• Title/Summary/Keyword: POCP

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Comparison of POCP values obtained from different analysis conditions (VOCs 분석조건이 POCP Value에 미치는 영향 분석)

  • 허귀석;정필갑;황승만;이진홍
    • Proceedings of the Korea Air Pollution Research Association Conference
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    • 2002.04a
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    • pp.241-242
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    • 2002
  • 최근 들어 지표면 오존농도의 증가에 기여하는 오존전구물질에 대한 관심이 증대되면서 오존전구물질에 대한 분석방법의 확립에 많은 노력을 기울이고 있는 실정이다. 지금까지는 비극성 column을 이용하여 저온 농축과정을 거쳐 분석을 수행하거나 극성 및 비극성 column을 병렬로 연결하여 환경대기 중의 오존전구물질을 측정한 연구사례가 대부분인 것으로 보고되고 있으나 이러한 저온농축과정 및 다수의 column을 사용할 경우 소요되는 장비 및 시간에 대한 비경제적인 측면을 고려하지 않을 수 없다. (중략)

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Characteristics of Ozone Precursor Emissions and POCP in the Biggest Port City in Korea

  • Song, Sang-Keun;Shon, Zang-Ho;Son, Hyun Keun
    • Asian Journal of Atmospheric Environment
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    • v.9 no.2
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    • pp.146-157
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    • 2015
  • Emissions of ozone precursors ($NO_x$ and VOCs) and photochemical ozone creation potentials (POCPs) of VOC emission sources were investigated in the largest port city (i.e., Busan), Korea during the year 2011. This analysis was performed using the Clean Air Policy Support System (CAPSS) national emission inventory provided by the National Institute of Environmental Research (NIER), Korea. For $NO_x$, the emissions from off-road mobile sources in Busan were the most dominant (e.g., $31,202ton\;yr^{-1}$), accounting for about 60% of the total $NO_x$ emissions. The emission from shipping of off-road mobile sources (e.g., $24,922ton\;yr^{-1}$) was a major contributor to their total emissions, amounting to 47% of the total $NO_x$ emissions due to the port-related activities in Busan. For VOCs, the emission source category of solvent usage was predominant (e.g., $36,062ton\;yr^{-1}$), accounting for approximately 82% of the total VOC emissions. Out of solvent usages, the emission from painting was the most dominant ($22,733ton\;yr^{-1}$), comprising 52% of the total emissions from solvent usages. The most dominant VOC species emitted from their sources in Busan was toluene, followed by xylene, butane, ethylbenzene, n-butanol, isopropyl alcohol, and propane. The major emission sources of toluene and xylene were found to be painting of coil coating and ship building, respectively. The value of POCP for the off-road mobile source (61) was the highest in ten major activity sectors of VOC emissions. Since the POCP value of ship transport of off-road mobile source (72) was also high enough to affect ozone concentration, the ship emission can play a significant role in ozone production of the port city like Busan.

Environmental Impact Evaluation on Landfill Treatment of Petro-Chemical Wastewater Sludge by Life Cycle Assessment (전과정평가를 이용한 석유화학 폐수처리슬러지의 매립처리에 대한 환경영향평가)

  • Kim, Hyeong-Woo;Park, Hung-Suck
    • Journal of Korean Society of Environmental Engineers
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    • v.38 no.11
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    • pp.589-595
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    • 2016
  • This study evaluated the environmental impacts for landfill treatment of the wastewater treatment sludge (WTS) from petrochemical firms by life cycle assessment (LCA) and reviewed the impact reduction by landfill gas (LFG) utilization. The functional unit was 'landfill of 1 ton of WTS', and the system boundary included the process of input and treatment for WTS in landfill site. The impacts were high at landfill process (LP) and leachate treatment process (LTP). Global warming (GWP) and photochemical oxidants creation (POCP) were high at LP, while abiotic depletion (ADP), acidification (AP), eutrophication (EP), ozone depletion (ODP) were high at LTP. The major substances of various impact categories were crude oil (ADP), $NO_X$ (AP, EP), $CH_4$ (GWP, POCP), $Cl_2$ (ODP), respectively. The major factor of ADP, AP, EP was attributed from the generation of electricity used in LTP, and the methane within uncollected LFG was main factor of GWP and POCP. Therefore, electricity consumption reduction is identified to be an impact improvement option, and the flaring system installation or enhanced LFG recovery could be an alternative to reduce impacts. Among the various categories, GWP accounted the highest impact (${\geq}90%$) followed by ADP, POCP. In the avoidance impact resulted from the utilization of LFG, to substitute B-C oil or LNG showed the impact reduction of 32.7% and 12.0%, respectively.

