• Journal of the Korean Chemical Society
• /
• v.42 no.2
• /
• pp.172-176
• /
• 1998

An anion exchange resin which has Alizarin Red S (ARS) as functional group was prepared by batch method. The resin is stable in acidic solutions below 0.5 M hydrochloric acid, nitric acid and sulfuric acid and adsorption capacity of Fe(Ⅱ) ion on the resin was larger than other metal ions. The preconcentration and the separation of Fe(Ⅱ) ion from the mixture solution were carried out with the pH 4.5 buffer solution and 0.1 M $HNO_{3}$ as eluents.

• Clean Technology
• /
• v.26 no.4
• /
• pp.263-269
• /
• 2020

Zeolite was synthesized hydrothermally using the water-treatment sludge, and the effects of various synthesis parameters like reaction temperature, reaction time, and Na2O/SiO2 molar ratio on the crystallization of zeolite were investigated. Crystal structure, physical property, and thermal stability of zeolite crystals were characterized by X-ray powder diffraction, FTIR spectroscopy, BET nitrogen adsorption, and TGA measurements. The removal efficiencies of nitrogen in ammonia, heavy metal ions, and TOC were calculated to evaluate zeolite's adsorption capacity. The primary chemical composition of water-treatment sludge was 28.79% Al2O3 and 27.06% SiO2. The zeolites were synthesized by merely employing the water-treatment sludge as silica and alumina sources without additional chemicals. Zeolite crystals synthesized through the water-treatment sludge were confirmed as an A-type zeolite structure. Zeolite A had the highest crystallinity obtained from a gel with the molar composition 2.1Na2O-Al2O3-1.6SiO2-65H2O after 5 h at a temperature of 90 ℃. The specific surface area of zeolite obtained was 55 ㎡ g-1, which was higher than commercial zeolite A. The removal efficiency of nitrogen in ammonia was 68% after 3 h of reaction time, while the removal efficiencies of Pb2+ and Cd2+ ions were 99.1% and 99.3%, respectively. These results indicate active ion exchange between Pb2+ or Cd2+ ion and Na+ ion in the zeolite framework. The adsorption experiments on the different zeolite addition conditions were performed for 3 h with 300 ppm humic acid. Based on the results, TOC's highest efficiency was 83% when 5 g of zeolite was added.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
• /
• 2010.06a
• /
• pp.340-340
• /
• 2010

본 연구에서는 유도결합형 플라즈마(ICP)를 이용하여, HBr/Ar 가스의 조성비 변화에 따른 Pb(Zr,Ti)$O_3$ 박막에 대한 식각특성을 연구 하였다. PZT박막의 식각속도와 Oxide($SiO_2$), Photo resister(PR)에 대한 식각선택비를 추출하였으며, 식각 메카니즘을 규명하기 위하여 optical emission spectroscopy(OES)와 double Langmuir prove(DLP) 이용하여 라디칼 특성변화와 이온 전류밀도(Ion current density)를 측정하였다.

• Economic and Environmental Geology
• /
• v.28 no.5
• /
• pp.455-467
• /
• 1995

In order to investigate the dispersion patterns and speciations of Cu, Pb, Zn and Cd in soils, stream sediments and stream waters, geochemical studies of soil, stream sediment and stream water samples collected in the vicinity of the Shi-Heung Cu-Pb-Zn mine was carried out Cation exchange capacity measurement, size analysis, X-ray diffraction analysis and batch test were performed to select applicable soil for adsorption treatment The average content of Cu, Pb, Zn and Cd in soils collected from tailings and ore dressing plant is 1084 ppm, 2292 ppm, 3512 ppm and 29.2 ppm, respectively, and therefore, tailings and ore dressing plant site may be the major contamination sources in this study area. The mean content of Cu, Pb, Zn and Cd in stream sediments is extremely high up to 794 ppm, 1633 ppm, 2946 ppm and 25.2 ppm, respectively. Tailing particles and heavy metal ions are dispersed along the tributary system. Results from the sequential extraction analysis indicate; (1) most of Cu is bound to organic matters and sulphides, (2) fraction of Pb is mainly bound to Fe and Mn oxides. Most of Zn is largely bound to Fe and Mn oxides and residual fraction. Ion exchangeable fraction of Cd is relatively higher than those of Cu, Pb and Zn. Batch test on soils collected from the kaolinite and/or pyrophyllite mines and from the control areas was carried out to select an applicable soil samples for adsorption treatment The sample, S10, collected from the control area 2 (clay content 33.2%) shows the highest $K_d$ (distribution coefficient). Organic content in soils and several clay minerals shows relatively good correlation with $K_d$. It means that applicable soils for adsorption treatment of heavy metals show high organic and clay content.

