DOI QR코드

DOI QR Code

국내 선박용 도료의 VOCs 함량분포 및 오존생성기여도에 관한 연구

The Analysis on the VOCs Contents and Ozone Production Contribution of A Marine Paint in Korea

  • 김수민 (광운대학교 환경공학과) ;
  • 이영수 (광운대학교 환경공학과) ;
  • 강경희 (국립환경과학원 대기공학연구과) ;
  • 유경선 (광운대학교 환경공학과)
  • Kim, Su Min (Department of Environmental Engineering, Kwangwoon University) ;
  • Lee, Young Soo (Department of Environmental Engineering, Kwangwoon University) ;
  • Kang, Kyoung Hee (Air Pollution Engineering Division, National Institute of Environmental Research) ;
  • Yoo, Kyung Seun (Department of Environmental Engineering, Kwangwoon University)
  • 투고 : 2014.10.28
  • 심사 : 2014.12.08
  • 발행 : 2014.12.31

초록

In this research, a few paints in the shipyard were selected and analyzed for the component and ozone production in marine paint using TVOC and GC/FID, ozone generation index (MIR, POCP) to establish measures of $VOC_s$ effectively. The concentrations of TVOC ranged between approximately 300~400 g/L and 400~500 g/L, respectively and these showed 37% of whole. Our results indicated that the main constituents of marine paints were m,p,oxylene (49%), ethyl benzene (10%), toluene (8%) and 2-propanol (5%). It was also found that xylene concentration have relatively higher impact on ozone generation. The types of paints were also investigated for their potentials. The biggest contributor was the 1 Pack Finish paint. The rest is, in their contributing order, 1 Pack Finish paint, 2 pack Finish paint, Anti-fouling paint, 2 Pack A/C paint, Ballast paint and 1 Pack A/C paint.

키워드

참고문헌

  1. Carter, W.P.L. and R. Atkinson (1989) Computer modeling study of incremental hydrocarbon reactivity, Envir. Sci. Technol., 23, 864-880. https://doi.org/10.1021/es00065a017
  2. Choi, Y.J. (2012) A Volatile Organic Compounds management plan for the improvement of atmosphere environment, SDI policy report of The Seoul Institute, 122, 1-15.
  3. Derwent, R.G., M.E. Jenkin, and S.M. Saunders (1996) Photochemical ozone creation potentials for a large number of reactive hydrocarbons under european conditions, Atmos. Environ., 30(2), 181-199. https://doi.org/10.1016/1352-2310(95)00303-G
  4. ISO (2006) Paints and varnishes application of paints and related products - Determination of volatile organic compound content - Part 2: Gas chromatographic, 5-9.
  5. Jung, S.Y., K.H. Kim, K.H. Kang, D.G. Kim, and J.H. Hong (2007) The Analysis on the $VOC_s$ contents of paint products on the domestic market in Korea, J. Korean Soc. Environ. Anal., 10(3), 154-168. (in Korean with English abstract)
  6. Kim, D.G., J.H. Hong, J.S. Kim, K.H. Kang, M.R. Won, and S.Y. Jung (2006) A Improvement of Evaluation Method for $VOC_s$ Content in Paint, Research papers of NIER, 2, 37-73.
  7. Kim, S.T. (2011) Ozone simulations over the seoul metropolitan area for a 2007 June episode, part I: evaluating volatile organic compounds emissions speciated for the SAPRC99 chemical mechanism, J. Korean Soc. Atmos. Environ., 27(5), 580-602. (in Korean with English abstract) https://doi.org/10.5572/KOSAE.2011.27.5.580
  8. Kim, S.T. and C.B. Lee (2011) Estimating influence of local and neighborhood emissions on ozone concentrations over the Kwang-Yang bay based on air quality simulations for a 2010 June episode, J. Korean Soc. Atmos. Environ., 27(5), 504-522. (in Korean with English abstract) https://doi.org/10.5572/KOSAE.2011.27.5.504
  9. Korea MOE (2002) The study for $VOC_s$ content standards of paint and ink, 1-13 pp.
  10. Korea MOE (2012) Notification No. 2012-130 of the Ministry of the Environment.
  11. Korea MOE (2013) Advance legislation notice of revised bill on Clean Air Conservation Act enforcement regulations, 10-12 pp.
  12. Korea NIER (2006) Guidelines for $VOC_s$ content analysis in paint, 3-53 pp.
  13. Korea NIER (2013) Mandatory of volatile organic compounds content mark, main culprit of ozone production, 1-5 pp.
  14. KOSAE (2006) Study on the THC reduction technology and regulatory standards in shipbuilding, 21-67.
  15. Ldartools (2011) http://www.ldartools.com/document/marketing/FID-response-factors.pdf
  16. Lee, J.H., J.S. Han, H.K. Yun, and S.Y. Cho (2007) Evaluation of incremental reactivity and ozone production contribution of $VOC_s$ using the PAMS data in seoul metropolitan area, J. Korean Soc. Atmos. Environ., 30(3), 245-250. (in Korean with English abstract)
  17. Seo, S.J., S.Y. Kim, M.D. Lee, J.S. Choi, S.Y. Kim, S.J. Lee, J.S. Kim, and G.W. Lee (2012) The analysis of spatial distribution of ozone in the southern coast of Korea using the aircraft (2009, summer), J. Korean Soc. Atmos. Environ., 28(1), 12-21. (in Korean with English abstract) https://doi.org/10.5572/KOSAE.2012.28.1.012