• 제목/요약/키워드: Ozone/UV

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VERTICAL OZONE DENSITY PROFILING BY UV RADIOMETER ONBOARD KSR-III

  • Hwang Seung-Hyun;Kim Jhoon;Lee Soo-Jin;Kim Kwang-Soo;Ji Ki-Man;Shin Myung-Ho;Chung Eui-Seung
    • Bulletin of the Korean Space Science Society
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    • 2004.10b
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    • pp.372-375
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    • 2004
  • The UV radiometer payload was launched successfully from the west coastal area of Korea Peninsula aboard KSR-III on 28, Nov 2002. KSR-III was the Korean third generation sounding rocket and was developed as intermediate step to larger space launch vehicle with liquid propulsion engine system. UV radiometer onboard KSR-III consists of UV and visible band optical phototubes to measure the direct solar attenuation during rocket ascending phase. For UV detection, 4 channel of sensors were installed in electronics payload section and each channel has 255, 290, 310nm center wavelengths, respectively. 450nm channel was used as reference for correction of the rocket attitude during the flight. Transmission characteristics of all channels were calibrated precisely prior to the flight test at the Optical Lab. in KARI (Korea Aerospace Research Institute). During a total of 231s flight time, the onboard data telemetered to the ground station in real time. The ozone column density was calculated by this telemetry raw data. From the calculated column density, the vertical ozone profile over Korea Peninsula was obtained with sensor calibration data. Our results had reasonable agreements compared with various observations such as ground Umkhr measurement at Yonsei site, ozonesonde at Pohang site, and satellite measurements of HALOE and POAM. The sensitivity analysis of retrieval algorithm for parameters was performed and it was provided that significant error sources of the retrieval algorithm.

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Surface Treatment and Dyeability of Poly(phenylene sulfide) Films by UV/O3 Irradiation (UV/Ozone 조사에 의한 Poly(phenylene sulfide) 필름의 표면처리와 염색성)

  • Jang, Yong-Joon;Jang, Jin-Ho
    • Textile Coloration and Finishing
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    • v.23 no.4
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    • pp.284-289
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    • 2011
  • Poly(phenylene sulfide)(PPS) films were photooxidized under UV/ozone irradiation. The effect of UV energy on the surface properties of the UV-irradiation PPS films were investigated by the measurement of reflectance, surface roughness, and contact angle. Reflectance decreased at the wavelength of 400nm and the surface roughness increased with increased UV energy. The improvement in hydrophilicity with increased $O_{1s}/C_{1s}$ was caused by the introduction of hydrophilic $SO_2$ bond. Surface energy increased from 46.6 to $78.3mJ/m^2$ with increased UV energy up to $21.2J/cm^2$. Also zeta potential decreased with increased UV energy. The increased dyeability to cationic dyes may be due to the photochemically introduced anionic and dipolar dyeing sites on the PPS films surfaces.he photochemically introduced anionic and dipolar dyeing sites on the PPS films surfaces.

Photooxidation of Poly(butylene succinate) Films by UV/Ozone Irradiation (자외선/오존 조사에 의한 Poly(butylene succinate) 필름의 광산화)

  • Joo, Jin-Woo;Jang, Jinho
    • Textile Coloration and Finishing
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    • v.26 no.3
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    • pp.159-164
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    • 2014
  • Biodegradable Poly(butylene succinate), PBS, was photooxidized by UV/ozone irradiation and the effect of UV energy on the surface properties of the UV-irradiated PBS film were investigated by the measurement of reflectance, surface roughness, contact angles, chemical composition, and zeta potential. With increasing UV energy, reflectance decreased in the visible and ultraviolet regions particularly at the wavelength of 380nm. The irradiation produced nano-scale surface roughness including the maximum peak-to-valley roughness increased from 106nm for the unirradiated sample to 221nm at the UV energy of $10.6J/cm^2$. The improved hydrophilicity was due to the higher $O_{1s}/C_{1s}$ resulting from the introduction of polar groups such as C-O and C=O bonds. The surface energy of the PBS increased from $42.1mJ/m^2$ for the unirradiated PBS to $56.8mJ/m^2$ at the irradiation of $21.2J/cm^2$. The zeta potentials of the UV-irradiated PBS also decreased proportionally with increasing UV energy. The cationic dyeability of the PBS increased accordingly resulting from the improved affinity of the irradiated PBS surfaces containing photochemically introduced anionic and dipolar dyeing sites.