Environmental Impact Assessment on Dismantling·Crushing·Sorting Process for Recycling of Used Small Household Appliances (폐소형가전 재활용을 위한 해체·파쇄·선별 공정의 환경영향 분석)

  • Park, Eun Kyu;Park, Ki Hak;Choi, Woo Zin;Kim, Soo Kyung
    • Resources Recycling
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    • v.25 no.2
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    • pp.17-24
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    • 2016
  • This study aims at evaluating environmental impacts on recycling process of used small household appliances. The recycling process mainly consists of manual dismantling, crushing and various sorting processes to effectively recover valuable resources and to minimize environmental impact. In this study, life-cycle assessment (LCA) methodology is applied to analyze major environmental parameters such as GWP, ADP, POCP, EP, etc. One of the major impact categories on the weight basis in the recycling process is global warming (GWP) 57.1%, next to ADP 35.4% and POCP 4.8%, respectively. As a result of environmental impact on recovery of valuable resources/ton, the GWP of plastics for ABS is highest (33.7%) compared to ferrous metals (9.4%). The effects of environmental and economical benefit are also analyzed to compare with the amount of virgin materials to be recycled by recycled materials. In addition, recycled materials are also more economical in comparison to virgin materials due to the environmental avoiding effect by recycling. In conclusion, the key environmental issues related to the recycling of e-wastes are analyzed and therefore, the effective recycling process will contribute to mitigate global warming potential in the near future.

A Study on the Environmental Evaluation of Bimodal Tram using Life Cycle Assessment (LCA) (전과정평가를 이용한 바이모달 저상굴절 차량의 환경성 진단에 관한 연구)

  • Lee, Jae-Young;Kim, Yong-Ki;Yoon, Hee-Taek;Lee, Cheul-Kyu;Lim, Noh-Hyun
    • Proceedings of the KSR Conference
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    • 2008.06a
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    • pp.1128-1130
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    • 2008
  • Bimodal tram is a new public transportation to improve the existing traffic system. The purpose of this study was to investigate the environmental characteristics of the developed bimodal tram through its life cycle. The used tool was life cycle assessment (LCA), which could evaluate environmental loads quantitatively for a product. Based on bill of material (BOM), the environmental impacts of bimodal tram was calculated from manufacturing to operating phase. Among impact categories, photochemical oxidant creation potential (POCP) was the highest, which was resulted from the manufacturing and the combustion of CNG used as a fuel of bimodal tram. In the future, the application of LCA results can enhance increasingly the environment of bimodal tram as an environmental-friendly transportation.

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Characteristics of long-term behavior of VOC species in Korea - PAMS data analysis (우리나라 휘발성유기화합물 화학종의 장기 거동 특성 - 광화학오염물질 측정자료 분석)

  • Park, Ji Hoon;Kang, Soyoung;Song, In-Ho;Lee, Dong-Won;Cho, SeogYeon
    • Journal of Korean Society for Atmospheric Environment
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    • v.34 no.1
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    • pp.56-75
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    • 2018
  • Korean Photochemical Assessment Monitoring Stations (PAMS) have been established since the late 2001 to monitor ambient air concentrations of VOC species, which would enhance understanding photo-chemical formation of ozone and subsequently contribute to developing efficient ozone control strategies. The present study aims at identifying major VOC species and examining their trends by analyzing PAMS monitoring data collected from the year 2006 to 2016. All the 18 PAMS sites operated by the Ministry of Environment were included in the study. PAMS monitored the 56 target VOC species, which are classified into four groups, alkenes, lower alkanes ($C{\leq}3$), higher alkanes ($C{\geq}4$), aromatics. The higher alkanes and aromatics dominated over the lower alkanes and alkenes in the type 2 and 3 PAMS sites except Joongheung site. N-butane was a major alkane species, toluene was a major aromatic species and most of VOCs showed decreasing trends in these sites. On the other hand, only the alkenes showed decreasing trends at the Joongheung site in Yeosu. Major sources of abundant species such as ethane, propane, n-butane, toluene were estimated by analyzing seasonal variations, correlation with other VOC species, and emission profiles. A major source of n-butane was identified as LPG cars, while major sources of toluene varied considerably from one site to another. The lower alkanes were composed of ethane and propane, both of which showed a strong seasonal variation, low in the summer and high in the winter, indicating that a major source might be the heating by gaseous fuels. Ozone formation potentials of VOC species were evaluated by applying MIR and POCP to the measured VOC species concentrations. Toluene contributed the most to total ozone forming potentials followed by m,p-xylene for all the type 2 and 3 PAMS sites except for two sites in Yeosu-Gwangyang. Ethylene and propylene were the first and second contributors to total ozone forming potentials at Joongheung site in Yeosu.

