• The Journal of Fisheries Business Administration
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• v.51 no.2
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• pp.71-87
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• 2020

Oysters are the most abundantly harvested type of shellfish in Korea. As export of this marine product increases, oysters have greatly contributed to an increase in fishing income. As the oyster aquaculture industry has rapidly grown since the late 1990s, issues of oyster-shell processing that occur in production processes have re-emerged as important topics in the oyster industry. The amount of oyster shells harvested in 2019 is estimated to be approximately 300,000 tons. With reductions in demand for pyrolytic fertilizer and feed, which are currently the greatest sources of demand, unprocessed shell quantities have doubled compared to 2018, causing them to be an issue once more. Such oyster-shell processing also incurs great costs, and a total of forty-six billion three hundred fifty million Korean won (46,350,000,000 KRW) has been provided from 2009 to 2020 for the use of oyster shells as a resource. According to current Korean laws, oyster shells are considered to be industrial waste if more than 300 kilograms are sent out in a day. Collection and processing must be conducted by a waste-consignment company. Consequently, there are many limitations to the use of oyster shells in Korea as a resource. However, in Japan, only oyster-shell waste is regulated by waste-processing As a result, local governments may apply exceptions when utilized as organic matter. Consequently, in Japan, oyster shells are being used as resources in more diverse fields than in Korea. This study observes the conditions and problems of oyster-shell processing in Korea and attempts to find new domestic oyster-shell resource solutions in light of Japan's recycling practices.

• Journal of Soil and Groundwater Environment
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• v.26 no.1
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• pp.17-23
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• 2021

In order to investigate change of shear strength of coastal muddy sediment by mixing pretreated oyster shells with different pyrolysis temperatures and particle sizes, a vane shear test was carried out. The shear strength of the sediment with oyster shells pyrolyzed at 800℃ was twice higher than that of the control, with a maximum shear strength of ca. 0.2 kPa. The Ca2+ concentration in the pore water was the highest at sediment with oyster shells pyrolyzed at 800℃ with a concentration of ca. 790 mg/L. From the above results, it is concluded that the application of the oyster shells pyrolyzed at 800℃ can affect the increase in shear strength of coastal sediments through the aggregation of clay particles and pozzolanic reactions with sediments.

• Journal of the Korean GEO-environmental Society
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• v.2 no.2
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• pp.33-39
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• 2001

In order to utilize mass of oyster shells for a partial substitute material for reclamation, the shear characteristics of two-phase mixture soil with oyster shells were investigated with $\overline{CU}$ test. From various experiments, it was found that the increase of mixed ratio of oyster shells causes the shear strength of mixed soil. And this phenomenon not only depends on friction due to confining pressure such as pure clay but also is influenced by shaping skeleton of oyster shells. Also, it was discovered that there were many influences by clay-oyster shell mixture from the study of the secant modulus and dilatancy characteristics of mixed soil. In addition, variation of oyster shell skeleton during shearing stage is examined applying modifying coefficient concept.

• Journal of the Korean Applied Science and Technology
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• v.27 no.4
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• pp.427-436
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• 2010

Much oyster shell is breeding by character and conduct of oyster-industry for a long time among them. An experimental study was carried out to investigate the recycling possibility of waste oyster shells, which induce environmental pollutions by piling up out at the open or the temporary reclamation. The purpose of this study is to develope eco-friendly binder using waste oyster shells, and to reinforce soils fur soft soil improvement. In this paper, a series of laboratory tests including compressive pot tests were performed to evaluate characteristics of soils treated by developed waste oyster shells with different water content of soils. Based on test results, eco-friendly Supporter manufactured from waste oyster shells were estimated as good resource materials for soft soil improvements. We got the conclusion by a series of experiment, It is verified that change of pH of soil is improved by mixing with oyster shells. The homogenization method for deducing apparent of oyster shells, which can consider micro-structure of mixed soil, is introduced. The improvement treatment leaded to enlarge fluctuation of soil moisture content. The effect of calcium concentration was good though improvement treatment of physical property. In addition, the crop yield in amelioration plots increased. It means that the increase of crop yield was caused by improvement of soil physical properties rather than improvement of calcium concentration.

• Journal of the Korea Concrete Institute
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• v.15 no.2
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• pp.280-287
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• 2003

To evaluate the practical application of oyster shells(OS) as construction materials, an experimental study was performed. More specifically, the long-term mechanical properties and durability of concrete blended with oyster shells were investigated. Test results indicate that long-term strength of concrete blended with 10% oyster shells is almost identical to that of normal concrete. However, the long-term strength of concrete blended with 20% oyster shells is appreciably lower than that of normal concrete. Thereby, concrete with higher oyster shell blend has the possibility of negatively influencing the concrete long-term strength. Elastic modulus of concrete blended with crushed oyster shells decreases as the blending mixture rate increases. Namely, the modulus is reduced to approximately 10∼15% when oyster shells are blended up to 20% as the fine aggregate. The drying shrinkage strain increases with an increasing crushed oyster shells substitution rate. In addition, the existing model code of drying shrinkage and creep do not coincide with the test results of this study. An adequate prediction equation needs to be developed. The utilization of oyster shells as the fine aggregate in concrete has an insignificant effect on fleering and thawing resistance, carbonation and chemical attack of concrete. However, water permeability is considerably improved.

