• Title/Summary/Keyword: P2X4

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Eu3+ Luminescence in Two-Dimensional Sr2-2xEuxKxSnO4 with K2NiF4 Structure (2차원적 K2NiF4형 구조의 Sr2-2xEuxKxSnO4에서 Eu3+ 이온의 Luminescence)

  • Yo, Chul-Hyun;Minh Chau, P.T.;Ryu, Kwang-Hyun;Kim, Anh-T.
    • Journal of the Korean Chemical Society
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    • v.41 no.4
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    • pp.175-179
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    • 1997
  • Luminescence of $Eu^{3+}$ has been studied in $Sr_{2-2x}Eu_xK_xSnO_4$ with two-dimensional $K_2NiF_4$ structure. The $^5D_o$$^7F_o$$Eu^{3+}$ ion represents the J=0 → J=0 transition which is forbidden by a Judd-Ofelt selection rule for electric dipole transition in 4f shell of $Eu^{3+}$ ions. However, the emission line of $^5D_o$$^7F_o$$Eu^{3+}$ emission spectra of Sr2-2xEuxKxSnO4$Sr_{2-2x}Eu_xK_xSnO_4$structure around $Eu^{3+}$ ions.

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Effect of Substituting B2O3 for P2O5 in Conductive Vanadate Glass

  • Choi, Suyeon;Kim, Jonghwan;Jung, Jaeyeop;Park, Hyeonjoon;Ryu, Bongki
    • Journal of the Korean Ceramic Society
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    • v.52 no.2
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    • pp.140-145
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    • 2015
  • In this study, we verified the relationship among the electrical conductivity, chemical durability, and structure of conductive vanadate glass in which $BO_3$ and $BO_4$ and $V^{4+}$ and $V^{5+}$ coexist simultaneously. We prepared samples of vanadium borophosphate glass with various compositions, given by $50V_2O_5-xB_2O_3-(50-x)P_2O_5$(x = 0 ~ 20 mol%) and $70V_2O_5-xB_2O_3-(70-x)P_2O_5$(x = 0 ~ 10 mol%), and analyzed the electrical conductivity, chemical durability, FT-IR spectroscopy, thermal properties, density, and molar volume. Substituting $B_2O_3$ for $P_2O_5$ was found to improve the electrical conductivity, chemical durability, and thermal properties. From these results, we can draw the following conclusions. First, the electrons shift from the electron rich $V^{4+}$ to the electron deficient $BO_3$ as the $B_2O_3$ content increases. Second, the improvement in chemical durability and thermal properties is attributed to an increase in cross-linked structures by changing from a $BO_3$ structure to a $BO_4$ structure.

A study on the Degradation and By-products Formation of NDMA by the Photolysis with UV: Setup of Reaction Models and Assessment of Decomposition Characteristics by the Statistical Design of Experiment (DOE) based on the Box-Behnken Technique (UV 공정을 이용한 N-Nitrosodimethylamine (NDMA) 광분해 및 부산물 생성에 관한 연구: 박스-벤켄법 실험계획법을 이용한 통계학적 분해특성평가 및 반응모델 수립)

