• Title/Summary/Keyword: P solubility

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Dispersion and Flocculation Behavior of Metal Oxide in Organic Solvent

  • Fujii, Katsuya;Yamamoto, Hideki;Shibata, Junji
    • Proceedings of the IEEK Conference
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    • 2001.10a
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    • pp.353-356
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    • 2001
  • The relation between the flocculation and dispersion of metal oxide powders and the properties of solvents, such as dielectric constant and solubility parameter, was investigated for TiO$_2$, $Al_2$O$_3$and Fe$_2$O$_3$particles. The particle size and median diameter of these metal oxides were measured in many organic solvents, from which the effect of solvents on the flocculation and dispersion of metal oxide powders was considered. The metal oxide powders of TiO$_2$, $Al_2$O$_3$and Fe$_2$O$_3$tend to disperse in a solvent of higher polarity, whereas they are apt to flocculate in a solvent of low dielectric constant, because the Hamaker constant between the particles becomes larger in such a solvent. There we, however, some solvents that do not obey these tendencies. It is possible to evaluate the flocculation and dispersion of these metal oxide powders in many solvents by using numeral balances of Hansen’s three-dimensional solubility parameter (f$_{d}$, f$_{p}$ and f$_{h}$). There exists a solvent giving the optimal dispersion for each metal oxide, and the optimal dispersion point of f$_{d}$, f$_{p}$ and f$_{h}$ is determined by the combination of various metal oxide powders and solvents.nts.nts.nts.

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Studies on the Protein of Peach seed flour (복숭아 종자의 단백질에 관한연구)

  • Lee, Kang-Ja
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.17 no.1
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    • pp.43-49
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    • 1988
  • The proteins of peach seed four was examined to utilize protein source. The peach seed flour contained 20.38% of crude proteins. The extractability of salt souble proteins of seed were 70% and recovery rate of main protein fractions separated by sephadex G-200 were about 51%. The electrophoretic analysis showed 11 bands and molecular weight showed 14,000-110,000 in seed proteins. The Amino acid of peach seed flour and isolated were mainly composed of arginine, asparic acid. glutamic acid, glycine and leucine. The solubility of isolated peach seed protein was lowest at pH 5.5.

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Buccal Transport of Paclitaxel using Ethanol and Glyceryl Monooleate

  • Lee, Yoon-Jin;Kang, Myung-Joo;Park, Young-Mi;Choi, Young-Wook;Lee, Jae-Hwi
    • Journal of Pharmaceutical Investigation
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    • v.37 no.5
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    • pp.311-314
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    • 2007
  • Paclitaxel (PTX) is an antineoplastic agent approved for the treatment of ovarian and breast carcinomas. However, the use of paclitaxel as an anticancer drug is limited by its extremely poor water solubility (below $0.3\;{\mu}g/mL$). Furthermore, it has very low bioavailability when administered orally because paclitaxel is a substrate of P-glycoprotein (P-gp) efflux pump. In this study, buccal delivery of PTX was investigated as one of the alternatives for PTX delivery. Ethanol and glyceryl monooleate (GMO) were selected as permeation enhancing agents to increase solubility and permeation across buccal mucosa of PTX. At the different concentrations of ethanol solution ($30{\sim}70\;w/w\;%$), PTX permeation was studied, followed effects of GMO in the concentration range of $2.5{\sim}25%$ with ethanol vesicle. The transbuccal ability of PTX was evaluated in vitro using Franz diffusion cells mounted with rabbit buccal mucosa. As a result, incorporation of PTX into ethanol vesicle with GMO significantly enhanced the PTX permeation in rabbit buccal mucosa. Particularly, the mixtures of ethanol:water:GMO at the ratio of 50:47.5:2.5 showed the most excellent enhancing ability. The results showed a promising possibility for buccal delivery of PTX.

