• Title/Summary/Keyword: Ozone/UV

Search Result 255, Processing Time 0.027 seconds

The Study of VOCs Decomposition Characteristics Using UV Photolysis Process (휘발성유기화합물의 광분해 제거 특성에 관한 연구)

  • 서정민;정창훈
    • Journal of Environmental Science International
    • /
    • v.11 no.7
    • /
    • pp.743-748
    • /
    • 2002
  • UV photolysis process is little known in parts of air pollution treatment, so there are not many applications in field. Therefore we have to do more experiment and study application possibility for treatment of VOCs(Volatile organic compounds). To solve these problems, we have been studying for simultaneous application of this technology. It has shown that concentration of TCE and B.T.X., diameter of reactor and wavelength of lamp have effected on decomposition efficiency. Analysis of TCE and B.T.X. concentration was carried out by GC-FID. A cylinderical reactor consisting of a quartz tube and a centrally located lamp(${\psi}25mm$) was used. The length and diameter of reactor were 1800mm, 75mm. It has shown that the generated ozone concentration goes up 250ppm when using 64watt ozone lamp. When using Photolysis process only, the rates of fractional conversion of each material are TCE 79%, Benzene 65%, Toluene 68%, Xylene 76%. This phenomenon can be rationalized in terms of the different bond energy that indicates how easily VOCs species can be decomposed.

A fundamental study on ozone oxidation of humic substances (휴믹물질의 오존산화에 관한 기초연구)

  • 김은호;김영웅;손희종;장성호
    • Journal of environmental and Sanitary engineering
    • /
    • v.14 no.3
    • /
    • pp.10-21
    • /
    • 1999
  • The purpose of study were to research the characteristics of water variation adding humic acids to distilled water after ozonation. Upon investigating pH variation with contact time after providing distilled water+air, distilled water+ozone and distilled water-humic acid-air in reactor, it reduced after 60 minute in inletting air and in spite of short contact time did suddenly in inletting ozone. TOC and UV-254 continued to increase with contact time of ozone and humic acids. $NH^{4+}-N$ did slowly increase or decrease after constant contact time of ozone, because $NH^{4+}-N$ was converted into $No^3-N$ by ozone. T-N did suddenly increase after 90minute, but T-P did rarely fluctuate for total experiment. Total 30 species of organic matter were detected by GS/MSD, but 14 species did really tend to increase except for matter identified in distilled water and blank test. Humic acids generated $aliphatic{\cdot}aromatic$ hydrocarbon, alcohol and amine etc., and did various matters without inflow course of contaminants.

  • PDF

DEVELOPMENT OF OZONE DETECTOR FOR KSR-III AND PRELIMINARY TEST RESULTS (과학 로켓 3호용 오존 측정기 개발 및 초기 모델 시험 결과)

  • Hwang, Seung-Hyun;Kim, Jhoon;Kim, Jun-Kyu;Lee, Soo-Jin;Park, Jeong-Joo;Cho, Gwang-Rae
    • Journal of Astronomy and Space Sciences
    • /
    • v.17 no.2
    • /
    • pp.277-284
    • /
    • 2000
  • KARI(Korea Aerospace Research Institute) has measured the ozone density profiles over the Korean Peninsular since the launch of the Korean Sounding Rocket-I (KSR-I) in 1993. The purpose of ozone measurements is to obtain the stratospheric and mesospheric vertical ozone density profiles over the Korean Peninsular with solar UV radiometers. With the visible channel of the radiometer, the attitude variation of the rocket was corrected and compensated. Developed system is based on ozone detector designs onboard the KSR-I and KSR-II. We discuss the development of ozone detector which will be onboard the KSR-III and its circuit and vibration test results for EM model.

  • PDF

Effect of Advanced Treatment Process for Residual Chlorine Decay and THM Formation in Water Distribution System (고도처리공정이 관로 내 잔류염소 감소 및 THM 생성에 미치는 영향)

