• Mass Spectrometry Letters
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• v.4 no.3
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• pp.51-54
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• 2013

Isotopic analysis using thermal ionization mass spectrometry coupled with scanning electron microscopy (SEM-TIMS) was performed to determine the isotopic ratios of uranium contained in micro-particles in the 6th Nuclear Signatures Interlaboratory Measurement Evaluation Programme (NUSIMEP-6) sample. Elemental analysis by energy dispersive X-ray spectroscopy (EDS) was conducted on uranium-bearing mirco-particles, which were transferred to rhenium filaments for TIMS loading using a micromanipulation system in a SEM. A multi-ion-counter system was utilized to detect the ion signals of the four isotopes of uranium simultaneously. The isotope ratios of uranium corrected by bracketing using a reference material showed excellent agreement with the certified values. The measurement accuracy for $n(^{234}U)/n(^{238}U)$ and (b) $n(^{235}U)/n(^{238}U)$ was 10% and 1%, respectively, which met the requirements for qalification for the NetWork of Analytical Laboratories (NWAL).

• Journal of the Korean Chemical Society
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• v.13 no.1
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• pp.49-55
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• 1969

X-ray Fluorescence Spectrographic method has been applied for the rapid determination of main components, such as $SiO_2$, $Al_2O_3$, $Fe_2O_3$, CaO, MgO and $K_2O$ in Silicate Minerals. In this method, Boric Acid was used as a binder after fusion with Lithium Tetraborate in the briquet-making process. The Lithium Flubride, Ammonium di-Hydrogen Phosphate and Ethylene Diamine d-Tartrate crystals were used with Scintillation counter and Gas Flow counter as the detectors. Several influences on this method were discussed, including the particle size of samples and reducing of the matrix effects by dilution with Boric Acid and addition of Lanthanum Oxide with the diluent. In order to test the reproducibility of this method described above, the determination of the same kind of samples were carried out repeatedly, and the results obtained were presented in the table. Calibration curves for each element were presented, and the application of the method was tested with International Rock Standard T-Ⅰ. All the results obtained by X-Ray Fluorescence Spectrographic method were compared with the results by conventional chemical method.

• Publications of The Korean Astronomical Society
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• v.27 no.3
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• pp.81-86
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• 2012

The International Space Station (ISS) orbits the Earth within the inner radiation belt, where high-energy protons are produced by collisions of cosmic rays to the upper atmosphere. About 6 astronauts stay in the ISS for a long period, and it should be important to monitor and assess the radiation environment in the ISS. The tissue equivalent proportional counter (TEPC) is an instrument to measure the impact of radiation on the human tissue. KASI is developing a TEPC as a candidate payload of the ISS. Before the detailed design of the TEPC, we performed simulations to test whether our conceptual design of the TEPC will work propertly in the ISS and to predict its performance. The simulations estimated that the TEPC will measure the dose equivalent of about 1:1 mSv during a day in the ISS, which is consistent with previous measurements.

• Journal of Korean Society of Occupational and Environmental Hygiene
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• v.32 no.2
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• pp.163-171
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• 2022

Objectives: Fit performance may vary depending on the ambient aerosol number and ratio in respective test environment. Although several instrument can measure it, they differ with respect to the measurement principle and the range of ambient aerosols collected to calculate the fit factor. Methods: In this study, the fit performance between a condensation nuclei counter(CNC) and an optical particle counter(OPC) was compared according to ambient aerosol number concentration, and evaluated consistency. One type respirators(N95 masks) was worn by 50 participants PortaCount®(Pro+ 8038) and MT®(05U) were connected with one probe to one mask, and Fit Factors(FFs) were measured simultaneously. Results: The interclass correlation coefficient of the fit factor and ambient aerosol number, as measured by the two instrument, was 0.82 and 0.79, respectively, indicating a high consistency level. On the other hand there was a significant correlation between the successful test performance of the OPC instrument and the ambient aerosol number. Conclusions: The test was passed with the CNC and OPC instruments when the ambient aerosol number was 635-3,332 particles/cm³ and 368-1,976 particles/cm³, respectively. Thus, the ideal ambient aerosol number of particles differed between the two instrument.