  • Chang, Soon-Woong;Lee, Si-Jin;Cho, Il-Hyoung
    • Journal of Korean Society of Environmental Engineers
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    • v.32 no.1
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    • pp.33-46
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    • 2010
  • We investigated and estimated at the characteristics of decomposition and by-products of N-Nitrosodimethylamine (NDMA) using a design of experiment (DOE) based on the Box-Behken design in an UV process, and also the main factors (variables) with UV intensity($X_2$) (range: $1.5{\sim}4.5\;mW/cm^2$), NDMA concentration ($X_2$) (range: 100~300 uM) and pH ($X_2$) (rang: 3~9) which consisted of 3 levels in each factor and 4 responses ($Y_1$ (% of NDMA removal), $Y_2$ (dimethylamine (DMA) reformation (uM)), $Y_3$ (dimethylformamide (DMF) reformation (uM), $Y_4$ ($NO_2$-N reformation (uM)) were set up to estimate the prediction model and the optimization conditions. The results of prediction model and optimization point using the canonical analysis in order to obtain the optimal operation conditions were $Y_1$ [% of NDMA removal] = $117+21X_1-0.3X_2-17.2X_3+{2.43X_1}^2+{0.001X_2}^2+{3.2X_3}^2-0.08X_1X_2-1.6X_1X_3-0.05X_2X_3$ ($R^2$= 96%, Adjusted $R^2$ = 88%) and 99.3% ($X_1:\;4.5\;mW/cm^2$, $X_2:\;190\;uM$, $X_3:\;3.2$), $Y_2$ [DMA conc] = $-101+18.5X_1+0.4X_2+21X_3-{3.3X_1}^2-{0.01X_2}^2-{1.5X_3}^2-0.01X_1X_2+0.07X_1X_3-0.01X_2X_3$ ($R^2$= 99.4%, 수정 $R^2$ = 95.7%) and 35.2 uM ($X_1$: 3 $mW/cm^2$, $X_2$: 220 uM, $X_3$: 6.3), $Y_3$ [DMF conc] = $-6.2+0.2X_1+0.02X_2+2X_3-0.26X_1^2-0.01X_2^2-0.2X_3^2-0.004X_1X_2+0.1X_1X_3-0.02X_2X_3$ ($R^2$= 98%, Adjusted $R^2$ = 94.4%) and 3.7 uM ($X_1:\;4.5\;$mW/cm^2$, $X_2:\;290\;uM$, $X_3:\;6.2$) and $Y_4$ [$NO_2$-N conc] = $-25+12.2X_1+0.15X_2+7.8X_3+{1.1X_1}^2+{0.001X_2}^2-{0.34X_3}^2+0.01X_1X_2+0.08X_1X_3-3.4X_2X_3$ ($R^2$= 98.5%, Adjusted $R^2$ = 95.7%) and 74.5 uM ($X_1:\;4.5\;mW/cm^2$, $X_2:\;220\;uM$, $X_3:\;3.1$). This study has demonstrated that the response surface methodology and the Box-Behnken statistical experiment design can provide statistically reliable results for decomposition and by-products of NDMA by the UV photolysis and also for determination of optimum conditions. Predictions obtained from the response functions were in good agreement with the experimental results indicating the reliability of the methodology used.

ON THE JUMP NUMBER OF SPLITS OF ORDERED SETS

  • Jung, Hyung-Chan;Lee, Jeh-Gwon
    • Bulletin of the Korean Mathematical Society
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    • v.37 no.4
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    • pp.685-690
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    • 2000
  • In this paper, we consider the jump number of the split P[S] of a subset S ordered set P. $For\ x\in\ P,\ we\ show\ that\ s(P)\leq\ s(P[x]\leq\ s(P)+2$ and give a necessary and sufficient condition for which s(P[x])=s(P).

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Classification of the Scolytidae and Platypodidae Intercepted From Imported Timbers I. (수입재해충 나무좀류의 분류 I. 나무좀과와 긴나무좀과)

  • Choo H.Y.;Woo K.S.;Kim B.H.
    • Korean journal of applied entomology
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    • v.20 no.4 s.49
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    • pp.196-206
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    • 1981
  • We examined the imported Scolytidae and Platypodidae (Coleoptera) specimens preserved at Incheon Plant Quarantine Station. Indentified species are the following 2 subfamilies, 6 genera, 14 species in Scolytidae and 2 subfamilies, 2 genera, 11 species in Platypodidae; Scolytidae Platypodidae Ipinae Platypodinae Arixyleborus granulifer Platypus agnatus A. rugosipes P. biuncus Xyleborus posticepilosus P. curtus X. similis P. geminatus X. subcostatus P. jansoni Ips pini P. maritimus I. plastographus P. pseudocupulatus pseudocupulatus I. tridens P. shoreanus bifurcus Trypodendron lineatum P. solidus Hylesininae Diaporinae Dendroctonus adjunctus Diapus pendleburyi D. brevicois D. pusillimus D. frontalis D. ponderosae Hylurgops porosus.

