• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.21 no.10
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• pp.923-929
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• 2008

On the piezoelectric polymer, PVDF (poly vinylidene fluoride), the transparent conducting oxide (TCO) electrode material thin film was deposited by roll to roll sputtering process mentioned as a mass product-friendly process for display application. The deposition method for ITO Indium Tin Oxides) as our TCO was DC magnetron sputtering optimized for polymer substrate with the low process temperature. As a result, a high transparent and good conductive ITO/PVDF film was prepared. During the process, especially, the gas mixture ratio of Ar and Oxygen was concluded as an important factor for determining the film's physical properties. There were the optimum ranges for process conditions of mixture gas ratio for ITO/PVDF From these results, the doping mechanism between the oxygen atom and the metal element, Indium or Tin was highly influenced by oxygen partial pressure condition during the deposition process at ambient temperature, which gives the conductivity to oxide electrode, as generally accepted. With our studies, the process windows of TCO for display and other application can be expected.

• Membrane Journal
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• v.23 no.4
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• pp.312-318
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• 2013

Poly vinylidene fluoride (PVDF) hollow fiber membranes were hydrophilized using polyethylenimine (PEI) and p-xylylene dichloride (XDC), and poly(vinyl alcohol) (PVA) and poly (acrylic acid -co- maleic acid) (PAM) mixed solutions by varying the concentration of PAM were coated onto PVDF membrane surface. The surface coating was verified by the observation of scanning electron microscope (SEM) and the permselective characteristcs of the resulting composite membranes were tested for 90 wt% aqueous ethanol solution by the pervaporation technique. The effects of the corsslinking agent concentraion, the temperature of feed solution, and the reaction temperature on the flux and separation factors were measured. Typically, the flux, $1,480g/m^2hr$ at the reaction temperature $100^{\circ}C$, PAM 3 wt%, feed temperature $70^{\circ}C$ was obtained, on the other hand, for the separation factor, ${\alpha}_{W/E}=82$ at the conditions of the reaction temperature $100^{\circ}C$, PAM 15 wt% and feed temperature $25^{\circ}C$ was shown.

• Proceedings of the Korean Fiber Society Conference
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• 2003.10b
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• pp.193-194
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• 2003

전기활성 고분자인 poly(vinylidene fluoride)(PVDF)를 전기 비활성 고분자와 블렌드시키는 경우 어떤 블렌드계에서는 용융 온도 이상에서 LCST(lower critical solution temperature) 상분리 거동을 나타내는데[1,2], 이때 외부 전장을 가해주면 이들의 상분리 거동에 영향을 미칠 수 있다[3]. PVDF와 블렌딩시켰을 때 LCST 상분리 거동을 나타내는 고분자로는 poly(methyl methacrylate), poly(ethyl methacrylate), poly(1,4-butylene adipate) (PBA) 등이 있다[l,3]. (중략)

• 한국신재생에너지학회:학술대회논문집
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• 2011.05a
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• pp.214.2-214.2
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• 2011

In this work, porous carbon based electrodes are prepared by carbonization using poly(vinylidene fluoride) (PVDF)/carbon nanotube (CNT) composites to further increase the specific capacitance for supercapacitors. Electrode materials investigate the aspects of specific capacitance, pore size distribution and surface area: influence of carbonization temperatures of PVDF/CNT composites. The electrochemical properties are investigated by cyclic voltammetry, impedance spectra, and galvanostatic charge-discharge performance with in $TEABF_4$ (tetraethylammonium tetrafluoroborate)/acetonitrile as non-aqueous electrolyte. From the results, the highest value of specific capacitance of ~101 $F{\cdot}g^{-1}$ is obtained for the samples carbonized at $600^{\circ}C$. Furthermore, pore size of samples control be low 7 nm through carbonization process. It is suggested that micropores significantly contribute to the specific capacitance, resulting from improved charge transfer.

