• Title/Summary/Keyword: PETN

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A Parametric Study of Constitutive Relations for PETN Based Explosive (PETN 기반 복합화약의 구성방정식 파라미터 결정 및 검증)

  • Baek, Donghyeon;Kim, Bohoon;Yoh, Jai-ick
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2017.05a
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    • pp.462-468
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    • 2017
  • KYP model is a pressure-based chemical kinetics that describes shock to detonation transition of energetic materials. In this research, the parameters of KYP model and JWL EOS for PETN-based explosive, namely PBXN-301, were determined. A series of unconfined rate stick tests and two dimensional hydrodynamic simulation were conducted to obtain the size effect behaviour of the explosive. As a result, it was confirmed that the parameters obtained from KYP modeling have more accuracy to predict the detonation velocities according to the inverse radius of PBXN-301 than the qualitatively obtained LLNL constitutive equations.

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Mass Spectrometric Analysis of Eight Common Chemical Explosives Using Ion Trap Mass Spectrometer

  • Park, Sehwan;Lee, Jihyeon;Cho, Soo Gyeong;Goh, Eun Mee;Lee, Sungman;Koh, Sung-Suk;Kim, Jeongkwon
    • Bulletin of the Korean Chemical Society
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    • v.34 no.12
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    • pp.3659-3664
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    • 2013
  • Eight representative explosives (ammonium perchlorate (AP), ammonium nitrate (AN), trinitrotoluene (TNT), 2,4-dinitrotoluene (DNT), cyclonite (RDX), cyclotetramethylenetetranitramine (HMX), pentaerythritol tetranitrate (PETN), and hexanitrostilbene (HNS)) were comprehensively analyzed with an ion trap mass spectrometer in negative ion mode using direct infusion electrospray ionization. MS/MS experiments were performed to generate fragment ions from the major parent ion of each explosive. Explosives in salt forms such as AP or AN provided cluster parent ions with their own anions. Explosives with an aromatic ring were observed as either $[M-H]^-$ for TNT and DNT or $[M]^{{\cdot}-}$ for HNS, while explosives without an aromatic ring such as RDX, HMX, and PETN were detected as an adduct ion with a formate anion, i.e., $[M+HCOO]^-$. These findings provide a guideline for the rapid and accurate detection of explosives once portable MS instruments become more readily available.

A Study on the Explosive Plugging of A Repair for Defective Tube/Tubeplate on the Nuclear Steam Generator (원자력 증기발생기 결함 세관 보수용 폭발 Plugging에 관한 연구)

  • 이병일;심상한;강정윤;이상래
    • Explosives and Blasting
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    • v.17 no.4
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    • pp.18-31
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    • 1999
  • The explosive forming has been used for many year to expand tubes into tubesheets. this process has demonstrated ability to direct carefully the energy of an explosive to expand tubes into tubesheet holes without damaging the tubesheet and without causing the excessive cold work at the tube I.D. that is normally associated with mechanical expansion. The success of explosive tube expansion provided the background for the development of the explosive tube plug. The main results are as follows : (1) The optimum explosives and explosive qualities are PETN, RDX, HMS and about 18~31gr/ft of explosive plugging in nuclear steam generator. (2) Explosive plugging's thickness is 0.9~1.8mm. If groove of 0.4 mm formed in plug outside, For the hydraulic leakage is go up, explosive plugging of formed groove are applicate tube and tubrplate. (3) Sheath is designed on the polyethylene of low density, In thermal impact test of the $430^\circ{C}$, hydraulic leakage is $300kg/cm^2$. (4) About 10~60mm oxide inclusions are existed on the space of explosive plug and tube protect to the leakage.

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A Study on the Explosive Sleeving of A Repair for Defective Tube/Tubeplate on the Nuclear Steam Generator (원자력 증기발생기 결함 세관 보수용 폭발 sleeving에 관한 연구)

  • 이병일;강정윤;이상래
    • Explosives and Blasting
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    • v.17 no.4
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    • pp.8-17
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    • 1999
  • Unfortunately leaks occur in heat exchangers periodically, usually at the tube to tubeplate joint. The usual method of repair is to plug off the defective area and isolate the tubes of concern from the circuit. If the leaks continua the thermal capacity of the units is progressively reduced and for this reason the alternative of using an internal bridging sleeve has been examined. This paper discusses the overall development activities that has been found necessary to bring this repair procedure to a successful conclusion for use on the nuclear steam generator. In this work we have investigated optimum explosives and explosive quality, explosive sleeving's thickness, the design of sheath stress relieving heat treatment pull-out load, hydraulic leakage, stress corrosion cracking properties. The results obtain are as follows : (1) The optimum explosives and explosive qualities are PETN and about 15~40 gr/ft of explosive sleeving in nuclear steam generator. (2) Explosive sleeving's thickness is 1.1~l.4mm, If groove of 0.35mm formed in sleeve outside existed, For the hydraulic leakage is go up, explosive sleeving of formed groove are applicate tube and turnplate. (3) If the stress relieving heat treatment are experiment in $750^\circ{C}$, $850^\circ{C}$, 15 minutes Pull-out strength of sleeving 1,500~2,300kg, hydraulic leakage is $250kg/cm^2$.