• Journal of the Korean Applied Science and Technology
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• v.33 no.2
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• pp.374-384
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• 2016

Concern about air pollution is gradually rising up in domestic and foreign, automotive and fuel researchers are trying to reduce vehicle exhaust emissions, through a lot of approaches, which consist of new engine design and innovative after-treatment systems, using clean (eco-friendly alternative) fuels and fuel quality improvement. This research is proceeding by two main issues : exhaust emissions and PM particle emissions of gasoline vehicle. Exhaust emissions, non-regulated emissions and PM (particulate matter) particles of automotive are causing many problems which ambient pollution and harmful effects on the human body. The main particulate fraction of automotive exhaust emissions consists of small particles. Because of their small size, inhaled particles can easily penetrate deep into the lungs. The rough surfaces of these particles make it easier for them to combine with other toxins in the environment. Thus, the hazards of particle inhalation are increased. Based on the oxygenated fuel additive types (MTBE, Bio-ETBE, Bio-ethanol, Bio-butanol), this paper discussed the influence of oxygen contents on gasoline vehicle exhaust emissions, non-regulated emissions and nano-particle emissions. Also, this paper assessed exhaust emission characteristics at 2 type test modes. The test modes were FTP-75 and HWFET. All measurement items be verified less than the value of regulated emissions. It could be known difference increase and decrease by each measurement item depending on increase the oxygen contents.

• Journal of Korean Society of Occupational and Environmental Hygiene
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• v.26 no.2
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• pp.225-236
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• 2016

Objectives: Nanomaterials have been used in various fields. As use of nanoproducts is increasing, workers dealing with nanomaterials are also gradually increasing. Exposure assessments for nanomaterials have been carried out for protection of worker's health in workplace. Exposure studies were mainly focused on manufacturing processes, but these studies on after-treatment processes such as refinement, weighing, and packing were insufficient. So, we investigated exposure characteristics of particles during after-treatment processes of $Al_2O_3$ fibers and Ni powders. Methods: Mass-production of Ni powder process was carried out in enclosed capture-type canopy hood. In a developing stage, $Al_2O_3$ was handled with a local ventilation unit. Exposure characteristics of particles were investigated for $Al_2O_3$ fiber and Ni powder processes during the periods of 10:00 to 16:00, 20 May 2014 and 13:00 to 16:00, 21 May 2014, respectively. Three real-time aerosol instruments were utilized in exposure assessment. A scanning mobility particle sizer(SMPS, nanoscan, model 3910, TSI) and an optical particle counter(OPC, portable aerosol spectrometer, model 1.109, Grimm) were used to determine the particle size distribution in the size range of 10-420 nm and $0.25-32{\mu}m$, respectively. In addition, a nanoparticle aerosol monitor(NAM, model 9000, TSI) was used to measure lung-deposited nanoparticle surface area. Membrane filters(isopore membrane filter, pore size of 100 nm) were also used for air sampling for the FE-SEM(model S-5000H, Hitachi) analysis using a personal sampling pump(model GilAir Plus by 2.5 L/min, Gilian). Conclusions: For Ni powder after-treatment process, only 27% increase in particle concentration was found during the process. However, for $Al_2O_3$ fiber after-treatment process, significant exposure(1.56-3.34 times) was observed during the process.

• Journal of Environmental Science International
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• v.18 no.7
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• pp.721-733
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• 2009

To examine the fluctuations of aerosol number concentration with different size in the boundary layer of marine area during summer season, aerosol particles were assayed in the Ieodo Ocean Research Station, which is located 419 km southwest of Marado, the southernmost island of Korea, from 24 June to 4 July, 2008. The Laser Particle Counter (LPC) was used to measure the size of aerosol particles and NCEP/NCAR reanalysis data and sounding data were used to analyze the synoptic condition. The distribution of aerosol number concentration had a large variation from bigger particles more than 3 ${\mu}m$ in diameter to smaller particles more than 1 ${\mu}m$ in diameter with wind direction during precipitation. The aerosol number concentration decreased with increasing temperature. An increase (decrease) of small size of aerosol (0.3${\sim}$0.5 ${\mu}m$ in diameter) number concentration was induced by convergence (divergence) of the wind fields. The aerosol number concentration of bigger size more than 3 ${\mu}m$ in diameter after precipitation was removed as much as 89${\sim}$94% compared with aerosol number concentration before precipitation. It is considered that the larger aerosol particles would be more efficient for scavenging at marine boundary layer. In addition, the aerosol number concentration with divergence and convergence could be related with the occurrence and mechanism of aerosol in marine boundary layer.

