• Title/Summary/Keyword: PbI2

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Characterization of the Material Properties of 0.68Pb ($Mg_{1}$3/$Nb_{2}$3/)$O_3$-0.32PbT$iO_3$ Single Crystals Grown by the Solid-State-Crystal-Growth Method (고상단결정법으로 성장시킨 0.68Pb ($Mg_{1}$3/$Nb_{2}$3/)$O_3$-0.32PbT$iO_3$ 압전단결정의 물성평가)

  • 이상한;노용래
    • The Journal of the Acoustical Society of Korea
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    • v.23 no.2
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    • pp.103-108
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    • 2004
  • In this paper, all the materials constants of the PMN-32%PT single crystals grown by the solid state crystal growth method were measured by the resonance method. PMN-PT crystals of tetragonal symmetry have six elastic constants, three piezoelectric constants and two dielectric constants for their independent material constants. These materials constants were extracted from six sets of crystal samples of each different geometry to have different vibration modes respectively. Measured results showed that the crystal has larger electromechanical coupling factor k/sub 33/ (∼86%) and piezoelectric constant d/sub 33/ (∼1200pC/N) than conventional piezoceramics. Validity of the measurement was confirmed through comparison of the results with the impedance spectrum from finite element analysis of the samples and the results measured with a commercial do meter.

Evaluation of usability of the shielding effect for thyroid shield for peripheral dose during whole brain radiation therapy (전뇌 방사선 치료 시 갑상선 차폐체의 주변선량 차폐효과에 대한 유용성 평가)

  • Yang, Myung Sic;Cha, Seok Yong;Park, Ju Kyeong;Lee, Seung Hun;Kim, Yang Su;Lee, Sun Young
    • The Journal of Korean Society for Radiation Therapy
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    • v.26 no.2
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    • pp.265-272
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    • 2014
  • Purpose : To reduce the radiation dose to the thyroid that is affected to scattered radiation, the shield was used. And we evaluated the shielding effect for the thyroid during whole brain radiation therapy. Materials and Methods : To measure the dose of the thyroid, 300cGy were delivered to the phantom using a linear accelerator(Clinac iX VARIAN, USA.)in the way of the 6MV X-ray in bilateral. To measure the entrance surface dose of the thyroid, five glass dosimeters were placed in the 10th slice's surface of the phantom with a 1.5 cm interval. The average values were calculated by measured values in five times each, using bismuth shield, 0.5 mmPb shield, self-made 1.0 mmPb shield and unshield. In the same location, to measure the depth dose of the thyroid, five glass dosimeters were placed in the 10th slice by 2.5 cm depth of the phantom with a 1.5 cm interval. The average values were calculated by measured values in five times each, using bismuth shield, 0.5 mmPb shield, self-made 1.0 mmPb shield and unshield. Results : Entrance surface dose of the thyroid were respectively 44.89 mGy at the unshield, 36.03 mGy at the bismuth shield, 31.03 mGy at the 0.5 mmPb shield and 23.21 mGy at a self-made 1.0 mmPb shield. In addition, the depth dose of the thyroid were respectively 36.10 mGy at the unshield, 34.52 mGy at the bismuth shield, 32.28 mGy at the 0.5 mmPb shield and 25.50 mGy at a self-made 1.0 mmPb shield. Conclusion : The thyroid was affected by the secondary scattering dose and leakage dose outside of the radiation field during whole brain radiation therapy. When using a shield in the thyroid, the depth dose of thyroid showed 11~30% reduction effect and the surface dose of thyroid showed 20~48% reduction effect. Therefore, by using the thyroid shield, it is considered to effectively protect the thyroid and can perform the treatment.

