• 제목/요약/키워드: PROCESS ADDITIVES

검색결과 516건 처리시간 0.028초

The Observation of Nucleation & Growth during Water Vapor Induced Phase Inversion of Chlorinated Poly(vinyl chloride) Solution using SALS

  • Jang, Jae Young;Lee, Young Moo;Kang, Jong Seok
    • Korean Membrane Journal
    • /
    • 제6권1호
    • /
    • pp.61-69
    • /
    • 2004
  • Small angle light scattering (SALS) and field emission scanning electron microscope (FE-SEM) have been used to investigate the effects of alcohol on phase separation of chlorinated poly(vinyl chloride) (CPVC)/tetrahydrofuran (THF)/alcohol (9/61/30 wt%) solution during water vapor induced phase separation. A typical scattering pattern of nucleation & growth (NG) was observed for all casting solutions of CPVC/THF/alcohol. In the case of the phase separation of CPVC dope solution containing 30 wt% ethanol or n-propanol, the demixing with NG was observed to be heterogeneous. Meanwhile, the phase separation of CPVC dope solution with 30 wt% n-butanol was found to be predominantly homogeneous NG. Although the different phase separation behavior of NG was observed with types of alcohol additives, the resultant surface morphology had no remarkable differences. That is, even though the NG process by water vapor is either homogeneous or heterogeneous, this difference does not play a main role on the final surface morphology. However, it was estimated from the result of hydraulic flux that the phase separation by homogeneous NG provided the membrane geometry with lower resistance in comparison with that by heterogeneous one.

수지의 함량 변화에 따른 잉크 비히클의 유변학적 특성에 관한 연구 (A Study for The Effect of Variation of Resin Content on The Rheological Characteristics of Ink Vehicle)

  • 방종관;김성빈;김태환;이규일
    • 한국인쇄학회지
    • /
    • 제23권2호
    • /
    • pp.117-128
    • /
    • 2005
  • Printing inks are basically dispersions of solid pigment particles in a vehicle. Pigment flocculation and/or colloidal aggregates created by thixotrope additives form a three- dimensional network in the inks. This structure complicates the flow behaviour of inks. However, if the internal structure is formed under control, the printing process will benefit from it because the ink must satify rheological requirements over a very wide range of shear conditions. The presence of internal structure results in the following prominent non-Newtonian rheological properties: viscoelasticity, yield stress, shear thinning and thixotropy. If the components of printing inks were changed, the rheological characteristics such as viscosity, yield stress, viscoelasticity and tack value were considerably varied. Thus, in this paper, the effects of changing the content of rosin modified phenolic resin on rheological properties of the vehicle will be studied. For that, the rheological properties were found by flow, yield stress, creep and oscillation measurements using Bohlin C-VOR Rotational Rheometer. And Emulsion rheology and its microstructure will be investigated.

  • PDF

동결건조법에 있어 Nocardia mediterranei의 세포막 손상과 재수화 방법에 따른 생존도 (Membrane Injury of Nocardia mediterranei upon Lyophilization and Viability Depending on Rehydration Methods)

  • 이동희;이노운;최남희
    • 한국미생물·생명공학회지
    • /
    • 제20권3호
    • /
    • pp.243-248
    • /
    • 1992
  • 동결건조법이 Nocardia mediterranei의 세포막 손상에 미치는 영향을 3H-thymidine 표지에 의한 DNA 유출 방법과 전자현미경으로 조사하였으며, 재수화 과정이 생존도에 미치는 영향을 연구하였다. 그 결과 N.mediterranei의 동결건조시 세포벽과 세포막의 손상이 세포 사멸의 원인으로 판명되었다.

