• Title/Summary/Keyword: Particle Growth

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Effects of Temperature and Precursor-concentration on Characteristics of TiO2 Nanoparticles in Chemical Vapor Condensation Process -Part I: Real-time Particle Characterization by SMPS (화학기상응축 공정에서 TiO2 나노입자 특성에 미치는 반응온도와 전구체 농도의 영향 - Part I: SMPS를 이용한 실시간 입자특성 평가)

  • Lee, Chang-Woo;Yu, Ji-Hun;Im, Sung-Soon;Yun, Sung-Hee;Lee, Jai-Sung;Choa, Yong-Ho
    • Korean Journal of Materials Research
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    • v.13 no.5
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    • pp.323-327
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    • 2003
  • Properties of nanoparticles synthesized during gas phase reaction were studied in terms of particle behaviors using real-time particle characterization method. For this study, $TiO_2$ nanoparticles were synthesized in the chemical vapor condensation process(CVC) and their in-situ measurement of particle formation and particle size distribution was performed by scanning mobility particle sizer(SMPS). As a result, particle behaviors in the CVC reactor were affected by both of number concentration and thermal coagulation, simultaneously. Particularly, growth and agglomeration between nanoparticles followed two different ways of dominances from coagulations by increase of number concentration and sintering effect by increased temperature.

The synthesis of high purity micro Ag particle using the rapid firing -liquid phase precursor method (RF-LPP법을 이용한 고순도 마이크로 Ag 입자 합성)

  • Lim, Byeong-Seok;Song, Young-Hyun;Lee, Min-Ji;Mang, Sung-Ryul;Yoon, Dae-Ho
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.25 no.3
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    • pp.93-97
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    • 2015
  • To synthesis of high purity micro silver particle, we extracted the silver from the waste by liquid-liquid extraction and used the rapid firing-liquid phase precursor (RF-LPP) method. The silver micro particle was synthesized at $500^{\circ}C$ for 3 hr in air atmosphere by RF-LPP method. As a result of the research, micro silver particle is measured X-ray diffraction (XRD), the main peak is nearly corresponded to the same as JCPDS card (No.87-0719). With using the RF-LPP method, the fine Ag micro particle indicated due to the control of nucleation site and the oxygen contents was decreased by reducing treatment. We expect this research contribute to advance in field of the recycling technology.

The study of geopolymer utilization of reclaimed ash by using magnetic separation method (자력선별법을 이용한 화력 발전소 매립회의 지오폴리머 원료화 연구)

  • Kim, Kangduk
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.27 no.5
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    • pp.249-255
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    • 2017
  • Using a magnetic separation process, pond ash generated in thermoelectric power plants was separated into magnetic materials and nonmagnetic materials in order to make it into a raw material of geopolymers and unburned carbon; screening characteristics according to the particle sizes and magnet strength levels of the pond ash were observed. Based on the results of magnetic separation into fine particle (0.15~0.84 mm) and rough particle (0.84~2.4 mm) pond ash using 3000 G magnets, the weight fraction and ignition loss of nonmagnetic materials were found to be higher than those of magnetic materials, regardless of the particle size. In the case of fine particle pond ash, when the magnet strength was increased from 3000 G to 10000 G, even those materials that were weakly magnetic were separated into magnetic materials, leading to drastic increases in the weight fraction of magnetic materials, such that the ignition loss accounted for 66.9 % (22.8 wt%) of the entire ignition loss of 32.6 wt%, despite of the low ignition loss. Based on the results of measurement of the compressive strength levels of geopolymers made of magnetic-separated rough particle pond ash, the compressive strength of geopolymers made of magnetic materials containing small amounts of unburned carbon was found to be 20 MPa.