• Atmosphere
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• v.22 no.1
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• pp.97-107
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• 2012

To investigate variation of aerosol number concentration at each different size with three-dimensional (3D) wind components in ocean area, aerosol particles and 3D wind components were measured in the Ieodo Ocean Research Station, which is located to 419 km southwest from Marado, the southernmost island of Korea, from 25 June to 8 July 2010. The Laser Particle Counter (LPC) and ultrasonic anemometer were used to measure the size of aerosol particles and 3D wind components (zonal (u), meridional (v), and vertical (w) wind) respectively. Surface weather chart, NCEP/NCAR reanalysis data and sounding data were used to analyze the synoptic condition. The distribution of aerosol number concentration had a large variation from bigger particles more than 1.0 ${\mu}m$ in diameter by wind direction during precipitation. In the number concentration of aerosol particles with respect to the weather conditions, particles larger than 1.0 ${\mu}m$ in size were decreased and sustained to the similar concentration at smaller particles during precipitation. The increase in aerosol number concentration was due to the sea-salt particles which was suspended by southwesterly and upward winds. In addition, the aerosol number concentration with vertical wind flow could be related with the occurrence and increasing mechanism of aerosol in marine boundary layer.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.23 no.10
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• pp.1265-1273
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• 1999

PIV(Particle Image Velocimetry) velocity field measurements inside the snout of a1/10 scale model of the Zn plating process were carried out at the strip speed $V_s=1.5m/s$. Aluminum powder particles ($1{\mu}m$) and atomized olive oil ($3{\mu}m$) were used as seeding particles to simulate the molten Zinc flow and deoxidization gas flow, respectively. A pulsed Nd:Yag laser and a $2K{\times}2K$ high-resolution CCD camera were synchronized for the PIV velocity field measurement. From flow visualization study, it is found that the liquid flow in the Zn pot is dominantly governed by the uprising flow caused by the rotating sink roll, with its effect on the steel strip inside the snout largely diminished by installing of the snout. The deoxidization gas flow in front of the strip inside the snout can be characterized by a large-scale vortex rotating clockwise direction formed by the moving strip. In the rear side of the strip, a counter-clockwise vortex is formed and some of the flow entrained by the moving strip impinges on the free surface of molten zinc. The liquid flow in front of the strip is governed by the flow entering the snout, caused by the spinning sink roll. Just below the free surface a counter-clockwise vortex is formed near the snout wall. The moving strip affects dominantly the flow behind the strip inside the snout, and large amount of the liquid flow follows the moving strip toward the sink roll. The thickness of the flow following the strip is very thin in the front side due to the uprising flow, however thick boundary layer is formed in the rear side of the strip. Its thickness is increased as moving downstream toward the sink roll. Inside the snout, the deoxidization gas flow above the free surface is much faster than the liquid flow in the zinc pot. Due to the larger influx of the flow following the moving strip in the rear side of the strip, higher percentage of imperfection can be anticipated on the rear surface of the strip.

• Korean Journal of Remote Sensing
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• v.32 no.5
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• pp.413-421
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• 2016

In this study, correlations between Moderate Resolution Imaging Spectroradiometer (MODIS) derived Aerosol Optical Depth (AOD) values and surface-level $PM_{2.5}$ concentrations at Gosan, Korea have been investigated. For this purpose, data from various instruments, such as satellite, sunphotometer, Optical Particle Counter (OPC), and Micro Pulse Lidar (MPL) on 14-24 October 2009 were used. Direct comparison between sunphotometer measured AOD and surface-level $PM_{2.5}$ concentrations showed a $R^2=0.48$. Since the AERONET L2.0 data has significant number of observations with high AOD values paired to low surface-level $PM_{2.5}$ values, which were believed to be the effect of thin cloud or Asian dust. Correlations between MODIS AOD and $PM_{2.5}$ concentration were increased by screening thin clouds and Asian dust cases by use of aerosol profile data on Micro-Pulse Lidar Network (MPLNet) as $R^2$ > 0.60. Our study clearly demonstrates that satellite derived AOD is a good surrogate for monitoring atmospheric PM concentration.