• 폴리머
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• 제26권3호
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• pp.335-343
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• 2002

블렌드 (PET/PETG 70/30 블렌드) 수지는 폴리에틸렌테레프탈레이트 (PET)와 폴리에틸렌테레프탈레이트 글리콜 (PETG)을 무게 비 70/30으로 혼합하여, 이축 압출기를 사용하여 제조하였다. 미연신 필름은 이 블렌드와 순수 PETG 수지를 압축성형기로 각각 용융 압축시켜 제조하였고 연신 필름은 미연신 필름을 모세관 레오메타를 사용하여 연신시켜 제조하였다. 제조된 블렌드 연신 필름과 PETG 연신 필름의 결정성, 수축율, 열적, 동역학적 및 기계적 특성을 X-선 회절분석기, 오븐기, DSC, 및 인장시험기를 사용하여 조사하였다. 블렌드와 PETG필름의 결정화도와 밀도는 연신비와 연신 속도의 증가와 더불어 증가하였으나 반면 연신 온도 증가와 더불어 감소하였다 또한 블렌드 필름의 결정화도와 밀도는 PETG 필름보다 높게 나타났다. 두 필름의 인장강도와 인장탄성률은 연신비 및 연신 속도 증가와 더불어 증가하였고 연신온도 증가에 따라 감소하였다. 또한 블렌드 필름의 인장강도와 인장탄성률이 PETG 필름 보다 높게 나타났다. 두 필름의 수축율은 연신비와 연신 속도가 증가할수록 감소하였고 미연신 블렌드 필름의 수축율이 순수 PET 필름보다 600% 증가함을 보였다.

• Composites Research
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• 제32권6호
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• pp.360-367
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• 2019

자전거 프레임 및 산업 부품과 같은 다양한 산업 분야에 PETG 열가소성 복합 재료를 적용하려면 제조 된 복합 재료의 내충격성, 내구성, 기계적 특성 및 3D 분석을 안정성 검증이 필수적이다. 본 연구에서는 비정질 수지인 PETG 수지의 기계적 특성, 내구성 및 내충격성을 향상시키기 위해 다양한 질량분율의 POE(폴리올레핀 엘라스토머)를 보강하여 화합물 및 사출 성형 공정을 수행 하였다. POE질량분율에 따른 PETG 열가소성 복합재의 열적 및 기계적 특성 및 샤르피 충격 강도 등에 대한 분석을 수행 하였다. 열적 및 기계적 특성 분석 결과, POE 소재가 첨가 된 PETG 열가소성 복합재의 경우 열적 및 기계적 특성이 감소하는 경향이 있지만 내충격성이 우수한 경향을 나타내었고, POE첨가에 따른 3D 전산해석 결과, 파손여부 없이 우수한 안정성을 나타내었다.

• 한국염색가공학회지
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• 제31권4호
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• pp.354-362
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• 2019

In order to apply thermoplastic composites using PETG resin to various industrial fields such as bicycle frames and industrial parts, it is necessary to verify the impact resistance, durability and mechanical properties of the manufactured composite materials. To improve the mechanical properties, durability and impact resistance of PETG resin, an amorphous resin, in this study, compound and injection molding process were carried out using various additives such as TiO2, carbon black, polyolefin elastomer, and PETG amorphous resin. The thermal and mechanical properties of the thermoplastic composites, and the Charpy impact strength. The analysis was performed to evaluate the characteristics according to the types of additives. DSC and DMA analyzes were performed for thermal properties, and tensile strength, flexural strength, and tensile strength change rate were measured using a universal testing machine to evaluate mechanical properties. Charpy impact strength test was conducted to analyze the impact characteristics, and the fracture section was analyzed after the impact strength test. In the case of POE material-added thermoplastic composites, thermal and mechanical properties tend to decrease, but workability and impact resistance tend to be superior to those of PETG materials.

• Journal of Pharmaceutical Investigation
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• 제16권1호
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• pp.8-11
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• 1986

There have been many difficulties in utilization of polyethylene (PE) container for volatile ingredients because of its high permeability. We selected glycol-modified polyethylene terephthalate (PETG) lately being used and evaluated the stability of 0.5% chlorobutanol solution for PETG. We used PE bottle, glass flask and rubber stoppered vial for comparison and assayed chlorobutanol contents of the samples stored at various temperatures for nine weeks by HPLC method. The results indicated that the stability of chlorobutanol in PETG container was almost similar to that in glass flask, and was superior to that in PE bottle and rubber stoppered vial.

