• Title/Summary/Keyword: PbI2

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The influence of BaO on the mechanical and gamma / fast neutron shielding properties of lead phosphate glasses

  • Mahmoud, K.A.;El-Agawany, F.I.;Tashlykov, O.L.;Ahmed, Emad M.;Rammah, Y.S.
    • Nuclear Engineering and Technology
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    • v.53 no.11
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    • pp.3816-3823
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    • 2021
  • The mechanical features evaluated theoretically using Makishima-Mackenzie's model for glasses xBaO-(50-x) PbO-50P2O5 where x = 0, 5, 10, 15, 20, 30, 40, and 50 mol%. Wherefore, the elastic characteristics; Young's, bulk, shear, and longitudinal modulus calculated. The obtained result showed an increase in the calculated values of elastic moduli with the replacement of the PbO by BaO contents. Moreover, the Poisson ratio, micro-hardness, and the softening temperature calculated for the investigated glasses. Besides, gamma and neutron shielding ability evaluated for the barium doped lead phosphate glasses. Monte Caro code (MCNP-5) and the Phy-X/PSD program applied to estimate the mass attenuation coefficient of the studied glasses. The decrease in the PbO ratio has a negative effect on the MAC. The highest MAC decreased from 65.896 cm2/g to 32.711 cm2/g at 0.015 MeV for BPP0 and BPP7, respectively. The calculated values of EBF and EABF showed that replacement of PbO with BaO contents in the studied BPP glasses helps to reduce the number of photons accumulated inside the studied BPP glasses.

Effects of the Pilose Antler on the Experimental Hepatocarcino- genesis and the Natural Killer Cell Activity in Rats (랫드의 실험적 간암발생과 자연살해세포의 활성에 미치는 녹용의 효과)

  • 정자영;길광섭;이영순
    • Toxicological Research
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    • v.14 no.4
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    • pp.475-481
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    • 1998
  • This study was performed to investigate the modifying effect of the general (GPA) and the fermented pilose antler (FPA) on experimental hepatocarcinogenesis and Natural Killer cell activity in rats. Specific pathogen free, 5-week male Sprague-Dawley rats were divided into four groups. To induce hepatocarcinogenesis, diethylnitrosamine (DEN, 200 mg/kg, i.p.) was used as a tumor initiator and was given in a single dose at experimental onset. All rats were given a partial hepatectomy (PH) at 3 weeks after experimental onset. Sodium phenobarbital (PB, 0.05% in diet), GPA (0.075% in diet) and FPA (0. 075% in diet) were given from 2 to 8 weeks. Group I of the initiation control group was only given DEN. As initiation-promotion group, Group II was given DEN and then PB. Group III and IV were given DEN-PB-GPA and DEN-PB-FPA, respectively. In hematological analysis, as compared with Group I. the number of white blood cells were significantly increased in the GPA (p<0.01) and the FPA treated group (p<0.05), respectively. Natural killer (NK) cell activity by flow cytometer (FCM) analysis was higher in group of treated with the GPA (35%) than that of the FPA (27.5%), but not significant. Result of the immunohistochemical staining of the glutathione S-transferase placental form (GST-p) indicated that the number of and area of the pre-neoplastic lesions was not significantly changed in Group III and IV compared Group II, respectively. In conclusion, the GPA and the FPA treatment significantly increased the number od WBC in peripheral blood, but the enhancing NK activity and the modifying effect on the experimental hepatocarcinogenesis were not observed.

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Influence of various metal oxides (PbO, Fe2O3, MgO, and Al2O3) on the mechanical properties and γ-ray attenuation performance of zinc barium borate glasses

