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The Removal of Hexavalent Chromium from Aqueous Solutions Using Modified Holly Sawdust: Equilibrium and Kinetics Studies

  • Siboni, M. Shirzad;Samarghandi, M.R.;Azizian, S.;Kim, W.G.;Lee, S.M.
    • Environmental Engineering Research
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    • v.16 no.2
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    • pp.55-60
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    • 2011
  • The removal of hexavalent chromium from aqueous solutions onto modified holly sawdust was studied at varying initial hexavalent chromium concentrations, adsorbent doses, pHs and contact times. The removal of hexavalent chromium from aqueous solutions increased with increasing adsorbent dosage and contact time. The percentage of hexavalent chromium removed from the aqueous solutions decreased with increasing hexavalent chromium concentration and pH of the solution. The kinetics of the adsorption of hexavalent chromium onto modified holly sawdust was analyzed using pseudo first-order and pseudo second-order models. The pseudo second-order model described the kinetics of adsorption of hexavalent chromium. The Langmuir and Freundlich isotherm models were used for modeling of the adsorption equilibrium data. The Langmuir isotherm model well described the equilibrium data for the removal of hexavalent chromium by modified holly sawdust. The obtained maximum adsorption capacity was 18.86 mg/g at pH 7. The results showed that modified holly sawdust can be used as a low cost adsorbent for the treatment of aqueous solutions containing chromium.

Anlaysis of Eukaryotic Sequence Pattern using GenScan (GenScan을 이용한 진핵생물의 서열 패턴 분석)

  • Jung, Yong-Gyu;Lim, I-Suel;Cha, Byung-Heun
    • The Journal of the Institute of Internet, Broadcasting and Communication
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    • v.11 no.4
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    • pp.113-118
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    • 2011
  • Sequence homology analysis in the substances in the phenomenon of life is to create database by sorting and indexing and to demonstrate the usefulness of informatics. In this paper, Markov models are used in GenScan program to convert the pattern of complex eukaryotic protein sequences. It becomes impossible to navigate the minimum distance, complexity increases exponentially as the exact calculation. It is used scorecard in amino acid substitutions between similar amino acid substitutions to have a differential effect score, and is applied the Markov models sophisticated concealment of the transition probability model. As providing superior method to translate sequences homologous sequences in analysis using blast p, Markov models. is secreted protein structure of sequence translations.

Modelling Stem Diameter Variability in Pinus caribaea (Morelet) Plantations in South West Nigeria

  • Adesoye, Peter Oluremi
    • Journal of Forest and Environmental Science
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    • v.32 no.3
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    • pp.280-290
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    • 2016
  • Stem diameter variability is an essential inventory result that provides useful information in forest management decisions. Little has been done to explore the modelling potentials of standard deviation (SDD) and coefficient of variation (CVD) of diameter at breast height (dbh). This study, therefore, was aimed at developing and testing models for predicting SDD and CVD in stands of Pinus caribaea Morelet (pine) in south west Nigeria. Sixty temporary sample plots of size $20m{\times}20m$, ranging between 15 and 37 years were sampled, covering the entire range of pine in south west Nigeria. The dbh (cm), total and merchantable heights (m), number of stems and age of trees were measured within each plot. Basal area ($m^2$), site index (m), relative spacing and percentile positions of dbh at $24^{th}$, $63^{rd}$, $76^{th}$ and $93^{rd}$ (i.e. $P_{24}$, $P_{63}$, $P_{76}$ and $P_{93}$) were computed from measured variables for each plot. Linear mixed model (LMM) was used to test the effects of locations (fixed) and plots (random). Six candidate models (3 for SDD and 3 for CVD), using three categories of explanatory variables (i.e. (i) only stand size measures, (ii) distribution measures, and (iii) combination of i and ii). The best model was chosen based on smaller relative standard error (RSE), prediction residual sum of squares (PRESS), corrected Akaike Information Criterion ($AIC_c$) and larger coefficient of determination ($R^2$). The results of the LMM indicated that location and plot effects were not significant. The CVD and SDD models having only measures of percentiles (i.e. $P_{24}$ and $P_{93}$) as predictors produced better predictions than others. However, CVD model produced the overall best predictions, because of the lower RSE and stability in measuring variability across different stand developments. The results demonstrate the potentials of CVD in modelling stem diameter variability in relationship with percentiles variables.

