• 제목/요약/키워드: PET waste

검색결과 83건 처리시간 0.028초

PET 나노섬유 강화 PEI 막의 제조 및 특성화 연구, 그에 따른 유기용매 나노여과막 가능성 검증 (Preparation and Characterization Study of PET Nanofiber-reinforced PEI Membrane, Investigation of the Application of Organic Solvent Nanofiltration Membrane)

  • 홍성배;임광섭;권동준;남상용
    • 접착 및 계면
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    • 제24권1호
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    • pp.17-25
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    • 2023
  • 본 연구는 투명 폐 Polyethylene Terephthalate (PET)병을 재활용하여 지지체를 제조 후에 Polyetherimide (PEI)를 이용하여 친환경적인 유기용매나노여과막 (Organic Solvent Nanofiltration)에 이용하고자 하였다. 제조된 복합막은 먼저, PET 지지체는 전기방사를 통해 제조를 하였으며 이후 내용매성이 우수한 PEI를 이용하여 지지체 위에 캐스팅하였고 비용매 유도상분리(Non-solvent Induced Phase Separation, NIPS) 방법을 이용하여 유기용매나노여과막을 제조하였다. 먼저 막제조에 앞서 제조된 PET 지지체는 모폴로지 분석을 통해 섬유의 직경과 인장강도를 파악하였으며 유기용매나노여과막의 최적 지지체 조건을 확인하였다. 이후 제조된 PET/PEI 복합막은 PEI의 농도에 따른 유기용매나노여과막으로서의 성능을 파악하기 위하여 에탄올에 분자량 697 g/mol을 가지는 Congo red의 제거율을 확인하였으며 최종으로 Congo red의 제거율이 90%이상의 제거율을 가지는 최적의 PET/PEI 복합막을 확인하였다.

마찰하전형(摩擦荷電型) 정전선별(靜電選別)에 의한 고비중(高比重) 플라스틱 혼합물(混合物)의 재질분리(材質分離)에 관한 연구(硏究) (A Study on Material Separation of Heavy Group Plastics by Triboelectrostatic Separation)

  • 전호석;백상호;박철현;김병곤
    • 자원리싸이클링
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    • 제16권2호
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    • pp.56-62
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    • 2007
  • 본 연구에서는 마찰하전형정전선별법을 적용하여 폐플라스틱 종말품으로부터 회수된 고비중 산물에 대한 재질분리 실험을 수행하였다. 하전장치의 재질선정을 위한 하전특성 연구결과, PP가 고비중 폐플라스틱의 재질분리에 가장 효과적인 하전재질로 확인되어, PP재질을 이용한 cyclone 하전장치를 개발하였다. 본 연구에서 개발된 cyclone 하전장치를 이용한 재질분리 실험결과, 최적 실험조건에서 PET의 품위와 회수율이 각각 98.5%와 86.2%인 결과를 얻어, 종말품 heavy group 폐플라스틱의 재활용을 위한 재질분리 기술을 확립하였다.

폐플라스틱 필름의 열분해특성에 대한 연구 (Research on Pyrolysis Properties of Waste Plastic Films)

  • 김영민;이보람;한태욱;김승도;류태우;방병열;김종수;박영권
    • 공업화학
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    • 제28권1호
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    • pp.23-28
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    • 2017
  • 열중량 분석기와 파이롤라이저-가스크로마토그래피/질량분석기를 이용하여 폐플라스틱 필름의 열분해 특성연구를 수행하였다. 열중량 분석 결과, 최근 사용량이 증가된 녹말 첨가 바이오 플라스틱의 영향으로 폐플라스틱 필름의 열분해는 $200^{\circ}C$에서 $370^{\circ}C$ 사이의 녹말 분해구간과 $370^{\circ}C$에서 $510^{\circ}C$ 사이의 PS, PP, PE와 같은 플라스틱계열의 고분자 분해구간을 가지는 것을 확인할 수 있었다. Revised Ozawa method를 이용한 동역학 분석 결과 폐플라스틱 필름의 열분해 반응 활성화 에너지는 녹말과 플라스틱계열 고분자의 다른 분해 반응에 의해 급격하게 변화되었다. 파이롤라이저-가스크로마토그래피/질량분석 결과 폐플라스틱 필름에 포함된 각 고분자의 열분해 부산물인 levoglucosan (녹말), terephthalic acid (PET), styrene monomer/dimer/trimer (PS), methylated alkenes (PP), alkadiene/alkene/alkane으로 구성된 triplet 피크 (PE)가 나타남을 확인할 수 있었다. 또한 고분자 첨가제로 사용되는 프탈레이트 성분도 검출되었다.