  • Aljawhara H. Almuqrin;K.A. Mahmoud;U. Rilwan;M.I. Sayyed
    • Nuclear Engineering and Technology
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    • v.56 no.7
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    • pp.2711-2717
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    • 2024
  • The current work aims to fabricate metal oxide-doped (PbO, Fe2O3, MgO, and Al2O3, each of which boasts a purity of 99%) zinc barium borate glasses through the melt quenching technique at the 1000 ℃ melting temperature. The results showed that adding 5 mol.% of metal oxides PbO, Fe2O3, Al2O3, and MgO increases the density of the zinc barium borate glasses. Additionally, the fabricated glasses' mechanical properties were determined based on the Makishima-Mackenzie model, which proved that the highest mechanical properties were achieved for glasses doped with Al2O3 compounds. The mechanical moduli for the glasses doped with Al2O3 reach 80.95 GPa (Young), 59.90 GPa (bulk), 31.75 GPa (shear), and 102.23 GPa (longitudinal). Additionally, the Al2O3-doped glasses' microhardness reaches 4.77 GPa. Moreover, estimation of the fabricated glasses' gamma-ray shielding capacity utilized Monte Carlo simulation. The highest linear attenuation coefficients are 29.132, 19.906, 19.243, and 18.923 cm-1 obtained at 0.033 MeV for glasses dopped by PbO, Fe2O3, MgO, and Al2O3, respectively. Therefore, glasses doped with 5 mol.% of PbO have high gamma-ray shielding capacities followed by glasses doped by Fe2O3.

The Effect of the Deposition Temperature and la Doping Concentration on the Properties of the (Pb, La)$\textrm{TiO}_3$ Films Deposited by ECR PECVD (증착온도와 La조성비가 ECR 플라즈마 화학기상증착법으로 증착한 (Pb, La)$\textrm{TiO}_3$박막의 물성에 미치는 영향)

  • Jeong, Seong-Ung;Park, Hye-Ryeon;Lee, Won-Jong
    • Korean Journal of Materials Research
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    • v.7 no.3
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    • pp.196-202
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    • 1997
  • Perovskite lanthanum doped lead titanate ($(Pb,La)TiO_{3}$ or PLT) thin films were successfully fabricated on Pt/TijSiO.iSi substrates at the temperatures as low as $440~500^{\circ}C$ by eleclron cyclotron resonance plasma-enhanced chemical vapor deposition (ECR PECVII). Since the volatilities of the MC sources arid oxide molecules (especially Ph oxide) increased with increasing deposition temperature, the film deposition rate and the (I'b + La)/'Ti ratio decreased Stoichiometric perovskite PL'T films with good dielectric and leakeage current properties were obtained at the temperatures of $460~480^{\circ}C$. The lanthanum content of the film was nearly directly propotional to $La(DPM)_{3}$ flow rate. As the La/Ti ratio increased from 3.0 to 9.5%, the dielectric constant increased from 360 to 650 and the leakeage current density at 100kV/cm electric field decreased from $4{\times}10^{-5}$ to $4{\times}10_{-8}A/cm^2$.

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Heavy Metal Concentrations of Sediment and Ruditapes philippinarum Inhabited in the Intertidal Zone of Kwangyang Bay (광양만 조간대의 퇴적토 및 바지락(Ruditapes philippinarum)내 중금속 분포)

  • Gwak, Yeong-Se;Hwangbo, Jun-Gwon;Lee, Chung-Il
    • The Korean Journal of Ecology
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    • v.24 no.5
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    • pp.297-301
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    • 2001
  • The objectives of this study were to evaluate the extent of heavy metals(As, Pb, Cd, Hg)accumulated in sediments of the Kwangyang Bay, and to investigate bioaccumulation of heavy metals(As, Pb, Cd, Hg) in shellfish(Ruditapes philippinarum) commonly found in the intertidal zone of the Kwangyang Bay. The data was also compared with that of Namhae and Kohung intertidal zones, which were regarded as control stations in this study. Substantial geographical variations in heavy metal concentrations in the sediment samples were found. However, heavy metal concentrations in the sediment collected from the intertidal zones of Yochon(stations I, J) and Myodo(stations G, H) close to Yochon Industrial Area exhibited relatively higher heavy metal concentrations, compared to those from other intertidal zones(stations A, B, C) adjacent to POSCO at Kwangyang Bay. In addition, stations A, B, C showed lower heavy metal concentrations in the sediments than controls(K, L). The annual mean concentrations of the heavy metals in the shellfish from the stations(G, H, I, J) were significantly higher than those from other stations(A, B, C, D, E, F). Nevertheless, heavy metal accumulation in sediments was not reflected in bioaccumulation of heavy metals in shellfish, probably indicating that interactions between the heavy metals in sediment and shellfish might be poor in the current study area, Kwangyang Bay.

