• 제목/요약/키워드: Oxygen-Rich

검색결과 291건 처리시간 0.023초

산소부화된 메탄 예혼합 화염에서 CF4 분해에 대한 연구 (The Investigation of CF4 Decomposition in Methane Premixed Flames on Oxygen Enrichment)

  • 이기용
    • 한국연소학회지
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    • 제22권4호
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    • pp.51-56
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    • 2017
  • The decomposition of tetrafluoromethane has been investigated with the reaction mechanism proposed for freely propagating $CH_4/CF_4/O_2/N_2$ premixed flames on the oxygen enrichment. The factors affecting on the removal efficiency of tetrafluoromethane were analyzed. The increase in flame temperature due to oxygen enrichment has a great influence on the removal efficiency of tetrafluoromethane. At the same oxygen enrichment condition, the removal efficiency in the rich flame is higher than one in the lean flame. The increase of the F/H ratio leads to decrease the flame temperature and the removal efficiency of tetrafluoromethan is decreased at the flame temperature of 2600 K or lower, The elementary reactions that dominate the consumption of tetrafluoromethane are (R1) $CF_4+M=CF_3+F+M$ and (R2) $CF_4+H=CF_3+HF$. (R1) has the greatest effect on the consumption of tetrafluoromethane under the oxygen enhanced flames.

나노 다층 TiAlSiN 박막의 고온 산화 (High-temperature Oxidation of Nano-multilayered TiAlSiN Filems)

  • 이동복;김민정
    • 한국표면공학회:학술대회논문집
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    • 한국표면공학회 2016년도 추계학술대회 논문집
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    • pp.189-189
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    • 2016
  • In this study, the Al-rich AlTiSiN thin films that consisted of TiN/AlSiN nano-multilayers were deposited on the steel substrate by magnetron sputtering, and their high-temperature oxidation behavior was investigated, which has not yet been adequately studied to date. Since the oxidation behavior of the films depends sensitively on the deposition method and deposition parameters which affect their crystallinity, composition, stoichiometry, thickness, surface roughness, grain size and orientation, the oxidation studies under various conditions are imperative. AlTiSiN nano-multilayer thin films were deposited on a tool steel substrate, and their oxidation behavior of was investigated between 600 and $1000^{\circ}C$ in air. Since the amount of Al which had a high affinity for oxygen was the largest in the film, an ${\alpha}-Al_2O_3-rich$ scale formed, which provided good oxidation resistance. The outer surface scale consisted of ${\alpha}-Al_2O_3$ incoporated with a small amount of Ti, Si, and Fe. Below this outer surface scale, a thin ($Al_2O_3$, $TiO_2$, $SiO_2$)-intermixed scale formed by the inwardly diffusing oxygen. The film oxidized slower than the $TiO_2-forming$ kinetics and TiN films, but faster than ${\alpha}-Al_2O_3-forming$ kinetics. During oxidation, oxygen from the atmosphere diffused inwardly toward the reaction front, whereas nitrogen and the substrate element of iron diffused outwardly to a certain extent.

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Design of Cooling Channels of Preburners for Small Liquid Rocket Engines with Computational Flow and Heat Transfer Analysis

  • Moon, In-Sang;Lee, Seon-Mi;Moon, Il-Yoon;Yoo, Jae-Han;Lee, Soo-Yong
    • Journal of Astronomy and Space Sciences
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    • 제28권3호
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    • pp.233-239
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    • 2011
  • A series of computational analyses was performed to predict the cooling process by the cooling channel of preburners used for kerosene-liquid oxygen staged combustion cycle rocket engines. As an oxygen-rich combustion occurs in the kerosene fueled preburner, it is of great importance to control the wall temperature so that it does not exceed the critical temperature. However, since the heat transfer is proportional to the speed of fluid running inside the channel, the high heat transfer leads to a trade-off of pressure loss. For this reason, it is necessary to establish a certain criteria between the pressure loss and the heat transfer or the wall surface temperature. The design factors of the cooling channel were determined by the computational research, and a test model was manufactured. The test model was used for the hot fire tests to prove the function of the cooling mechanism, among other purposes.

소형 액체로켓용 산화제과잉 예연소기 제작 (Manufacture of Oxygen Rich Preburner for Small Liquid Rocket)

  • 강진모;방정석;이병호;유재한;문인상;이수용
    • 한국추진공학회:학술대회논문집
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    • 한국추진공학회 2010년도 제35회 추계학술대회논문집
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    • pp.533-536
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    • 2010
  • 고성능 소형 액체로켓에 적용되는 산화제 과잉 예연소기의 시제품 제작을 수행하였다. 항공우주연구원에서 해석, 설계한 모델을 바탕으로 예연소기의 레이아웃을 설계하고 시제품 설계와 제작을 위해 수류시험용 평판 브레이징 시제품 제작 및 시험, 구조강도 시험용 헤드 시제품 제작 및 시험, 구조강도 시험용 채널 시제품 제작 및 시험 등을 진행하였다. 이러한 일련의 시험을 통해 예연소기 시제품을 설계하고 제작을 위한 세부사항을 확인하였으며, 이러한 노력을 통해 향후 고성능 액체로켓 개발을 위한 기술기반을 확립할 수 있으리라 사료된다.