• Proceedings of the Korean Fiber Society Conference
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• 1998.04a
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• pp.54-57
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• 1998

Recently, Manley's group published several papers on the blend of PVDF and poly(1, 4-butylene adipate) (PBA) chosen as a model system of somicrystallineisemicrystalline polymer blend.[1-4]. This blend system has several advantages over the other PVDF/semicrystalline polymer blends.(omitted)

• Composites Research
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• v.33 no.1
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• pp.19-24
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• 2020

In this paper, the microwave irradiation process was conducted during the Poly(vinylidene fluoride) (PVDF) nano-composite film fabrication process to analyze how the β-crystalline is increased. TiO₂ was added as a nanoparticle reinforcement to further improve the β-crystalline conformation of the PVDF films by van der Waals force due to the difference of electronegativity between PVDF and the metal oxide nanoparticle. The crystalline conformation of the fabricated films was analyzed by X-ray diffraction and Fourier transform infrared spectroscopy. According to these analysis results, it was confirmed that the microwave irradiation process during the solvent evaporation process increases the crystallinity of the PVDF films, and more β-crystalline can be obtained after additional film stretching process. It was also found that the PVDF nano-composite films with the metal oxide have relatively higher β-crystalline conformation rather than the neat PVDF films.

• Journal of Electrochemical Science and Technology
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• v.9 no.1
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• pp.1-8
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• 2018

The effect of mixing ratio on the corrosion protection of carbon steel coated by a film composed of poly(vinylidene) fluoride (PVDF) and poly(methyl methacrylate) (PMMA) was examined using electrochemical impedance spectroscopy. Surface crystallization behavior and thermal properties of the PVDF/PMMA coated carbon steel were evaluated using polarized optical microscopy and differential scanning calorimetry, respectively. A Maltese cross-pattern spherulite crystal was observed in the PVDF/PMMA coating film, which became more apparent with increasing PVDF content. The highest corrosion protection performance was achieved with 60 wt.% PVDF-coated carbon steel, and delamination and corrosion reactions were observed for 20 wt.% PVDF-coated carbon steel. Further, corrosion protection performance with an amorphous/crystal mixture (PVDF/PMMA, 60/40 (w/w)) was better than those observed in the amorphous domain and the perfect-crystal domain of the PVDF/PMMA blended coating system.

• Journal of the Korean Society of Safety
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• v.19 no.3 s.67
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• pp.26-31
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• 2004

The radiation-induced changes taking place in poly(vinylidene fluoride) (PVDF) exposed to $^{60}Co$ $\gamma-ray$ irradiation were investigated in correlation with the applied doses. Samples were irradiated in air at room temperature by $^{60}Co$ $\gamma-ray$ to doses in the range of 200 to 1000kGy. Various properties of the irradiated PVDF were studied using FTIR, differential scanning calorimetry (DSC), gel fraction and elongation. $^{60}Co\gamma-ray$ irradiation was found to induce changes in chemical, thermal, mechanical and structural properties of PVDF and such changes vary depending on the radiation dose.

• Membrane Journal
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• v.27 no.2
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• pp.189-198
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• 2017

In this study, we used thermally induced phase separation (TIPS) to produce water treatment membrane and poly(vinylidene fluoride) (PVDF), silica with excellent mechanical properties and chemical resistance to evaluate characterization of the membrane. The diluents used for the characterization were dioctyl phthalate (DOP) and dibutyl phthalate (DBP). We observed the crystallization temperature, cloud point and SEM images to see the manufacture conditions according to the ratio of PVDF and silica. The crystallization temperature and cloud point increased with the contents of silica. Through the phase diagram drawn from these results, the conditions for the preparation of the membrane confirmed.

• Fashion & Textile Research Journal
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• v.13 no.2
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• pp.279-284
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• 2011

In this study, the process of preparation nonwoven with coated carbon nano fibers (CNFs) /poly(vinylidene fluoride-co-hexafluoropropylene) (PVDF-HFP) composite solution is described. The various contents of CNFs/PVDF-HFP composite coated nonwoven were prepared and characterized by morphological, mechanical, and electrical methods. Nonwovens are coated with CNFs/PVDF-HFP composite solution and decreased the pick up ratio with increasing CNFs contents in range from 0% to 16%. In the results of SEM images, it was clear that the CNFs were evenly distributed in coated nonwoven by SEM images, the existence of CNFs in coated nonwoven was confirmed regularly. The mechanical properties of various contents of CNFs/PVDF-HFP coated nonwoven were examined. The tensile linearity and compression linearity increased with increasing CNFs contents. The electrical properties of the CNFs/PVDF-HFP coated nonwoven increased with increasing CNFs contents.