• Title/Summary/Keyword: PMMA (polymethyl methacrylate)

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Pentacene Thin-Film Transistor with Different Polymer Gate Insulators (게이트 절연막에 따른 펜타신 박막 트랜지스터의 전기적 특성 분석)

  • Kim, Jae-Kyoung;Her, Hyun-Jung;Kim, Jae-Wan;Choi, Y.J.;Kang, C.J.;Kim, Yong-Sang
    • Proceedings of the KIEE Conference
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    • 2007.07a
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    • pp.1345-1346
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    • 2007
  • 다양한 게이트 절연막의 펜타신 박막 트랜지스터의 전기적 특성을 atomic force microscope (AFM), X-선 회절을 사용하여 분석하였다. 펜타신 박막 트랜지스터는 thermal evaporator 방법을 사용하여 여러 폴리며 기판위에 제작하였다. Hexamethylsilasane (HMDS), polyvinyl acetate (PVA), polymethyl methacrylate (PMMA)등의 폴리머 기판을 사용하여 다양한 온도에서 증착시켰다. 이 때 PMMA위에 증착시킨 펜타신의 경우가 가장 큰 그레인 크기를 보였고, 가장 적은 트랩 농도를 보였다. 그리고 상부 전극 구조를 가진 박막 트랜지스터를 HMDS 처리를 한 $SiO_2$와 PMMA 절연막을 사용하여 제작하고 비교하였다. 이때 PMMA기판 위에 제작한 트랜지스터는 전계효과 이동도가 ${\mu}_{FET}=0.03cm^{2}/Vs$ 이고, 문턱이전 기울기 0.55V/dec, 문턱전압 $V_{th}=-6V$, on/off 전류비 $>10^5$의 전기적 특성을 보였고, $SiO_2$ 기판위에 제작한 트랜지스터는 전계효과 이동도 ${\mu}_{FET}=0.004cm^{2}/Vs$, 문턱이전 기울기 0.518 V/dec, 문턱전압 $V_{th}=5V$, on/off 전류비 $>10^4$의 전기적 특성을 보였다.

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Comparative evaluation of shear bond strength of orthodontic brackets bonded to three-dimensionally-printed and milled materials after surface treatment and artificial aging

  • Ameer Biadsee;Ofir Rosner;Carol Khalil;Vanina Atanasova;Joel Blushtein;Shifra Levartovsky
    • The korean journal of orthodontics
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    • v.53 no.1
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    • pp.45-53
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    • 2023
  • Objective: This study aimed to evaluate the shear bond strength (SBS) of orthodontic brackets bonded to three-dimensionally (3D)-printed materials after various surface treatments and artificial aging compared with that bonded to computer-aided design/computer-aided manufacturing (CAD-CAM) polymethyl methacrylate (PMMA)-milled materials. Methods: Eighty cylindrical specimens were 3D printed and divided into the following four subgroups (n = 20 each) according to the surface treatment and artificial aging procedure. Group A, sandblasted with 50 ㎛ aluminum oxide particles (SA) and aging; group B, sandblasted with 30 ㎛ silica-coated alumina particles (CO) and aging; group C, SA without aging; and group D, CO without aging. For the control group, 20 CAD-CAM PMMA-milled cylindrical specimens were sandblasted with SA and aged. The SBS was measured using a universal testing machine (0.25 mm/min), examined at ×2.5 magnification for failure mode classification, and statistically analyzed (p = 0.05). Results: The retention obtained with the 3D-printed materials (groups A-D) was higher than that obtained with the PMMA-milled materials (control group). However, no significant difference was found between the study and control groups, except for group C (SA without aging), which showed significantly higher retention than the control group (PMMA-SA and thermocycling) (p = 0.037). Study groups A-D predominantly exhibited a cohesive specimen mode, indicating specimen fracture. Conclusions: Orthodontic brackets bonded to 3D-printed materials exhibit acceptable bonding strengths. However, 3D-printed materials are prone to cohesive failure, which may result in crown fractures.