Effects of Feed Particle Size, Stocking Density, and Dissolved Oxygen Concentration on the Growth of Olive Flounder Paralichthys olivaceus (배합사료의 크기, 사육밀도 및 용존산소 농도가 넙치(Paralichthys olivaceus)의 성장에 미치는 영향)

  • Kim, Sung-Sam;Lee, Jin-Hyuck;Kim, Kang-Woong;Kim, Kyoung-Duck;Lee, Bong-Joo;Lee, Kyeong-Jun
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.48 no.3
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    • pp.314-321
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    • 2015
  • We performed three sets of feeding trials to establish the optimal feed size (Exp-I), stocking density (Exp-II), and dissolved oxygen level (DO) (Exp-III) for olive flounder Paralichthys olivaceus. In Exp-1, four replicate groups of fish ($53.6{\pm}0.9g$) were fed commercial diets with three particle sizes (small, medium, and large). In Exp-II, fish ($30.0{\pm}0.1g$) were reared at four stocking densities (1.8, 3.5, 5.3, and $7.1kg/m^3$). In Exp-III, fish ($187{\pm}1.48g$) were reared under two different DO levels (2-3 and 6-7 mg/L). In Exp-I, fish fed the large-particle diet gained significantly more weight and had a lower feed conversion ratio than fish fed the small- and medium-particle diets. In Exp-II, fish reared at 1.8 and $3.5kg/m^3$ gained slightly more weight and had lower feed conversion ratios than fish reared at 5.3 and $7.1kg/m^3$, although these differences were not significant. In Exp-III, negative effects were observed in the low DO groups. Therefore, under our experimental conditions, the optimal feed particle size, stocking density, and DO level for olive flounder were 9-9.4 mm, $3.5kg/m^3$, and 6-7 mg/L, respectively.

The synthesis and formation mechanism of the fine $BaTiO_3$ powders by ultrasonic spray pyrolysis (초음파 분무 열분해법에 의한 $BaTiO_3$ 미분말의 합성 및 형성기구 규명)

  • Heo, H.B.;Shin, K.C.
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.4 no.2
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    • pp.178-189
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    • 1994
  • Fine $BaTiO_3$ powder was synthesized from the various starting solution with 0.05 M by ultrasonic spray pyrolysis method. The conditions of synthesis were fixed on flow rate was 0.5 cm/sec, low temperature furnace was $300^{\circ}C$, and high temperatures furnace was $700^{\circ}C$. The formation procedure was investigated directly by SEM with the collected particle from the each reaction step. Also, the trace of particle in reaction tube was researched theoretically. Fine $BaTiO_3$ was synthesized only in the case of nitrate aqueous solution. The synthesized $BaTiO_3$ powder was porous and spherical which was consist of primary particle at the size of 19.1 nm. The formation procedure was as follows : the particle size decreased in drying step and then increased in initial thermal decomposition step. Finally, particle size was decreased to $0.42 {mu}m$. The trace of particle in reaction tube was also theoretically simulated and discussed.

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Analysis on NOX Removal Efficiencies and Particle Growth Using Pulsed Corona Discharge Reactor (펄스 코로나 방전 반응기를 이용한 NOX 제거 효율 및 입자 성장 분석)

  • Park, Jung-Hwan;Kim, Dong-Joo;Kim, Kyo-Seon
    • Journal of Industrial Technology
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    • v.21 no.B
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    • pp.155-161
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    • 2001
  • In this study, we analyzed the $NO_X$ removal efficiency and particle size distribution by the pulsed corona discharge process and investigated the effect of several process variables. The NO removal efficiencies and the particle characteristics were measured and analyzed as the function of initial concentrations of NO, $H_2O$, and $NH_3$, applied voltage, pulse frequency and residence time. As the frequency of applied voltage increases, or as the applied voltage increases or as the residence time increases, the NO removal efficiency increases. The change of initial $NH_3$ and $H_2O$ concentrations do not affect the NO removal efficiency significantly. The particle concentration and size increases with the increases of initial NO concentration, residence time and applied voltage.