• 대한치과교정학회지
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• 제45권5호
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• pp.268-272
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• 2015

Clear thermoplastic retainers have been widely used in daily orthodontics; however, they have inherent limitations associated with thermoplastic polymer materials such as dimensional instability, low strength, and poor wear resistance. To solve these problems, we developed a new type of clear orthodontic retainer that incorporates multi-layer hybrid materials. It consists of three layers; an outer polyethylenterephthalate glycol modified (PETG) hard-type polymer, a middle thermoplastic polyurethane (TPU) soft-type polymer, and an inner reinforced resin core. The resin core improves wear resistance and mechanical strength, which prevent unwanted distortion of the bucco-palatal wall of the retainer. The TPU layer absorbs impact and the PETG layer has good formability, optical qualities, fatigue resistance, and dimensional stability, which contributes to increased support from the mandibular dentition, and helps maintain the archform. This new type of vacuum-formed retainer showed improved mechanical strength and rate of water absorption.

• 한국식품조리과학회지
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• 제12권4호
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• pp.499-505
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• 1996

김치의 맛을 더욱 좋게 유지하면서 상품적인 가치를 높이는 한 가지 방법으로 김치 포장 용기를 개발하고자 본 연구에 착수하였다. 기존으로 사용되고 있는 PP(Polypropylene), PS(Polystyrene), PPC(Polypropylene+ceramic)와 본 연구에서 개발하고자 하는 용기인 3층으로 laminate 된 PPP(PETG+PS+PETG) 용기에 김치를 담고 6일간 발효시키면서 총젖산균수, pH, 산도, 색상, 포장내 기체조성과 자유용적, 그리고 관능적인 성질을 측정하여 비교한 결과는 다음과 같았다. 총젖산균수는 PP, PS, PPP 공기내의 김치는 발효 6시간 후부터 급증한 데 반하여 PPC는 24시간 후에 급증하였고 PPP의 것은 120시간까지도 높은 수가 유 지된 것으로 나타났다. pH는 발효 72시간에 모든 시료가 pH 4로 떨어졌으룩 PPP의 것은 발효 144시간까지 pH 4를 유지하여 다른 것보다 pH 저하가 다소 둔하였다. 색도에 있어서도 PP, PS, PPC 용기의 것이 발효48시간에 L b/a 값이 45.6-49로 떨어진 데 비하여 PPP는 53.21로 붉은색이 더 좋았고 5일 후에도 같은경향을 보였다. 또한 $CO_2$와 $O_2$의 존재량과 자유용적을 비교한 결과 PPP와 PPC가 $CO_2$량이 비교적 적고 내부자유용적의 팽창도가 높은 것으로 나타나 기체 투관성이 다른 용기에 비해 낮은 것을 알 수 있었다. 그리고 색, 풍미, 텍스쳐, 종합적인 기호도 등에 대한관능검사 결과에서도 PPP내의 김치가 발효 48시간까지 좋은 결과를 보였다. 또한 PPP 용기를 김치 포장용기로 사용하면 투명하므로 내용물의 종류와 상태를 용이하게 확인하여 선택을 확실하게 할 수 있게 하며 PP나 PS 용기보다 견고하여 내용물의 발효에 의한 팽 창시 파열되지 않아 유통기간 중 안전하며 김치의 품질도 좀 더 좋은 것으로 나타나 김치 포장용기로 적절하게 사용될 수 있을 것으로 사료된다.

• 대한기계학회논문집A
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• 제24권4호
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• pp.824-829
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• 2000

The industries use polymer materials for many purposes because they have many merits. But these materials' costs take up too much proportion in overall cost of products that use these materials as their major material. So it is very economical for polymer industries to reduce these costs. Microcellular foaming process appeared in 1980's to solve this problem and it proved to be quite successful. This process uses inert gases such as CO2, N2. As these gases are dissolved into polymer matrices. many properties are changed. Glass transition temperature is one of these properties. DSC, DMA are devices that measures this temperature, but these are not sufficient to measure the temperature of polymer containing gas. In this paper, we devised a new tester that uses magnetism. We used this device to acquire data of the change of glass transition temperature and made Cha-Yoon model that can predict the change of glass transition temperature. Using this model, the change of this temperature can be estimated as a function of weight gain of gas. Cha-Yoon model proved that Chow's model is inappropriate to predict the change of glass transition temperature of polymer matrices containing gas.

