• Title/Summary/Keyword: Particle concentration

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Effects of Temperature and Precursor-concentration on Characteristics of TiO2 Nanoparticles in Chemical Vapor Condensation Process -Part I: Real-time Particle Characterization by SMPS (화학기상응축 공정에서 TiO2 나노입자 특성에 미치는 반응온도와 전구체 농도의 영향 - Part I: SMPS를 이용한 실시간 입자특성 평가)

  • Lee, Chang-Woo;Yu, Ji-Hun;Im, Sung-Soon;Yun, Sung-Hee;Lee, Jai-Sung;Choa, Yong-Ho
    • Korean Journal of Materials Research
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    • v.13 no.5
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    • pp.323-327
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    • 2003
  • Properties of nanoparticles synthesized during gas phase reaction were studied in terms of particle behaviors using real-time particle characterization method. For this study, $TiO_2$ nanoparticles were synthesized in the chemical vapor condensation process(CVC) and their in-situ measurement of particle formation and particle size distribution was performed by scanning mobility particle sizer(SMPS). As a result, particle behaviors in the CVC reactor were affected by both of number concentration and thermal coagulation, simultaneously. Particularly, growth and agglomeration between nanoparticles followed two different ways of dominances from coagulations by increase of number concentration and sintering effect by increased temperature.

A Study of Particle Diffusion from a Cavity in Flow Tube (유동관에 형성된 Cavity로부터의 입자확산현상 연구)

  • Lee, J.W.;Goo, J.H.;Kim, H.Y.
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.6 no.1
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    • pp.29-38
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    • 1994
  • Particle contamination into and out of a cavity-cylindrical cavities with aspect ratios(width/depth) less than, equal to 1 and langer than 1, and also three dianensional T's attached to a cylindrical flow tube was studied numerically, using a finite difference method. In the process of unsteady particle diffusion, the particles contained in a concentration boundary layer near the tube wall plays an important role in the initial stage, after which a quasi-steady concentration profile is developed inside the cavity, resulting in an exponential change of concentration with time. Average concentration and its rate of change are observed to be closely correlated by a power law function in terms of Reynolds number and the logarithm of Schmidt number. Effects of the three parameters-Re, Sc, and aspect ratio-are analysed and well explained.

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Experimental Study on Thermophoretic Particle Deposition for an Agglomerated and Non-Agglomerated Particles (입자의 형상에 따른 열영동 영향에 대한 실험적 연구)

  • Choi, Gwang-Yul;Yoon, Jin-Uk;Ahn, Kang-Ho
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.28 no.7
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    • pp.741-746
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    • 2004
  • Agglomerated and non-agglomerated SiO$_2$ particles are synthesized in a furnace by oxidation of TEOS vapor. These polydispersed particles are classified with DMA to extract particles. Then these particles are introduced into a thermal precipitator through the ESP(Electrostatic Precipitator) to investigate the themophoretic particle deposition using CNCs(Condensation Nuclei Counter). The efficiency of themophoretic particle deposition according to agglomerated and non-agglomerated particles in the thermal precipitator has been studied as a function of particle size and TEOS mole concentration using monodisperse particles classified by DMA. The results show that the particle deposition efficiency decreases as TEOS mole concentration increases and particle size increases. Thereffre, it is concluded that the thermophoretic deposition efficiency is dependent of the particle morphology.

Particle Loss Reduction Technique Using Dielectrophoresis in Microfluidic Channel (유전영동을 이용한 미세유체채널 내부의 입자 손실 저감 기술)

  • Kang, Dong-Hyun;Kim, Min-Gu;Kim, Yong-Jun
    • Journal of Sensor Science and Technology
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    • v.20 no.5
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    • pp.357-362
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    • 2011
  • This paper demonstrates a novel electrodynamic technique to remove particles from the wall of microchannels. Dielectrohporesis(DEP) is generated by applying alternating electric potentials to the interdigitated electrodes integrated at the bottom of the micro-channel. The proposed technique is applied to a general microfluidic channel as a feasibility test. To examine the wall loss reduction efficiency, 10 ${\mu}m$ diameter Polystyrene latexes(PSL) were supplied to the inlet of the device. Then, the concentration of collected particles through devices was measured. In the experiment for 10 ${\mu}m$ diameter PSL particles, the concentration of the injected particles was $174.25{\times}10^4$ particles/ml. However, the concentration of collected particles at the outlet was $52.25{\times}10^4$ particles/ml. Only 30 % of particles had arrived at the outlet and 70 % of particles had adhered to the wall of the microfluidic channel. By applying alternating electric potentials from 0 to 20 $V_{pp}$ at 3 MHz, the concentration of injected particles was 135.00${\times}10^4$ particles/ml, the concentration of collected particles was increased as $105.25{\times}10^4$ particles/ml at 20 $V_{pp}$ at the outlet. When the electric potential was 20 $V_{pp}$, the particle loss was decreased by 39 % (initial loss: 70 %, loss at 20 Vpp: 31 %) with 10 ${\mu}m$ particle. The particle loss was decreased along to the incensement of electric potentials and the enlargement of the diameter of particles. According to these measured results, it was confirmed that the proposal of using DEP technique could be a good candidate for particle loss reduction in micro-particle processing chip application. Moreover, it is expected that the proposed technique could enhance performance of microfluidic and biochip devices.