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A Study on Reduction of Radiation Exposure by Nuclear Medicine Radiation Workers (핵의학 방사선 작업종사자 피폭 감소 방안에 대한 연구)

  • Lee, Wanghui;Ahn, Sungmin
    • Journal of the Korean Society of Radiology
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    • v.13 no.2
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    • pp.271-281
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    • 2019
  • This study investigated the shielding efficiency of various types of shielding materials and measured the dose by organ using the phantom. Results of Shielding Efficiency Measurement Using Personal Radiation Meter. Among the various shielding materials, 1.1 mm RNS-TX composed of nano tungsten showed the highest shielding efficiency and 0.2 mm lead shielding showed the lowest shielding efficiency. 99mTc 30 mCi was exposed to the phantom for 120 minutes and the result of the measurement of the organs. 20.53 mSv without radiation protective clothing, 8.75 mSv when wearing 0.25 mm Pb protective clothing, 6.03 mSv when wearing 0.5 mm Pb protective clothing. 131I 2 mCi mCi was exposed to the phantom for 120 minutes and the result of the measurement of the organs. 7.71 mSv without radiation protective clothing, 4.88 mSv when wearing 0.25 mm Pb protective clothing, 2.79 mSv when wearing 0.5 mm Pb protective clothing. 18F 5 mCi was exposed to the phantom for 120 minutes and the result of the measurement of the organs. 16.39 mSv without radiation protective clothing, 15.84 mSv when wearing 0.25 mm Pb protective clothing, 12.52 mSv when wearing 0.5 mm Pb protective clothing. None of the radiation workers working in the nuclear medicine department exceeded the dose limit. However, when compared with other workers in the hospital, they showed a relatively high dose. Therefore, it is necessary to prepare measures to reduce and manage the dose of radiation workers in the nuclear medicine department through the wearing of radiation protective clothing made of lightweight, shielding material with good shielding efficiency, circulation task, task sharing, and substitution equipment such as auto dispenser.

A Preliminary Design Concept of the HYPER System

  • Park, Won S.;Tae Y. Song;Lee, Byoung O.;Park, Chang K.
    • Nuclear Engineering and Technology
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    • v.34 no.1
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    • pp.42-59
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    • 2002
  • In order to transmute long-lived radioactive nuclides such as transuranics(TRU), Tc-99, and I- l29 in LWR spent fuel, a preliminary conceptual design study has been performed for the accelerator driven subcritical reactor system, called HYPER(Hybrid Power Extraction Reactor) The core has a hybrid neutron energy spectrum: fast and thermal neutrons for the transmutation of TRU and fission products, respectively. TRU is loaded into the HYPER core as a TRU-Zr metal form because a metal type fuel has very good compatibility with the pyre- chemical process which retains the self-protection of transuranics at all times. On the other hand, Tc-99 and I-129 are loaded as pure technetium metal and sodium iodide, respectively. Pb-Bi is chosen as a primary coolant because Pb-Bi can be a good spallation target and produce a very hard neutron energy spectrum. As a result, the HYPER system does not have any independent spallation target system. 9Cr-2WVTa is used as a window material because an advanced ferritic/martensitic steel is known to have a good performance under a highly corrosive and radiation environment. The support ratios of the HYPER system are about 4∼5 for TRU, Tc-99, and I-129. Therefore, a radiologically clean nuclear power, i.e. zero net production of TRU, Tc-99 and I-129 can be achieved by combining 4 ∼5 LWRs with one HYPER system. In addition, the HYPER system, having good proliferation resistance and high nuclear waste transmutation capability, is believed to provide a breakthrough to the spent fuel problems the nuclear industry is faced with.