마찰대전을 이용한 혼합폐플라스틱 분리에 관한 연구 (A Study on the Separation of Mixed Waste Plastics by Trioboelectrification)

  • 이종호;신진혁;김두현;김장우;이재근
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2000년도 추계학술대회논문집B
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    • pp.538-543
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    • 2000
  • The purpose of this study is to develope electrostatic separation system for recycling of mixed waste plastics. The electrostatic separation system is designed and investigated the separation efficiency for separating of mixed waste plastics. Electrostatic separation system consisted of a tribocharger, separator (two electrode), collector (5 tray) and controller (positive/negative high voltage power supply). The tribocharger is a fluidized bed using tribo-electrification mechanism between particles and particles. In experimental results, the tribocharger of the fluidized bed was more effective separation efficiency. It showed the purity of $85{\sim}99\;%$ and the recovery of $80{\sim}98\;%$ from the powder of mixed plastics such as LDPE, HDPE, PP, PS, PET and PVC. Especially, In the separation experiment of Polyvinylchloride(PVC) which generates hazardous hydrogen chloride gas in case of the combustion. its purity was over 99 % and recovery was over 95 %.

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Study on Concrete Activation Reduction in a PET Cyclotron Vault

  • Bakhtiari, Mahdi;Oranj, Leila Mokhtari;Jung, Nam-Suk;Lee, Arim;Lee, Hee-Seock
    • Journal of Radiation Protection and Research
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    • 제45권3호
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    • pp.130-141
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    • 2020
  • Background: Concrete activation in cyclotron vaults is a major concern associated with their decommissioning because a considerable amount of activated concrete is generated by secondary neutrons during the operation of cyclotrons. Reducing the amount of activated concrete is important because of the high cost associated with radioactive waste management. This study aims to investigate the capability of the neutron absorbing materials to reduce concrete activation. Materials and Methods: The Particle and Heavy Ion Transport code System (PHITS) code was used to simulate a cyclotron target and room. The dimensions of the room were 457 cm (length), 470 cm (width), and 320 cm (height). Gd2O3, B4C, polyethylene (PE), and borated (5 wt% natB) PE with thicknesses of 5, 10, and 15 cm and their different combinations were selected as neutron absorbing materials. They were placed on the concrete walls to determine their effects on thermal neutrons. Thin B4C and Gd2O3 were placed between the concrete wall and additional PE shield separately to decrease the required thickness of the additional shield, and the thermal neutron flux at certain depths inside the concrete was calculated for each condition. Subsequently, the optimum combination was determined with respect to radioactive waste reduction, price, and availability, and the total reduced radioactive concrete waste was estimated. Results and Discussion: In the specific conditions considered in this study, the front wall with respect to the proton beam contained radioactive waste with a depth of up to 64 cm without any additional shield. A single layer of additional shield was inefficient because a thick shield was required. Two-layer combinations comprising 0.1- or 0.4-cm-thick B4C or Gd2O3 behind 10 cm-thick PE were studied to verify whether the appropriate thickness of the additional shield could be maintained. The number of transmitted thermal neutrons reduced to 30% in case of 0.1 cm-thick Gd2O3+10 cm-thick PE or 0.1 cm-thick B4C+10 cm-thick PE. Thus, the thickness of the radioactive waste in the front wall was reduced from 64 to 48 cm. Conclusion: Based on price and availability, the combination of the 10 cm-thick PE+0.1 cmthick B4C was reasonable and could effectively reduce the number of thermal neutrons. The amount of radioactive concrete waste was reduced by factor of two when considering whole concrete walls of the PET cyclotron vault.

순환재료를 사용한 그린 변형 경화형 시멘트 복합체의 역학적 특성 (Mechanical Properties of Green Strain-Hardening Cement-based Composites with Recycled Materials)

  • 윤현도;김선우;이영오;남상현;차준호;김윤용
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2010년도 춘계 학술대회 제22권1호
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    • pp.399-400
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    • 2010
  • 본 연구에서는 순환재료를 사용한 그린 변형 경화형 시멘트 복합체의 압축, 휨 및 직접 인장거동 특성에 대하여 평가한다. 순환재료로 재생 PET 섬유, 플라이애쉬 및 폐콘크리트로부터 생산된 순환잔골재 등이 사용되었다. 실험결과, 5개의 덤벨형 인장 시험편의 직접 인장강도는 4.76MPa, 휨 및 압축강도는 7.40MPa 및 38MPa로 각각 평가되었다.

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개고기 식용이 위생과 음식물 쓰레기 처리에 미치는 영향 (The Effect of Dogmeat Eating on Sanitation and Food Waste Consumption)