ESTIMATE OF CHLOROPHYLL CONCENTRATION FROM OCEAN COLOR: UNCERTAINTY ASSOCIATED WITH UNKNOWN BACKSCATTERING

  • Zhang, Xiaodong;Kirilenko, Andrei
    • Proceedings of the KSRS Conference
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    • v.1
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    • pp.446-449
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    • 2006
  • It is backscattering of solar radiation by water body that makes ocean color observable from above, either by airplanes or satellites. Given the very low direct contribution to backscattering by phytoplankton cells, it is curious why the retrieval of phytoplankton concentration from remotely observed ocean color is evidently successful. From semianalytical bio-optical models, a dataset is created of spectral absorption, scattering and backscattering coefficients as a function of chlorophyll concentration. Four scenarios are considered, 1) only molecular and no particle scattering, 2) random particle backscattering uncorrelated with chlorophyll concentration, 3) constrained random particle scattering with known backscattering ratio, and 4) constrained random scattering with random backscattering ratio. Scenario 1 only introduces moderate errors of -20% - 90%. And for scenarios 3 and 4, the errors are largely within 30% and 100%. Scenario 2 introduces the largest errors, with the retrieved chlorophyll concentration virtually uncorrelated with the true values, implying the backscattering must somehow be related to the trophic state. The results of the study suggested These 3 cases confirmed that while it is the absorption by phytoplankton that in large part decides the accuracy of chlorophyll concentration retrieval, for the success of monitoring of global ocean primary productivity we have to improve our knowledge on particle backscattering.

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Characteristics of Incheon Aerosol during Asian Dust Period in 2004 using Optical Particle Counter (OPC) (광학적 입자계수기를 이용한 2004년 황사기간 인천지역 에어로졸 특성)

  • Jung Chang-Hoon;Cho Yong-Sung;Lee Jong-Tae
    • Journal of Environmental Science International
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    • v.14 no.6
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    • pp.565-575
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    • 2005
  • The characteristics for the aerosol number distribution was studied during spring, 2004 in Incheon. Optical Particle Counter (OPC, HIAC/ROYCO 5230) was used in order to measure the number concentration of aerosol in the range of $0.3\~25{\mu}m.$. The obtained results were compared with $PM_{2.5}\;and\;PM_{10}$ data during Asian dust events. The results show that the size resolved aerosol number concentration from OPC measurement has a similar tendency with $PM_{10}\;and\;PM_{2.5}$ mass concentration. During Asian dust periods, the number concentrations in large particle $(CH5\~CH8)$ increase more than small particles which diameter is less than $2.23{\mu}m(CH5)$ and the same results were shown when $PM_{10}$ was compared with $PM_{2.5}$ data compared with non-dust days, Consequently, this study shows that size resolved aerosol number concentration from OPC measurement can be used as a useful tool in comparison of mass concentration data.

Study on the Unsteady Contaminated Particle Transportation in the Flow Field for the Super Clean Room (초청정 클린룸 난류유동장내에서의 오염입자 비정상 전파거동에 관한 연구)

  • 오명도;임학규;배귀남
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.14 no.2
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    • pp.430-439
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    • 1990
  • Steady state turbulent airflow and unsteady characteristics of generation, transportation, and recovery behavior of contaminate particles in the simplified 2 dimensional Vertical Laminar Flow (VLF) type clean room was numerically simulated using the low Reynolds number k-over bar.epsilon- turbulent model. Characteristics of airflow in VLF type clean room are greatly affected by the recirculation zone around working surface. The recirculation zone must be considered at the time of clean room design because the recirculation zone whose area increases with increment of inlet velocity exerts bad influence upon the performance of clean room in terms of particle contamination. The location of maximum particle concentration changes from the location of particle source to the recirculation zone, while averaged particle concentration is reduced exponentially with time. Recovery time of clean room with spontaneous particle generation source is inversely proportional to inlet velocity. We introduce nondimensionalized recovery time through the dimensional analysis, which can indicates the general performance of clean room with design structure change. It was identified that .tau. is independent of inlet velocity and background concentration. Therefore .tau. can be the simple factor to compare the different structure of clean room in terms of dynamic response to contamination and becomes larger with better structure of clean room.