Functional Properties of $\alpha$-Lactalbumin Separated from Bovine Whey (우우 유청으로부터 분리한 $\alpha$-락트알부민의 기능적 특성)

  • 홍윤호
    • Food Science of Animal Resources
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    • v.18 no.1
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    • pp.9-18
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    • 1998
  • This study was performed to obtain a large quantity of $\alpha$-lactalbumin ($\alpha$-LA) from milk by an improved separation and purification method. Functional properties-solubility viscosity, emulsifying activity, foamability surface hydrophobicity and gelation-of the purified $\alpha$-LA were investigated, $\alpha$-LA was purified in a large quantity by DEAE-Sephacel chromatography using 0.15M NaCl in 20mM Tris-HCl buffer(pH 7.2), as an eluent. The yield and purity of the purified $\alpha$-LA were 23.6%, 92.5%, respect-ively. The solubility viscosity and emulsifying activity of the purified $\alpha$-LA were 92.2$\pm$2% 3.46$\pm$0.19 cP and 345$\pm$5.0m^2$-/g respecively. The foamability of $\alpha$ -LA was 762 after 5min whipping which was lower than that of WPC and showed decreasing tendency with whipping time. The relative surface hydrophobicity of the $\alpha$-LA was formed when a 10% $\alpha$-LA solution containing 100mM NaCl and 20 mM $CaCl_2$ was heated at 92$^{\circ}C$for 40min. The $\alpha$-LA gel showed 31.5 as hardness and showed low springiness and cohesiveness.

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EXISTENCE OF THE SOLUTION OF COUNTABLY INFINITE SYSTEM OF DIFFERENTIAL EQUATIONS IN SEQUENCE SPACES mp(𝜙) AND np(𝜙) WITH THE HELP OF MEASURE OF NON-COMPACTNESS

  • KHAN, MOHD SHOAIB;UDDIN, IZHAR;LOHANI, Q.M. DANISH
    • Journal of applied mathematics & informatics
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    • v.37 no.5_6
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    • pp.329-339
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    • 2019
  • The Banach spaces $m^p(\phi)$ and $n^p(\phi)$ are very important sequence spaces related to $l_p$, which were defined to fill the gaps between $l_p(1{\leq}p{\leq}{\infty})$. In this paper, we investigated the solubility of the infinite system of differential equations in $m^p(\phi)$ and $n^p(\phi)$ by proving related theorems. Moreover, one example has been included for the justification of the claim of this paper.

Molecular System Design for the Acetylcholine Fluorescent Chemosensor

  • Kah, Kwang-Nak
    • Journal of Sensor Science and Technology
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    • v.6 no.6
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    • pp.508-513
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    • 1997
  • We exploited a new molecular system - acetylcholine (neurotransmitter) detection system as a building block for the perfect molecular information system (sensing membrane of the chemical sensor) - using water soluble calix[n]arene-p-sulfonates which are useful even in aqueous (water/methanol) neutral solution. This achievement is due to several outstanding properties of these calix[n]arene derivatives such as low $pK_{a}$ values, cation-interactions, and high water-solubility, etc.

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Functional Polythiophene Bearing Hydroxyethyl Groups and Their Derivatives

  • Kim Hyun-Chul;Kim Jong-Seong;Baek Sung-Sik;Ree Moon-Hor
    • Macromolecular Research
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    • v.14 no.2
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    • pp.173-178
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    • 2006
  • Poly(3-(2-hydroxyethyl)thiophene) (P3HET) was synthesized using oxidative coupling polymerization that involved the protecting and deprotecting of hydroxyl groups but not the chlorine substitution or oxidative decomposition of the hydroxyl groups. The resulting P3HET exhibited good solubility in aprotic solvents, in contrast to the insoluble polymer product synthesized directly from the monomer, 3-(2-hydroxyethyl)thiophene (3HET). P3HET had low conductivity due to the strong hydrogen bonding of its hydroxyl groups. The ester-functionalized poly(3-(2-acetoxyethyl)thiophene) and poly(3-(4-pentylbenzoateethyl)thiophene) were also prepared with reasonably high molecular weights in order to examine how this functionalization modified the physical and chemical properties of P3HET. These polymers exhibited better solubility in common solvents and higher conductivity than P3HET. All these polymers exhibited bathochromic shifts of their film state absorption maxima with respect to those found in the UV-visible spectra of their solution phases. The extent of the bathochromic shift was found to vary with the lengths of the side chains of the ester-functionalized polymers.