Evaluation of Incremental Reactivity and Ozone Production Contribution of VOCs Using the PAMS Data in Seoul Metropolitan Area (수도권에서 오존생성 기여도 산출에 관한 연구)

  • Lee, J.H.;Han, J.S.;Yun, H.K.;Cho, S.Y.
    • Journal of Korean Society for Atmospheric Environment
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    • v.23 no.3
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    • pp.286-296
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    • 2007
  • Ozone creation potentials suited for Seoul metropolitan area was derived by utilizing the PAMS monitoring data and the source inventory. A simple box model with variable height was developed to calculate the incremental reactivity for all the ozone episode days in the year 2003 and 2004. RIR (Relative Incremental Reactivity) was introduced as a measure of contribution to ozone generation in the Seoul metropolitan area. RIR was defined as a function of ratio of VOC to $NO_x$ and therefore it addresses both VOC and $NO_x$ limited regime. For the days that more than 10 monitoring stations out of 27 monitoring station in Seoul recorded the daily maximum ozone concentrations higher than 70 ppb, toluene had the highest RIR value in all the type II and type III PAMS site and m/p-xylene followed with the second highest RIR value. Analyses using MIR (Maximum Incremental Reactivity) and POCP (Photochemical Ozone Creation Potential) instead of RIR also yields dominance of toluene and m/p-xylene in generating ozone concentrations to demonstrate the validity of RIR.

The Analysis on the VOCs Contents and Ozone Production Contribution of A Marine Paint in Korea (국내 선박용 도료의 VOCs 함량분포 및 오존생성기여도에 관한 연구)

  • Kim, Su Min;Lee, Young Soo;Kang, Kyoung Hee;Yoo, Kyung Seun
    • Journal of Korean Society for Atmospheric Environment
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    • v.30 no.6
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    • pp.569-576
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    • 2014
  • In this research, a few paints in the shipyard were selected and analyzed for the component and ozone production in marine paint using TVOC and GC/FID, ozone generation index (MIR, POCP) to establish measures of $VOC_s$ effectively. The concentrations of TVOC ranged between approximately 300~400 g/L and 400~500 g/L, respectively and these showed 37% of whole. Our results indicated that the main constituents of marine paints were m,p,oxylene (49%), ethyl benzene (10%), toluene (8%) and 2-propanol (5%). It was also found that xylene concentration have relatively higher impact on ozone generation. The types of paints were also investigated for their potentials. The biggest contributor was the 1 Pack Finish paint. The rest is, in their contributing order, 1 Pack Finish paint, 2 pack Finish paint, Anti-fouling paint, 2 Pack A/C paint, Ballast paint and 1 Pack A/C paint.

Analysis of Environmental Impacts using LCA for the Carcass Burial (전과정평가를 활용한 가축매몰지의 환경영향 분석)

  • Kim, Mi Hyung;Kim, Geon Ha
    • Journal of Korean Society on Water Environment
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    • v.29 no.2
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    • pp.239-246
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    • 2013
  • The foot and mouth disease and AI were highly contagious. The virus can be transmitted in a number of ways, including close-contact animal to animal spread, long-distance aerosol spread and fomites, or inanimate objects, typically fodder and motor vehicles. A lot of burial sites were constructed in a short time for preventing the rapid spread of the virus. The carcass burial sites have a risk potential because the sites were constructed without any appropriate and systematic management. It resulted from lacking of time, equipments and man power. The carcass burial sites more than 4,700 constructed in 2011. Approximately 7 million poultry and 3.5 million livestock including head of cattle and swine were buried in farm land. It is time to be concerned if the secondary pollutions occur from the burial sites. The environmental impacts should be analyzed for managing the burial sites effectively and minimizing damages and risks to the environment and human health. This study was to analyze environmental impacts of the process of carcass burial construction using a life cycle assessment methodology. All input data of raw materials and energy usage were collected and the inventory was constructed. The results showed that 1 ton of carcass burial of the environmental impacts were $0.51yr^{-1}$ for ADP, 0.09 kg of 1,4DCB-eq for FAETP, 31.17 kg of $CO_2-eq$ for GWP, 0.04 kg of $C_2H_4-eq$ for POCP, 0.06 kg of $SO_2-eq$ for AP.