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Control of Water-Adsorption Properties of Mesoporous Silica and MOF by Ion Exchange and Salt Impregnation (양이온 교환 및 염 함침을 통한 메조다공성 실리카와 유기-금속 구조체의 수분 흡착 특성 조절)

  • Lee, Eun Kyung;Cho, Kanghee;Kim, Sang Kyum;Lim, Jong Sung;Kim, Jong-Nam
    • Clean Technology
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    • v.24 no.1
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    • pp.55-62
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    • 2018
  • The adsorbent used in water-adsorption cooling system utilizing low-temperature heat of below $90^{\circ}C$ is required to exhibit high water uptake capacity at a relative humidity ($P/P_0$) between 0.1 and 0.3. Mesoporous silica (MCM-41) and MOF(MIL-101) exhibit quite large water adsorption capacity under saturated water vapor at $35^{\circ}C$. However, these adsorbents show small water adsorption capacity ($0.027{g_{water}\;g_{ads}}^{-1}$, $0.074{g_{water}\;g_{ads}}^{-1}$, respectively) in the relative humidity ($P/P_0$) range of 0.1 to 0.3. In this study, the surface properties of mesoporous silica and MOF were modified by simple methods to develop an adsorbent having a higher water uptake than the conventional water adsorbents at a relative humidity ($P/P_0$) of 0.1 ~ 0.3. In the case of mesoporous silica (MCM-41) exhibiting mainly water adsorption at $P/P_0=0.5{\sim}0.7$, aluminum species was functionalized on the mesopore walls and then cations existing near the aluminum were exchanged with various cations (e.g., $Na^+$, ${NH_4}^+$, and $(C_2H_5)_4N^+$). In addition, 20 wt% (to total weight of the composites) of hygroscopic inorganic salt ($CaCl_2$) was impregnated on the MCM-41. In the case of the MIL-101 (MOF), 20 wt% of hygroscopic inorganic salt ($CaCl_2$) was impregnated on the MIL-101. The MCM-41 which was ion-exchanged with various cations has main adsorption branch around 0.5 of $P/P_0$ which was slightly shifted with low-pressure direction in comparison with pristine MCM-41. However, tiny increases were observed on the adsorption in the range of $P/P_0$ between 0.1 and 0.3. After salt impregnation on the MCM-41, the adsorption capacity under $P/P_0=0.1{\sim}0.3$ at $35^{\circ}C$ was increased from $0.027{g_{water}\;g_{ads}}^{-1}$ to $0.152{g_{water}\;g_{ads}}^{-1}$. In the case of MIL-101, the amount of water adsorption at $35^{\circ}C$ under $P/P_0=0.1{\sim}0.3$ was increased from $0.074{g_{water}\;g_{ads}}^{-1}$ to $0.330{g_{water}\;g_{ads}}^{-1}$ after the salt impregnation.

The Effect of Addition of Egg Yolk and Sucrose on the pH and Specific Gravity for Heated Egg Albumen (난백의 가열처리에 있어서 난황과 자당 첨가가 pH 및 비중의 변화에 미치는 영향)

  • 황경규;양기원;하정기
    • Korean Journal of Poultry Science
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    • v.19 no.1
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    • pp.1-12
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    • 1992
  • This study was divided into experiment I(129g egg-albumen plus 150g sucrose) and experiment II(161g egg-albumen plus 150g sucrose) which were subdivided into groups treated with 0, 8.71, 17.43 and 26.149 egg yolk. These experiments were incubated in a shaking water bath(5$0^{\circ}C$) with a speed of 92(turnaround) per minute for a period of times. The pH and specific gravity were measured after 2, 4, 6, 8, 10 and 12 hour incubations. The results obtained were as follows: 1. The pH and specific gravity were steadily increased by shaking time, but variably was influenced by the amount of egg yolk and egg-albumen. 2. In the groups treated with egg-albumen, egg yolk, and sucrose of experiments I and II, pH was increased by the amount of egg-albumen in conjunction with shaking time, but specific gravity was decreased. 3. Ten hours after shaking maximum pH 8.60 was shown in the groups treated with 161g egg-albumen : however, in :he groups treated with 129g egg-albumen the maximum pH 8.39 was shown 12 hours after shaking. The different time exhibited maximum pH resulted from the amount of egg-albumen used. 4. The pH specific gravity were higher in the ,groups treated without egg yolk than in the groups with egg yolk. 5. In the experiment I which was added four levels of egg yolk to 1509 of sucrose and 129g of egg albumen, specific gravity(Table 2) had a high (r=0.9692$^{* *}$) correlation with pH (Table 1) and the regression equation between specific gravity and pH (X) was Y=0.050+0.145x. 6. In the experiment II which was added four levels of egg yolk to 150g of sucrose and 161g of egg albumen, specific gravity(Table 4) had a high (r=0.8963$^{* *}$) correlation with pH (Table 3) and the regression equation between specific gravity and pH (X) was Y=0.294+0.110X.10X.