  • PDF

탄화붕소 소결 거동 연구를 위한 율속제어소결의 적용 (Application of rate-controlled sintering into the study of sintering behavior of boron carbide)

  • 이혁재
    • 한국결정성장학회지
    • /
    • 제25권1호
    • /
    • pp.6-12
    • /
    • 2015
  • 율속제어소결은 소결 공정 중 실시간으로 측정되는 시편의 팽창/수축거동을 이용해 일정한 수축거동을 하도록 로의 파워를 조정하는 소결방법으로, 온도를 조절하기 위해 로의 파워를 제어하는 일반적인 소결에 비해 시편의 소결 과정을 세밀히 제어할 수 있으며, 특히 소결공정의 최적화를 이룰 수 있는 장점이 있다. 본 연구에서는 탄화붕소의 소결에 율속 제어소결을 적용해 각 공정변수의 조절에 따른 소결온도 및 입자성장의 변화를 조사하여 그 상관관계를 규명하고 이를 기존의 이론에 맞추어 해석함으로써 율속제어소결을 어떻게 소결공정 최적화에 이용할 수 있는지 그 가능성을 알아보았으며 이를 통해 향후 미지 소재의 소결공정에 율속제어공정을 어떻게 적용할 수 있는지 고찰해 보았다.

식품안전 위해요인에 대한 소비자 인식 : 질적연구를 통한 접근 (A Qualitative Study on Consumers' Perceptions of Food Safety Risk Factors)

  • 윤여임;김경자
    • 가정과삶의질연구
    • /
    • 제31권4호
    • /
    • pp.15-31
    • /
    • 2013
  • Consumers are quite worried about food safety because food is one of the most important necessities in everyday life. Many studies have been conducted regarding the food safety issues, however, most researches have focused only on a limited range of risk factors and used only quantitative survey methods. The purpose of this study was to investigate consumers' perceptions of the risky components of food safety and how the perceptions have been formed. For this study in-depth interviews were conducted. For the interviewees, nine housewives, who are in their 30s to 50s, were selected taking into consideration their age, education level, number of children, and employment status. Results showed that the risk factors many consumers worried about were agricultural pesticides, MSG, food additives, GMO, Mad Cow Disease, preservatives, and growth hormones, etc. Consumers were worried about the risk of the retail process the most because they thought it was not informed and controlled well. Consumers tend to worry much more when the risks are involuntary, uncontrollable, unreliable, and have a gradual negative effect. Some of the food safety-oriented behaviors of consumers were also investigated.

Ni/Cu 금속전극 태양전지의 Ni electroless plating에 관한 연구 (The Research of Ni Electroless Plating for Ni/Cu Front Metal Solar Cells)

  • 이재두;김민정;권혁용;이수홍
    • 한국전기전자재료학회논문지
    • /
    • 제24권4호
    • /
    • pp.328-332
    • /
    • 2011
  • The formation of front metal contact silicon solar cells is required for low cost, low contact resistance to silicon surface. One of the front metal contacts is Ni/Cu plating that it is available to simply and inexpensive production to apply mass production. Ni is shown to be a suitable barrier to Cu diffusion into the silicon. The process of Ni electroless plating on front silicon surface is performed using a chemical bath. Additives and buffer agents such as ammonium chloride is added to maintain the stability and pH control of the bath. Ni deposition rate is found to vary with temperature, time, utilization of bath. The experimental result shown that Ni layer by SEM (scanning electron microscopy) and EDX analysis. Finally, plated Ni/Cu contact solar cell result in an efficiency of 17.69% on $2{\times}2\;cm^2$, Cz wafer.

SPG 막유화법을 이용한 고분자 입자 제조기술의 동향 (Technology Trend for the Preparation of Polymeric Particles by SPG Technique)

  • 이상국;김성욱;최경호;임은희
    • Elastomers and Composites
    • /
    • 제44권3호
    • /
    • pp.222-231
    • /
    • 2009
  • 단분산이면서 마이크로 크기의 입자로 쉽게 조절이 가능한 SPG (Shirasu porous glass) 막유화법이 최근 각광을 받고 있다. SPG 막유화법은 다중에멀젼, 단분산, 다양한 형태 등을 쉽게 제조할 수 있는 장점을 가지고 있어서 기능성 입자를 만드는데 적합한 방법으로 최근 적용분야로는 토너입자, 식품첨가제, 약물전달 등으로 적용분야가 넓다. SPG 막유화법에서 입자크기 및 형태 조절 요소로는 개시제, 첨가제, 단량체, 가교제, 중합금지제 등이 있으며, SPG의 장점인 단분산을 싼 단가로 대량생산에 접목시킬 수 있기 때문에 여러 분야에서 다양한 접근이 가능하다.

