• Title/Summary/Keyword: PBT

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Contact Stress Analysis of Stick Type Ignition Coil Jacket PBT (Stick Type Ignition Coil Jacket PBT의 접촉응력해석)

  • Kim Yangsul;Kim Namsu;Lee Jongseok
    • Transactions of the Korean Society of Automotive Engineers
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    • v.13 no.1
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    • pp.45-50
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    • 2005
  • Stick type ignition coil(called a Cigar coil) is a kind of transformer for an automobile modulaized of distributer and electric cable. A material of cigar coil is PBT $GF30\%$ resin. This is an excellent engineering plastic with both mechanical and electrical properties. When we insert an HV terminal into the PBT $GF30\%$ resin jacket, it breaks the jacket, because the HV terminal is bigger than the jacket. It is a fatal on durability of a part. In this study, We used ANSYS FEM tool in order to stress analysis by contact. In order to automatically estimate possible maximum diameter of an HV terminal, we used an APDL. In the contact part, we considered the relation of the HV terminal's diameter with the amount of stress that occurred. This relation is able to be applied, in part, to the dimensions of the part design.

Isolation and characterization of acid-soluble bluefin tuna (Thunnus orientalis) skin collagen

  • Tanaka, Teruyoshi;Takahashi, Kenji;Tsubaki, Kazufumi;Hirata, Maika;Yamamoto, Keiko;Biswas, Amal;Moriyama, Tatsuya;Kawamura, Yukio
    • Fisheries and Aquatic Sciences
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    • v.21 no.4
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    • pp.7.1-7.8
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    • 2018
  • In this study, we isolated and characterized the acid-soluble skin collagen of Pacific bluefin tuna (PBT, Thunnus orientalis). The PBT skin collagen was composed of two ${\alpha}$ chains (${\alpha}1$ and ${\alpha}2$) and one ${\beta}$ chain. The denaturation temperature of PBT collagen was low although it was rich in proline and hydroxyproline. The primary structure of PBT skin collagen was almost identical to that of calf and salmon skin collagen; however, it differed with respect to the epitope recognition of the antibody against salmon type I collagen. These results suggest that the primary structure of skin collagen was highly conserved among animal species, although partial sequences that included the epitope structure differed among collagens.

Evaluation of Subgrade Stiffness using Pressuremeter Test (공내재하시험에 의한 포장하부기초 강성도 평가)

  • Lim, Yu-Jin;Hai, Nguyen Tien;Jang, Duk-Sun
    • International Journal of Highway Engineering
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    • v.6 no.2 s.20
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    • pp.25-36
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    • 2004
  • The pressuremeter test can be used as an effective tool for evaluating stiffness of lower pavement layers including subgrade and subbase. At present, the most practical and applicable methods for evaluation of the stiffness of the subgrade and subbase are PBT and CBR in Korea. However, these methods have inherent drawbacks and large variabilities of test results themselves. In this study, an evaluation method and a test procedure that can be used for decision of pavement stiffness using pressuremeter were developed. The obtained results representing stiffness of the subgrade and subbase can replace PBT's soil reaction value k and CBR in design methods. It is found that the developed procedure based on the pressuremeter can provide an effective correaltion between the PBT's soil reaction value k and PMT's reloading modulus ($E_R$).

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Transesterification Kinetics of Dimethyl Terephthalate with 1,4-Butanediol (디메틸테레프탈레이트와 1,4-부탄디올의 에스테르교환 반응 특성)

  • Cho, Impyo;Lee, Jinhong;Jo, Sanhwan;Cho, Minjung;Han, Myungwan;Kang, Kyungsuk
    • Korean Chemical Engineering Research
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    • v.51 no.1
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    • pp.58-67
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    • 2013
  • PBT (polybutylene terephthalate) has excellent mechanical properties such as low absorption, dimensional stability, abrasion resistance. It is used in manufacturing electronic components, the automobile part and the various precise parts. Bis (hydroxybutyl) terephthalate (BHBT) which is a PBT monomer, can be produced by transesterification reaction of DMT (dimethyl terephthalate) with 1,4-butandiol (BD). The kinetics of transesterification reaction of DMT with BD using zinc acetate as a catalyst was studied in a batch reactor. Previous kinetic studies was carried out in a semibatch reactor where generated methanol was removed so that reverse reactions were not considered in the kinetic expressions, resulting in inaccuracy of the kinetic model. Mathematical models of a batch reactor for the transesterification reaction were developed and used to characterize the reaction kinetics and the composition distribution of the reaction products. More accurate models than previous models was obtained and found to have a good agreement between model predictions and experimental data.

Fine structural characteristics of Poly(butylene terephthalate) sheets prepared from roll-drawing (롤 연신에 의한 PBT시트의 미세구조적 특성)

  • Lee, Sun-Hee;Satoru Furunishi;Cho, Hyun-Hok;Kazuo Nakayama
    • Proceedings of the Korean Fiber Society Conference
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    • 2003.04a
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    • pp.243-246
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    • 2003
  • Poly(butylene terephthalate)(PBT) is an important engineering polyester. It crystallizes much more easily and faster than PET. And these crystallization properties determine its use as an injection molding resin. Although it is more extensive than PET, its crystallization can be controlled much more easily during processing. General electric (Schenectady, NY) is the main producer of PBT films. Its production capacity was 3-5million pounds per year in 1987. (omitted)

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Synthesis and Properties of Novel Flame Retardant Poly(butylene terephthalate)

