• Carbon letters
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• v.22
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• pp.14-24
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• 2017

Carboxylated multi-wall carbon nanotubes (MWCNTs-COOH) have been used as efficient adsorbents for the removal of picric acid from aqueous solutions under stirring and ultrasound conditions. Batch experiments were conducted to study the influence of the different parameters such as pH, amount of adsorbents, contact time and concentration of picric acid on the adsorption process. The kinetic data were fitted with pseudo-first order, pseudo-second-order, Elovich and intra-particle diffusion models. The kinetic studies were well described by the pseudo-second-order kinetic model for both methods. In addition, the adsorption isotherms of picric acid from aqueous solutions on the MWCNTs were investigated using six two-parameter models (Langmuir, Freundlich, Tempkin, Halsey, Harkins-Jura, Fowler-Guggenheim), four three-parameter models (Redlich-Peterson, Khan, Radke-Prausnitz, and Toth), two four-parameter equations (Fritz-Schlunder and Baudu) and one five-parameter equation (Fritz-Schlunder). Three error analysis methods, correlation coefficient, chi-square test and average relative errors, were applied to determine the best fit isotherm. The error analysis showed that the models with more than two parameters better described the picric acid sorption data compared to the two-parameter models. In particular, the Baudu equation provided the best model for the picric acid sorption data for both methods.

• Journal of the Korean Data and Information Science Society
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• v.9 no.2
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• pp.289-298
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• 1998

We investigate the distribution of likelihood ratio test(LRT) of null hypothesis a sample is from single gamma with unknown shape and scale against the alternative hypothesis a sample is from a mixture of two gammas, each with unknown scale and unknown (but equal) scale. To obtain stable maximum likelihood estimates(MLE) of a mixture of two gamma distributions, the EM(Dempster, Laird, and Robin(1977))and Modified Newton(Jensen and Johansen(1991)) algorithms were implemented. Based on EM, we made a simple structure likelihood equation for each parameter and could obtain stable solution by Modified Newton Algorithms. Simulation study was conducted to investigate the distribution of LRT for sample size n = 25, 50, 75, 100, 50, 200, 300, 400, 500 with 2500 replications. To determine the small sample distribution of LRT, I considered the model of a gamma distribution with shape parameter equal to 1 + f(n) and scale parameter equal to 2. The simulation results indicate that the null distribution is essentially invariant to the value of the shape parameter. Modeling of the null distribution indicates that it is well approximated by a gamma distribution with shape parameter equal to the quantity $0.927+1.18/\sqrt{n}$ and scale parameter equal to 2.16.

• Journal of the Korean Society for Nondestructive Testing
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• v.37 no.2
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• pp.115-121
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• 2017

The nonlinear ultrasonic technique is a potential nondestructive method to evaluate material degradation, in which the ultrasonic nonlinearity parameter is usually measured. The ultrasonic nonlinearity parameter is defined by the elastic nonlinearity coefficients of the nonlinear Hooke's equation. Therefore, even though the ultrasonic nonlinearity parameter is not equal to the elastic nonlinearity parameter, they have a close relationship. However, there has been no experimental verification of the relationship between the ultrasonic and elastic nonlinearity parameters. In this study, the relationship is experimentally verified for a heat-treated aluminum alloy. Specimens of the aluminum alloy were heat-treated at $300^{\circ}C$ for different periods of time (0, 1, 2, 5, 10, 20, and 50 h). The relative ultrasonic nonlinearity parameter of each specimen was then measured, and the elastic nonlinearity parameter was determined by fitting the stress-strain curve obtained from a tensile test to the 5th-order-polynomial nonlinear Hooke's equation. The results showed that the variations in these parameters were in good agreement with each other.

• Journal of the Korean Society of Hazard Mitigation
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• v.10 no.6
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• pp.119-130
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• 2010

The universal model for the parameter estimation of the Storage Function Model(SFM) was developed through the applications of the distributed model for various hypothetical watersheds and runoff conditions. The existing parameter estimation equations are based on observations and these equations which are derived from the restricted conditions are not sensitive to the variation of physical characteristics of a watershed. This study developed the universal model for the parameter estimation through the runoff simulations of 35,000 times. As the simulation results, we have known that the lag time is related to the longest stream channel characteristics and the storage coefficient is related to the watershed characteristics.

• The Transactions of the Korean Institute of Electrical Engineers A
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• v.51 no.2
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• pp.69-75
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• 2002

AVR parameter tuning for voltage control of power system generators has generally been performed with the analytic methods and the simulation methods, which mostly depend on off-line linear mathematical models of excitation control system. However, due to the nonlinear nature of excitation control system, excitation control system performance of the tuned Parameters using the above conventional tuning methods may not be appropriate for some operating conditions. This paper presents an AVR parameter tuning method using actual on-line data of the excitation control system with the parameter optimization technique. As this method utilizes on-line operating data of the target excitation control system not the mathematical model of the system, it can overcome the limitation of model uncertainty Problems in conventional method, and it can tune the AVR parameter set which gives desired performance at the operating conditions. For the verification of proposed tuning method, two case studies with scaled excitation systems and the real-time power system simulator are presented.