Application of Proportional Odds Models to the Effects of Removing Dental Plaque in Use of Proxabrush (치간칫솔 사용에 따른 치면세균막 제거효과에 대한 비례오즈모형(proportional odds models) 적용)

  • Kim, Jin-Soo;Kim, Jee-Yun;Jorn, Hong-Suk
    • Journal of dental hygiene science
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    • v.8 no.3
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    • pp.169-173
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    • 2008
  • As a result of analyzing the effects of removing dental plaque according to using proxabrush by using the proportional odds models, targeting patients of practicing oral prophylaxis in juniors for the Department of Dental Hygiene at S university from March 10, 2007 to June 3, 2007, the following conclusions were obtained. 1. The goodness-of-fit in the proportional odds models is 1.2552 whose degree of freedom is 3, and p value is .7398, thereby implying that the proportional odds models are appropriate. And, regarding the effects of removing dental plaque and the independent matter of using proxabrush, as the test on $H_0:{\beta}=0$, the test statistics is 15.5496 whose degree of freedom is 1, and p value is 15.5496. This implies that there is high correlation between the effect of removing dental plaque and the use of proxabrush. 2. ML estimate on $\beta$ in the model can be $\hat{\beta}=1.2493$ (ASE = 0.3207). And, as for the tendency that the response will belong to being very good(this can be expressed to be $Y{\leq}j$) rather than being very bad, the tendency of using proxabrush is higher by the estimated odds ratio exp(1.2493) = 3.49 times than the response of not using proxabrush. 3. As for the estimated response in the proportional odds models, the estimated(cumulative) probability, which the response of using proxabrush is very good and will belong to the good effect of removing dental plaque, is 0.38(0.50).

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Simulation of Moving Storm in a Watershed Using Distributed Models

  • Choi, Gye-Woon;Lee, Hee-Seung;Ahn, Sang-Jin
    • Korean Journal of Hydrosciences
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    • v.5
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    • pp.1-16
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    • 1994
  • In this paper distributed models for simulating spatially and temporally varied moving storm in a watershed were developed. The complete simulation in a watershed is achieved through two sequential flow simulations which are overland flow simulation and channel network flow simulation. Two dimensional continuity equation and momentum equation of kinematic approximation were used in the overland flow simulation. On the other hand, in the channel network simulation two types of governing equations which are one dimensional continuity and momentum equations between two adjacent sections in a channel, and continuity and energy equations at a channel junction were applied. The finite difference formulations were used in the channel network model. Macks Creek Experimental Watershed in Idaho, USA was selected as a target watershed and the moving storm on August 23, 1965, which continued from 3:30 P.M. to 5:30 P.M., was utilized. The rainfall intensity fo the moving storm in the watershed was temporally varied and the storm was continuously moved from one place to the other place in a watershed. Furthermore, runoff parameters, which are soil types, vegetation coverages, overland plane slopes, channel bed slopes and so on, are spatially varied. The good agreement between the hydrograph simulated using distributed models and the hydrograph observed by ARS are Shown. Also, the conservations of mass between upstreams and downstreams at channel junctions are well indicated and the wpatial and temporal vaiability in a watershed is well simulated using suggested distributed models.

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Theoretical Exploration of a Process-centered Assessment Model for STEAM Competency Based on Learning Progressions (학습발달과정에 근거한 과정중심 STEAM 역량 평가 모델에 대한 이론적 탐색)

  • Ryu, Suna;Kwak, Youngsun;Yang, Sung Ho
    • Journal of Science Education
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    • v.42 no.2
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    • pp.132-147
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    • 2018
  • The goal of this research is to suggest a theoretical process-centered assessment model based on Learning Progressions of key competencies in the context of STEAM instructions. The "Process-Products Combined Module-type (P2CM) STEAM Assessment Model (P2CM STEAM Assessment Model, hereafter) can be used both as an instructional model and as an assesment model, applicable for various STEAM topics and instructional types. consists of 3 axes. The first X axis stands for 4C competencies that should be emphasized through STEAM instruction. The second Y axis stands for the types and the hierarchy of STEAM instructions. The third Z axis stands for the assessment standards based on LP. We also exemplified an assessment module combined creativity competency with creativity-based instruction based on . Based on the research results, we suggested elaboration of assessment models based on Korean LP research outcomes, development and supply of formative assessment models through field-based in-depth research, modification of formative assessment models with the participation of teacher communities and in-service teachers, and the necessity of further research on assessment models for tracking LP.