  • Park Jong Min;Park Yun Heum
    • Macromolecular Research
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    • v.13 no.2
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    • pp.128-134
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    • 2005
  • The phosphorus comonomer [(6-oxido-6H-dibenz<1,2>oxaphosphorin-6-yl)methyl]-methyl butane-dioate (DOP-MBDA) was synthesized through the addition reaction of dimethyl itaconate (DMI) with 9,10-dihydro­9-oxa-10-phosphaphenan threne-10-oxide (DOP). A series of novel flame retardant poly(butylene terephthalate)s (PBTs) containing different amounts of phosphorus were prepared using DOP-MBDA as a comonomer. These novel polymers were characterized by $^{1}H-NMR$, IR, and differential scanning calorimetry (DSC). The novel phosphorus­containing poly(butylene terephthalate)s, referred to as FR-PBTs, exhibited interesting thermal and mechanical behavior, as well as superior flame retardancy. These properties are attributed to the effect of incorporating the rigid structure of DOP-MBDA and the pendant phosphorus group into the poly(butylene terephthalate) (PBT) homopolymer. The UL 94-V2 rating could be achieved with this novel flame retardant PBT, which has a phosphorus content as low as $0.5 wt\%$, and the FR-PBTs emitted less fumes and toxic gases than the PBT homopolymer.

Development of Thermoplastic-Thermoset Multi Component Injection Mold for a Waterproof Connector (방수커넥터용 열가소성-열경화성 이종소재 사출금형 개발)

  • Jung, T. S.;Choi, K. S.
    • Transactions of Materials Processing
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    • v.24 no.6
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    • pp.418-425
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    • 2015
  • Based on eco-friendly advantages and the enhanced development in the chemical and physical characteristics, liquid silicone rubber (LSR) is widely used in producing precision parts in the automotive, medical, electronics, aeronautical and many other industries. In the current work, a thermoplastic-thermoset multi component injection molding (MCM) was developed for a waterproof automotive connector housing using PBT and LSR resins. Measurements of the rheological characteristics of PBT and LSR were made to improve the reliability of the numerical analysis for the multi component injection process. With the measured viscosity, pvT and curing data, numerical analysis of the multi cycle injection molding was conducted using simulation software (Sigma V5.0).

Changes on the Fine Structure of PBT Sheets with Various Drawing Methods (PBT시트의 연신 방법에 따른 미세구조 변화)

  • Lee, Sun-Hee;Cho, Hyun-Hok;Kazuo Nakayama
    • Proceedings of the Korean Fiber Society Conference
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    • 2003.10b
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    • pp.197-198
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    • 2003
  • Poly(butylene terephthalate)(P5T) has long history as an engineering thermoplastic. PBT was first introduced commercially to the market place as an injection molding resin about 1969 by Celanese Plastics in the U.S.A. It is still widely used as a molding resin. Processing or forming methods for solid-phase deformation, such as stretching, hydrostatic extrusion. roller stretching, rolling, and so on can improve the mechanical properties effectively. (omitted)

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Synthesis and Thermal Properties of Poly(cyclohexylene dimethylene terephthalate-co-butylene terephthalate

  • Lee, Sang-Won;Wansoo Huh;Hong, Yoo-Seok;Lee, Kyung-Mi
    • Macromolecular Research
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    • v.8 no.6
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    • pp.261-267
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    • 2000
  • It is well known that poly(cyclohexylene dimethylene terephthalate) (PCT) is used as the engineering plastics with high melting temperature and fast crystallization rate compared with poly(butylene terephthalate)(PBT). However, poor thermal stability of PCT has limited its practical application due to the drastic decrease of molecular weight during the processing temperature. In order to improve the thermal stability of PCT homopolymer, the copolymer of PCT and PBT was synthesized and the thermal properties of the copolymer have been studied. P(CT/BT) copolymer was obtained by condensation polymerization of DMT, CHDM, and 1,4-butanediol. The chemical structure and composition of the copolymer was investigated by FTIR and NMR analysis. The thermal behavior of copolymer was studied using DSC and it was found that the crystallization-melting behavior of the copolymer was observed for the whole composition range. TGA analysis exhibited that P(CT/BT) copolymer is more stable at the initial stage of thermal decomposition compared with PCT and PBT homopolymers.

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Synthesis of a Novel Nitrogen-Phosphorus Flame Retardant Based on Phosphoramidate and Its Application to PC, PBT, EVA, and ABS

  • Nguyen, Congtranh;Kim, Jin-Hwan
    • Macromolecular Research
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    • v.16 no.7
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    • pp.620-625
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    • 2008
  • A novel nitrogen-phosphorus compound, diphenyl piperazine-1,4-diylbis(methylphosphinate)(DPPMP) was synthesized via a two step reaction and its flame retarding efficiency as a single component additive was investigated. The success of synthesis was confirmed by FTIR and $^1H$ and $^{31}P$ NMR analysis. The product was mixed with polycarbonate (PC), poly(butylene terephtalate) (PBT), ethylene-vinyl-acetate copolymer (EVA), and acrylonitrile-butadiene-styrene copolymer (ABS). The flame-retarding efficiency was evaluated using the limiting oxygen index (LOI) and the UL-94 vertical test methods. The addition of DPPMP enhanced the flame retardancy of the polymers and the V-0 ratings were obtained for the polymers examined in this study at a loading of 7-30 wt%. The gas-phase flame retardancy mode of action was suggested for this material from the thermogrametry experiment results.