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Optimization of Hobakjook (pumpkin soup) with Added Glutinous Rice Powder (호박 재료 배합비율을 달리한 호박죽의 품질 특성 연구)

  • Kim, Hyun-Ah;Kim, Jae-Hwan
    • Journal of the East Asian Society of Dietary Life
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    • v.25 no.1
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    • pp.162-175
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    • 2015
  • The purpose of this thesis was to develop pumpkin soup with different ratios of ingredients, using high-nutrient sweet pumpkins. P10G0 without sweet pumpkin and glutinous rice powder showed the highest moisture content, whereas, P5G0 whit Cheongdung pumpkin and sweet pumpkin at the same ratio whitout glutinous rice powder showed the lowest moisture content. For chromaticity lightness of control pumpkin soup scored the lowest. Lightness of P10G0 without sweet pumpkin and glutinous rice powder also scored the lowest. For redness, the P5 group with Cheongdung pumpkin and sweet pumpkin at the same ratio scored the highest while the P10 group without sweet pumpkin scored the lowest. As for yellowness, increased ratio of glutinous rice powder in pumpkin soup scored resulted in reduced yellowness in all groups P5 (p<0.01), P7 and P10 (p<0.001) A higher ratio of Cheongdung pumpkin was thus generally associated whit reduced yellowness (p<0.001). For the spread-ability, higher ratio of sweet pumpkin to Cheongdung pumpkin resulted in significant reduction of spread-ability. However, groups with 12% glutinous rice powder showed no significant differences. Spread-ability of the P5 and P10 groups significant increased and thereafter decreased according to the addition ratio of glutinous rice powder, viscosity of the G0 and G4 groups decreased according to the addition ratio of Cheongdung pumpkin, whereas they first decreased and then increased in the G8 and G12 groups. All groups showed increased viscosity whit more glutinous rice powder. For the sensory evaluation, P5G8 was mostly preferred in all aspects. P7G4 was superior in all aspects except for flavor. P10G4 scored the highest in all aspects except viscosity. For acceptance test, except for the control group, P7G4 whit added of 70% Cheongdung pumpkin, 30% sweet pumpkin and 4% glutinous rice powder was the most preferred in all aspects except color (gloss, viscosity, flavor, taste and overall quality).

COMMUTING ELEMENTS WITH RESPECT TO THE OPERATOR Λ IN INFINITE GROUPS

  • Rezaei, Rashid;Russo, Francesco G.
    • Bulletin of the Korean Mathematical Society
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    • v.53 no.5
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    • pp.1353-1362
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    • 2016
  • Using the notion of complete nonabelian exterior square $G\hat{\wedge}G$ of a pro-p-group G (p prime), we develop the theory of the exterior degree $\hat{d}(G)$ in the infinite case, focusing on its relations with the probability of commuting pairs d(G). Among the main results of this paper, we describe upper and lower bounds for $\hat{d}(G)$ with respect to d(G). Here the size of the second homology group $H_2(G,\mathbb{Z}_p)$ (over the p-adic integers $\mathbb{Z}_p$) plays a fundamental role. A further result of homological nature is placed at the end, in order to emphasize the influence of $H_2(G,\mathbb{Z}_p)$ both on G and $\hat{d}(G)$.