Distribution and Pollution Assessment of Trace Metals in the Surface Sediments around Farming Area of Jinhae Bay (진해만 양식어장 주변 표층 퇴적물 중 미량금속의 분포 특성 및 오염 평가)

  • Choi, Tae-Jun;Kwon, Jung-No;Lee, Garam;Hwang, Hyunjin;Kim, Youngsug;Lim, Jae-Hyun
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.21 no.4
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    • pp.347-360
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    • 2015
  • Trace metals(As, Cd, Co, Cr, Cu, Fe, Hg, Mn, Pb and Zn) concentrations in surface sediments of Jinhae bay in August of 2013 were measured to investigate the characteristics of trace metals distribution and to evaluate the metal pollution. Assessment for metal pollution was carried out using the sediment quality guidelines(SQGs) such as threshold effects level(TEL) and probable effects level(PEL) proposed by the ministry of onceans and fisheries(MOF) in Korea and geochemical assessment techniques(enrichment factor(EF) and geoaccumulation index ($I_{geo}$)). The mean concentration of trace metals in the sediments are as follows: 11.1 mg/kg for As, 0.52 mg/kg for Cd, 14.1 mg/kg for Co, 69.8 mg/kg for Cr, 57.2 mg/kg for Cu, 3.7 % for Fe, 0.064 mg/kg for Hg, 600 mg/kg for Mn, 40.1 mg/kg for Pb, 167.2 mg/kg for Zn. The spatial distributions of As, Co, Cr and Fe were not distinguished clearly in whole area. However, Cd, Hg, Pb and Zn were high in northern area of bay, and Cu and Mn were high in southeastern and eastern area of bay, respectively. The distribution pattern of trace metals, correlation matrix and R-mode factor analyses results revealed that the distribution of trace metals were mainly effected by the sediment grain size(Co, Cr and Fe), redox condition of sediments(Mn) and anthropogenic factors(As, Cd, Cu, Hg, Pb and Zn). Comparing the concentrations of several trace metals(As, Cd, Cr, Hg and Pb) with SQGs from Korea(TEL and PEL), the concentrations of Hg, Cd and Pb in sediment of northern area of bay were higher than TEL. EF and $I_{geo}$ values of As, Cd, Cu, Hg, Mn, Pb and Zn showed that these metals in sediments are enriched by anthropogenic activities in some areas, and pollution status for Cd, Hg and Pb in northern area and Cu in southeastern area of bay were concerned about current level, although those for As, Mn and Zn were not.

Influences of ${Nb_2}{O_5}$ and MnO Addition on the Electrical Properties of ${Pb_{0.6}}{Sr_{0.4}}{TiO_3}$Semiconducting Ceramics (${Nb_2}{O_5}$와 MnO 첨가가 ${Pb_{0.6}}{Sr_{0.4}}{TiO_3}$ 반도체 세라믹의 전기적 특성에 미치는 영향)

  • Moon, Jung-Ho;Kim, Keon;Kim, Seong-Ho;Kim, Yoon-Ho
    • Journal of the Korean Ceramic Society
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    • v.37 no.10
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    • pp.968-974
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    • 2000
  • Nb$_2$O$_{5}$와 MnO 첨가에 따른 Pb$_{0.6}$Sr$_{0.4}$TiO$_3$반도체 세라믹의 미세구조와 전기적 특성은 유전특성, I(current)-V(voltage) 측정, 그리고 복소 임피던스 측정 등을 이용하여 고찰하였다. Nb 도핑량이 0.4 mol% 이하인 경우 Nb 도핑량에 따라 전도성과 입성장은 증가되었으나 그 이상의 도핑량에서는 Sr이나 Pb 공공의 생성으로 인하여 전도성이 감소되고 입성장도 억제되는 것을 관찰할 수 있었다. 0.4 mol% Nb-doped Pb$_{0.6}$Sr$_{0.4}$TiO$_3$에 0.01 mol% MnO를 첨가한 경우 비저항비($ ho$$_{max}$/$\rho$/min/)가 $10^2$에서 $10^4$으로 크게 향상되었다. 그리고 전이 온도 주변에서 여러 개의 변곡점을 지니는 비옴성 거동이 발견되었다. 이와 같은 현상은 입계에 존재하는 Mn 이온이 부분적으로 편석되어 표면 전하의 보상 효과에 영향을 미치는 것이라고 사료된다.

