• Proceedings of the Materials Research Society of Korea Conference
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• 2005.05a
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• pp.194-194
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• 2005

• Proceedings of the Membrane Society of Korea Conference
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• 2002.11a
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• pp.146-149
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• 2002

• Membrane Journal
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• v.16 no.3
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• pp.235-239
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• 2006

This study illustrated the results of pervaporation separation using crosslinked poly(vinyl alcohol) (PVA) with poly(styrene sulfonic acid-co-maleic acid) (PSSA-MA) for water-ethanol system at 25, 35, and $45^{\circ}C$. The contents of the crosslinking agents were 7, 9, and ll wt% against PVA and the feed compositions of 50, 20, 10 and 4.4% in water were investigated. Typical trends of permeability and separation factor in pervaporation were observed for both the crosslinking agents and operating temperatures. For water : ethanol = 10 : 90, and at $45^{\circ}C$, PSSA-MA 11 wt% membrane showed the permeability $58.92g/m^2{\cdot}hr$ and the separation factor 12003 respectively.

• Polymer(Korea)
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• v.35 no.4
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• pp.296-301
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• 2011

This study focuses on the investigation of the impregnation of poly (vinyl alcohol) (PVA) crosslinked with poly(styrene sulfonic acid-co-maleic acid) (PSSA-MA) to porous polyethylene membrane for the fuel cell application. The membranes were characterized by the measurements of the water content, contact angle, FTIR spectra, thermal gravimetric analysis, ion exchange capacity, proton conductivity, methanol permeability and elastic modulus. The existence of hydrophilic moieties in the impregnated membranes was confirmed by contact angle and FTIR measurements. The impregnated PVA/PSSAMA(90:10) membrane exhibited a higher ion exchange capacity (1.2 meq./g dry membrane) than Nafion membrane (0.91 meq./g dry membrane). Through the elastic modulus measurement, the dimensional stability of the resulting membranes was expected to increase higher than the polyethylene membranes. The methanol crossover and water content decreased even if the PSSA-MA content increased due to the reduction of the free volume.

• Journal of the Korean Electrochemical Society
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• v.12 no.2
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• pp.173-180
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• 2009

In order to develop a novel polymer electrolyte membrane for direct methanol fuel cell (DMFC), styrene monomer was graft-polymerized into poly(tetrafluoroethylene perfluoropropyl vinyl ether) (PFA) film followed by a sulfonation reaction. The graft polymerization was prepared by the $\Upsilon$-ray radiation-grafting method. Subsequently, sulfonation of the radiation-grafted film was carried out in a chlorosulfonic acid/1,2-dichloroethane (2 v/v%) solution. The chemical, physical, electrochemical and morphological properties of the radiation-grafted membranes (PFA-g-PSSA) were characterized by fourier transform infrared spectroscopy (FTIR) and scanning electron microscopy (SEM). The water uptake, ionic conductivity, and methanol permeability of the PFA-g-PSSA membrane were also measured. The cell performances of MEA prepared with the PFA-g-PSSA membranes were evaluated and the cell resistances were measured by an impedance analyzer. The MEA using PFA-g-PSSA membranes showed superior performance for DMFCs in comparison with the commercial Nafion 112 membrane.

• Membrane Journal
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• v.20 no.1
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• pp.1-7
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• 2010

A graft copolymer, i.e. poly(vinylidene fluoride-co-chlorotrifluoroethylene )-g-poly(styrene sulfonic acid) (P(VDF-co-CTFE)-g-PSSA) with 47 wt% of PSSA was synthesized via atom transfer radical polymerization (ATRP). This copolymer was combined with titanium isopropoxide (TTIP) to produce graft copolymer/$TiO_2$ nanocomposite membranes via sol-gel process. $TiO_2$ precursor (TTIP) was selectively incorporated into the hydrophilic PSSA domains of the graft copolymer and grown to form $TiO_2$ nanoparticles, as confirmed by FT-IR and UV-visible spectroscopy. Water uptake and ion exchange capacity (IEC) decreased with TTIP contents due to the decrease in number of sulfonic acid in the membranes. At 5 wt% of TTIP, the mechanical properties of membranes increased while maintaining the proton conductivity.

