• Journal of Korea Foundry Society
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• v.28 no.3
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• pp.129-135
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• 2008

The reheating stage of electromagnetically stirred Al billet is a critical factor in the thixoforming process. When reheated to the solid-liquid state, the microstructure evolves to a more globular and more homogeneous structure by a coarsening mechanism, the kinetics depending on the initial microstructure. Microstructural evolution has been characterized by conventional parameters (mean size of particle and shape factor) as a function of holding time in the solid-liquid state. The aim of this study is to report experimental results concerning microstructural evolution in the solid-liquid state of electromagnetically stirred Al billet. The material was elaborated in the form of continuously cast bars solidified with electromagnetic stirring to degenerate the dendritic structure. The choice of the reheating conditions is determined by a dendritic ripening and coalescence mechanism, involving variations of both the shape and size of the particles. The reheating time has to be long enough to allow a minimum degree of spheroidizing, but has to be limited as much as possible in order to avoid excessive ripening. The optimum microstructure was obtained at the reheating temperature of near $584^{\circ}C$ and the holding time of 5 min. The only means of combining high productivity with good casting quality was to use feedstock billets whose microstructure showed rapid transformation characteristics.

• Current Research on Agriculture and Life Sciences
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• v.32 no.3
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• pp.125-130
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• 2014

This study used transmission electron microscopy (TEM) to investigate the micro-morphological features of two formaldehyde to urea (F/U) mole ratio liquid urea-formaldehyde (UF) resins with three hardener levels as a function of the curing time. The micro-morphological features of the liquid UF resins were characterized after different curing times. As a result, the TEM examination revealed the presence of globular/nodular structures in both liquid UF resins, while spherical particles were only visible in the low F/U mole ratio resins. The high F/U mole ratio liquid UF resins also showed extensive particle coalescence after adding the hardener, along with the appearance of complex filamentous networks. When the resins were cured with a higher amount of hardener and longer curing time, the spherical particles disappeared. For the low mole UF resins, the particles tended to coalesce with a higher amount of hardener and longer curing time, although discrete spherical particles were still observed in some regions. This is the first report on the distinct features of the crystal structures in low F/U mole ratio UF resins cured with 5% hardener and after 0.5 h of curing time. In conclusion, the present results indicate that the crystal structures of low F/U mole ratio UF resins are formed during the curing process.

• Structural Engineering and Mechanics
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• v.68 no.5
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• pp.537-547
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• 2018

This research presents the effect of anisotropy of the hollow disc mode under Brazilian test using PFC3D. The Brazilian tensile strength test was performed on the hollow disc specimens containing the bedding layers and then these specimens were numerically modeled by using the two dimensional discrete element code (PFC3D) to calibrate this computer code for the simulation of the cracks propagation and cracks coalescence in the anisotropic bedded rocks. The thickness of each layer within the specimens varied as 5 mm, 10 mm and 20 mm and the layers angles were changed as $0^{\circ}$, $25^{\circ}$, $50^{\circ}$, $75^{\circ}$ and $90^{\circ}$. The diameter of internal hole was taken as 15 mm and the loading rate during the testing process kept as 0.016 mm/s. It has been shown that for layers angles below $25^{\circ}$ the tensile cracks produce in between the layers and extend toward the model boundary till interact and break the specimen. The failure process of the specimen may enhance as the layer angle increases so that the Brazilian tensile strength reaches to its minimum value when the bedding layers is between $50^{\circ}$ and $75^{\circ}$ but its value reaches to maximum at a layer angle of $90^{\circ}$. The number of tensile cracks decreases as the layers thickness increases and with increasing the layers angle, less layer mobilize in the failure process.

• Journal of Powder Materials
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• v.24 no.1
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• pp.6-10
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• 2017

This study investigates the main growth mechanism of InP during InP/ZnS reaction of quantum dots (QDs). The size of the InP core, considering a synthesis time of 1-30 min, increased from the initial 2.56 nm to 3.97 nm. As a result of applying the proposed particle growth model, the migration mechanism, with time index 7, was found to be the main reaction. In addition, after the removal of unreacted In and P precursors from bath, further InP growth (of up to 4.19 nm (5%)), was observed when ZnS was added. The full width at half maximum (FWHM) of the synthesized InP/ZnS quantum dots was found to be relatively uniform, measuring about 59 nm. However, kinetic growth mechanism provides limited information for InP / ZnS core shell QDs, because the surface state of InP changes with reaction time. Further study is necessary, in order to clearly determine the kinetic growth mechanism of InP / ZnS core shell QDs.

• Journal of Surface Science and Engineering
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• v.44 no.4
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• pp.131-136
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• 2011

A kinetic study has been made for the growth of nanocrystalline diamond (NCD) particles to a continuous thin film on silicon substrate in a microwave plasma chemical vapor deposition reactor. Parameters of deposition have been microwave power of 1.2 kW, the chamber pressure of 110 Torr, and the Ar/$CH_4$ ratio of 200/2 sccm. The deposition has been carried out at temperatures in the range of $400\sim700^{\circ}C$ for the times of 0.5~16 h. It has been revealed that a continuous diamond film evolves from the growth and coalescence of diamond crystallites (or particles), which have been heterogeneously nucleated at the previously scratched sites. The diamond particles grow following an $h^2$ = k't relationship, where h is the height of particles, k' is the particle growth rate constant, and t is the deposition time. The k' values at the different deposition temperatures satisfy an Arrhenius equation with the apparent activation energy of 4.37 kcal/mol or 0.19 eV/ atom. The rate limiting step should be the diffusion of carbon species over the Si substrate surface. The growth of diamond film thickness (H) shows an H = kt relationship with deposition time, t. The film growth rate constant, k, values at the different deposition temperatures show another Arrhenius-type expression with the apparent activation energy of 3.89 kcal/mol or 0.17 eV/atom. In this case, the rate limiting step might be the incorporation reaction of carbon species from the plasma on the film surface.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.18 no.12
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• pp.74-79
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• 2017

The fire extinguishing performance of hybrid nozzle systems is improved by injecting an extinguishing agent concentrically into the target site and, in this study, water mist is used as a water curtain to confine the droplets of the agent. In this study, we numerically investigated the effect of the foundation angle and injection pressure on the performance of a hybrid nozzle by evaluating the mean radius of the volume fractions of the agent and water mists. An experiment involving a water mist nozzle was carried out to validate the numerical method and then the droplet behaviors, e.g., stochastic collision, coalescence and breakup, were calculated with 2-way interaction Discrete Particle Modeling (DPM) in the steady state for the hybrid nozzle system. The mean radius of the water mists increased by about 40 %, whereas that of the agent decreased by about 21 %, when the injection pressure was increased from 30 bar to 60 bar. In addition, the mean radius of the agent increased by about 24 % as the foundation angle of the hybrid nozzle head increased from $30^{\circ}$ to $60^{\circ}$. As a result, it can be inferred that the injection angle and pressure are important factors for hybrid water mist designs.