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Change in the Fractrue Toughness of Pb (Zr, Ti)$O_3$ Ceramics before and after Poling Treatment (분극처리 전후의 Pb(Zr, Ti)$O_3$ 세라믹스의 파괴인성의 변화)

  • Tae, Won-Pil;Kim, Song-Lee
    • Korean Journal of Materials Research
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    • v.3 no.5
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    • pp.546-552
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    • 1993
  • 본 연구에서는 입계의 성질을 이용한 PTCR 재료에 입계 modifier로서 $Bi_{2}$$O_{3}$와 BN을 첨가하고 입계의 미세구조와 결함농도를 변화시켜 이에 따른 소결 및 전기적 특성변화를 TMA, XRD, 복합 임피던스방법 등을 이용하여 해석하였다. 실험 결과 Y이 도우핑된 BaT$iO_{3}$ PTCR 재료에 $Bi_{2}$$O_{3}$를 첨가하였을때 약 0.1mol%까지 고용이 되는 것으로 밝혀졌다. $Bi_{2}$$O_{3}$를 고용한계 이하로 첨가시에는 생성되는 vacancy등의 결함으로 말미암아 Y-BaT$iO_{3}$의 치밀화가 촉진되었으나, 그 이상 첨가하면 치밀화 뿐만 아니라 결정립 성장도 억제되었다.$Bi_{2}$$O_{3}$ 결정립 내부에 Ba와 Ti vacancy가 동시에 생길 수 있어 고온저항이 높아짐을 알 수 있었다. BN은 BaT$iO_{3}$에 고용이 되지 않는 것으로 밝혀졌으며 $B_{2}$O/wub/3를 주성분으로한 액상형성으로 인하여 저온에서의 급격한 치밀화가 관찰되었다. 또 Ba-Y-Ti-B-O의 비정질 상이 tripie junction에 존재함으로서 상온저항이 크게 변화하였으며, PTCR jump도 높아졌다.

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Ag(Ⅰ) Ion Selective Macrocyclic Ligands: The Complexation and Liquid Membrane Transport Phenomena of Benzylated Nitrogen-Oxygen Donor Macrocyclic Ligands (Ag(Ⅰ) 이온 선택성을 갖는 거대고리 리간드: 벤질 치환기를 갖는 질소-산소 주개 거대고리 리간드의 착물 형성과 액체막 이동 현상)

  • Kim, Jeong;Ahn, Tae Ho;Lee, Myoung Ro;Cho, Moon Hwan;Kim, Si Joong
    • Journal of the Korean Chemical Society
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    • v.43 no.2
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    • pp.167-171
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    • 1999
  • An investigation of the interaction of Co(II), Ni(II), Cu(II), Zn(II), Cd(II), Pb(II) and Ag(I) with two N,N'-dibenzylated nitrogen-oxygen mixed donor macrocyclic ligands, has been carried out. Tle log K values for the respective complexes in 95% methanol have been determined potentiometrically. Both ligands have formed stable complex with only Cu(II) and Ag(I) ion. Transport measurements in a bulk liquid membrane system exhibited a very high selectivity of Ag(I) ion over the other metal ions used.

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Chemical Composition of the Cretaceous Granitoids and Related Ore Deposits in the Taebaegsan Basin, Korea (태백산분지내 백악기화강암류의 화학조성과 관련광상)

  • Lee, Jae Yeong;Lee, In Ho;Hwang, Duk Hwan
    • Economic and Environmental Geology
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    • v.29 no.3
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    • pp.247-256
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    • 1996
  • Mineral commodities of metallic ore deposits related to Cretaceous granitoids in the Taebaegsan basin are distinguishable by rock types, diffferenciation index (D.I.) and chemical compositions. Deposits of Fe-Cu are related to granodiorite-quartz monzonite, those of Pb-Zn and W-Mo to granite-granodiorite and granite respectively. The ranges of D.I. of the granitoids are 39~71 for Fe-Cu deposits, 68~81 for Pb-Zn deposits, 78~89 for W-Mo deposits and 91~94 for Mn deposits. Major oxides of $K_2O$, CaO, MgO, FeO and $TiO_2$ and some trace elements and Rb/K, Sr/Ca and Cu/Fe also show distinguishable differences among the Cretaceous granitoids related to various mineral commodities of the ore depsits.