Effects of Gelatin Hydrolysates Addition on Technological Properties and Lipid Oxidation of Cooked Sausage

  • Ham, Youn-Kyung;Song, Dong-Heon;Noh, Sin-Woo;Gu, Tae-Wan;Lee, Jae-Hyeok;Kim, Tae-Kyung;Choi, Yun-Sang;Kim, Hyun-Wook
    • Food Science of Animal Resources
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    • v.40 no.6
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    • pp.1033-1043
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    • 2020
  • This study investigated the impacts of gelatin hydrolysate addition on the technological properties and lipid oxidation stability of cooked sausage. Gelatin hydrolysate was prepared from pork and duck skin gelatin, through stepwise hydrolysis using collagenase and pepsin. The cooked sausages were formulated without gelatin (control) or with 1% pork skin gelatin, 1% duck skin gelatin, 1% pork skin gelatin hydrolysate, and 1% duck skin gelatin hydrolysate. The pH, color characteristics, protein solubility, cooking loss, and textural properties of cooked sausages were evaluated, and the 2-thiobarbituric acid reactive substances (TBARS) value was measured weekly to determine lipid oxidation stability during 4 wk of refrigerated storage. Enzymatic hydrolysis of gelatin decreased protein content and CIE L* but increased redness and yellowness (p<0.05). When 1% gelatin or gelatin hydrolysate was incorporated in cooked sausage, however, little to no impacts on pH value, moisture content, protein content, color characteristics, protein solubility, and cooking loss were found (p>0.05). The addition of 1% duck skin gelatin hydrolysate increased the cohesiveness and chewiness of cooked sausages. The inclusion of 1% duck skin gelatin accelerated lipid oxidation of cooked sausages during refrigerated storage (p<0.05), whereas duck skin gelatin hydrolysate caused a lower TBARS value in cooked sausage compared to duck skin gelatin. The results show comparable effects of gelatin and gelatin hydrolysate addition on the technological properties of cooked sausages; however, the oxidative stability of raw materials for gelatin extraction should be evaluated clearly in further studies.

Effects of Bromelain and Double Emulsion on the Physicochemical Properties of Pork Loin

  • Shin, Hyerin;Kim, Hyo Tae;Choi, Mi-Jung;Ko, Eun-Young
    • Food Science of Animal Resources
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    • v.39 no.6
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    • pp.888-902
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    • 2019
  • Our aim was to investigate the effects of bromelain embedded in double emulsion (DE) on physicochemical properties of pork loin. We evaluated DE characteristics such as size, zeta potential, and microscopy after fabrication. We marinated meat with distilled water (DW), 1% (w/v) bromelain solution, blank DE, and 1% (w/v) bromelain loaded in double emulsion (DE E) for 0, 24, 48, and 72 h at 4℃, and prepared raw meat for control. The marinated samples were assessed for color, water holding capacity, cooking loss, moisture content, pH, protein solubility, Warner-Bratzler shear force (WBSF) and gel electrophoresis. The droplet size of 1% (w/v) bromelain embedded in DE was increased compared with blank DE (p<0.05) and values of zeta potential decreased. The increase in lightness and color difference range of the DE-treated group was lower than that of the DW-treated group (p<0.05). Moreover, treatment by immersion in 1% (w/v) DE E resulted in the highest water holding capacity values (p<0.05) and lower cooking loss values than water base treatment (p<0.05). Results for myofibrillar protein solubility and WBSF showed a similar trend. 1% (w/v) DE E showed degradation of myosin heavy chain after 48 h in sodium dodecyl sulfate-polyacrylamide gel electrophoresis. Thus, bromelain-loaded DE is useful for controlling and handling enzyme activity in food industry.

Removal of Copper and Zinc Ions by Neutralization from the Spent Sulfate Solutions of Brass Bulb Base (황동(黃銅) 전구(電球) Base 제조과정(製造過程)에서 발생(發生)한 구리와 아연 함유(含有) 황산폐수(黃酸廢水)의 중화법(中和法)에 의한 제거(除去))

  • Lee, Man-Seung;Ahn, Jae-Woo;Lee, Chang-Hae
    • Resources Recycling
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    • v.16 no.6
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    • pp.39-45
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    • 2007
  • Optimum condition for neutralization has been studied to remove the copper and zinc ions from spent sulfate solutions which resulted from the acid washing of the base of brass bulb. Chemical distribution of copper and zinc species and the variation of solubility of the two ions with solution pH were obtained by considering the complex formation reaction and mass balance. Removal percentage of zinc was more sensitive to solution pH than that of copper. This results from the fact that the solubility of zinc is higher than that of copper. The form of coagulant affected little the removal percentage of zinc, while addition of coagulant as the phase of solution resulted in higher removal percentage of copper than as the phase of solid.