STANDARD STELLAR MODELS; $\alpha$ CEN A AND B

  • KIM YONG-CHEOL
    • Journal of The Korean Astronomical Society
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    • v.32 no.2
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    • pp.119-126
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    • 1999
  • The standard stellar models for $\alpha$ Cen A and B have been constructed without resorting to the arbitrary constraint of the Solar mixing length ratio. Assuming that the chemical compositions and the ages of the two stars are the same, series of models have been constructed. Using the observational constraints, [Z/X], we were able to constrain the number of the 'possible' models. We find that utilizing the observational constraints of [Z/X] the best models for $\alpha$ Cen system are with the initial Z = 0.03, X = 0.66$\~$0.67. In particular, the primary and the secondary stars may have the same mixing length ratio 1.6$\~$1.7, which is the same as that of the calibrated Solar model. And, the age of the system is about 5.4 Gyr. Finally, the large spacing of the p-modes is predicted to be 104 $\pm$ 4$\mu$Hz for $\alpha$ Cen A.

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Tempo of Diversification of Global Amphibians: One-Constant Rate, One-Continuous Shift or Multiple-Discrete Shifts?

  • Chen, Youhua
    • Animal Systematics, Evolution and Diversity
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    • v.30 no.1
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    • pp.39-43
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    • 2014
  • In this brief report, alternative time-varying diversification rate models were fitted onto the phylogeny of global amphibians by considering one-constant-rate (OCR), one-continuous-shift (OCS) and multiple-discrete- shifts (MDS) situations. The OCS diversification model was rejected by ${\gamma}$ statistic (${\gamma}=-5.556$, p<0.001), implying the existence of shifting diversification rates for global amphibian phylogeny. Through model selection, MDS diversification model outperformed OCS and OCR models using "laser" package under R environment. Moreover, MDS models, implemented using another R package "MEDUSA", indicated that there were sixteen shifts over the internal nodes for amphibian phylogeny. Conclusively, both OCS and MDS models are recommended to compare so as to better quantify rate-shifting trends of species diversification. MDS diversification models should be preferential for large phylogenies using "MEDUSA" package in which any arbitrary numbers of shifts are allowed to model.

The Effects of "Me-model" Body-size Discrepancy on Young Korean Consumer's Shopping Mood, Store Satisfaction, and Intention to Revisit Online Apparel Stores

  • Lee, Ji Young;Johnson, Kim K.P.
    • Journal of the Korean Society of Clothing and Textiles
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    • v.36 no.12
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    • pp.1297-1309
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    • 2012
  • This study examined the effects of "me-model" body-size discrepancy on consumer's shopping mood, store satisfaction, and intention to revisit two types of online apparel stores (one featuring thin models and one featuring average-sized models). A convenience sample of women (n = 528) participated. Structural equation modeling was used to analyze the data. Participants who were thinner or similar to the models indicated positive shopping moods, a high level of online store satisfaction, and intended to revisit the stores when compared to participants who were larger than the models. Participants preferred the 'average-sized' model. This preference was attributed to the familiarity of the model and ability to effectively evaluate merchandise. The results revealed how models can influence apparel consumers in an online context.

The Comparative Study on the Effects of Three kinds of Teaching Model (Deductive, Inductive and Analogical Teaching Models) in Boiling Point Elevation (끓는점 오름의 학습에서 세 가지 수업모형의 효과 비교 - 연역식, 귀납식, 비유를 사용한 수업모형)

  • Kim, Do-Wook
    • Journal of The Korean Association For Science Education
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    • v.12 no.1
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    • pp.35-46
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    • 1992
  • The purpose of this study was to investigate the most effective teaching model in the study of boiling point elevation. The teaching models were classified into three group-deductive, inductive and analogical teaching models. Learning materials, based on three teaching models respectively, were applied to 11th grade students, and the effect of teaching models were investigated and analyzed. The average achievement score(4.24) of the group treated with the analogical teaching model was higher than those(3.06 respectively) of each group treated with inductive or deductive teaching model(p<0.001). Most students answered that the analogical teaching model was helpful and interesting one for the comprehension of scientific concept.

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