ON THE MONOPHONIC NUMBER OF A GRAPH

  • Santhakumaran, A.P.;Titus, P.;Ganesamoorthy, K.
    • Journal of applied mathematics & informatics
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    • v.32 no.1_2
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    • pp.255-266
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    • 2014
  • For a connected graph G = (V,E) of order at least two, a set S of vertices of G is a monophonic set of G if each vertex v of G lies on an x - y monophonic path for some elements x and y in S. The minimum cardinality of a monophonic set of G is the monophonic number of G, denoted by m(G). Certain general properties satisfied by the monophonic sets are studied. Graphs G of order p with m(G) = 2 or p or p - 1 are characterized. For every pair a, b of positive integers with $2{\leq}a{\leq}b$, there is a connected graph G with m(G) = a and g(G) = b, where g(G) is the geodetic number of G. Also we study how the monophonic number of a graph is affected when pendant edges are added to the graph.

LABELLING OF SOME PLANAR GRAPHS WITH A CONDITION AT DISTANCE TWO

  • Zhang, Sumei;Ma, Qiaoling
    • Journal of applied mathematics & informatics
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    • v.24 no.1_2
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    • pp.421-426
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    • 2007
  • The problem of vertex labeling with a condition at distance two in a graph, is a variation of Hale's channel assignment problem, which was first explored by Griggs and Yeh. For positive integer $p{\geq}q$, the ${\lambda}_{p,q}$-number of graph G, denoted ${\lambda}(G;p,q)$, is the smallest span among all integer labellings of V(G) such that vertices at distance two receive labels which differ by at least q and adjacent vertices receive labels which differ by at least p. Van den Heuvel and McGuinness have proved that ${\lambda}(G;p,q){\leq}(4q-2){\Delta}+10p+38q-24$ for any planar graph G with maximum degree ${\Delta}$. In this paper, we studied the upper bound of ${\lambda}_{p,q}$-number of some planar graphs. It is proved that ${\lambda}(G;p,q){\leq}(2q-1){\Delta}+2(2p-1)$ if G is an outerplanar graph and ${\lambda}(G;p,q){\leq}(2q-1){\Delta}+6p-4q-1$ if G is a Halin graph.

An Emergence of Equine-Like G3P[8] Rotaviruses Associated with Acute Gastroenteritis in Hospitalized Children in Thailand, 2016-2018

  • Chaiyaem, Thanakorn;Chanta, Chulapong;Chan-it, Wisoot
    • Microbiology and Biotechnology Letters
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    • v.49 no.1
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    • pp.120-129
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    • 2021
  • Rotavirus A (RVA) is recognized as a major etiology responsible for the development of acute gastroenteritis in children worldwide. The purpose of the present study was to perform the molecular characterization of RVA. A total of 323 stool specimens collected from hospitalized children with acute gastroenteritis in Chiang Rai, Thailand, in 2016-2018 were identified for G- and P-genotypes through RT-PCR analysis. RVA was more prevalent in 2017-2018 (37.8%) than in 2016-2017 (23.2%). The seasonal peak of RVA occurred from March to April. G3P[8] was predominant in 2016-2017 (90.6%) and 2017-2018 (58.6%). Other genotypes including G1P[8], G8P[8], G9P[8], and mixed infections were also identified. G3P[8] strains clustered together in the same lineage with other novel human equine-like G3P[8] strains previously identified in multiple countries and presented a genotype 2 constellation (G3-P[8]-I2-R2-C2-M2-A2-N2-T2-E2-H2). Several amino acid differences were observed in the antigenic epitopes of the VP7 and VP8* capsid proteins of the equine-like G3P[8] compared with those of the RVA vaccine strains. The homology modeling of the VP7 and VP8* capsid proteins of the equine-like G3P[8] strains evidently exhibited that these residue differences were present on the surface-exposed area of the capsid structure. The emergence of the equine-like G3P[8] strains in Thailand indicates the rapid spread of strains with human and animal gene segments. Continuous surveillance for RVA is essential to monitor genotypes and genetic diversity, which will provide useful information for selecting rotavirus strains to develop a safe and effective RVA vaccine that is efficacious against multiple genotypes and variants.

