• Title/Summary/Keyword: PROCESS ADDITIVES

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Fabrication and Physical Properties of Honeycomb Type Cordierite Ceramic Filter Using Fly-Ash (플라이 애쉬를 이용한 코디어라이트 세라믹 하니컴 필터 제조 및 물성)

  • Kim, Sung-Jin;Bang, Hee-Gon;Park, Sang-Yeup
    • Journal of the Korean Ceramic Society
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    • v.43 no.6 s.289
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    • pp.351-357
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    • 2006
  • The fabrication process of the honeycomb filter was investigated using synthesized cordierite with the addition of pore former and extrusion additives (either organic matter or graphite). Also, the effect of additives on the resultant properties of honeycomb filter such as porosity, thermal expansion coefficient and mechanical strength were investigated. With increasing the organic matter up to 10 wt%, porosity was increased but compressive strength was decreased. With increasing the graphite content, however, both porosity and compressive strength were increased. The specimen with an optimum processing condition (C-17A30G, sintering at $1150^{\circ}C$) was demonstrated 59% in porosity, 69 MPa in compressive strength, and $2.4{\times}10^{-6}/^{\circ}C\;(25{\sim}1000^{\circ}C$) in thermal expansion coefficient, which physical properties are appropriate for the honeycomb filter applications.

A Study on the Recycling of Metals and Removal of Organics By Electrochemical Treatment of Mixed Waste Water of Surface Finishing Industry (표면처리 공정에서 발생하는 혼합 폐수의 전기화학적 처리에 의한 중금속의 재활용 및 유기물의 제거에 관한 연구)

  • 김영석;이중배
    • Journal of Surface Science and Engineering
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    • v.36 no.2
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    • pp.184-193
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    • 2003
  • Cyclic sweep voltametry was performed to investigate the electrochemical behavior of heavy metal ions and the organic additives in surface finishing process. And electrolysis using parallel plate electrode electrolyzer was carried out to simulate the treatment of real waste water. Results showed that more than 99 percent of Cu was recovered and selective recovery of Cu in mixed waste water was possible, but the possibility of economical recovery of Ni and Cr were very low due to the evolution of hydrogen gas. Electrochemical oxidation of cyanide and organic additives on anode showed very excellent removal rate. The complete removal of several hundred ppm of cynide was possible within several tens minutes and organics within 2 or 3 hours. Even in case of concentrate waste water, the complete removal of COD by using NaCl and air stirring seemed to be possible.

Effect of MgO on Microstructural Evolution of Alumina Prepared from Hydrosol-Gel Process of Boehmite in Plaster Mold (석고몰드속에서 Boehmite의 Hydrosol-Gel로부터 제조된 알루미나의 미세구조에 미치는 M\ulcorner의 영향)

  • 오경영;정창주
    • Journal of the Korean Ceramic Society
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    • v.30 no.12
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    • pp.1029-1038
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    • 1993
  • The microstructures of aluminas, included of dissolved CaO as $\alpha$-alumina seeded pseudo-boehmite hydrosol was gelled in plaster mold and doped of MgO as dipping of calcines(120$0^{\circ}C$-2h) into Mg-nitrate solution, were compared to the one of which additives are excluded during the gellation. It was formed the boundary layer of 300~350${\mu}{\textrm}{m}$ distance from surface to the inside, containing of approximately 500ppm CaO by dissolved Ca from plaster mold. As the MgO addition to the boundary layer with dissolved CaO, the microstructure of the layer was uniformed and inhibited the grian growth, compared to one of that additives be excluded specimen and of MgO doped-inside region. This result was considered as abnormal grain growth and effect of flat boundary formation be appeared by effects of dissolved CaO, were decreased by MgO co-doping.

