• Title/Summary/Keyword: Paramagnetic

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Magnetization and Intrinsic Coercivity for τ-phase Mn54Al46/α-phase Fe65Co35 Composite

  • Park, Jihoon;Hong, Yang-Ki;Lee, Jaejin;Lee, Woncheol;Choi, Chul-Jin;Xu, Xia;Lane, Alan M.
    • Journal of Magnetics
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    • v.19 no.1
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    • pp.55-58
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    • 2014
  • We have synthesized ferromagnetic ${\tau}$-phase $Mn_{54}Al_{46}/{\alpha}$-phase $Fe_{65}Co_{35}$ composite by annealing a mixture of paramagnetic ${\varepsilon}$-phase $Mn_{54}Al_{46}$ and ferromagnetic ${\alpha}$-phase $Fe_{65}Co_{35}$ particles at $650^{\circ}C$. The volume fraction ($f_h$) of hard ${\tau}$-phase $Mn_{54}Al_{46}$ of the composite was varied from 0 to 1. During the annealing, magnetic phase transformation occurred from paramagnetic ${\varepsilon}$-phase to ferromagnetic ${\tau}$-phase $Mn_{54}Al_{46}$. The magnetization and coercivity of the composite monotonically decreased and increased, respectively, as the $f_h$ increased. These results are in good agreement with our proposed composition dependent coercivity and modified magnetization equations.

DIRECT NUMERICAL SIMULATION OF MAGNETIC CHAINS IN SIMPLE SHEAR FLOW (전단유동에서 자성사슬의 거동에 대한 직접수치해석)

  • Kang, T.G.
    • 한국전산유체공학회:학술대회논문집
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    • 2009.11a
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    • pp.88-92
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    • 2009
  • When exposed to uniform magnetic fields externally applied, paramagnetic particles acquire dipole moments and the induced moments interacting with each other lead to the formation of chainlike structures or clusters of particles aligned with the field direction. A direct simulation method, based on the Maxwell stress tensor and a fictitious domain method, is applied to solve flows with magnetic chains in simple shear flow. We assumed that the particles constituting the chains are paramagnetic, and inertia of both flow and magnetic particles is negligible. The numerical scheme enables us to take into account both hydrodynamic and magnetic interactions between particles in a fully coupled manner, enabling us to numerically visualize breakup and reformation of the chains by the combined effect of the external field and the shear flow. Simple shear flow with suspended magnetic chains is solved in a periodic domain for a given magnetic field. Dynamics of interacting magnetic chains is found to be significantly affected by a dimensionless parameter called the Mason number, the ratio of the viscous force to the magnetic force in the shear flow. The effect of particle area fraction on the chain dynamics is investigated as well.

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The Evaluation of Surface Crack in Paramagnetic Material by FEF Technique (FEF 탐상법을 이용한 상자성체 표면결함 평가)

  • Kim, Hoon
    • Journal of the Korean Society for Nondestructive Testing
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    • v.24 no.5
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    • pp.532-537
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    • 2004
  • FEF(Focused Electromagnetic Field) technique was newly developed that is based on the induction principle exciting electromagnetic field. The technique consists of an induction wire and a sensor for detecting electromagnetic field, and is applied in a non-contact mode. In this study, the technique was applied to the evaluation of EDM slits in some conductive materials - aluminum alloy, stainless steel and Inconel alloy. The voltage in the non-defect region is depended upon the measurement lift-off. The voltage signals on defects are measured with peak values, and the peak values changed with the depth of defects. The voltage distributions for all conductive materials are the same trend.

EPR Spectra of Spin-Labeled Cytochrome c Bound to Acidic Membranes: Implications for the Binding Site and Reversibility

  • Min, Tong-Pil;Park, Nan-Hyang;Park, Hee-Young;Hong, Sun-Joo;Han, Sang-Hwa
    • BMB Reports
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    • v.29 no.2
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    • pp.169-174
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    • 1996
  • Yeast cytochrome c (cyt c) was modified at cysteine-102 with a thiol-specific spin label and its interaction with liposomes containing acidic phospholipids was studied by electron paramagnetic resonance (EPR) spectroscopy. Association of cyt c with liposomes resulted in a significant reduction in the mobility of the spin label and a fraction of cyt c even seemed to be immobilized. Based on a large spectral change upon binding and the proximity of the spin-label to lysine-86 and -87, we propose these two residues to be the potential binding site at neutral pH. The interaction is electrostatic in nature because the spectral changes were reversed by addition of anions. Dissociation of the bound cyt c by anions, however, became less effective as the lipid/protein ratio increased. This suggests a repulsive lateral interaction among the bound cyt c. Unlabeled cyt c molecules added to preformed cyt c-liposome complex displaced the bound (spin labeled) cyt c and the process was competitive and reversible.