Photooxidation of Poly(vinyl butyral) Films by UV/Ozone Irradiation (자외선/오존 조사에 의한 Poly(vinyl butyral)의 광산화)

  • Joo, Jin-Woo;Jang, Jinho
    • Textile Coloration and Finishing
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    • v.27 no.2
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    • pp.113-118
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    • 2015
  • Poly(vinyl butyral), PVB was photooxidized by UV/ozone irradiation and the effect of UV energy on the surface properties of the UV-irradiated PVB film were investigated by the measurement of reflectance, surface roughness, contact angles, elemental composition, and zeta potential. With increasing UV energy, reflectance decreased in the visible and ultraviolet regions particularly at the wavelength of 400nm. The irradiation produced nano-scale surface roughness including the maximum peak-to-valley roughness increased from 274nm for the unirradiated PVB to 370nm at the UV energy of $5.3J/cm^2$. The improved hydrophilicity was due to the higher $O_{1s}/C_{1s}$ resulting from the introduction of polar groups such as C=O bonds. The surface energy of the PVB film increased from $35.3mJ/m^2$ to $39.3mJ/m^2$ at the irradiation of $15.9J/cm^2$. While the zeta potentials decreased proportionally with increasing UV energy, the cationic dyeability of the PVB increased accordingly resulting from the improved affinity of the irradiated PVB surfaces containing the photochemically introduced anionic and dipolar dyeing sites.

Effects of UV ozone annealing on conduction mechanism in Ta2O5 thin films deposited by atomic layer deposition (Atomic layer deposition으로 증착된 Ta2O5 박막의 전도기구에 대한 UV ozone annealing 효과)

  • 엄다일;전인상;노상용;황철성;김형준
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2003.11a
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    • pp.57-57
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    • 2003
  • High dielectric constant materials (high K) have attracted a great deal of interest because of the dramatic scaling down of DRAM capacitor reaching its physical limit in terms of reduction of thickness. Among high-K materials that can replace silicon dioxide, tantalum pentoxide (Ta2O5) thin film, with their high dielectric constant (∼25) and good step coverage, is the candidate of choice.

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Development of a new efficient UV/Ozone duplex sterilizer (새로운 고효율 UV/Ozone 복합 살균기의 개발)

  • Park, Eun-Cheol;Kim, Gang-Seok;Ji, Jeong-Eun;Yang, Won-Gyun;Ju, Jeong-Hun
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2007.11a
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    • pp.48-49
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    • 2007
  • 자외선 살균기는 기존의 살균기보다 효율적으로 작동되어, 모델의 세균살균을 향상시키기 위하여 투과 반사와 오존을 복합적으로 사용하였다. 투과 반사 효과가 기존의 모델에 비해 세균살균의 효율에 상당한 영향을 주었음을 알 수 있었다.

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Inactivation of Infectious Cryptosporidium parvum by Various Disinfectants (다양한 소독제에 의한 감염성 크립토스포리디움 불활성화율 평가)

