• Macromolecular Research
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• v.15 no.6
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• pp.575-580
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• 2007

Water-soluble, chiral conducting, poly(diphenylamine) (PDPA) nanocomposites were synthesized by chemical oxidative polymerization of diphenylamine in the presence of poly(acrylic acid) (PAA) as a template and camphor sulphonic acid (CSA) as the chiral inductor, Composites were formed as stable aqueous dispersions under different experimental conditions, such as DPA to PAA molar ratios, PAA molecular weight, etc. Circular dichroism(CD) spectra of the composites indicated the induction of chirality to PDPA. Compared to simple chiral PANI, the PDPA/PAA/CSA nanocomposites showed a different Cotton effect. The appearance of a CD band in the composite was complimentary to the bisignate, exciton-coupled band in the UV-Visible spectrum. FTIR spectra indicated the intimate mixing of PDPA and PAA.

• Journal of ILASS-Korea
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• v.3 no.1
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• pp.1-9
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• 1998

Two measurement techniques of droplet sizing, an imaging technique(PMAS) and a phase-Doppler measurement technique (PDPA), have been compared using a water spray from a pressurized-type swirl nozzle. The result showed that SMD measured by PDPA was larger than that measured by PMAS by about 40 %. Such discrepancy of SMD could be explained by the fact that the light signal intensity used by PDPA can be biased towards larger particles. On the other hand there could be lower opportunity to capture the images of the large particles with PMAS, since the large particles could be out of sight due to their high speed.

• Journal of ILASS-Korea
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• v.4 no.1
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• pp.45-54
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• 1999

The spray characteristics of a direct injection multi-hole diesel nozzle having the 2-spring nozzle holder were investigated by using the image processing system and a PDPA(phase Bowler particle analyzer) system. The spray tip penetration, the spray angle, and the droplet diameter and velocity with the variation of the pump speed, injection quantity were measured. From, the experiments, we know that there are small droplets which are not to be detected with spray image around the leading edge of the spray. In order to represent the mean characteristics of the intermittent spray very well, it is very important to set the time windows accurately. From the measurements along the axis of the spray, close to the nozzle, the initially injected droplets are overtaken by droplets that follow them. And also there are the maximum axial mean velocity and SMD at the following part of the leading edge of the spray.

• Analytical Science and Technology
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• v.19 no.3
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• pp.211-217
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• 2006

Diphenyl amine (DPA) was polymerized inside the channels of the mesoporous silica (MCM-41). MCM-41 (C) and MCM-41 (D) were prepared with cetyltrimethyl ammonium bromide (CTAB) and dodecyltrimethyl ammonium bromide (DTAB), respectively and used as hosts. Initially, the self assembly of DPA inside the pores of MCM-41 was made in ${\beta}$-naphthalene sulfonic acid (NSA) medium and subsequently poly (diphenylamine), PDPA was formed by oxidative polymerization. $N_2$ adsorption-desorption measurements of PDPA loaded MCM-41 (C) and MCM-41 (D) show variations in pore volume and surface area between them. A tubular form of poly (diphenylamine), PDPA was envisaged to form in the pores of MCM-41 and supported by high resolution transmission microscopy. The presence of PDPA inside the channel of MCM-41 was further confirmed by FTIR spectroscopy, thermogravimetric analysis (TGA), X-ray diffraction.

• Transactions of the Korean hydrogen and new energy society
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• v.28 no.3
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• pp.300-307
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• 2017

This study is to investigate particle size and velocity profile of gasoline port injector using Phase Doppler Particle Analyzer (PDPA). In this experiment, a GV 250 Delphi port injector used for motorcycles was used for liquid injection. The injector consists of four holes and has a static flow rate of 2.13 g/s. The fuel used in the injection was N-heptane, which is similar to gasoline, as an alternative fuel. The test fuel was injected at an atmospheric temperature of $20^{\circ}C$ and an open atmosphere of 1 atm. The injection time was 10 ms and the injection pressure was 3.5 bar in PDPA experiment. The experimental target position was fiexd at 30, 50 and 75 mm from the nozzle tip and data were collected for a total of 10,000 samples. The experimental results show that the length diameter (D10), the Sauter mean diameter ($D_{32}$), and the mean droplet velocity (MDV) are $45-54{\mu}m$, $99-115{\mu}m$ and 15-21 m/s, respectively.

• Journal of Advanced Marine Engineering and Technology
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• v.28 no.3
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• pp.466-474
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• 2004

The characteristics of liquefied butane spray are expected to be different from conventional diesel fuel spray, because a flash boiling spray is expected when the surround pressure is below the saturated vapor pressure of the butane(0.23MPa 98K). The axial velocities. radial velocities. and size distributions in butane sprays were measured with PDPA(Phase Doppler Particle Analyzer) system. Sprays were macroscopically observed by using the high speed camera in case that the surround pressure is 0.37MPa and 0.15MPa. respectively. Compared with the conventional spray. the reversed results were investigated when the surround pressure is below the saturated vapor pressure of the butane.

• Proceedings of the KSME Conference
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• 2004.04a
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• pp.1316-1321
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• 2004

An experimental study is performed on atomization characteristics and stable operating condition for injection of high viscous waste vegetable oil using effervescent atomizer with two aerator tubes. Consideration is given to the effects of ALR and liquid viscosity on the velocity and mean diameter of the injected droplet. It is found that (i) as ALR increases, the axial velocity of the droplet is increased, while half-velocity width and SMD are decreased regardless of the change in liquid viscosities, (ii) the rate of fine drop distribution occupied in the total spray field is increased with an increasing in ALR, and (iii) the effect of viscosity on atomization characteristics is minor.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2017.05a
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• pp.236-239
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• 2017

A part of the development of Scramjet Engine, this study was performed about Injectors. Barbotage injectors were used for experiment. To study characteristics of injector spray, water is supplied as a main fuel and Nitrogen is supplied for water atomization. Spray test facility and PDPA equipment were used in KARI(Korea Aerospace Research Institute). It was found that gas pressure change and spray distance is important value to spray atomization.

• 한국연소학회:학술대회논문집
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• 2003.05a
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• pp.179-188
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• 2003

The spray characteristics of dual orifice injector were investigated under two different fuels through measurement of SMD, number density and volume flux by using PDPA system. In this experiment, we found out that the droplet size and spray structure are strongly depend on fuel density and viscosity.

• Macromolecular Research
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• v.15 no.4
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• pp.385-391
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• 2007

Block copolymer micelles are generally formed via the self-assembly of amphiphilic block copolymers in an aqueous medium. The hydrophilic and hydrophobic blocks form shell and core micelles, respectively. The block copolymers of methoxy poly(ethylene glycol) (MPEG)-b-poly(2-diisopropylamino)ethyl methacrylate (PDPA) were synthesized via atom transfer radical polymerization, with the macro initiator synthesized by the coupling of 2-bromoisobutyryl bromide with MPEG in the presence of a triethyl amine base catalyst. The atom transfer radical polymerization of 2-diisopropylamino)ethyl methacrylate was performed in conjunction with an N,N,N',N",N"-pentamethyl-diethylenetriamine/copper bromide catalyst system, in DMF, at $70^{\circ}C$. The pH induced micellization/demicellization was studied using fluorescence, with a pyrene probe. Furthermore, the pH dependent micellization was confirmed using the microviscosity method, with a dipyme fluorescence probe. The pH dependant micelle size distribution was studied using dynamic light scattering. The characterization of the synthesized polymers was established using gel permeation chromatography and from the $^1H-nuclear$ magnetic resonance spectroscopy.