• 한국의학물리학회지:의학물리
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• 제30권4호
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• pp.155-159
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• 2019

Radiological properties of newly introduced and existing 3-dimensional (3D) printing materials were evaluated by measuring their Hounsfield units (HUs) at varying infill densities. The six materials for 3D printing which consisted of acrylonitrile butadiene styrene (ABS), a unique ABS plastic blend manufactured by Zortrax (ULTRAT), high impact polystyrene (HIPS), polyethylene terephthalate glycol (PETG), polylactic acid (PLA), and a thermoplastic polyester elastomer manufactured by Zortrax (FLEX) were used. We used computed tomography (CT) imaging to determine the HU values of each material, and thus assess its suitability for various applications in radiation oncology. We found that several material and infill density combinations resembled the HU values of fat, soft tissues, and lungs; however, none of the tested materials exhibited HU values similar to that of bone. These results will help researchers and clinicians develop more appropriate instruments for improving the quality of radiation therapy. Using optimized infill densities will help improve the quality of radiation therapy by producing customized instruments for each field of radiation therapy.

• Elastomers and Composites
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• 제55권1호
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• pp.46-50
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• 2020

Material extrusion (ME)-type 3D printing is the most popular among the 3D printing processes. In this study, the cross-section morphologies of ME-type 3D printing manufactured specimens were observed with respect to the thermal properties of the material. The cross-section morphology of a specimen is related to the deposition strength, and the outside profile of the cross-section is related to the surface roughness. The filaments used in this study, with different thermal conductivities, were the acrylonitrile-butadiene-styrene (ABS), the high impact polystyrene (HIPS), the glycol-modified polyethylene terephthalate (PETG), and the polylactic acid (PLA). The cross-sections and the surfaces of the 3D manufactured specimens were examined. In ME-type 3D printing, the filaments are extruded through a nozzle and they form a layer. These layers rapidly solidify and as a result, they become a product. The thermal conductivity of the material influences the cooling and solidification of the layers, and subsequently the cross-section morphology and the surface roughness.

• 한국산업보건학회지
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• 제32권2호
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• pp.153-162
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• 2022

Objectives: Fused deposition modeling (FDM) 3D printer which is one of the material extrusion (MEX) technologies is an additive manufacturing (AM) process. 3D printers have been distributed widely in Korea, particularly in school and office, even at home. Several studies have shown that nanoparticles and volatile organic compounds (VOCs) were emitted from an FDM 3D printing process. The objective of this study was to identify types of chemicals possibly emitted from FDM 3D printing materials such as PLA (polylactic acid), ABS (acrylonitrile butadiene styrene), nylon, PETG (polyethylene terephthalate glycol), PVA (polyvinyl alcohol), PC (polycarbonate) filaments. Methods: 19 FDM 3D printing filaments which have been distributed in Korea were selected and analyzed VOCs emitted of 3D printing materials by headspace gas chromatography mass spectrometry (headspace GC-MS). Subsamples were put into a vial and heated up to 200℃ (500 rpm) during 20 minutes before analyzing FDM 3D printing filaments. Results: In the case of PLA filament, lactide and methyl methacrylate, the monomer components of one, were detected, and the volume ratio ranged 27~93%, 0.5~37% respectively. In the case of ABS filaments, styrene (50.5~59.1%), the monomer components of one, was detected. Several VOCs among acetaldehyde, toluene, ethylbenzene, xylene, etc were detected from each FDM 3D printing filaments. Conclusions: Several VOCs, semi-VOCs were emitted from FDM 3D printing filaments in this study and previous studies. Users were possibly exposed to ones so that we strongly believe that we recommend to install the ventilation system such as a local exhaust ventilation (LEV) when they operate the FDM 3D printers in a workplace.