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Predicting Single-hole Blast-induced Fracture Zone Using Finite Element Analysis

  • Jawad Ur Rehman;Duhee Park
    • Journal of the Korean GEO-environmental Society
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    • v.25 no.7
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    • pp.5-19
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    • 2024
  • During the blasting process, a fracture zone is formed in the vicinity of the blast hole. Any damage that extends beyond the excavation boundary line necessitates the implementation of an additional support system to assure safety. Typically, fracture zone radius is estimated from blast hole pressure using theoretical methods due to its simplicity. However, linear charge concentration (kg/m) is used for tunnel blasting. This paper compiles Swedish experimental datasets to estimate the radius of fracture zones based on linear charge concentration. Further numerical analyses are performed in LS-DYNA for coupled single-hole blasting. The Riedel-Hiermaier-Thoma (RHT) model has been selected as the constitutive model for this investigation. The numerical model is validated against small-scale laboratory tests. Parametric studies are conducted to predict fracture zones in granite and sandstone rocks using two kinds of explosives, PETN and AFNO. The analyses evaluate ten types of blast hole sizes, ranging from 17 to 100 mm. The results indicate that granite has a larger fracture zone than sandstone, and the PETN explosive predicts more damage than ANFO. Smaller blast holes exhibit smaller fracture zones in comparison to larger blast holes. Wave propagation is more rapidly attenuated in granite than in sandstone. Subsequently, the predicted fracture zone outcomes are compared with the empirical dataset. Fracture zones of medium blast hole diameter align well with the experimental data set. A predictive equation is derived from the data set, which may be used to evaluate blast design to manage fracture zones beyond the excavation line.

The Corridor Development of Eurasia High-Speed Railway Network (유라시아 고속철도의 Corridor 개발에 관한 연구)

  • Lee Yong-Jae
    • Proceedings of the KSR Conference
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    • 2004.06a
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    • pp.461-471
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    • 2004
  • The primary objective of this paper is to investigate the corridor of Eurasia High-Speed Railway Network from the governmental view of the Republic of Korea, whose High-Speed Train has been recently operated. The country is also expected to figure out the changes of Eurasia infrastructure system under the assumption that Trans-Korean Railway is connected to the Continent. As a result of research, the corridor connecting the TKR to TSR seems to be more attractive to the Republic of Korea than that of the TKR-TCR under the current economic and operational environments. However, even in a case, the railway linkage through the TSR between Europe and Asia should remain a supplementary means of the sea transportation route. Lastly, TSR may need a program of structural reforms, in order to continuously provide preferable services like the Pan-European Transport Network (PETN) which is currently initiated by the European Union, such as to improve outdated infrastructure (railway, bridges, signal systems, etc.), to simplify and to standardize the process of custom clearance and internal tariffs, and ultimately to construct a uniform management system for the corridor linking the TKR to TSR.

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The Effect of Paste Rate on Shaped Charges and Metal Type Liner to Explosive Jet Cutting Ability (폭발절단력에 미치는 성형폭약 및 금속성 Liner의 가소화 영향)

  • 이병일;공창식;이익주;인영수;조영곤;박근순
    • Explosives and Blasting
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    • v.18 no.3
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    • pp.89-97
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    • 2000
  • 최근 노후화 된 콘크리트 및 털 구조물에 대하여 환경 공해가 발생하지 않는 해체 기술의 필요성이 급증하고 있어서 이에 대한 연구가 활발히 이루어지고 있다. 그 결과 콘크리트 구조물을 일시에 해체하기 위하여 사용되고 있던 화약을 이용한 발파해체공법 및 군용 폭파 공법 등으로부터 응용되어 특수한 형태의 크기로 제작된 성형폭약을 철골구조물에 부착시킨 후 이를 폭발 시켜서 순간적으로 철골구조물의 철판(또는 빔이나 기타 부자재)을 절단 해체할 수 있게 되었다. 그 동안은 성형폭약의 폭발절단 효과에 영향을 주는 요소들인 대상 구조물의 재질 및 형상, 두께와 강도 특성, 성형폭약의 형상, 폭약의 종류, 장약량, Liner의 종류, Stand-off Distance, 성형폭약의 폭 및 너비, 기폭방법에 따른 영향과 폭발 절단시 발생되는 폭풍압에 의한 진동 및 소음의 영향 등에 대한 연구가 대부분이었다. 따라서 본 연구에서는 성형폭약의 주 구성요소인 화약과 금속성 Liner를 유연성이 탁월하고 조성 성분들의 혼합성과 성형성이 우수한 가소화제를 사용하여 제작된 성형폭약의 가소화 정도가 폭발절단력에 미치는 영향을 검토하였다. 이를 위하여 본 연구는 PETN 과 RDX 화약이 각각 25wt% 및 75wt%로 흔합된 화약원료를 85wt%로 하고 폴리이소부틸렌(P.I.B) 성분이 80 wt% 이상인 폴리부텐(P.B) 7wt% 와 부틸고무 4wt% 그리고 디에칠헥실세바케이트 4wt%로 구성된 가소화제를 사용하여 실험하였다.