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Inelastic Electron Tunneling Spectroscopy of 1-layer Arachidicacid films using a Polyimide barrier (Polyimide 터널 장벽을 이용한 Arachidicacid 단분자막의 비탄성 터널 스펙트라)

  • Lee, Won-Jae;Kang, Dou-Yol;Iwamoto, Mitsumasa
    • Proceedings of the KIEE Conference
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    • 1994.11a
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    • pp.234-236
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    • 1994
  • We fabricated Au/PI/Pb and Au/PI/1-layer Arachidic acid/Pb structures in order to electron transport properties through the junctions. It was found that 9-layer PI LB films function as a good tunneling barrier from the I-V properties. And several peaks originating in the vibrational modes of the constituent molecules of 1-layer arachidicacid LB films were clearly observed in $d^2V/dI^2-V$ curves.

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Impact of the Expansion of Private Brands on Korean Retail and Manufacturing

  • LEE, JINKOOK
    • KDI Journal of Economic Policy
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    • v.40 no.2
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    • pp.1-21
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    • 2018
  • The private brands (PB) of corporate retailers are booming in Korea. This paper examines the effect of the rise of PB on Korean retail and manufacturing. By utilizing both store-level data and firm-level data, I find that the expansion of PB elevates the profits of corporate retailers but does not significantly affect, and in some cases even reduces, those of subcontracting manufacturers. This occurs not only because sales of national brands (NB) decline due to the launch of similar PBs but also because the imbalance in the bargaining positions of the two parties has caused retail margins to be set high while manufacturers' operating profits are set low. The paper provides policy recommendations for fair contracts and cooperative development between retail and manufacturing companies.

Pollution of Pb in paddy field soil and rice plants at roadside areas;I. Pollution of Pb in paddy field soil and its chemical forms (도로변(道路邊)에 인접(隣接)한 경작지(耕作地) 토양(土壤) 및 작물체중(作物體重)의 연오염(鉛汚染) 제(第)1보(報) 경작지(耕作地) 토양중(土壤中)의 연오염(鉛汚染) 및 화학적(化學的) 형태(形態))

  • Lee, Seog-June;Kim, Jang-Eok
    • Korean Journal of Environmental Agriculture
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    • v.10 no.1
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    • pp.1-10
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    • 1991
  • The object of this stduy was to investigate the pollution of Pb in paddy field soil with different distance from roadside and to find out the relationship between the ratio of chemical fractions of total Pb and soil characteristics. Lead from automobiles is exhausted as particulates composed primarily of halide compounds (PbBrCl, $PbBr_2$, $PbCl_2$). The samples of soil were collected directly from the paddy fields with different distance from the roadside of highway and expressway which are located in Kyungpook province. A sequential extraction procedure was used to fractionate Pb in paddy field soil into the disignated forms of water soluable, exchangeable, organically bounded, carbonate, sulfide, and residual Pb. Results obtained are summerized as follows. 1. The content of Pb in paddy field soil was the highest in Chungdo, 30.0 ppm, the lowest in Koryung, 14.8 ppm, and the total average content was 21.9 ppm. The effect of traffic volume was not clear, but a slight difference according to the order of opened year of roads was showed. 2. The effect of distance from roadside was not clear. The content of Pb in paddy field soil with different distance from roadside was 22.2 ppm within l0m, 22.1 ppm in 10∼30m, 22.2 ppm in 30∼50m. and 21.3 ppm beyond 50m. 3. The distribution of Pb fractions in soil showed a wide difference depending on soil properties. The average content of exchangeable. organically bounded, carbonate, sulfide, and residual Pb was 8.6%, 33.6%, 29.8%, 21.5%, and 6.7%, of total Pb in the soil, respectively. 4. The content of organically bounded Pb in soil showed highly positive correlation with organic matter and CEC, while the content of exchangeable Pb was highly negative correlation. 5. With higher soil organic matter and CEC, organically bounded Pb fraction tend to be higher but exchangeable Pb fraction tend to be lower. Other forms of Pb showed no difference with soil organic matter contend and CEC. The distribution of Pb fraction related to CEC showed similiar tendency with that of organic matter content.

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