• Title/Summary/Keyword: PMN substitution

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Piezoelectric and Dielectric Characteristics of Low Temperature Sintering PMN-PZT ceramics with the amount of PMN substitution (PMN 치환량에 따른 저온소결 PMN-PZT 세라믹스의 유전 및 압전특성)

  • Kim, Kook-Jin;Yoo, Ju-Hyun;Lee, Chang-Bae;Lee, Sang-Ho;Hong, Jae-Il
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2005.11a
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    • pp.178-180
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    • 2005
  • In this study, in order to develop multilayer low temperature sintering piezoelectric transformer, $Pb_{0.97}Sr_{0.03}[(Mn_{1/3}Nb_{2/3})x(Zr_{0.48}Ti_{0.52})_{1-x}O_3]+$ 0.25wt% $CeO_2$+0.3 wt% $Nb_2O_5$ system ceramics were fabricated using $Li_2CO_3-CaCO_3$ and CuO as sintering aids and their piezoelectric and dielectric characteristics were investigated with the amount of PMN substitution. With increasing PMN substitution, electromechanical coupling factor kp and dielectric constant were increased.

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The Effect of PNN Substitution on the Piezoelectric Properties of Low Temperature Sintering PMN-PZT Ceramics (PNN치환이 저온소결 PMN-PZT 세라믹스의 압전특성에 미치는 영향)

  • Lee, Sang-Ho;Yoo, Ju-Hyun;Hwang, Jung-Min;Lee, Chung-Ho;Jeong, Yeong-Ho;Lee, Hyung-Gyu;Kang, Hyung-Won
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2005.07a
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    • pp.66-67
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    • 2005
  • In this study, in order to develop multilayer piezoelectric actuator, PMN-PNN-PZT ceramics were fabricated using $Li_2CO_3-Na_2CO_3$ as sintering aids and their piezoelectric and dielectric characteristics were investigated with the function of PNN substitution. With increasing PNN substitution, dielectric constant(${\varepsilon}r$), electromechanical coupling factor(kp), and piezoelectric d constant($d_{33}$) were increased at 10~12[mol%] PNN substitution and then decreased at all sintering temperature. With increasing PNN substitution, phase changed from tetragonal to rhombohedral at [10~12mol%] PNN substitution. At the 12[mol%] PNN substituted PMN-PZT composition ceramic sintered at 950[$^{\circ}C$], density, ${\varepsilon}r$, kp, $d_{33}$ and Qm showed the optimum value of 7.79[$g/cm^3$], 1160, 0.599, 419[pC/N) and 894, respectively for multilayer piezoelectric actuator application.

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A study on Dielectric Properties using PMN Ceramics with La substitution (La치환된 PMN계 세라믹스의 유전특성에 관한 연구)

  • Ji, S.H.;Lee, N.H.;Kim, Y.H.;Kim, J.S.;Lee, D.C.
    • Proceedings of the KIEE Conference
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    • 1995.07c
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    • pp.1242-1244
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    • 1995
  • The dielectric and polarizable properties of $0.9Pb_{1-x}La_x({Mg}_{1/3}Nb_{2/3})O_3-0.1PbTiO_3$ (x=0,1,2,3,4,5) have been investigated. The temperature-dependant electrostictive characteristics of 0.9PMN-0.1PT relaxor ferroelectric system were improved by enhencing the extent of the diffuse phase transition(DPT). This was achieved using PMN-PTceramics by the partial substitution of La at the Pb site. The curie temperature and the maximum dielectric permittivity decreased by substituting La and the electric field-related hysteresis phenomena decreased with increasing La substitution amount.

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The effect of PCN substitution on dielectric and piezoelectric properties of PMN-PZT Ceramics (PCN 치환이 PMN-PZT 세라믹스에 유전 및 압전특성에 미치는 영향)

  • Nam, Seung-Hyon;Yoo, Ju-Hyun;Lee, Su-Ho;Jeong, Yeong-Ho;Park, Chang-Yub
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.04b
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    • pp.161-164
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    • 2004
  • In this study, to develop the composition ceramics for the Ultrasonic vibrator, $Pb(Mn_{1/3}Nb_{2/3})O_3Pb(Zr.Ti)O_3$ system ceramics were manufactured as a function of PCN substitution. Its dielectric and piezoelectric characteristics were investigated. With increasing the amount of PCN substitution, electromechanical coupling factor(kp) were increased until 3mol% PCN and that after decreased. mechanical quality factor(Qm) showed the maxinum value at 2mol% PCN. Eletromechanical coupling factor, mechanical quality factor and dielectric constant were showed optimum value at PCN 2mol% as 0.58, 1630 and 1407, respectively for ultrasonic vibrator applications.

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Dielectric and Piezoelectric Characteristics of Low Temperature PMN-PZT Ceramics with the amount of PFW substitution (PFW치환에 따른 저온소결 PMN-PZT 세라믹스의 유전 및 압전 특성)

  • Lee, Kab-Soo;Yoo, Kyung-Jin;Lee, Hyun-Seok;Yoo, Ju-Hyun;Paik, Dong-Soo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2005.11a
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    • pp.181-182
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    • 2005
  • In this study, in order to develop multilayer piezoelectric transformer, PMN-PZT ceramics were fabricated according to PFW substitution using $Li_2CO_3-CaCO_3$ as sintering aids and their dielectric and piezoelectric characteristics were investigated. As increasing the amount of PFW substitution, density was slightly increased due to the increased sinterability. At the 1[mol%] PFW substituted PMN-PZT ceramic sintered at 950[$^{\circ}C$], density, dielectric constant $\varepsilon_r$, electromechanical coupling factor kp, mechanical quality factor Qm and piezoelectric $d_{33}$ constant showed the optimum value of 7.761[$g/cm^3$], 1251, 0.479, 1425 and 282[pC/N], respectively.