Central Corneal Thickness of Normal Eyes and Contact Lens-wearing Eyes Aged in their 20s and 30s (20․30대 정상안과 콘택트렌즈 착용안의 각막 중심 두께)

  • Park, Mijung;Park, Kyeong Sun;Ahn, So Yeoun
    • Journal of Korean Ophthalmic Optics Society
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    • v.12 no.4
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    • pp.29-35
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    • 2007
  • This study was conducted to measure the central corneal thickness(CTT) changes associated with kinds of wearing contact lens. The CCT was measured using ultrasonic pachymeter in three hundred four subjects in their 20s and 30s. Although the CCT of Group 1 who had never worn any kinds of contact lens had no differences between left and right eye as well as between genders, the CCT tended to become thinner depending on the increment in refractive error. In Group 2 wearing only soft contact lens, the CCT was thinner depending on wearing period, and subjects wearing for more than 10 years had significantly thin CCT comparing with subjects wearing for less than 4 years. There was no significant difference in the CCT between Group 3 wearing only RGP lens and Group 2 for less than 4 years. Furthermore, when comparing the CCT between the Group 2 and Group 4 changing to RGP lens after wearing soft contact lens, there was no statistically significant change in the CCT. However, the CCT was significantly thinner in Group 5 changing to soft contact lens after wearing PMMA(polymethyl methacrylate) hard lens compared with Group 2.

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Synthesis of PLLA-block-PMMA Copolymer and Characteristics of Biaxially Oriented PLA Film Including the Same (PLLA-block-PMMA 공중합수지의 합성 및 이를 포함하는 PLA 이축연신 필름의 특성)

  • Kim, Moon-Sun;Lee, Sangeun
    • Applied Chemistry for Engineering
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    • v.26 no.3
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    • pp.251-258
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    • 2015
  • In the study, PLLA with 12,000 g/mol ($M_n$) and 14,000 g/mol ($M_w$) was synthesized from L-lactide, and used to synthesize PLLA-Br intermediate. PLLA-block-PMMA with 84,000 g/mol ($M_n$) and 126,000 g/mol ($M_w$) was finally synthesized from PLLA-Br intermediate. The glass transition temperature ($T_g$) and initial pyrolysis temperature of PLLA-block-PMMA are $95.5^{\circ}C$ and $289^{\circ}C$, respectively. The PLA film of $50{\pm}3{\mu}m$ thickness was prepared by blending PLA with 9 phr PLLA-block-PMMA followed by stretching biaxially at 3 times under $95^{\circ}C$, and annealing at $120^{\circ}C$ for 2 min. The light transmittance at 550 nm and tensile strength of the film are 88.5% and 44.5 MPa, respectively. To enhance the tensile strength of PLA film, it was required to keep the film more than 2 min at $120^{\circ}C$ during the annealing step after a biaxially orientation.

Comparison of accuracy of digital data obtained by intra-oral scanner and extra-oral scanner (구강 내 스캐너와 구강 외 스캐너를 사용하여 취득된 스캔 데이터 정확도 비교)

  • Lee, Jae-Jun;Jeong, Il-Do;Kim, Chong-Myung;Park, Jin-Young;Kim, Ji-Hwan;Kim, Woong-Chul
    • Journal of Technologic Dentistry
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    • v.37 no.4
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    • pp.191-197
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    • 2015
  • Purpose: The purpose of this study was to compare the accuracy of the scan data acquired by the extra-oral and intra-oral scanner. Methods: The maxillary right first molar was made of polymethyl methacrylate(PMMA) specimen. This PMMA specimen was scanned with a engineering scanner and intra-oral scanner. Meanwhile, extra-oral scanner scanned stone die duplicated from PMMA master die. Trueness and precision of scan datas was measured by 3-dimensinal inspection. Independent t-test was conduct to analysis the significant difference(a=0.05). Results: In the trueness analysis, mean of discrepancies were 13.82um for intra oral scanner and 16.84 um for extra-oral scanner. In the precision analysis, mean of discrepancies were 11.72 for inta-oral scanner and 9.2 for extra-oral scanner. Both trueness and precision showed a statistically significant difference (Table 1, p<0.05). Conclusion: Intra-oral scanner can show higher trueness than extra-oral scanner, it has lower precision.