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Development of the formulation and the process of DXD-19 sheet explosive (판상 화약 DXD-19 조성 및 성형 공정개발)

  • Cheun Young Gu;Lee Jin Sung
    • Journal of the Korea Institute of Military Science and Technology
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    • v.7 no.3 s.18
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    • pp.129-139
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    • 2004
  • DXD-19 is a flexible sheet explosive, which is a new polymer-bonded explosives(PBX's). DXD-19 is relatively insensitive and can be extruded into various configurations to be applied to munitions. A typical application includes multi-point initiation for the warhead, cutting/severance devices and transfer lines. The DXD-19 composition employs a binder system derived from the thermoplastic elastomer(HyTemp 4454) containing $5\%$ OH terminated with isocyanate curable for increasing mechanical properties. The use of an elastomer CAB increases its mechanical properties and the use of an energetic plasticizer BDNPF/BDNPA(F/A) improves the process ability as well as energy contents. The composition of the extruded DXD-19 formulation is formed $\%$ weight of $PETN/HyTemp/ATEC/(F/A)/CAB=72\~73/12\~13/6\~7/6\~7/1\~2$. Our safety tests of DXD-19 shows Insensitivity to an impact test and friction test, good thermal stability and excellent mechanical properties.

A Parametric Study of Ridge-cut Explosive Bolts using Hydrocodes

  • Lee, Juho;Han, Jae-Hung;Lee, YeungJo;Lee, Hyoungjin
    • International Journal of Aeronautical and Space Sciences
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    • v.16 no.1
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    • pp.50-63
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    • 2015
  • Explosive bolts are one of pyrotechnic release devices, which are highly reliable and efficient for a built-in release. Among them, ridge-cut explosive bolts which utilize shock wave generated by detonation to separate bolt body produce minimal fragments, little swelling and clean breaks. In this study, separation phenomena of ridge-cut explosive bolts or ridge-cut mechanism are computationally analyzed using Hydrocodes. To analyze separation mechanism of ridge-cut explosive bolts, fluid-structure interactions with complex material modeling are essential. For modeling of high explosives (RDX and PETN), Euler elements with Jones-Wilkins-Lee E.O.S. are utilized. For Lagrange elements of bolt body structures, shock E.O.S., Johnson-Cook strength model, and principal stress failure criteria are used. From the computational analysis of the author's explosive bolt model, computational analysis framework is verified and perfected with tuned failure criteria. Practical design improvements are also suggested based on a parametric study. Some design parameters, such as explosive weights, ridge angle, and ridge position, are chosen that might affect the separation reliability; and analysis is carried out for several designs. The results of this study provide useful information to avoid unnecessary separation experiments related with design parameters.

A Study of Explosive Jet-cutting Technology by Linear Shape Charges (성형폭약에 의한 폭발절단기술에 관한 연구)

  • 이병일;박근순;공창식;김광태
    • Tunnel and Underground Space
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    • v.10 no.4
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    • pp.516-525
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    • 2000
  • Recently, the demand for pollution-free demolition work of old reinforced concrete and steel structure has rapidly increased as the redevelopment of urban area has been accelerated. This study deals with linear shape charges for explosive jet cutting on steel structure. We have tested material and shape of steel structure, characteristics of thickness and strength, shape of linear shape charges, type of shape charges, cumulative charges, type of liner, stand-off distance, detonation method. effect of sound and vibration by air blast in explosive jet cutting method. So, We developed linear shape charges in order to take advantage of optimum explosive jet cutting condition. Shape charges were made of PETN explosives. We obtained the experimental formula to decide the amount of explosive needed for thickness of steel structure plate. There are prospects for application of the explosion curving technology under the open space conditions for dismantling the steel structure and steel bridge, scrapped old boats, which are going out of service.

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