• 대한기계학회논문집B
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• 제23권8호
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• pp.997-1009
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• 1999

Silica particle formation and growth process including chemical reaction, coagulation and sintering was studied in a counterflow diffusion flame burner. The counterflow geometry provides a one dimensional flow field, along the stagnation point streamline, which greatly simplifies interpretation of the particle growth characteristics. $SiCl_4$ has been used as the source of silicon in hydrogen/oxygen/argon flames. The temperature profiles obtained by calculation showed a good agreement with experiment data. Using one and two dimensional sectional method, aerosol dynamics equation in a flame was solved, and these two results were compared. The two dimensional section method can consider sintering effect and growth of primary particle during synthesis, thus it showed evolution of morphology of non-spherical particles (aggregates) using surface fractal dimension. The effects of flame temperature and chemical loading on particle dynamics were studied. Geometric mean diameter based on surface area and total number concentration followed the trend of experiment results, especially, the change of diameters showed the sintering effect in high temperature environment.

• 한국재료학회지
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• 제17권1호
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• pp.50-55
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• 2007

Ultra-fine Copper powder for a conductive paste in electric-electronic field have been synthesized by chemical reduction of aqueous $CuSO_4$ with hydrazine hydrate $(N_2H_4{\cdot}H_2O)$ as a reductor. The effect of reaction conditions such as dispersant and reaction temperature on the particle size and shape for the prepared Cu powders was investigated by means of XRD, SEM, TEM and TGA. Experiments showed that type of dispersant and reaction temperature were affected on the particle size and morphology of the copper powder. When the carboxymethyl cellulose (CMC) was added as a dispersant the relative mono-dispersed and spherical Cu powder was obtained. Cu powders with particle size of approximately 140nm and narrow particle size distribution were obtained from 0.3M $CuSO_4$ with adding of 0.03M CMC and 40ml $N_2H_4{\cdot}H_2O$ at a reaction temperature of $70^{\circ}C$.

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2008년도 춘계 학술논문 발표대회
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• pp.61-65
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• 2008

This study, having combined and displaced blast furnace slag("BS" hereinafter) known as admixture material that delays hydration reaction with coarse particle cement("CC" hereinafter) collected in particle classification method during ordinary portland cement("OPC" hereinafter), reviewed the hydration heat characteristics affecting the concrete. To reduce hydration heat, the study plain-mixed which used 100% OPC for W/B 50% level 1, displaced CC at level 3 of 25%, 50% and 75% for OPC, and by displacing BS with admixture material at level 5 of 0%, 20%, 40%, 60% and 80% for cement(OPC+CC), experimented totally 16 batches. As a result of experiment, in the case of flow, the more CC displacement rate increased, the more it tended to decrease, and the more BS displacement rate increased, the more it decreased. Also, as for simple adiabatic temperature rise by the CC and BS displacement rates, it decreased as displacement rate increased, and particularly in the case of displaced BS of 80%, It showed temperature reduction effect of about 63% companing with plain. Compressive strength decreased in proportion to displacement rate, however strength reduction increment was shown to decrease with age progress.

• 한국전자파학회논문지
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• 제15권4호
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• pp.406-413
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• 2004

본 연구에서는 페라이트 입자크기와 시편의 제작온도가 Sheet형 전파홉수체의 전파홉수능에 미치는 영향을 조사한 것으로 분쇄 전 초투자율이 2,500과 10,000인 폐 처리된 MnZn ferrite를 이용하여 휴대전화용 전파홉수체를 제작하고 그 전파흡수능을 조사하였다. 페라이트 입자크기가 증가함에 따라 휴대전화촌 주파수인 1.8 ㎓에서 전파흡수능이 증가하였으며, 시편제작 온도가 증가함에 따라 역시 전파흡수능이 향상되었다. 본 연구에서는 주파수 1.8 ㎓에서 3.8 ㏈의 우수한 홉수능을 나타내는 두께 1 mm인 전파흡수능이 매우 우수하면서도 두께가 얇은 전파흡수체를 개발하였다.

• 한국안전학회지
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• 제14권1호
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• pp.78-85
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• 1999

The removal characteristics of H$_2$S from IGCC process over the natural manganese ore(NMO) containing several metal oxides($MnO_x$ : 51.85%, $FeO_y$ : 3.86%, CaO : 0.11%) were carried out in a batch type fluidized bed reactor(I.D.=40mm, height=0.8m). The $H_2S$ breakthrough curves were obtained as a function of temperature, initial gas velocity, initial gas concentration, and aspect ratio. The effect of particle size ratio and particle mixing fraction on $H_2S$ removal were investigated with binary system of different particle size. From this study, the adsorption capacity of $H_2S$ increased with temperature but decreased with excess gas velocity. The breakthrough time for $H_2S$ is reduced as the gas velocity is increased which leaded to gas by-passing and gas-solid contacting in a fluidized bed reactor. The results of the binary particle system with different size in batch experimental could predict to improve the behavior of continuous process of $H_2S$ removal efficiency. The natural manganese ore could be considered as potential sorbent in $H_2S$ removal.