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Effects of Sr Substitution on the PSN-PMN-PZT Ceramics for High Frequency (고주파 필터용 PSN-PMN-PZT 세라믹스의 Sr 치환효과)

  • 오동언;민석규;류주현;박창엽;김종선;윤현상
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.11a
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    • pp.229-233
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    • 2000
  • In this study, the temperature coefficient of resonant frequency($TCF_r$), dielectric and piezoelectric properties of $Pb_{1-x}Sr_x[(Sb_{1/2}Nb_{1/2})_{0.035}(Mn_{1/3}Nb_{2/3})_{0.065}(Zr_{0.49},Ti_{0.51})_{0.90}]O_3$ ceramics were investigated with the Sr substitution to Pb site. The dielectric constant was increased according to the increase of Sr substitution and electromechanical coupling factor($k_t$) also showed the highest values of 0.485 when the Sr substitution was 5 mol%. Moreover, the mechanical quality factor($Q_{mt}$) showed the highest value of 233 when the Sr substitution was 2 mol%.

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A study on Dielectric and Electrical Properties using PMN Ceramics with $La_{2}O_{3}$ substitution ($La_{2}O_{3}$ 치환된 PMN계 세라믹스의 유전 및 전기적특성에 관한 연구)

  • Ji, S.H.;Kim, B.S.;Lee, N.H.;Lee, H.K.;Kim, Y.H.;Lee, D.C.
    • Proceedings of the KIEE Conference
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    • 1996.07c
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    • pp.1621-1623
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    • 1996
  • The dielectric and polarizable properties of 0.85Pb$Mg_{1/3}Nb_{2/3}$)$O_3$-$0.125PbTiO_3$-$0.25BaTiO_3$ Ceramics have been investigated as a addition of the amount of $La_{2}O_{3}$($0{\leq}x{\geq}0.05$). The Temperature-dependant electrostictive characteristics of 0.85PMN-0.125PT-0.25BT relaxor ferroelectic system were improved by enhencing the extent of the diffuse phase transition(DPT). This was achieved using PMN-PT-BTceramics by the partial substitution of La at the Pb site. The curie temperature and the maximum dielectic permittivity decreased by substituting $La_{2}O_{3}$ and the electic field-related hysteresis phenomena decreased with increasing $La_{2}O_{3}$ substitution amount. It is showed decreasing in induced strain for electric field with increasing $La_{2}O_{3}$ substitution.

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Piezoelectric Characteristics of Low temperature sintering PMW-PMN-PZT Ceramics for Piezoelecric Transformer (저온소결 압전변압기용 PMW-PMN-PZT 의 압전특성)

  • Lee, Hyun-Seok;Chung, Kwang-Hyun;Yoo, Ju-Hyun;Park, Chang-Yub;Ryu, Sung-Lim;Jeong, Yeong-Ho
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2005.11a
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    • pp.214-215
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    • 2005
  • In this paper, in order to develop low temperature sintering piezoelectric ceramics for piezoelectric transformer, PMW-PMN-PZT ceramics using 0.25wt%$CaCO_3$ and 0.2wt%$Li_2CO_3$ as sintering aids were fabricated according to the variation of amount of PMW and Zr/Ti ratio. Specimens could be sintered at 900$^{\circ}C$ by adding sintering aids. As Zr/Ti ratio was increased, kp was increased and Qm was decreased by approaching MPB region, and kp showed the largest value of 0.58 at Zr/Ti:50/50. The variation of amount of PMN substitution affected the liquid phase sintering of the ceramics using sintering aids, and decreased piezoelectric properties.

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Piezoelectric and dielectric properties of PMN-PZT ceramics with PNN substitution (PNN 치환에 따른 PMN-PZT 세라믹스의 유전 및 압전 특성)

  • Hwang, S.M.;Lee, J.S.;Yoon, K.H.;Yoo, J.H.;Jong, H.S.
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.11b
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    • pp.434-437
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    • 2001
  • In this study piezoelectric and dielectric properties of $Pb(Mn_{1/3}Nb_{2/3})O_{3}-Pb(Zr,Ti)O_{3}$ ceramics were investigated with $Pb(Ni_{1/3}Nb_{2/3})O_{3}$ substitution. As the $Pb(Ni_{1/3}Nb_{2/3})O_{3}$ substitution was increased, dielectric constant and electromechanical coupling factor (kp) were increased while mechanical quality factor decreased.

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A study on Dielectric Properties usig PMN Ceramics with $MnO_2$ substitution ($MnO_2$치환된 PMN계 세라믹스의 유전특성)

  • Ji, S.H.;You, D.H.;Lee, Y.H.;Kim, Y.I.;Park, K.H.;Lee, D.C.
    • Proceedings of the KIEE Conference
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    • 1997.07d
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    • pp.1537-1539
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    • 1997
  • In this study, the dielectric properties of $Pb(Mg_{1/3}Nb_{2/3})O_3-PbTiO_3$ Ceramics have been investigated as a addition of the amount of $MnO_2(0{\leq}x{\leq}0.9wt%)$. The Temperature-dependant dielectric characteristics of 0.9PMN-0.1PT relaxor ferroelectric system were improved by enhencing the extent of the diffuse phase transition(DPT). The maximum dielectric permittivity decreased by substitution $MnO_2$ and the dielectric loss decreased with increasing $MnO_2$ substitution amount. It is expected decreasing in inner heat energy for temperature with increasing $MnO_2$ substitution.

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