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Measurement of Flash Points of Epoxy Resin Solutions by Using Additives (첨가제 사용에 의한 Epoxy Resin 용액의 인화점 측정)

  • Ha, Dong-Myeong
    • Journal of the Korean Society of Safety
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    • v.22 no.3 s.81
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    • pp.22-27
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    • 2007
  • The knowledge of the flash point of the various liquid substances is required because of process safety and control in industrial fire protection. The epoxy resin is one of versatile resins that has wide selection of using curing agents and additives to achieve various applications such as coatings, adhesives, interior materials, reinforced plastics and electrical insulation. In this study, the lower flash points for p-xylene+epoxy resin, o-xylene+epoxy resin and n-butanol+epoxy resin systems were measured by using Pensky-Martens closed cup tester. The lower flash points for p-xylene+epoxy resin, o-xylene+epoxy resin and n-butanol+epoxy resin systems rapidly increased 80wt%, 90wt% and 95wt% of epoxy resin concentration, respectively. This results serve as a guide to estimate flash point of any epoxy resin solution.

Effects of Additives and Hot-Pressing Conditions on the Surface and Performance of MEAs for PEMFCs (첨가제를 이용한 촉매슬러리 조성 안정화 및 열-압착 공정 최적화 통한 PEMFC용 MEA 개발)

  • Jang, Hyun-Sook;Cho, Eun-Ae
    • Journal of Hydrogen and New Energy
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    • v.21 no.5
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    • pp.398-404
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    • 2010
  • Process conditions for MEA fabrications have significant effects on properties and performance of the MEAs for PEMFCs. In this study, effects of additives on the surface properties of the MEA was investigated to improve homogeneity of the coated catalyst layer. Another parameter that affects on characteristics of the MEAs is hot-pressing condition. Hot pressing condition was optimized by using DOE (design of experiment) method.

Extinguishment of n-heptane Pool Fire by Water Mist Containing Alkali Metal Agent (알칼리 금속염을 함유한 미분무수의 헵탄 Pool Fire 소화)

  • Park, Jae-Man;Shin, Chang-Sub
    • Journal of the Korean Society of Safety
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    • v.20 no.3 s.71
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    • pp.105-111
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    • 2005
  • An experimental study is performed for extinguishing of n-heptane pool fire by water mist containing potassium acetate as a fire suppression additive. Water mist was generated by a single pressure nozzle in a small-scale chamber. The drop size distribution of water mist was measured using laser diffraction(Malvern particle sizer). The flame temperature, oxygen concentration and carbon monoxide concentration were measured. In case of using additives, the fire extinguishing time was shorter than that of pure water at a given discharge pressure and it was because the momentum of a water droplet containing additives was increased. And also dissociated metal atoms, potassium, were reacted as a scavenger of the major radical species OH, H which were generated for combustion process. Moreover, at a high pressure of 4MPa, the fire was extinguished through blowing effect as well as primary extinguishing mechanisms.

Improvement of DeNOx efficiency of SNCR Process with Chemical Additives in Urea Soution (환원제로 우레아를 사용하는 SNCR 공정에서 첨가제 적용에 따른 탈질효율 향상 연구)

  • Yoo, Kyung Seun;Park, Sung Woo
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.18 no.10
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    • pp.663-668
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    • 2017
  • Dye waste water generated in the dye industry is categorized as hazardous waste water that requires appropriate treatment. The pilot scale experimental trials were carried out using dye waste water as an effective additive for the selective non-catalytic reduction (SNCR) of NOx in combustion flue gases. The additives were waste liquor obtained from the dye industry and several purification steps were taken to make a standardized reagents. The dye waste water was shown to possess valuable SNCR qualities (at least 87% NOx reduction efficiency) considering its availability as a waste product, which has to be strictly treated, and have little effects on CO removal. The results indicated that the NO removal efficiency increased first and then decreased with increasing temperature within $750-1150^{\circ}C$. The maximum NO reduction efficiency was approximately 87% at the optimal reaction temperature. A more than 10% increase in NO reduction was achieved in the presence of 1000 ppm Na-additives (dye waste water) compared to that without additives. The Na-based additives have also a significant promoting effect on $N_2O$ reduction and within the SNCR temperature window.