• Composites Research
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• v.24 no.6
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• pp.1-6
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• 2011

A new water-soluble and self-doped poly(styrenesulfonic acid-graft-aniline), PSSA-g-PANI, for dispersing carbon nanotubes (CNTs) in water was synthesized and its ability to stabilize aqueous CNT dispersions was examined. It was observed that the PANI in PSSA-g-PANI, which has benzoid and quinoid structure, was strongly adsorbed onto the nanotube surface via a strong ${\pi}-{\pi}$ interaction, and thus only gentle sonication causes exfoliation of CNT ropes to small bundles and the long-term stability of their resulting dispersions was much better than commercial surfactants. Furthermore, when thin films of PSSA-g-PANI/CNT are prepared from aqueous dispersion and their electrical conductivities are measured by the four probe technique, it is observed that their conductivities are in the range of 1.5-2.5 S/cm.

• Macromolecular Research
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• v.15 no.5
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• pp.412-417
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• 2007

In the present study, crosslinked poly(vinyl alcohol) (PVA) membranes were prepared at different temperatures using poly(styrene sulfonic acid-co-maleic acid) (PSSA_MA) (PVA:PSSA_MA = 1:9). The hybrid mem-branes were prepared by varying the TEOS content between 5 and 30 wt%. The PSSA_MA was used both as a crosslinking agent and the hydrophilic group donor ($-SO_3H$ and/or-COOH). The proton conductivity increased with up to 20 wt% TEOS, but decreased above this level, although the water content decreased with increasing TEOS content. This result suggests that the silica doped into the membrane improved the formation of proton-conduction pathways due to the absorption of molecular water. The PVA/PSSA_MA/Silica containing TEOS 20% showed both high proton conductivity (0.026 S/cm at $90^{\circ}C$) and low methanol permeability ($5.55{\times}10^{-7}cm^2/s$).

• Membrane Journal
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• v.25 no.5
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• pp.440-446
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• 2015

Nanofiltration composite membranes were prepared through the ion exchange polymers coating onto the porous microfiltration polyethylene (PE) membrane surfaces the salting-out and phase separated and pressurization (PSP) methods. The existence of coating on the surfaces was confirmed by the scanning electronic microscopy. The resulting membranes were characterized under the various conditions, such as the coating material, coating time, ionic strength etc., in terms of flux and rejection for NaCl 100 ppm solution. Under the same coating conditions of 10,000 ppm coating solution concentration and 3 atm coating pressure for both the coating materials of PEI and PSSA_MA, the flux 91.2 LMH and rejection 64.6% were obtained for PEI whereas 122.7 LMH and 38.1% were observed for PSSA_MA. From this study, it may be concluded that the composite membrane preparation is possible.

• Polymer(Korea)
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• v.34 no.6
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• pp.540-546
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• 2010

In this manuscript, in order to reduce methanol permeability and, at the same time, to increase proton conductivity THS-PSA containing silica compound, responsible for methanol permeability reduction, and sulfonic acid, responsible for proton conductivity enhancement, was applied onto PVA/PSSA-MA membranes. And in order to improve durability, the resulting membranes, PVA/PSSAMA/THS-PSA, were exposed to 500ppm F2 gas at varying reaction times. The surface-fluorinated membranes were characterized through the measurement of contact angles, thermo-gravimetric analysis, and X-ray photoelectron spectroscopy to observe the physico-chemical changes. For the evaluation of the electro-chemical changes in the resulting membranes, its water contents, ion exchange capacity, proton conductivity, and methanol permeability were measured and then compared with the commercial membrane, Nafion 115. Finally, the membran electrode assembly(MEA) was prepared and the cell voltage against the current density was measured. As fluorination time increased, the contents of F2 increased up to maximum 4.3% and to depth of 50 nm. At 60 min of fluorination, the proton conductivity was 0.036 S/cm, larger than Nafion 115 at 0.024 S/cm, and the methanol permeability was $9.26E-08cm^2/s$, less than Nafion 115 at $1.17E-06cm^2/s$.