Fabrication of Nano-Sized Ni-ferrite Powder from Waste Solution Produced by Shadow Mask Processing (새도우마스크 제조공정 중 발생되는 폐액으로부터 니켈 페라이트 나노 분말 제조)

  • 유재근;서상기
    • Journal of Powder Materials
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    • v.10 no.4
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    • pp.262-269
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    • 2003
  • Nano-sized Ni-ferrite powder was fabricated by spray pyrolysis process using the waste solution resulting from shadow mask processing. The average particle size of the powder was below 100 nm. The effects of the concentration of raw material solution, the nozzle tip size and air pressure on the properties of powder were studied. As the concentration increased, the average particle size of the powder gradually increased and its specific surface area decreased, but size distribution was much wider and the fraction of the Ni-ferrite phase greatly increased as the concentration increasing. As the nozzle tip size increased from 1 mm to 2 mm, the average particle size of the powder decreased. In case of 3 mm nozzle tip size, the average particle size of the powder increased slightly. On the other hand, in case of 5 mm nozzle tip size, average particle size of the powder decreased. Size distribution of the powder was unhomogeneous, and the fraction of the Ni-ferrite phase decreased as the nozzle tip size increasing. As air pressure increased up to 1 kg/$cm^2$, the average particle size of the powder decreased slightly, on the other hand, the fraction of the Ni-ferrite phase was almost constant. In case of 3kg/$cm^2$ air pressure, average particle size of the powder and the fraction of the Ni-ferrite phase remarkably decreased, but size distribution was narrow.

Spatial Distributions of On-road Ultrafine Particle Number Concentration on Naebu Express Way in Seoul during Winter Season (겨울철 서울 내부순환로 도로상 초미세입자 오염의 공간분포 특징)

  • Woo, Daekwang;Lee, Seung-Bok;Lee, Seung Jae;Kim, Jin Young;Jin, Hyun Chul;Kim, Taesung;Bae, Gwi-Nam
    • Journal of Korean Society for Atmospheric Environment
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    • v.29 no.1
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    • pp.10-26
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    • 2013
  • To understand the traffic emissions with high temporal and spatial resolutions on road, a mobile laboratory was developed. The objective of this study is to characterize on-road air pollution on Naebu express way surrounding the northern area of Seoul, Korea. We measured the number concentration of ultrafine particles larger than 5 nm and particle size distribution using a condensation particle counter and a fast mobility particle sizer, respectively on 3, 7, and 8 December 2009. The average ultrafine particle number concentration on the Naebu express way excluding tunnels was 126,000 particles/$cm^3$ and 4.2 times higher than that on internal road at Korea Institute of Science and Technology in Seoul, and more than twice higher than that measured on and at the arterial roads of Seoul in previous studies. The maximum ultrafine particle number concentration was observed at the tunnel sections. It was 232,000 particles/$cm^3$ and 1.8 times higher than average ultrafine particle number concentration for the other sections on Naebu express way. The ultrafine particle number concentration on the wider roads with higher traffic volume along the Han River was similar to that in the residential section, probably because of enhanced dilution effect in widely open environment. The size distribution of particles on the Naebu express way was highly fluctuated for a short duration. Ultrafine particles measured at the tunnel showed a bimodal size distribution with mode diameters of ~10 nm and ~50 nm. At the Han riverside section, ~10 nm particles appeared significantly compared with size distribution at the tunnel. This on-road measurement approach can be utilized to manage vehicle-related air pollution in urban area.

Comparison on Nano-particle Number Measurement Characteristics for Different Particle Generators between Spray type and Soot Type (Spray type과 Soot type 입자발생기별 나노입자 개수농도분포 측정특성 비교)

  • Kim, M.S.;Kwon, J.W.;Chung, M.C.;Lee, J.W.
    • Journal of ILASS-Korea
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    • v.17 no.4
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    • pp.185-191
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    • 2012
  • Particulate matters (PM) that is generated by most diesel engine is regulated by the mass concentration measured by the conventional method it had been. Recently, Europe PMP (Particle Measurement Program) decided to start the regulation of vehicle's nano-sized particle number (PN) from the year of 2011 because of nano-particle's higher degree of harm to the human body. So firstly, the standard level of PN emission is introduced in the Euro 5/6 emissions regulation with a limit of $6{\times}10^{11}$ per km for light duty vehicle. Also KPMP(Korea Particle Measurement Program) was organized to copy quickly international technical trend. In this paper, it was investigated the nano-sized PN measurement characteristics for different particle generators between spray type and soot type. And the difference ratio between particle generators, the characteristic of PN concentration, counting efficiency and linearity was analyzed. Then, we make conclusions as followed. When particle diameter is increased, counting efficiency of two generators is decreased. Also Secondary calibration method is more higher 3% than Primary calibration method. Finally, SOF which is included in soot particles is not totally removed so it have great influence on test result of counting efficiency and linearity.