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Dynamics of the mobile insert helix in the domain III-IV of Aux/IAA17 probed by site-directed spin labeling and paramagnetic NMR spectroscopy

  • Han, Mookyoung;Suh, Jeong-Yong
    • Journal of the Korean Magnetic Resonance Society
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    • v.19 no.2
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    • pp.61-66
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    • 2015
  • The plant hormone auxin is involved in all stages of plant development. Aux/IAAs are the transcriptional repressors that bind to the Auxin Response Factors (ARFs) to regulate the gene expression upon auxin release. Aux/IAA have highly conserved C-terminal domains (domains III-IV) that mediate both homotypic and heterotypic interactions between Aux/IAA and ARF family proteins. Recent studies revealed that the conserved domains III-IV share a common ${\beta}$-grasp fold that oligomerizes in a front-to-back manner. In particular, Aux/IAA contains a mobile insert helix in the domain III-IV, whereas ARFs do not. Here, we investigated the dynamics of the insert helix using paramagnetic NMR spectroscopy. The insert helix exhibited fast motions in the ps-ns time scale from $^{15}N$ relaxation data, but the amplitude of the motion is likely limited to the local neighborhood. Our result suggests that the motion of the helix may have functional implications in protein-protein interactions for transcriptional regulations.

The Influence of Magnetic Field on Diffusion Flames: Role of Magnetic Field On/Off Frequency and Duty Ratio (자기장 분포가 확산화염의 연소특성에 미치는 영향: 자기장 On/Off 주기와 Duty Ratio의 역할)

  • Lee, Won-Nam;Bae, Seung-Man
    • Journal of the Korean Society of Combustion
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    • v.17 no.1
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    • pp.58-65
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    • 2012
  • The influence of magnetic field on propane and acetylene diffusion flames have been experimentally investigated using an electromagnetic system. Periodically induced magnetic field having various frequencies and duty ratios was established in square wave form. The maximum intensity and gradient of magnetic field were 1.3 T and 0.27 T/mm, respectively. The width of a propane flame was reduced up to 4.5% and the brightness was enhanced up to 25% when the magnetic field was induced. The soot emission from an acetylene flame was ceased when magnetic field was induced. The alteration of flow field, which is due to the paramagnetic characteristics of oxygen molecule, is most likely to be responsible for the change in flame size and brightness. The effect of magnetic field on diffusion flames, which competes with the gravitational effect, was more apparent from a smaller size flame. The magnetic field effect, therefore, could be important under microgravity conditions. Since the time required to alter the flow field must be finite, the magnetic field effect is likely to be less significant for a periodically oscillating magnetic field at a high frequency or having a small duty ratio.

Susceptibility Contrast Enhancement Imaging in MRI (핵자기 공명 단층 촬영에서의 자화율 강조 영상법)

  • Ro, Y.M.;Mun, C.W.;Lim, T.H.;Cho, Z.H.
    • Proceedings of the KOSOMBE Conference
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    • v.1992 no.05
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    • pp.85-91
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    • 1992
  • In MRI, an image contrast can be developed as a result of the susceptibility effect if an object has paramagnetic substances. This is mainly due to the non-uniform phase distribution or linear gradient developed by the magnetic susceptibility within a voxel, which in turn reduces the signal intensity; e.g., spin phases are dephased and thereby cancel each other resulting in a reduced signal. In this paper, a new concept for manipulating the susceptibility effect through the use of tailored RF pulses is proposed. As potential applications of the method, two different types of tailored RF pulses are introduced: one for susceptibility artifact correction and the other for contrast enhancement. The latter, for example, can be applied to angiography utilizing the paramagnetic property of deoxygenated blood. Both a theoretical study of the method and experimental results are reported.