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IDEALS OF Zpn[X]/(Xl-1)

  • Woo, Sung-Sik
    • Communications of the Korean Mathematical Society
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    • v.26 no.3
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    • pp.427-443
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    • 2011
  • In [6, 8], we showed that any ideal of $\mathbb{Z}_4[X]/(X^l\;-\;1)$ is generated by at most two polynomials of the `standard' forms when l is even. The purpose of this paper is to find the `standard' generators of the cyclic codes over $\mathbb{Z}_{p^a}$ of length a multiple of p, namely the ideals of $\mathbb{Z}_{p^a}[X]/(X^l\;-\;1)$ with an integer l which is a multiple of p. We also find an explicit description of their duals in terms of the generators when a = 2.

SOME RESULTS ON STARLIKE TREES AND SUNLIKE GRAPHS

  • Mirko, Lepovic
    • Journal of applied mathematics & informatics
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    • v.11 no.1_2
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    • pp.109-123
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    • 2003
  • A tree is called starlike if it has exactly one vertex of degree greate. than two. In [4] it was proved that two starlike trees G and H are cospectral if and only if they are isomorphic. We prove here that there exist no two non-isomorphic Laplacian cospectral starlike trees. Further, let G be a simple graph of order n with vertex set V(G) : {1,2, …, n} and let H = {$H_1$, $H_2$, …, $H_{n}$} be a family of rooted graphs. According to [2], the rooted product G(H) is the graph obtained by identifying the root of $H_{i}$ with the i-th vertex of G. In particular, if H is the family of the paths $P_k_1,P_k_2,...P_k_2$ with the rooted vertices of degree one, in this paper the corresponding graph G(H) is called the sunlike graph and is denoted by G($k_1,k_2,...k_n$). For any $(x_1,x_2,...,x_n)\;\in\;{I_*}^n$, where $I_{*}$ = : {0,1}, let G$(x_1,x_2,...,x_n)$ be the subgraph of G which is obtained by deleting the vertices $i_1,i_2,...i_j\;\in\;V(G)\;(O\leq j\leq n)$, provided that $x_i_1=x_i_2=...=x_i_j=o.\;Let \;G[x_1,x_2,...x_n]$ be characteristic polynomial of G$(x_1,x_2,...,x_n)$, understanding that G[0,0,...,0] $\equiv$1. We prove that $G[k_1,k_2,...,k_n]-\sum_{x\in In}[{\prod_{\imath=1}}^n\;P_k_i+x_i-2(\lambda)](-1)...G[x_1,x_2,...,X_n]$ where x=($x_1,x_2,...,x_n$);G[$k_1,k_2,...,k_n$] and $P_n(\lambda)$ denote the characteristic polynomial of G($k_1,k_2,...,k_n$) and $P_n$, respectively. Besides, if G is a graph with $\lambda_1(G)\;\geq1$ we show that $\lambda_1(G)\;\leq\;\lambda_1(G(k_1,k_2,...,k_n))<\lambda_1(G)_{\lambda_1}^{-1}(G}$ for all positive integers $k_1,k_2,...,k_n$, where $\lambda_1$ denotes the largest eigenvalue.

Eugenol Inhibits ATP-induced P2X Currents in Trigeminal Ganglion Neurons

  • Li, Hai Ying;Lee, Byung-Ky;Kim, Joong-Soo;Jung, Sung-Jun;Oh, Seog-Bae
    • The Korean Journal of Physiology and Pharmacology
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    • v.12 no.6
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    • pp.315-321
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    • 2008
  • Eugenol is widely used in dentistry to relieve pain. We have recently demonstrated voltage-gated $Na^+$ and $Ca^{2+}$ channels as molecular targets for its analgesic effects, and hypothesized that eugenol acts on $P2X_3$, another pain receptor expressed in trigeminal ganglion (TG), and tested the effects of eugenol by whole-cell patch clamp and $Ca^{2+}$ imaging techniques. In the present study, we investigated whether eugenol would modulate 5'-triphosphate (ATP)-induced currents in rat TG neurons and $P2X_3$-expressing human embryonic kidney (HEK) 293 cells. ATP-induced currents in TG neurons exhibited electrophysiological properties similar to those in HEK293 cells, and both ATP- and $\alpha$, $\beta$-meATP-induced currents in TG neurons were effectively blocked by TNP-ATP, suggesting that $P2X_3$ mediates the majority of ATP-induced currents in TG neurons. Eugenol inhibited ATP-induced currents in both capsaicin-sensitive and capsaicin-insensitive TG neurons with similar extent, and most ATP-responsive neurons were IB4-positive. Eugenol inhibited not only $Ca^{2+}$ transients evoked by $\alpha$, $\beta$-meATP, the selective $P2X_3$ agonist, in capsaicin-insensitive TG neurons, but also ATP-induced currents in $P2X_3$-expressing HEK293 cells without co-expression of transient receptor potential vanilloid 1 (TRPV1). We suggest, therefore, that eugenol inhibits $P2X_3$ currents in a TRPV1-independent manner, which contributes to its analgesic effect.