• Transactions of the Korean Society of Mechanical Engineers
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• v.13 no.5
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• pp.807-819
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• 1989

Buckling and vibration of laminated non-circular cylindrical shells with constant thickness and simply supported boundary condition is considered. Governing equations are derived based on the Donnell and Flugge shell theory and Galerkin method is applied for the numerical analysis. Comparisons are made between present results and others. Variations of frequency parameter and buckling load parameter on the change of stacking angle, eccentricity parameter and shell theories are investigated. Conclusion of this study is as follows: (1) General solutions of buckling and vibration of laminated non-circular cylindrical shell are obtained. (2) Frequency parameter is decreased as the initial axial load is increased. (3) In general, frequency and buckling load parameter of laminated non-circular cylindrical shells are decreased as increasing of eccentricity parameter and stacking angle.

• Proceedings of the Korea Water Resources Association Conference
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• 2018.05a
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• pp.448-448
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• 2018

In this study, the regression models (Load ESTimator and eight-parameter model) were evaluated to estimate instantaneous pollutant loads under various criteria and optimization methods. As shown in the results, LOADEST commonly used in interpolating pollutant loads could not necessarily provide the best results with the automatic selected regression model. It is inferred that the various regression models in LOADEST need to be considered to find the best solution based on the characteristics of watersheds applied. The recently developed eight-parameter model integrated with Genetic Algorithm (GA) and Gradient Descent Method (GDM) were also compared with LOADEST indicating that the eight-parameter model performed better than LOADEST, but it showed different behaviors in calibration and validation. The eight-parameter model with GDM could reproduce the nitrogen loads properly outside of calibration period (validation). Furthermore, the accuracy and precision of model estimations were evaluated using various criteria (e.g., $R^2$ and gradient and constant of linear regression line). The results showed higher precisions with the $R^2$ values closed to 1.0 in LOADEST and better accuracy with the constants (in linear regression line) closed to 0.0 in the eight-parameter model with GDM. In hence, based on these finding we recommend that users need to evaluate the regression models under various criteria and calibration methods to provide the more accurate and precise results for pollutant load estimations.

• Structural Engineering and Mechanics
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• v.71 no.1
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• pp.45-56
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• 2019

A modified mechanical model of pre-pressed spring self-centering energy dissipation (PS-SCED) brace is proposed, and the hysteresis band is distinguished by the indication of relevant state variables. The MDOF frame system equipped with the braces is formulated in an incremental form of linear acceleration method. A multi-objective genetic algorithm (GA) based brace parameter optimization method is developed to obtain an optimal solution from the primary design scheme. Parameter sensitivities derived by the direct differentiation method are used to modify the change rate of parameters in the GA operator. A case study is conducted on a steel braced frame to illustrate the effect of brace parameters on node displacements, and validate the feasibility of the modified mechanical model. The optimization results and computational process information are compared among three cases of different strategies of parameter change as well. The accuracy is also verified by the calculation results of finite element model. This work can help the applications of PS-SCED brace optimization related to parameter sensitivity, and fulfill the systematic design procedure of PS-SCED brace-structure system with completed and prospective consequences.

• Smart Structures and Systems
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• v.11 no.1
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• pp.1-17
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• 2013

This paper intended to investigate the feasibility of bridge health monitoring using a linear system parameter of a time series model identified from traffic-induced vibrations of bridges through a laboratory moving vehicle experiment on scaled model bridges. This study considered the system parameter of the bridge-vehicle interactive system rather than modal ones because signals obtained under a moving vehicle are not the responses of the bridge itself but those of the interactive system. To overcome the shortcomings of modal parameter-based bridge diagnosis using a time series model, this study considered coefficients of Autoregressive model (AR coefficients) as an early indicator of anomaly of bridges. This study also investigated sensitivity of AR coefficients in detecting anomaly of bridges. Observations demonstrated effectiveness of using AR coefficients as an early indicator for anomaly of bridges.

• Journal of Korean Association for Spatial Structures
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• v.17 no.4
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• pp.123-132
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• 2017

A smart tuned mass damper (TMD) was developed to provide better control performance than a passive TMD for reduction of earthquake induced-responses. Because a passive TMD was developed decades ago, optimal design methods for structural parameters of a TMD, such as damping constant and stiffness, have been developed already. However, studies of optimal design method for structural parameters of a smart TMD were little performed to date. Therefore, parameter studies of structural properties of a smart TMD were conducted in this paper to develop optimal design method of a smart TMD under seismic excitation. A retractable-roof spatial structure was used as an example structure. Because dynamic characteristics of a retractable-roof spatial structure is changed based on opened or closed roof condition, control performance of smart TMD under off-tuning was investigated. Because mass ratio of TMD and smart TMD mainly affect control performance, variation of control performance due to mass ratio was investigated. Parameter studies of structural properties of a smart TMD was performed to find optimal damping constant and stiffness and it was compared with the results of optimal passive TMD design method. The design process developed in this study is expected to be used for preliminary design of a smart TMD for a retractable-roof spatial structure.