  • Lee, Doo-Jin;Kim, Young-Il;Kim, Sung-Su;Lee, Kyung-Hyuk;Park, Hyun-A
    • Journal of Korean Society of Environmental Engineers
    • /
    • v.29 no.4
    • /
    • pp.419-424
    • /
    • 2007
  • According to increase of consumer's desire for clean tap water, advanced treatment processes include with membrane, ozone, and granular activated carbon(GAC) were introduced. In order to evaluate the effect of advanced treatment processes for residual chlorine decay and trihalomethane(THM) formation in water distribution system, dissolved organic matter(DOC) removal of each advanced treatment process was investigated. The residual chlorine decay and THM formation using bottle tests were also evaluated. $UV_{254}$ removal in all advanced treatment was better than DOC removal. Especially, DOC by ozone treated was removed as 4% in contrast with sand filtered water, but $UV_{254}$ was removed about 17%. This result might be due to convert from hydrophobic DOC to hydrophilic DOC by ozonation. Ozone/GAC process was most effective process for DOC removal. The residual chlorine decay constants in treated water by sand filtration, ozonation, GAC adsorption, and ozone/GAC processes were 0.0230, 0.0307, 0.0117 and 0.0098 $hr^{-1}$, respectively. The sand filtered water was produced 81.8 ${\mu}g/L$ of THM after 190 hours of reaction time, as the treated water by ozone, GAC, and Ozone/GAC was less produced 6.0, 26.2, 30.3% in contrast with sand filtered water, respectively. Consequently, the durability of residual chlorine and reduction of THM formation were improved by advanced treatment processes.

Varietal Difference of Resistance to Ozone Injury in Rice Plant (벼 품종별 오존 피해 저항성 차이)

  • 손재근;이상철
    • KOREAN JOURNAL OF CROP SCIENCE
    • /
    • v.42 no.3
    • /
    • pp.338-343
    • /
    • 1997
  • The response of seventy-five rice cultivars to ozone (O$_3$) were tested in the open-top chamber with ozone producing and monitoring system to determine the varietal difference of resistance to $O_3$ stress. Ozone was produced by electrostatic discharge in oxygen and was monitored by UV absorption ozone analyzer. Difference in response of rice to ozone was more clearly appeared on rice plants treated for 2 to 4 hours at 0.3 ppm concentration of $O_3$. Varietal resistance of rice to ozone was more distinctly classified at 21- to 35-day seedlings compared with 14-day rice plants. Most of indica and Tongil(indica$\times$japonica) type rice cultivars were more resistant than that of japonica cultivars based on the leaf injury to $O_3$. Eight Korean cultivars belong to japonica groups showed highly resistant reaction to $O_3$. Ozone exposure during booting stage caused lower grain fertility than exposures during seedling, maximum tillering and heading stages of rice.

  • PDF

Livestock Wastewater Treatment Using the DOF and PO2 System with High Concentration of Ozone (고농도 오존을 적용한 DOF와 PO2 시스템의 축산폐수처리)

  • Lee, Byoung-Ho;Kim, Sung-Hyuk
    • Journal of Korean Society of Environmental Engineers
    • /
    • v.27 no.11
    • /
    • pp.1162-1167
    • /
    • 2005
  • Livestock wastewater is known to be very difficult to treat because it contains highly non-biodegradable organic material. Thus the DOF(Dissolved Ozone Flotation) system and the PO2(Pressurized Ozone Oxidation) system were built at the livestock wastewater treatment plant, and characteristics of treatments were investigated in this paper. Suspended Solids(SS) removal efficiency was over 94% by DOF system. 90% of $COD_{Mn}$ was removed, from 620 mg/L down to 63 mg/L by the DOF-PO2 system. During the period of operation, $SCOD_{Cr}$ was removed an average of 82%, from 890 mg/L down to 160 mg/L. 96% of UV-254 absorbance was also removed. TP removal efficiency was over 98%, from 27 mg/L to 0.35 mg/L, and TN was also removed 68% along with suspended solids. It was possible to meet effluent standards of the livestock wastewater treatment plant by the DOF-PO2 system along with biological treatment.

Characteristic of wastewater treatment using Boron-doped Diamond Electrode (붕소가 도핑된 다이아몬드전극을 이용한 폐수처리특성)

  • Lee, Eun-Ju;Einaga, Y.;Fujishima, A.;Park, Soo-Gil
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 2003.07b
    • /
    • pp.795-798
    • /
    • 2003
  • Toxic organics are of great environmental concern primarily because they are toxic to mammals and birds, and are relatively soluble in water to contaminate surface water and groundwater. In this study, the decomposition of phenol, a widely used organic, in aqueous solutions by Boron doped diamond(BDD) electrode was examined. Thin, Boron-doped conducting diamond films are expected to be excellent electrodes for industrial electrolysis. Boron-doped diamond (BDD) were used as anode for generating ozone gas by electrolysis of acid solution. In this work. we have studied ozone generating system using BDD electrode. In order to determine the ozone generation properties of diamond electrode, experimental conditions, electrolyte concentration, temperature, flow rate and reaction time were varied diversely. As a result, we could confirm that ozone gas was generated successfully and the performance of diamond electrode was stable for electrolyte while $PbO_2$ electrode was disintegrated. Actually we are found that ozone amount increased by lowering the temperature of electrolyte. Decomposition of phenol concentration in the reaction solution by photolytic ozonation( $UV/O_3$) was analyzed by HPLC epuipped with a UV detector.