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A simple guide to the structural study on membrane proteins in detergents using solution NMR

  • Sim, Dae-Won;Lee, Yoo-sup;Seo, Min-Duk;Won, Hyung-Sik;Kim, Ji-hun
    • Journal of the Korean Magnetic Resonance Society
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    • v.19 no.3
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    • pp.137-142
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    • 2015
  • NMR-based structural studies on membrane proteins are appreciated quite challenging due to various reasons, generally including the narrow dispersion of NMR spectra, the severe peak broadening, and the lack of long range NOEs. In spite of the poor biophysical properties, structural studies on membrane proteins have got to go on, considering their functional importance in biological systems. In this review, we provide a simple overview of the techniques generally used in structural studies of membrane proteins by solution NMR, with experimental examples of a helical membrane protein, caveolin 3. Detergent screening is usually employed as the first step and the selection of appropriate detergent is the most important for successful approach to membrane proteins. Various tools can then be applied as specialized NMR techniques in solution that include sample deteuration, amino-acid selective isotope labeling, residual dipolar coupling, and paramagnetic relaxation enhancement.

EFFECT OF PARAMAGNETIC Co$_{67}$Cr$_{33}$ UNDERLAYER ON CRYSTALLOGRAPHIC AND MAGNETIC CHARACTERISTICS OF Co-Cr-Ta LAYERS IN PERPENDICULAR MAGNETIC RECORDING MEDIA

  • Kim, Kyung-Hwan;Nakagawa, Shigeki;Takayama, Seiryu;Naoe, Masahiko
    • Journal of the Korean institute of surface engineering
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    • v.29 no.6
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    • pp.847-850
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    • 1996
  • The bi-layered films composed of Co-Cr-Ta layers and paramagnetic $Co_{67}Cr_{33}$ underlayer were deposited by suing Facing Targets Sputtering(FTS). The effects of $Co_{67}Cr_{33}$ underlayer on the crystallographic and magnetic characteristics of the Co-Cr-Ta layer deposited on the underlayer was investigated. The diffraction intensity $I_{p(002)}$ of Co-Cr-Ta layers on the $Co_{67}Cr_{33}$ layer was stronger than that of single layer and Co-Cr-Ta/Ti double layer. Therefore, the crystallinity of Co-Cr-Ta layer was imporved by the $Co_{67}Cr_{33}$ underlayer rather than Ti ones. However, te coercivity H$_{c\bot}$ of Co-Cr-Ta layers deposited on $Co_{67}Cr_{33}$ underlayer was as low as 250 Oe even at substrate temperature of $220^{\circ}C$. This H$_{c\bot}$ decrease seems to be attributed to the effect of the $Co_{67}Cr_{33}$ underlayer as well as interval time between deposition of the underlayer and the Co-Cr-Ta layer.

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Room-temperature Ferromagnetism in Fe-doped Reduced TiO2-δ (산소 결핍에 따른 Fe가 도핑된 TiO2-δ의 상온 강자성 현상에 관한 연구)

  • Lee, H.M.;Kim, C.S.;Uhm, Y.R.;Rhee, C.K.
    • Journal of Powder Materials
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    • v.13 no.6 s.59
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    • pp.401-407
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    • 2006
  • Effects of oxygen deficiency on the room temperature ferromagnetism in Fe-doped reduced $TiO_2$ have been investigated by comparing the air-annealed $Ti_{0.97}Fe_{0.03}O_2$ compound with secondly post-annealed one in vacuum ambience. The air-annealed sample showed a paramagnetic behavior at room temperature. However, when the sample was further annealed in vacuum, a strongly enhanced ferromagnetic behavior was observed at same temperature. $M{\"{o}}ssbauer$ spectra of air-annealed sample at 295K showed a single doublet of $Fe^{3+}$, suggesting that the Fe ions are paramagnetic. On the other hand, the absorption spectra after vacuum-annealing exhibited two doublets, in which one is the same component with air-annealed sample and the other is new doublet corresponding to $Fe^{2+}$ state. This result suggests that the occurrence of ferromagnetism in reduced sample may be interpreted as the contribution of unquenched orbital moment of $Fe^{2+}$ ions.