SiC 필러 함량이 탄소 함유 Polysiloxane으로부터 제조된 고기공률 탄화규소 세라믹스의 미세조직과 꺾임강도에 미치는 영향 (Effect of SiC Filler Content on Microstructure and Flexural Strength of Highly Porous SiC Ceramics Fabricated from Carbon-Filled Polysiloxane)

  • 엄정혜;김영욱;송인혁
    • 한국세라믹학회지
    • /
    • 제49권6호
    • /
    • pp.625-630
    • /
    • 2012
  • Highly porous silicon carbide (SiC) ceramics were fabricated from polysiloxane, SiC and carbon black fillers, AlN-$Y_2O_3$ additives, and poly (ether-co-octene) (PEOc) and expandable microsphere templates. Powder mixtures with a fixed PEOc content (30 wt%) and varying SiC filler contents from 0-21 wt% were compression-molded. During the pyrolysis process, the polysiloxane was converted to SiOC, the PEOc generated a considerable degree of interconnected porosity, and the expandable microspheres generated fine cells. The polysiloxane-derived SiOC and carbon black reacted and synthesized nano-sized SiC with a carbothermal reduction during a heat-treatment. Subsequent sintering of the compacts in a nitrogen atmosphere produced highly porous SiC ceramics with porosities ranging from 78 % to 82 % and a flexura lstrength of up to ~7 MPa.

Support vector machine for prediction of the compressive strength of no-slump concrete

  • Sobhani, J.;Khanzadi, M.;Movahedian, A.H.
    • Computers and Concrete
    • /
    • 제11권4호
    • /
    • pp.337-350
    • /
    • 2013
  • The sensitivity of compressive strength of no-slump concrete to its ingredient materials and proportions, necessitate the use of robust models to guarantee both estimation and generalization features. It was known that the problem of compressive strength prediction owes high degree of complexity and uncertainty due to the variable nature of materials, workmanship quality, etc. Moreover, using the chemical and mineral additives, superimposes the problem's complexity. Traditionally this property of concrete is predicted by conventional linear or nonlinear regression models. In general, these models comprise lower accuracy and in most cases they fail to meet the extrapolation accuracy and generalization requirements. Recently, artificial intelligence-based robust systems have been successfully implemented in this area. In this regard, this paper aims to investigate the use of optimized support vector machine (SVM) to predict the compressive strength of no-slump concrete and compare with optimized neural network (ANN). The results showed that after optimization process, both models are applicable for prediction purposes with similar high-qualities of estimation and generalization norms; however, it was indicated that optimization and modeling with SVM is very rapid than ANN models.

첨가제 변화에 따른 Ni0.8Zn0.2Fe2O2 의 미세구조와 자기적 특성 (The Effects of Additives on Microstructure and Magnetic Properties of Ni0.8Zn0.2Fe2O2)

  • 오영우;이선학;이해연;김현식
    • 한국전기전자재료학회논문지
    • /
    • 제15권5호
    • /
    • pp.406-411
    • /
    • 2002
  • Ni-Zn ferrite is required to have predominant and stable characteristics in the range of high frequency for the power line communication, so that microstructures and magnetic properties such as power loss and initial permeability in $Ni_{0.8}Zn_{0.2}Fe_2O_4$ were investigated in terms of variable $Bi_2O_3,CaO$ and $V_2O_5$ contents. $Bi_2O_3$ and $V_2O_5$ liquid phase created during sintering process promoted sintering and grain growth but much of the closed pore existed in the grains. The grain size of the specimens with $V_2O_5$ of over 0.5 wt% decreased as the result of "pinning effect"and the resonance frequency increased with CaO of 0.3we%. The high initial permeability of 81.52%, resonance frequency of 17.05 MHz and low power loss of 17,858 kW/$\textrm{m}^3$ were obtained from the samples with $Bi_2O_3$ of 0.5, CaO of 0.3, and $V_2O_5$ of 0.7 wt%.