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Light Mediated Yeast Cell Growth and Metabolism

  • Dowd Jr, Christopher J.;Tanner, Robert D.
    • KSBB Journal
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    • v.6 no.3
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    • pp.299-307
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    • 1991
  • In this paper the effect of light on non-aerated Baker's Yeast(Saccharomyces cereuisiae) production and the protein excretion to the extracellular fluid is studied. Previous results in our laboratory indicate that at pH=5 and T-32$^{\circ}C$ yeast may be affected by light, but those differences seem to be within statistical variation of the data. In this paper, cell and extracellular protein concentrations along with redox potential are monitored for batch fermentations in the presence and absence of light at pH levels of 3 and 5 and at 31$^{\circ}C$, in order to explore whether possible light effects can be more readily discerned at lower pH values. Yeast particle size distributions are also determined over the course of fermentation using a particle counter in order to add one more measuring tool to our usual cell and total protein measurements. An apparently noticeable difference in the redox potential is observed between the light and the dark runs for early times for the pH=3 runs. The particle size distributions show differences in the particle diameters between light and dark runs at pH=3, but those differences fall within one standard deviation of the mean particle diameters.

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Characterization of Soot Particles Generated in Non-sooting and Sooting Normal Diffusion Flames (Sooting 및 Non-Sooting 정상 확산 화염에서 생성되는 매연 입자의 특성에 대한 연구)

  • Choi, In-Chul;Lee, Jae-Bok;Hwang, Jung-Ho
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.24 no.7
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    • pp.984-993
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    • 2000
  • Characteristics of carbon soot particles generated in diffusion flames were studied. Non-sooting and sooting normal diffusion flames using propane or ethylene as fuel were selected. In the flames, soot volume fraction was measured by a thermocouple, and primary particle diameter and cluster size were analyzed by TEM photographs. The characteristics of soot particles depended on flame(non-sooting or sooting) and fuel(propane or ethylene) type. Unlike the sooting diffusion flames, particle growth and oxidation processes were clearly observed in the non-sooting diffusion flames. In the sooting diffusion flames, soot particle size was slightly changed at the flame tip.

Current Trend of Second Phase Particle-grain Boundary Interaction Research using Computer Simulations (컴퓨터 시뮬레이션 기법을 이용한 입계면 - 이상 입자 간 상호작용 모사 연구 동향)

  • Chang, Kunok
    • Journal of Powder Materials
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    • v.27 no.4
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    • pp.339-342
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    • 2020
  • Since the interaction between the second-phase particle and grain boundary was theoretically explained by Zener and Smith in the late 1940s, the interaction of the second-phase particle and grain boundary on the microstructure is commonly referred to as Zener pinning. It is known as one of the main mechanisms that can retard grain growth during heat treatment of metallic and ceramic polycrystalline systems. Computer simulation techniques have been applied to the study of microstructure changes since the 1980s, and accordingly, the second-phase particle-grain boundary interaction has been simulated by various simulation techniques, and further diverse developments have been made for more realistic and accurate simulations. In this study, we explore the existing development patterns and discuss future possible development directions.

Anti-biofouling properties of silver nano-particle coated artificial light-weight aggregates (은 나노 입자가 코팅된 인공경량골재의 생물오손 방지 특성)

  • Kim, Seongyeol;Kim, Yooteak;Park, Yongjoon
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.25 no.5
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    • pp.212-217
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    • 2015
  • Ships and marine structures have a lot of problems in their high maintenance and operating cost by biofouling. A biofouling occurrs by the adhesion of marine microorganism, algae and bacteria. In this study, the aim is to prevent or to reduce the biofouling phenomena through silver nano-particle coating on artificial light-weight aggregates and geopolymer. The antibacterial activity on them is tested according to ASTM E2149-2013a. The test results showed, it is estimated that silver nano-particles removed 99.99 % of bacteria. Specimens were set up in the sea side of field test area in Korea Institute of Ocean Science and Technology (KIOST) and have been observed for five months. The anti-biofouling effect and difference in weight change rate have been detected two months later after the installation. Because silver nanoparticles inhibit bacterial growth and kill the cells by destroying bacterial membranes, silver nano-particle coating on artificial lightweight aggregates is a well-suited and eco-friendly method for preventing biofouling in the sea up to 5 months.