Comparison of the Internal Fitness of Prostheses Fabricated with Non-Contact Extra-Oral Scanner and Intra-Oral Video Scanner (비접촉식 구강외 스캐너와 비디오방식 구강내 스캐너를 이용하여 제작된 보철물의 내면정확도 비교)

  • Park, Jin-Young;Kim, Ji-Hwan;Jeong, Il-Do;Lee, Gwang-Young;Kim, Won-Soo
    • Journal of Technologic Dentistry
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    • v.41 no.4
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    • pp.263-269
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    • 2019
  • Purpose: The purpose of this study was to evaluate the internal fitness of prostheses fabricated with non-contact extra-oral scanner and those fabricated with intra-oral video scanner, with a comparative accuracy analyses of their precision and trueness. Methods: A polymethyl methacrylate (PMMA) model was fabricated by replicating a master model. The prostheses in the first group were fabricated based on the PMMA model with an intra-oral video scanner (IVS group). Following the fabrication of work models with Type IV Stone that were based on the PMMA model, the prostheses in the second group were fabricated with a non-contact extra-oral scanner (ENB group). The precision and trueness of the prostheses were calculated from comparisons of the three-dimensional images of the internal surfaces of the prostheses and those of the master model. Kruskal-Wallis tests were used to determine the statistical significance, with the level of type 1 error set at 0.05. Results: Trueness (P < 0.009) and precision (P < 0.001) did not differ significantly between the ENB and IVS groups. The IVS group exhibited lower trueness values and larger precision values than the ENB group. Conclusion: Although no significant differences were found in the internal fitness of the prostheses that were fabricated by the two different scanners, the intraoral video scanner-fabricated prostheses had better trueness, whereas the non-contact extra-oral scanner-fabricated prostheses had better precision.

Preparation of Porous PMMA/TiO2 Microspheres by Spray Drying Process (스프레이 건조법을 이용한 PMMA/TiO2 다공성 입자 제조 및 특성 연구)

  • Paik, Dong-Hyun;Lee, Hyunsuk;Gang, Rae-Hyoung;Kim, Yong-Jin;Lee, John Hwan;Choi, Sung-Wook
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.42 no.1
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    • pp.1-7
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    • 2016
  • Highly porous polymethyl methacrylate (PMMA) microspheres impregnated by $TiO_2$ powder were prepared by spray drying method. The particle size and the porosity were controlled by optimizing the co-solvent ratio and the polymer concentration. $TiO_2$ powder was impregnated into the microspheres upto 74.6 wt% content based on the weight of the resultant $PMMA/TiO_2$ microspheres. SEM images showed that $TiO_2$ powder was well distributed throughout the inside of the microsphere. EDX mapping showed that the Ti signal was well detected from every part of the microspheres, which was the evidence of the formation of the $PMMA/TiO_2$ composite. Hg porosimetry result showed that the porosity was found to be over 50% regardless of the $TiO_2$ contents. The final product was found to have high oil-absorbing capacity and great hiding power, both of which are key properties in designing the microsphere materials for make-up cosmetics application.

Effect of artificial aging on mechanical and physical properties of CAD-CAM PMMA resins for occlusal splints