POLARIZED REAL TORI

  • Yang, Jae-Hyun
    • Journal of the Korean Mathematical Society
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    • v.52 no.2
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    • pp.269-331
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    • 2015
  • For a fixed positive integer g, we let $\mathcal{P}_g=\{Y{\in}\mathbb{R}^{(g,g)}{\mid}Y=^tY&gt;0\}$ be the open convex cone in the Euclidean space $\mathbb{R}^{g(g+1)/2}$. Then the general linear group GL(g, $\mathbb{R}$) acts naturally on $\mathcal{P}_g$ by $A{\star}Y=AY^tA(A{\in}GL(g,\mathbb{R}),\;Y{\in}\mathcal{P}_g)$. We introduce a notion of polarized real tori. We show that the open cone $\mathcal{P}_g$ parametrizes principally polarized real tori of dimension g and that the Minkowski modular space 𝔗g = $GL(g,\mathbb{Z}){\backslash}\mathcal{P}_g$ may be regarded as a moduli space of principally polarized real tori of dimension g. We also study smooth line bundles on a polarized real torus by relating them to holomorphic line bundles on its associated polarized real abelian variety.

CENTROIDS AND SOME CHARACTERIZATIONS OF PARALLELOGRAMS

  • Kim, Dong-Soo;Lee, Kwang Seuk;Lee, Kyung Bum;Lee, Yoon Il;Son, Seongjin;Yang, Jeong Ki;Yoon, Dae Won
    • Communications of the Korean Mathematical Society
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    • v.31 no.3
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    • pp.637-645
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    • 2016
  • For a polygon P, we consider the centroid $G_0$ of the vertices of P, the centroid $G_1$ of the edges of P and the centroid $G_2$ of the interior of P, respectively. When P is a triangle, the centroid $G_0$ always coincides with the centroid $G_2$. For the centroid $G_1$ of a triangle, it was proved that the centroid $G_1$ of a triangle coincides with the centroid $G_2$ of the triangle if and only if the triangle is equilateral. In this paper, we study the relationships between the centroids $G_0$, $G_1$ and $G_2$ of a quadrangle P. As a result, we show that parallelograms are the only quadrangles which satisfy either $G_0=G_1$ or $G_0=G_2$. Furthermore, we establish a characterization theorem for convex quadrangles satisfying $G_1=G_2$, and give some examples (convex or concave) which are not parallelograms but satisfy $G_1=G_2$.

Production of Fructose 6-Phoschate from Starch Using Thermostable Enzymes (내열성 효소를 이용한 전분으로부터 6-인산과당의 제조)

  • Kwun, Kyu-Hyuk;Cha, Wol-Suk;Kim, Bok-Hee;Shin, Hyun-Jae
    • KSBB Journal
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    • v.22 no.5
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    • pp.345-350
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    • 2007
  • Phosphosugars are found in all living organisms and are commercially valuable compounds with possible applications in the development of a wide range of specialty chemicals and medicines. In carbohydrate metabolism, fructose 6-phosphate (F6P) is an essential intermediate formed by phosphorylation of 6' position of fructose in glycolysis, gluconeogenesis, pentose phosphate pathway and Calvin cycle. In glycolysis, F6P lies within the glycolysis metabolic pathway and is produced by isomerisation of glucose 6-phosphate. For large-scale production, F6P could be produced from starch using many enzymes such as pullulanase, starch phosphorylase, isomerase and mutase. In enzymatic reactions carried out at high temperatures, the solubility of starch is increased and microbial contamination is minimized. Thus, thermophile-derived enzymes are preferred over mesophile-derived enzymes for industrial applications using starch. Recently, we reported the production of glucose 1-phosphate (G1P) from starch by Thermus caldophilus GK24 enzymes. Here we report the production of F6P from starch through three steps; from starch to glucose 1-phosphate (glucan phosphorylase, GP), then glucose 6-phosphate (phosphoglucomutase, GM) and then F6P (phosphoglucoisomerase, GI). Using 200 L of 1.2% soluble starch solution in potassium phosphate buffer, 1,253 g of G1P were produced. Then, 30% yields of F6P were attained at the optimum reaction conditions of GM : G1 (1 : 2.3), 63.5$^{\circ}C$, and pH 6.85. The optimum conditions were found by response surface methodology and the theoretical values were confirmed by the experiments. The optimum starch concentrations were 20 g/L under the given conditions.