• Journal of the Korean Chemical Society
• /
• v.40 no.9
• /
• pp.607-614
• /
• 1996

The structural changes and dielectric properties of Pb1-x(Na1/2La1/2)x(Mg1/3Nb2/3)O3 compounds substituted by 0∼50 mol.% of Na+/La3+ mixed ions were investigated by X-ray diffraction method, IR and Raman spectroscopy, and LCR meter. The amount of perovskite phase increased with the increases of Na+/La3+ substituents and sintering temperatures. Although the superlattice lines due to 1:1 ordering were not detected by X-ray diffraction method, it was found, from the Raman spectroscopy and the increase of diffuseness coefficient, that the ordering behavior was related to the decrease of A site ion size. Dielectric properties in Pb1-x(Na1/2La1/2)x(Mg1/3Nb2/3)O3 were affected by the amount of perovskite phase, grain size, and density. The phase transitions were broadened and phase transition temperatures were lowered by the increase of Na+/La3+ ions.

• Analytical Science and Technology
• /
• v.10 no.6
• /
• pp.427-432
• /
• 1997

A selective method for the determination of iron(III) ion with a sodium dodecyl sulfate(SDS) modified glassy carbon electrode was proposed. It was based on the electrostatic attraction and complexation of the SDS modifier, $(DS^-)_n-Fe^{3+}$. The determination of iron(III) ion was performed by a differential pulse voltammetry(DPV), and the reduction peak potential of $(DS^-)_n-Fe^{3+}$ was +0.466(${\pm}0.002$)V vs. Ag/AgCl. For the determination of iron(III) ion, a linear calibration curve was obtained within the iron(III) ion concentration range of $0.50{\times}10^{-5}{\sim}10{\times}10^{-5}mol/L$, and the detection limit was $0.14{\times}10^{-5}mol/L$. $Cu^{2+}$, $Ni^{2+}$, $Co^{2+}$, $Pb^{2+}$, $Zn^{2+}$, and $Mn^{2+}$ showed little or no effect on the determination of iron(III) ion, respectively. But, ion such as each $CN^- $ and $SCN^-$ interfered seriously.

• Clean Technology
• /
• v.12 no.3
• /
• pp.171-174
• /
• 2006

The adsorbent for removal of heavy metal ions is prepared reutilizing the leached sludge generated in process of making the red mud coagulant we have develope. The pellet-type adsorbent is made by heat-treating a mixture of 10g of the leached sludge, 1g of kaolin, and 2 g of sodium silicate solution at $600^{\circ}C$ for 2 hours. In experiments of batch adsorption, the adsorbent shows good performance in adsorption of $Pb^{2+}$ ion.

• Journal of the Korean Chemical Society
• /
• v.43 no.2
• /
• pp.167-171
• /
• 1999

An investigation of the interaction of Co(II), Ni(II), Cu(II), Zn(II), Cd(II), Pb(II) and Ag(I) with two N,N'-dibenzylated nitrogen-oxygen mixed donor macrocyclic ligands, has been carried out. Tle log K values for the respective complexes in 95% methanol have been determined potentiometrically. Both ligands have formed stable complex with only Cu(II) and Ag(I) ion. Transport measurements in a bulk liquid membrane system exhibited a very high selectivity of Ag(I) ion over the other metal ions used.

• Journal of Environmental Science International
• /
• v.10 no.2
• /
• pp.153-158
• /
• 2001

The biosorption abilities of different parts of waste brown seaweeds and their derivatives to remove heavy metals (Cd, Zn, Pb, Cu, Fe, Ni, Mn) from waste were evaluated. The two parts of waste brown seaweeds (Undaria pinnatifida) were stems and sporophyls, and the brown seaweed derivatives were alginic fibers, active carbon added alginate(AC-alginate) and dealginate. The abilities of the sporophyls to adsorb the heavy metal ions were higher than those of stems, and those of alginates were slightly higher than those of dealginate in single ion solution. With decreasing the size of biosorbents, the velocity and the amount of adsorption increased. The abilities of alginate to remove the heavy metal ions increased in multi-ion solutions by adding active carbon to alginate. The selectivity of these biosorbents(alginate, AC-alginate) to lead ion was highest and to manganese ion was lowest.

• Journal of the Korean Chemical Society
• /
• v.11 no.2
• /
• pp.63-69
• /
• 1967

The stability constants of lead acetato conplexes were evaluated in various ionic strengths (2.00, 1.00, and 0.75), and at various temperature (15, 20, 25, 30, and $35^{\circ}C$), respectively, by the polarographic and potentiometric method of which Hume and Leden had described. The existence of three complex ions, $PbAc^+$, $PbAc_2$, and $PbAc_3^-$ have been shown in the range of concentration of 0~0.8 mole acetate ion. Referring to values obtained, we have derived the following empirical formula with the stability constant (Kijk), ternperature (Tk) and ionic strength (${\mu}j$). log Kijk = (Ai/${\mu}j^3$+ Bi) / Tk + Ci/${\mu}j^3$ + Di . The deduced and observed stability constants are matched in 5% for the K, and $K_3$, and 20% for the $K_2$.