• Journal of Energy Engineering
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• v.27 no.1
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• pp.1-11
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• 2018

Oysters have been continuously produced from all around the world including South Korea every year. The oyster shell by-products accompanied by the oysters have caused the social and environmental problems due to the absence of any method or technique to deal with the by-products. In order to solve those problems, diverse researches and environmental friendly methods using the oyster shells are in development by now due to the possibility as cheap materials. In this review, we discuss the worldwide status of oyster shells and investigate the physical and chemical characteristics of the oyster shells. In addition, we discuss the recent trends about the sustainable methods to utilize the oyster shells.

• Journal of Korean Society on Water Environment
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• v.32 no.5
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• pp.458-464
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• 2016

This study evaluated the dewatering efficiency of inorganic dehydrating agents that contain oyster shells. A filter press dehydrator was used for this study. The experiments were performed by the single injection of calcium-based chemicals, the single injection of oyster shells, and the mixed injection of oyster shells and calcium-based chemicals. The moisture content of the dewatered cake generated after dehydration confirmed that the best dewatering efficiency was found at the mixing ratios of CaCO₃ to sludge, oyster shell to sludge, and inorganic dehydrating agent to sludge of 3:1, 10:1, and 1.5:2.5:1, respectively. The moisture contents exhibited less than 58% when the injection mixing ratio of inorganic dehydrating agent to sludge was 1.5:2.5:1. From EPS, SEM, and EDX analysis, it was found that the calcium adsorbed on the sludge surface could reduce extracellular polymeric substances (EPSs) and enhanced the dewaterbility. Based on the above results, it is considered possible to apply inorganic dehydrating agents containing recycled oyster shells in sludge dewatering in order to reduce sludge.

• Journal of Environmental Health Sciences
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• v.27 no.2
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• pp.17-21
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• 2001

The object of this study is to find out the characteristics of waste oyster shells and determine the proper dosage of powdered waster oyster shells as the conditioning agent for water treatment sludge dewatering process. The large amount of waste oyster shells which discharges from the oyster farming, occurs serious environmental hazards. However, oysters shell contain large amount(about 38% by weight) of alkaline minerals, such as calcium and magnesium and so on, this natural material is thought to have the petential ability as a good conditioning agent. The results of this study are as follows. The optimum condition for improvement of the water treatment sludge dewaterability is when 6 g of waste oyster shell powder added to 200$m\ell$ of water treatment sludge. At optimum condition, the solid contents can reach to 31.78% and the specific resistance of conditioned sludge is 0.16$\times$10$^{8}$ sec$^2$/g. However, exceeding the of powdered waste oyster shell is needed to get the effective result. Consequently, the waste oyster shell can be a recyclable material to improve the dewaterability of water treatment sludges.

• Journal of the Korea institute for structural maintenance and inspection
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• v.10 no.5
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• pp.137-147
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• 2006

This is an experimental study on the properties and the strength development of concrete using of the oyster shells as a substitute fine aggregate of concrete. For this purpose, the fundamental experiments of the materials and the main factors on it were considered and then the workability and many kinds of strength about the specimens were also studied. As the experimental results, there were strength differences of less than 10% between concrete with oyster shells and normal and the most excellent grain size of oyster shells is 5.0mm and less with taking uniformly and the percentage of practicable substitution of them to fine aggregate about 30%. This paper also represents the relationship equations among many kinds of strength and elastic modulus of concrete with the oyster shells decreased with increase in proportion of oyster shells and curve of it is similar about the percentage of substitution of 10%.

• Korean Journal of Environmental Agriculture
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• v.28 no.4
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• pp.378-385
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• 2009

Arsenic (As) is known to be very toxic and carcinogenic to human beings. Arsenic contaminated soil was collected from a timber mill site at Busan Metropolitan City, Korea, where chromated copper arsenate (CCA) had been used to protect wood from rotting caused by insects and microbial agents. The soil was stabilized using both natural oyster shells (NOS) and calcinated oyster shells (POS). The calcination of natural oyster shells was accomplished at a high temperature in order to activate quicklime from calcite. Two different oyster shell particle sizes (-#10 mesh and -#20 mesh) and curing periods of up to 28 days were investigated. The stabilization effectiveness was evaluated based on the Korean Standard Test (KST) method (1N HCl extraction). The stabilization results showed that the POS treatment was more effective than the NOS treatment at immobilizing the As in the contaminated soils. A significant As reduction (96%) was attained upon a POS treatment at 20 wt% and passed the Korean warning standard of 20 mg/kg ('Na' area). However, an As reduction of only 47% (169 mg/kg) was achieved upon a NOS treatment at 20 wt%. The -#20 mesh oyster shells seem to perform better than the -#10 materials. The scanning electron microscopy (SEM)-energy dispersive X-ray spectroscopy (EDX) results showed that As immobilization was strongly associated with Ca and O in the presence of Al and Si.