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DUST SHELL MODELS FOR LOW MASS-LOSS RATE OXYGEN-RICH AGB STARS

  • SUH KYUNG-WON
    • 천문학회지
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    • 제38권2호
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    • pp.267-270
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    • 2005
  • We investigate the spectral energy distributions (SEDs) of low mass-loss rate O-rich asymptotic giant branch (AGB) stars using the infrared observational data including the Infrared Space Observatory (ISO) data. Comparing the results of detailed radiative transfer model calculations with observations, we find that the dust formation temperature is much lower than 1000 K for standard dust shell models. We find that the superwind model with a density-enhanced region can be a possible alternative dust shell model for LMOA stars.

CHEMICAL COMPOSITION OF DUST GRAINS IN NOVAE

  • Suh, Kyung-Won
    • Journal of Astronomy and Space Sciences
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    • 제11권2호
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    • pp.165-174
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    • 1994
  • We have investigated the chemical composition of dust grains in novae by computing the model spectra for the novae that showed temporary infrared developments shortly after their optical explosions. We find that a simple spherical dust shell models with hot blackbody central sources fit observations fairly well. Optical properties of dust grains deduced from modeling of AGB stars have been used for present calculations. We find that amorphous carbon grains appear to be the major infrared re-emission sources for the carbon-rich nova shells, and the silicate grains for the oxygen-rich nova shells.

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Effective Oxygen-Defect Passivation in ZnO Thin Films Prepared by Atomic Layer Deposition Using Hydrogen Peroxide

  • Wang, Yue;Kang, Kyung-Mun;Kim, Minjae;Park, Hyung-Ho
    • 한국세라믹학회지
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    • 제56권3호
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    • pp.302-307
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    • 2019
  • The intrinsic oxygen-vacancy defects in ZnO have prevented the preparation of p-type ZnO with high carrier concentration. Therefore, in this work, the effect of the concentration of H2O2 (used as an oxygen source) on the oxygen-vacancy concentration in ZnO prepared by atomic layer deposition was investigated. The results indicated that the oxygen-vacancy concentration in the ZnO film decreased by the oxygen-rich growth conditions when using H2O2 as the oxygen precursor instead of a conventional oxygen source such as H2O. The suppression of oxygen vacancies decreased the carrier concentration and increased the resistivity. Moreover, the growth orientation changed to the (002) plane, from the combined (100) and (002) planes, with the increase in H2O2 concentration. The passivation of oxygen-vacancy defects in ZnO can contribute to the preparation of p-type ZnO.

산화제 과잉 예연소기 저주파 연소특성 연구 (Research on the Low-Frequency Combustion Characteristics of an Oxygen-Rich Preburner)

  • 문인상;문일윤;하성업
    • 한국추진공학회지
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    • 제17권1호
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    • pp.89-96
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    • 2013
  • 산화제 과잉 예연소기의 연소안정성을 알아보기 위하여 예연소기의 각 부위에서 압력을 측정하였다. 압력측정은 정압센서와 동압센서를 모두 이용하여 이루어졌다. 이 때 사용된 정압센서와 동압센서의 해상도는 각각 최고 1000 Hz와 25,600 Hz이다. 예연소기의 정격압은 200 bar이나 위험을 줄이기 위하여 초기에는 80 bar로 낮추어 시험을 하였고 안정성이 확인된 이후 200 bar 시험을 실시하였다. 또한 모든 시험에서 점화충격을 줄이기 위하여 저압점화 후 연소압을 정격압력까지 올리는 2단 점화를 사용하였다. 시험은 최대 약 10초가량 실시되었으며 메인모드 진입 이후에는 연소압에 큰 변화 보이지 않았다. 연소압의 측정결과는 FFT를 통해 좀 더 심도 있게 분석되었으며 그 결과 예연소기의 연소안정성을 해할 만한 주파수의 커플링은 발견되지 않았다. 따라서 현재 개발되고 있는 예연소기는 향후 다단 연소사이클 엔진 연구에 활용할 수 있을 것으로 기대한다.

연료과농 조건에서의 기체메탄-기체산소 반응물의 연소특성 (Combustion Characteristics of the Gaseous-methane & Gaseous-oxygen Reactants under Highly Fuel-rich Conditions)

  • 강윤형;안현종;배창한;김정수
    • 한국추진공학회지
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    • 제25권6호
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    • pp.45-52
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    • 2021
  • 본 연구에서는 액체 추진제 소형로켓엔진의 개발을 위한 선행연구로 연료과농 조건의 기체메탄-기체산소 연소시험 결과를 제시한다. 다양한 당량비에 대한 연소특성을 비교하기 위해 산소 공급 유량을 12 g/s로 설정하고 메탄 공급 유량을 변화시켰다. 시험 결과, 연소시험 중 형성되는 정상상태 특성속도가 후반에서 급작스럽게 증가하는 현상이 관측되었으며, 그 변화량은 당량비에 비례하여 커지는 경향을 확인할 수 있었다. 이를 바탕으로 특성속도의 변이특성에 종속하는 당량비 구간을 총 3가지 연소 범주로 구분하였다.