  • 안용근
    • 한국식품영양학회지
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    • 제23권1호
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    • pp.124-133
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    • 2010
  • The total number of the dogs bred in Korea as of 2007 was 1,917,709, and among them, 77%, 1,476,776 dogs were edible dogs. Dogmeat has been legalized edible as food from Choseon dynasty, Daehan imperial state, Japan-occupied era till the present Korea. Dogs had been included in the article 2, Enforcement Ordinance of Processing and Disposal Rule of Livestock and Its Products until the end of Jan. 1979, but it was crossed out by the Notification No 3,005(Feb. 1 1979 effective) of the Minister of Agriculture and Marine Products, and as a result, the obligation that dogs should be slaughtered at the slaughtering ground was defunct. Thus, the arbitrarily dog slaughtering was empowered. As a matter of fact, the new law was not legalized in order to ban dogs from being slaughtered. The waste amount of slaughtered edible dogs amounts to 7,282 tons annually, and most of its waste from the arbitrarily-slaughtered dog is being illegally dumped without proper management and supervision. Edible dogs defecate 292,509 tons(calculates urine as dung) annually, but it is sanitarily disposed according to the Law of Management and Use of Livestock's Dung and Urine which took effective from Sep. 2009. Annual sales amount of edible dogs comes to 590 billion won on the basis of the shipment at breeding ground, but after passing through various level of marketing, and being processed as Gaesoju, and Boshintang, it forms 4 trillion won market when it reaches customers. The amount of food waste in Korea in 2007 came to 5,274,944 tons, and 633 billion won was spent for its disposal cost. Korean edible dogs of 1,476,776 heads consumed 1,266,705 tons, the 24% of total food waste. Edible dogs are the most effective means to convert food waste into food for man, not entailing the cost of disposal. On the other hand, pet dog culture brought about disposal cost, and the 51,188 dogs were abandoned at 2007, while 7 billion won was spent for the protection, euthanasia of them and the disposal of their dead bodies.

리브 형상 및 개수에 따른 사각플라스틱 페트병의 강성보강에 관한 연구 (A study of Improvement of Stiffness for Plastic PET bottle with Different Geometries and Numbers of Rib)

  • 이영훈;박범진;정의철;오정길;홍석관
    • Design & Manufacturing
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    • 제17권4호
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    • pp.33-41
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    • 2023
  • Excessive use of plastic bottles contributes to a significant environmental issue due to the high volume of plastic waste generated. To address this, efforts are needed to reduce the weight of plastic bottles. However, indiscriminate weight reduction may compromise the essential rigidity required for plastic bottles. Extensive research on rib shape for pressure vessels are exists, but there is a few research of rib shapes to enhance the stiffness of plastic bottles. The following results were obtained from the analyses conducted in this study. 1) Among the rib cross-sections of square, trapezoid, and triangle, the buckling critical load of PET bottles with square-shaped ribs is improved by about 14% compared to the buckling critical load of PET bottles without ribs. 2) The buckling critical load is improved by about 18% when a square-shaped rib with an aspect ratio of 0.2 is applied, compared to the buckling critical load of the bottle without the rib. 3) When longitudinal and transverse square ribs were applied to the axial direction of the PET bottle, the buckling critical load was improved by about 32% and 58% compared to the buckling critical load of the PET bottle without ribs, respectively, indicating that applying longitudinal ribs is effective in reinforcing the stiffness of PET bottles. 4) When 14 transverse ribs were applied, the maximum improvement was about 48% compared to the buckling critical load of the plastic bottle without ribs. 5) When 3 longitudinal ribs were applied on each side, the maximum improvement was about 76% compared to the buckling critical load of the bottle without ribs. Therefore, it was concluded that for effective stiffness reinforcement of a 500ml square bottle with a thickness of 0.5mm, 3 square-shaped ribs with an aspect ratio of 0.2 should be applied in the longitudinal direction relative to the axial direction of the bottle.

고체 산촉매에서 폐플라스틱의 분해 반응 (Catalytic degradation of waste plastics over solid acid catalysts)

  • 이경환;전상구;김광호;노남선;신대현;서영화
    • 한국에너지공학회:학술대회논문집
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    • 한국에너지공학회 2002년도 추계 학술발표회 논문집
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    • pp.185-186
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    • 2002
  • 폐 플라스틱은 석유 물질인 탄화수소로 구성하고 있지만 효과적으로 재활용되지 못하고 대부분 매립, 소각 등의 방법으로 처리하고 있다. 플라스틱은 다양한 용도로 사용되기 때문에 플라스틱의 이용과 소비의 증가는 필연적이다. 예로 미국 가정의 폐 플라스틱은 63% 폴리에틸렌, 11% 폴리프로필렌, 11% 폴리스타이렌, 7% PET 그리고 7% PVC가 발생되는데 이들 화합물 구조가 포화탄화수소형이기 때문에 70% 정도가 방향족 화합물인 석탄에 비해 수소첨가 반응이 요구되지 않는다.(중략)

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Compatibilization of PET/LDPE Blends

  • Park, Young-Ok;Park, Chang-Nam;Lee, Moo-Sung
    • 한국섬유공학회:학술대회논문집
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    • 한국섬유공학회 1998년도 봄 학술발표회 논문집
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    • pp.63-66
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    • 1998
  • The steady growth in the use of plastic materials in packaging applications has caused an increasing concern about the environment and the problem of solid waste disposal. Therefore, the recycling of plastics is the very important problem, which must be solved technically and environmentally [1]. It is technically feasible to recycle, recover and reuse all of the plastics discarded, but economics limit the degree of recycling at this time.(omitted)

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