  • PDF

A Study on Removal of Organic Matter and Chromaticity from Urine Using Chemical Oxidization Process (화학적 산화공정을 이용하여 소변의 색도 및 유기물 처리를 통한 재이용 기술 연구)

  • Shin, Sung-Hoon;Jung, Jong-Tai;Cho, Yong-Chul
    • Journal of Korean Society of Water Science and Technology
    • /
    • v.26 no.6
    • /
    • pp.109-115
    • /
    • 2018
  • This study was conducted to solve the water shortage problem by reclaiming urine from homes or public places and using it as cleaning water for toilets. The process used in this experiment is a chemical oxidation process combining ozone, hydrogen peroxide, and UV. We set the key substance that is to be removed as chromaticity and conducted the experiment to remove it. If the quantity or concentration of injected ozone, UV, and hydrogen peroxide is insufficient, then the chromaticity will initially increase due to low oxidizing power, and will later decrease. In addition, the efficiency of removing chromaticity appeared to be higher, depending on the quantity of ozone injected, for medium concentrated urine than highly concentrated urine. However, the absolute quantity of removed chromaticity was about 68% higher for highly concentrated urine, when 16 g/hr of ozone was injected. The higher the pH level, the reaction time and efficiency of removing chromaticity were higher, and in normal conditions, in reference to a pH of 8.55, there was a 6% difference in efficiency between a pH level of 5.05 and a pH level of 10.12. Finally, when processing urine through an ozone-only process, COD decreased steadily over time, but DOC did not decrease. This is because ozone reacts selectively with organic matter.

Economy Analysis to Retrofit Ballast Water Treatment System for an Existing Vessel (선박 평형수 처리장치 선정을 위한 경제성 분석)

  • JEE, Jae-Hoon;PARK, Sang-Kyun;OH, Cheol
    • Journal of Fisheries and Marine Sciences Education
    • /
    • v.28 no.5
    • /
    • pp.1319-1328
    • /
    • 2016
  • Since Ballast Water Management Convention has been effected, BWTS, applied to new-building vessels and existing vessels, have been developed from many countries with various treatment methods. However, BWTS is mainly typed Electrolysis, Ozone and UV type. Approximately 70 products have been type approved by the Flag Administrations. For the new-building vessels, the vessels' design and construction have been considered for arrangements and installations for BWTS. However, existing vessels which already construction had finished have problem with selection of BWTS type for installation and arrangement. The selection of the most economized BWTS system is important though, CAPEX has not been made any significant differences. However, OPEX is more important factor. Consequently, detail analysis of OPEX is the key to the selection of the most economized BWTS system and also it can be the purpose of this study. The feasibility study on the main three type of BWTS (Electrolysis, Ozone and UV type) for 175K Bulk Carrier and 57K Cargo ship has been conducted for this study. Because, these three type of BWTS have been the most frequently installed and used and the two type of object vessels are consist of the 40% of the world merchant ship market. For this study, interest rate, project duration (operation time after installation), maintenance cost and fuel oil price are considered as major factor of feasibility study. In addition, expecting Interest rates to sensitivity analysis conducted for more accurate feasibility study. For 175K Bulk carrier, ozone treatment system is more economical than other types. For 57K cargo ship, UV type is considered more economical than other types. However, it is concluded that electrolysis type is more suitable compare to installation space, total weight and electrical power consumption.

Ozone Monitoring in the Lower Tropospheric Atmosphere by LIDAR System (라이다 시스템을 이용한 하층 대류권 오존농도 측정)

  • 최성철;차형기;김덕현;김영상
    • Journal of Korean Society for Atmospheric Environment
    • /
    • v.17 no.5
    • /
    • pp.385-393
    • /
    • 2001
  • We have developed a Differential Absortion LIDAR (DIAL) method for the measurement of lower tropospheric ozone concentration. We used two laser beams from quadrupled Nd:YAG (266 nm) for the resonance wavelength and dye lasers (299.5 nm) for non -resonance wavelength. Aerosol extinction coefficients in the lower troposphere was computed by both Klett and Slope methods. To correct the SIN (Signal -Induced Noise) effect caused by photo detector, we subtracted a new-fitted baseline on the background part of a LIDAR signal, after the subtraction of the DC level. This is because SIN can be treated as an exponentially decaying tail. Using theme results, ozone profiles were obtained approximately 2km at daytime and 3km at nighttime. We compared the results derided by the Slope method with those measured by UV spectrometer. The computed results are in mostly good agreement with experimental results. In the measurement of the vertical layer, we observed the variation of the ozone profiles around the top mixed layer.

  • PDF