  • Byun, Seung-Heon;Lee, Mok-Young;Cho, Eun-Ju;Yoon, Tae-Ho;Kim, Tae-Ho;Han, Sun-Hee
    • Journal of Korean Society of Environmental Engineers
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    • v.29 no.5
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    • pp.533-539
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    • 2007
  • Cell culture infectivity assay using HCT-8 cell was combined with most-probable-number technique to evaluate the inactivation of Cryptosporidium parvum by various disinfectants, including chlorine, ozone, and UV light. The assay was demonstrated to be as sensitive as animal infectivity assay, which has been considered the "gold standard" for assessing Cryptosporidium oocyst infectivity, and a valuable tool to evaluate inactivation of C. parvum by disinfectants. Bench-scale inactivation study showed that at the condition of $5^{\circ}C$ and pH 7.0, CT value of $1,250mg{\cdot}min/L$ by chlorine and $16mg{\cdot}min/L$ by ozone were required to achieve approximately 1.0 log inactivation of C. parvum, suggesting that even ozone could not be sufficient to inactivate C, parvum at low. temperature. Unlike chlorine and ozone, UV light is very effective to inactivate C. parvum, regardless of temperature. A UV light dose of 2 $mJ/cm^2$ provided at least 3 log inactivation of C. parvum.

Ozone resistance of radiosensitive strains of escherichia coli K-12 (Escherichia coli K-12 방사선 감수성 균주의 오존 내성)

  • Harvey, Michel
    • Korean Journal of Microbiology
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    • v.26 no.2
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    • pp.113-121
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    • 1988
  • Ozone, an atmospheric pollutant, can damage similar UV and X-rays DNA and its components. It is possible then that the KNA damage produced by this gas are similar, to some extent, to those of radiations and that they could be repaired by the same DNA repair mechanisms. It has been observed in Escherichia coli that radiosensitive strains such as lex A, rec A and pol A, all deficient to some extent for DNA repair, are more sensitive to ozone than a wild type strain. We have thendetermined the ozone resistance and host-cell reactivation of ozone-damaged T3 phages for the E. coli double mutants pol A, lex A, uvr B, lex A, uvr A, rec A and rec A lox A. According to the results, the DNA polymerase 1 plays a key role in ozone resistance and Type 11 mechanism and/or shory patch excision repair are the most important for it. The interactions between the different DNA repair mechanisms are secondary. There is a strong correlation between ozone resistance and the capacity to reactivate T3 phages damaged by ozone.

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Overview of UV-B Effects on Marine Algae (자외선이 해조류에 미치는 영향에 관한 고찰)

  • 한태준
    • Korean Journal of Environmental Biology
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    • v.17 no.1
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    • pp.1-9
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    • 1999
  • Numerous observations revealed strong evidence of increased middle ultraviolet radiation or UV-B (280 ~ 320 nm) at the earth's surface resulting from stratospheric ozone depletion. UV is the waveband of electromagnetic radiation which is strongly absorbed by nucleic acids and proteins, thus causing damage to living systems. It has been recorded in the East Sea, Korea that solar UV-B impinging on the ocean surface penetrates seawater to significant depths. Recent researches showed that exposure to UV-B for as short as 2h at the ambient level (2.0 Wm$^{-2}$) decreased macroalgal growth and photosynthesis and destroyed photosynthetic pigments. These may suggest that UV-B could be an important environmental factor to determine algal survival and distribution. Some adaptive mechanisms to protect macroalgae from UV-damage have been found, which include photoreactivation and formation of UV-absorbing pigments. Post-illumination of visible light mitigated UV-induced damage in laminarian young sporophytes with blue the most effective waveband. The existence of UV-B absorbing pigments has been recognized in the green alga, Ulva pertusa and the red alga, Pachymeniopsis sp., which is likely to exert protective function for photosynthetic pigments inside the thalli from UV-damage. Further studies are however needed to confirm that these mechanisms are of general occurrence in seaweeds. Macroalgae together with phytoplankton are the primary producers to incorporate about 100 Gt of carbons per year, and provide half of the total biomass on the earth. UV-driven reduction in macroalgal biomass, if any, would therefore cause deleterious effects on marine ecosystem. The ultimate impacts of increasing UV-B flux due to ozone destruction are still unknown, but the impression from UV studies made so far seems to highlight the importance of setting up long-term monitoring system for us to be able to predict and detect the onset of large -scale deterioration in aquatic ecosystem.

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