Ha, H.S.;Oh, S.S.;Tsuruta, T.;Horiuchi, S.
    • 한국초전도학회:학술대회논문집
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    • v.9
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    • pp.280-290
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    • 1999
  • The microstructures of a Tl$_{0.8}Pb_{0.2}Bi_{0.2}Sr_{1.6}Ca_2Cu_3O_{9+{\delta}}$/Ag tape (tape I ) with J$_c$ of 17,600 A/cm$^2$ at 77 K and 0 T and three Tl$_{0.8}Pb_{0.2}Bi_{0.2}Sr_{1.8}Ba_{0.2}Ca_{2.2}Cu_3O_{9+{\delta}}$/Ag tapes with J$_c$'s of 9,300 (tape II), 16,700 (tape III) and 25,200 A/cm$^2$ (tape IV)prepared using the powder-in-tube method and an in-situ reaction method, were investigated using scanning electron microscopy and high-resolution transmission electron microscopy, and compared each other. ln the tape preparation, an intermediate rolling process was incorporated during final heat-treatment for the last tape, but not for the rest of the tapes. The microstructural analysis revealed clear differences in grain-texturing, crystallographic defects and impurity phases, depending on the chemical composition of the tape. Tendency of directional grain-alignment increased in an order of tapes I, II III and IV. In tape IV, T1-1223 grains are textured, at least in local regions. In crystallographic defects, while stacking faults were prevalent in the former composition, dislocations and voids were frequently observed in the latter. Also impurity phases were appeared to be more abundant in the former than in the latter. The relationship between 1,and the microstructure in the tapes was attempted to explain in a term of grain-linking.

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Sputtering deposition and post-annealing of $Pb(Zr, Ti)O_3$ ferroelectric thin films ($Pb(Zr, Ti)O_3$강유전체 박막의 스퍼터링 증착과 후속열처리)

  • 장지근;박재영;윤진모;임성규;장호정
    • Journal of the Korean Vacuum Society
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    • v.6 no.1
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    • pp.36-43
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    • 1997
  • FECAPS(ferroelectric capacitors) have been fabricated by RF magnetron sputtering deposition of 3000$\AA$ PZT thin films on the Pt/Ti/$SiO_2$/Si substrates and post-annealing with the temperature of $550^{\circ}C$~$650^{\circ}C$ for 10 sec~50 sec in a RTA system. The electrical characteristics of the fabricated capacitors showed the highest dielectric constant and remanent polarization[${\varepsilon_r(1kHz)$=690, $2P_r$(-5V~5V sweep)=22$\mu$C/$ \textrm{cm}^2$] in the samples annealed at $650^{\circ}C$ for 30 sec, while the lowest tangent loss and leakage current [$tan\delta(\ge10kHz)\le0.02, \; J_i(5V)=3\mu\textrm{A}/\textrm{cm}^2$]in the samples annealed at $600^{\circ}C$ for 30 sec.

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