Interpretation of heavy metal elements from the road dusts using GIS (GIS를 이용한 도로 분진의 중금속원소 함량 해석에 관한 연구)

  • 이효재;이근상;이언호;장영률
    • Spatial Information Research
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    • v.10 no.2
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    • pp.201-213
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    • 2002
  • Chemical analyzes were carried out the samples from roadsides of the Gwangju city. The purpose of this research is to investigate the concentrations and distribution patterns of heavy metals due to urbanization and industrialization in the Gwangju city This study area is not significantly contaminated based on the concentrations of Cd, Cu, Fe, Mn, Pb and Zn. However, the concentrations of the chemical elements analyzed are locally higher than those of serious contamination level indicated by Ministry of environment. The dust pH is in the rage of 5.60-7.09 and was generally neutral, and there are no difference in pollution area and nonpollution area. Chemical analyses utilized are dilution by 0.1N HCl. In result of analysis by the method using 0.1N HCl, concentrations of Cd and Cu are a little high in Gwangchondong of Seo-Gu. Concentrations of Mn and Pb are a little high in Buk-Gu and Nam-gu, and Concentrations of Zn are generally higher than average of soils. Zn, in the study area, keeps polluting greatly as Zn concentration of average is 150.9ppm. All of P.I values are lower than 1, it means heavy metal pollution is not serious.

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Real-time Highly Sensitive Measurement of Myocardial Infarction Biomarkers Using Silicon-based Ellipsometric Biosensors (실리콘 기반 타원편광계식 바이오센서를 이용한 심근경색 생체표지자의 실시간 초고감도 진단 농도 측정)

  • Min, Yoon Gi;Cho, Hyun Mo;Jo, Jae Heung
    • Korean Journal of Optics and Photonics
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    • v.30 no.2
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    • pp.59-66
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    • 2019
  • We report highly sensitive detection of myocardial infarction biomarkers, such as myoglobin and cTnI, within several hundred seconds using a rotating-analyzer ellipsometer and a biosensor with biochips fabricated on a $SiO_2$-coated tilted silicon substrate. We choose the running buffer to be pure phosphate-buffered saline (PBS) or 10% mixed human serum. When we choose the running buffer to be pure PBS, we obtain diagnostic densities of pure myocardial infarction biomarkers of up to 1 ng/ml and 5 pg/ml respectively. Meanwhile, when we use PBS with 10% human serum, the measured densities of myoglobin and cTnI were up to 1 ng/mL and 1 pg/mL respectively. The measured diagnostic densities are less than 1/15 and 1/80 (in cases of myoglobin and cTnI respectively) of those referenced by the World Health Organization.

Relationship between the Biological Lead Exposure Indices and Air lead Concentrations measured by Personal Air Samplers (개인용 공기포집기를 이용한 기중 연농도와 생물학적 연 폭로지표와의 관련성)

  • Lee, Haeng-Ryeol;Kim, Jung-Man;Jung, Kap-Yull;Kim, Joon-Youn
    • Journal of Preventive Medicine and Public Health
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    • v.26 no.1 s.41
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    • pp.65-73
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    • 1993
  • This study was carried out to evaluate the relationship between the biological lead exposure indices and air lead concentrations measured by personal air samplers. The 72 occupationally lead exposed workers were observed and the bioiogical lead Exposure indices chosen for this study were blood lead(PbB), urine lead(PbU), zinc protoporphyrin in whole blood(ZPP), $\delta$-aminolevulinic acid in urine(ALAU), $\delta$-aminolevulinic acid dehydratase activity (ALAD), coproporphyrin in urine(CPU) and hemoglobin(Hb). The workers were divided into four groups by air lead concentrations: Group I; under $0.05mg/m^3$, Group II; $0.05-0.10mg/m^3$, Group III; $0.10-0.15mg/m^3$ and Group IV; and over $0.15mg/m^3$. For evaluation the relationship between the biological lead exposure indices and air lead concentrations was used as correlation coefficients. The results obtained were as follows: 1. In Group I, II, III and IV, the mean value of PbB were $25.45{\pm}1.84{\mu}g/dl,\;27.87{\pm}3.53{\mu}g/dl,\;31.21{\pm}1.76{\mu}g/dl\;and\;47.02{\pm}13.96{\mu}g/dl$. Between Group IV and other groups showed statistically significant difference(p<0.05). 2. There was an increasing tendency of PbB, PbU, ALAU and ZPP according to the increase the mean air lead concentration, while ALAD has decreasing tendency. CPU and Hb did not show any constant tendency. 3. Correlation coefficients between PbB, PbU, ZPP, ALAU, ALAD, CPU, Hb and air lead concentration were 0.95, 0.83, 0.89, 0.72, -0.83, 0.51 and -0.45 respectively, and regression coefficient between PbB(Y) and PbA(X) was Y=126.8746X+16.9996(p<0.01).

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