• Journal of Magnetics
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• 제21권4호
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• pp.622-628
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• 2016

Magnetization property is a critical factor for magnetorheological fluids (MRFs) to achieve the liquid-solid transition. The main focus of this study is on exploring the influence factors on magnetization properties of MRFs. In this paper, a theoretical analysis is performed to discuss the magnetization characteristics of MRFs firstly. Then, a method for the preparation of carbonyl iron-based MRFs is illustrated and five MRFs samples with various material parameters are prepared. It is succeeded by a series of experiments on testing the hysteresis loop and the magnetization curve of each sample and the influence factors are compared and analyzed. Experimental results indicate that there is basically no hysteresis phenomenon on MRFs which exhibits superparamagnetic behavior at room temperature. A surfactant coating on magnetic particles can slightly improve the MRFs magnetization. Additionally, the magnetic susceptibility and the saturation magnetization both increase with the particle concentration, whereas the influence of particle diameter is relatively very small. Moreover, as the temperature increases, the magnetization decreases and the declining rate accelerates gradually.

• 한국표면공학회지
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• 제36권4호
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• pp.291-295
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• 2003

Many steam turbine components encounter solid particle erosion damage. It has been reported that particle erosion damage is caused by oxide scale exfoliation from boiler tubes. One of the most effective solutions to combat the erosion damage is the application of erosion resistant coatings on the turbine components. In this study, particle erosion resistance for various hard coatings such as nitride, Cr carbide and boride coatings was evaluated under the simulated erosion conditions of steam turbines. Based on the particle erosion tests, the boride coating was found to be more superior to others.

• 한국입자에어로졸학회지
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• 제10권4호
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• pp.155-162
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• 2014

The internal temperature will change depending on operation conditions and material of cyclone dust collector. This study compares the results of collection efficiency and temperature distribution on the different heat flux at wall of dust collector. The previous researcher's experiment results were used to confirm the reliability of CFD(Computational Fluid Dynamics) model. Based on this verified CFD model, we extended the analysis on the cyclone dust collectors. In CFD study, we used RNG k-epsilon model for analysis of turbulence flow, fluid is air, the velocity at inlet is 10 m/s, the temperature of air is $600^{\circ}C$. Because of the difference of outer vortex and inner vortex temperature, the collection efficiency will reduce with the increase of heat flux, showed the highest collection efficiency at heat insulation.

• Corrosion Science and Technology
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• 제14권2호
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• pp.76-84
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• 2015

The components in ultra super critical (USC) steam turbine, which is under development for high efficient power generation, are encountering harsher solid particle erosion by iron oxide scales than ones in the existing steam turbines. Therefore, the currently used boride coating will not be able to hold effective protection from particle erosion in USC system and should be replaced by new particle erosion resistant coatings. One of the best protective coatings developed for USC steam turbine parts was found to be vanadium-boride (V-boride) coating which has a hardness of about 3000 HV, much higher than that of boride, 1600~2000 HV. In order to evaluate particle erosion resistance of the various coatings such as V-boride, boride and Cr-carbide coatings at high temperature, particle erosion test equipments were designed and manufactured. In addition, erosion particle velocity was simulated using FLUENT software based on semi-implicity method for pressure linked equations revised (SIMPLER). Based on experimental results of this work, the vanadium-boride coating was found to be superior to others and to be a candidate coating to replace the boride coating.

• 한국수소및신에너지학회논문집
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• 제19권4호
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• pp.305-312
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• 2008

ZnO/Zn redox cycle is the one of the promising thermochemical cycles for hydrogen production via water splitting with high temperature heat source like a concentrated solar energy. This paper reports the particle size effect of Zinc on water splitting behavior. Water splitting reaction experiments were carried out at isothermal conditions of 350 and 400$^{\circ}C$ in TGA (Thermo Gravimetric Analyzer) using four commercial Zinc powders (nano, <10 ${\mu}m$, <150 ${\mu}m$ and $150{\sim}600\;{\mu}m$ particle sizes). Before the experiments, average particle size of Zinc powders was analyzed by PSA (Particle Size Analysis). After the experiments, XRD (X-Ray Diffraction) and SEM (Scanning Electron Microscope) analyses were conducted on the samples. The experimental results showed that particle size had a effect on the conversion of Zinc to ZnO. Zinc conversion was increased, as the particle size decreased. Especially, the nano size particles were aggregated and the particle's morphology changed on the surface during hydrolysis reaction.