  • Julia Correa Raffaini;Eduardo Jose Soares;Rebeca Franco de Lima Oliveira;Rocio Geng Vivanco;Ayodele Alves Amorim;Ana Lucia Caetano Pereira;Fernanda Carvalho Panzeri Pires-de-Souza
    • The Journal of Advanced Prosthodontics
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    • v.15 no.5
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    • pp.227-237
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    • 2023
  • PURPOSE. This study aimed to assess and compare the color stability, flexural strength (FS), and surface roughness of occlusal splints fabricated from heat-cured acrylic resin, milled polymethyl methacrylate (PMMA)-based resin, and 3D-printed (PMMA) based-resin. MATERIALS AND METHODS. Samples of each type of resin were obtained, and baseline measurements of color and surface roughness were recorded. The specimens were divided into three groups (n = 10) and subjected to distinct aging protocols: thermomechanical cycling (TMC), simulated brushing (SB), and control (without aging). Final assessments of color and surface roughness and three-point bending test (ODM100; Odeme) were conducted, and data were statistically analyzed (2-way ANOVA, Tukey, P <.05). RESULTS. Across all resin types, the most significant increase in surface roughness (Ra) was observed after TMC (P < .05), with the 3D-printed resin exhibiting the lowest Ra (P < .05). After brushing, milled resin displayed the highest Ra (P < .05) and greater color alteration (∆E00) compared to 3D-printed resin. The most substantial ∆E00 was recorded after brushing for all resins, except for heat-cured resin subjected to TMC. Regardless of aging, milled resin exhibited the highest FS (P < .05), except when compared to 3D-printed resin subjected to TMC. Heat-cured resin exposed to TMC demonstrated the lowest FS, different (P < .05) from the control. Under control conditions, milled resin exhibited the highest FS, different (P < .05) from the brushed group. 3D-printed resin subjected to TMC displayed the highest FS (P < .05). CONCLUSION. Among the tested resins, 3D-printed resin demonstrated superior longevity, characterized by minimal surface roughness and color alterations. Aging had a negligible impact on its mechanical properties.

Estimation of Computed Tomography Dose in Various Phantom Shapes and Compositions (다양한 팬텀 모양 및 재질에 따른 전산화단층촬영장치 선량 평가)

  • Lee, Chang-Lae
    • Journal of radiological science and technology
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    • v.40 no.1
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    • pp.13-18
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    • 2017
  • The purpose of this study was to investigate CTDI (computed tomography dose index at center) for various phantom shapes, sizes, and compositions by using GATE (geant4 application for tomographic emission) simulations. GATE simulations were performed for various phantom shapes (cylinder, elliptical, and hexagonal prism PMMA phantoms) and phantom compositions (water, PMMA, polyethylene, polyoxymethylene) with various diameters (1-50 cm) at various kVp and mAs levels. The $CTDI_{100center}$ values of cylinder, elliptical, and hexagonal prism phantom at 120 kVp, 200 mAs resulted in 11.1, 13.4, and 12.2 mGy, respectively. The volume is the same, but $CTDI_{100center}$ values are different depending on the type of phantom. The water, PMMA, and polyoxymethylene phantom $CTDI_{100center}$ values were relatively low as the material density increased. However, in the case of Polyethylene, the $CTDI_{100center}$ value was higher than that of PMMA at diameters exceeding 15 cm ($CTDI_{100center}$ : 35.0 mGy). And a diameter greater than 30 cm ($CTDI_{100center}$ : 17.7 mGy) showed more $CTDI_{100center}$ than Water. We have used limited phantoms to evaluate CT doses. In this study, $CTDI_{100center}$ values were estimated and simulated by GATE simulation according to the material and shape of the phantom. CT dosimetry can be estimated more accurately by using various materials and phantom shapes close to human body.

Stabilization using Screws, Wire, and PMMA for Traumatic Cervical Fracture in a Maltese Dog (말티즈 견에서 Screw, Wire와 PMMA를 사용한 외상성 경추 골절의 안정화)

  • Kim, KeunYung;Kim, Minkyung;Park, Ji-Hun;Shin, Jeong-In;Kim, Junsu;Jang, Yun-Seol;Lee, Jae-Hoon
    • Journal of Veterinary Clinics
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    • v.31 no.6
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    • pp.519-522
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    • 2014
  • A 2-year-old, 2 kg Maltese dog was evaluated for progressive tetraparesis and neck pain. The dog had been treated with steroids for the preceding 2 weeks after unknown trauma but was deteriorating progressively and had become tetraparetic. The dog was presented with a non-ambulatory tetraparesis. Radiographic and computed tomographic examinations revealed a transverse C2 fracture with subluxation of the atlantoaxial joint and C2-C3. In addition, hydrocephalus was observed on magnetic resonance imaging. Stabilization of C1-C3 using screws, wires, and polymethyl methacrylate (PMMA) was performed. Application of ventral screws, wires, and PMMA resulted in improvement of the clinical signs after 4 weeks, and the dog could walk as before the tetraparesis 6 weeks after the operation. This stabilization method is an effective surgical treatment for management of cervical instability.