Studies on the Relation between Tree Injury and Acid Precipitation (수목피해와 산성강하물의 관련성에 관한 연구)

  • 이총규;김종갑;조현서
    • Korean Journal of Environment and Ecology
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    • v.12 no.2
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    • pp.131-137
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    • 1998
  • This study was performed to investigate tree injury with air pollution and acid precipitation in industrial area and rural area. This study analyzed the ion properties of pollutant precipitated in the forest of Ulsan & Onsan area and correlation between S $O_2$concentration in air and the degree of forest decline. pH of industrial area was lower than that of rural area and electrical conductivity and pH had a negative correlation(r=-.7861$^{**}$). Correlation of cation and anion(especially S $O_{4}$$^{2-}$, N $O_{3}$$^{[-10]}$ ) in precipitation and S $O_2$in air was higher in industrial area. In seasonal change, winter and spring were higher. In the analysis of correlation between forest decline and variables of precipitation properties, correlation coefficient was higher by following order: S $O_{4}$$^{2-}$>pH>EC>N $O_{3}$$^{[-10]}$ >S $O_{2}$$^{2-}$>C $l^{[-10]}$ . Regression formula by computation was Y = 5.1007-0.7811 $X_2$(pH) +0.0253 $X_{5}$ (S $O_{4}$$^{2-}$) +0.0275 $X_{6}$ (N $O_{3}$$^{[-10]}$ ). In considering the result of this study, it was predicted that air pollution and acid rain would affect soil acidification and forest decline continuously.y.

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Functional characterization of $P_{2X}/P_{2Y}$ receptor in isolated swine renal artery

  • Kim, Joo-heon;Jeon, Je-cheol;Lee, Sang-kil;Lee, Su-jin;Lee, Younggeon;Won, Jinyoung;Kang, Jae seon;Hong, Yonggeun
    • Korean Journal of Veterinary Research
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    • v.47 no.4
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    • pp.371-378
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    • 2007
  • To understand the role of $PM_{2X}/P_{2Y}$ receptor in cortex region of kidney and renal artery, molecular and functional analysis of $PM_{2X}/P_{2Y}$ receptor by pharmacophysiological skill in conventional swine tissues were performed. In functional analysis of $P_{2Y}$ receptor for vascular relaxation, 2-methylthio adenosine triphosphate, a strong agonist of $P_{2Y}$ receptor, induced relaxation of noradrenaline (NA)-precontracted renal artery in a dose-dependent manner. Strikingly, relaxative effect of ATP, 2-msATP, agonists of $P_{2Y}$ receptor, abolished by treatment of reactive blue 2, a putative $P_{2Y}$ receptor antagonist. In contrast, no significant differences of gene encoding $PM_{2X}/P_{2Y}$ and protein expression in immortalized suprachiasmatic nucleus from brain, primary isolated vascular smooth muscle cells from renal artery of pigs and HEK293 from human embryonic kidney under with/without adenosine triphosphate were observed. Taken together, the relationship between molecular and functional characteristic of $PM_{2X}/P_{2Y}$ receptors in conventional pig should be considered that they are another important factor which regulate the kidney function in swine. Based on this study, we propose the purinergic receptor as well as adrenergic and cholinergic receptors is an essential component of the renal homeostasis.