Fundamental study on sustainable treatment system of mine water using magnetized solid catalyst

  • Mukuta, Chisato;Akiyama, Yoko
    • Progress in Superconductivity and Cryogenics
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    • v.21 no.2
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    • pp.15-21
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    • 2019
  • In the mine exploration sites, sustainable treatment system of mine water with energy saving and minimized chemical additives is required. Since most of the mine water contains highly-concentrated ferrous ion, it is necessary to study on the removal method of iron ions. We propose the system consisting of two processes; precipitation process by air oxidation using solid catalyst-modified magnetite and separation process combining gravitational sedimentation and magnetic separation using a permanent magnet. Firstly, in the precipitation process (a former process of the system), we succeeded to prepare solid catalyst-modified magnetite. Air oxidation using solid catalyst-modified magnetite using $Fe_2(SO_4)_3$ as a starting material showed high iron removal capability. Secondly, in the separation process (latter process of the system), solid catalyst-modified magnetite using $Fe_2(SO_4)_3$ as a starting material can be separated by a superconducting bulk magnet and a permanent magnet.

Composting of Organic Wastes by solid State Fermentation Reactor (Solid State Fermentation Reactor를 이용한 유기성 폐기물의 발효)

  • 홍운표;이신영
    • Microbiology and Biotechnology Letters
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    • v.27 no.4
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    • pp.311-319
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    • 1999
  • Leaves of Aloe vera Linne and bloods of domestic animal were composted in a soild state fermentation reactor (SSFR) by using microbial additive including a bulking and moisture controlling agent. From solid-culture of microbial additive, 10 species of bacteria and 10 species of fungi were isolated and, their enzyme activities including amylase, carboxy methyl cellulase CMCase, lipase and protease were detected. Optimum fermentation conditions of Aloe leaves and domestic animal bloods in SSFR were obtained from the studies of response surface analysis employing microbial additive content, initial moisture content, and fermentation temperature as the independent variables. The optimum conditions for SSFR using Aloe leaves were obtained at 9.45$\pm$73%(w/w) of microbial additives, 62.73$\pm$4.54%(w/w) of initial moisture content and 55.32$\pm$3.14$^{\circ}C$ of fermentation temperature while those for SSFR using domestic animal bloods were obtained at 10.25$\pm$2.04%, 58.68$\pm$4.97% and 57.85$\pm$5.$65^{\circ}C$, respectively. Composting process in SSFR was initially proceeded through fermentation and solid materials were decomposed within 24 hours by maintaining higher moisture level, and maturing and drying steps are followed later. After the fermentation step, the concentrations of solid phase inorganic components were increased while that of organic components were decreased. Also, concentrations of total organic carbon(TOC), peptides, amino acids, polysaccharides, and low fatty acids in water extracts were increased. As fermentation in composting process depends on initial C/N ratios in water extracts of two samples were increased because of increased water-soluble TOC. From these results, it was revealed that solid state fermentation reactor using microbial additives can be used in composting process of organic wastes with broad C/N ratio.

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Reaction Characteristics of Kaolinite-based Additives and Alkali Salts (Kaolinite 계열의 첨가제와 알칼리염의 반응 특성)

  • Jun, HyunJi;Choi, Yujin;Shun, Dowon;Han, Keun-Hee;Bae, Dal-Hee;Rhee, Young-Woo
    • Clean Technology
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    • v.26 no.3
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    • pp.221-227
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    • 2020
  • When the waste solid fuel (SRF, Bio-SRF) is burnt in a boiler, a problem occurs in the combustion process involving the alkali components (Na, K) contained in large amounts in the fuel. The alkaline component has a low melting point, which usually forms low melting point salt in the temperature of the furnace, with the resulting low melting point salts attaching to the heat pipe to form a clinker. Various additives are used to suppress clinker generation, and the additive based on the kaolinite has alkali-aluminum-silica to inhibit the clinker. In this study, the reactivity of the additives based on the kaolinite was compared. The additives utilized were R-kaolinite, B-kaolinite, and A-kaolinite. Also silica and MgO were sourced as the comparison group. The experimental group was employed as a laboratory-scale batch horizontal reactor. The additive and alkaline salts were reacted at a weight ratio of 1 : 1, and the reaction temperature was performed at 900 ℃ for 10 hours. The first measurement of HCl occurring during the experiment was performed 30 minutes after the detection tube was used, and the process was repeated every hour after the experiment. After the reaction, solid residues were photographed for characterization analysis by means of an optical microscope. The reaction characteristics of the kaolinite were confirmed based on the analysis results.