• 제목/요약/키워드: Oxygen transfer

검색결과 620건 처리시간 0.02초

Effect of Ce0.9Gd0.1O1.95 as a promoter upon the oxygen transfer properties of MgMnO3-δ-Ce0.9Gd0.1O1.95 composite oxygen carrier materials for chemical looping combustion

  • Hwang, Jong Ha;Lee, Ki-Tae
    • Journal of Ceramic Processing Research
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    • 제20권1호
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    • pp.18-23
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    • 2019
  • Chemical looping combustion (CLC) is a promising carbon capture and storage (CCS) technology whose efficiency and cost primarily relies on the oxygen carrier materials used. In this paper, gadolinium-doped ceria (GDC, Ce0.9Gd0.1O1.95) was added as a promoter to improve the oxygen transfer rate of MgMnO3-δ oxygen carrier materials. Increasing GDC content significantly increased the oxygen transfer rate of MgMnO3-δ-GDC composites for the reduction reaction due to an increase in the surface adsorption of CH4 via oxygen vacancies formed on the surface of the GDC. On the other hand, the oxygen transfer rate for the oxidation reaction decreased linearly with increasing GDC content due to the oxygen storage ability of GDC. Adsorbed oxygen molecules preferentially insert themselves into oxygen vacancies of the GDC lattice rather than reacting with (Mg,Mn)O to form MgMnO3-δ during the oxidation reaction.

HYDRAULIC ANALYSIS OF OXYGEN TRANSFER THROUGH AIR ENTRAINMENT IN RIPARIAN RIFFLES

  • Kim, Jin-Hong
    • Water Engineering Research
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    • 제4권3호
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    • pp.127-139
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    • 2003
  • This paper presents the hydraulic analysis of the oxygen transfer through the air entrainment and the relationships between the efficiency of the oxygen transfer and the hydraulic parameters in the riparian riffles. Field survey on the pool-riffle formation of the river reach and the measurements of the oxygen transfer in the riffles were performed. Air entrainment occurred more frequently in the edged gravels rather than in the round and edgeless ones, and it was formed mainly from behind the trailing edges of the gravels. Oxygen transfer was found to be proportional to the flow velocity, the flow discharge, and the Froude number, but to be not closely related to the particle diameter. Average value of oxygen transfer in the riffles of study area was about 0.085, which shows good efficiency compared with results of smooth chute. Variation of the water level, which increases in proportion to the flow velocity and the flow discharge, seems to make the air entrainment more active, but has not been verified quantitatively. Relationships between the air entrainment and the variation of the water level must be considered in the further study.

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Oxygen Transfer Characteristics of an Ejector Aeration System

  • Yang, Hei-Cheon;Park, Sang-Kyoo
    • International Journal of Fluid Machinery and Systems
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    • 제5권1호
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    • pp.10-17
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    • 2012
  • The objective of this study was to investigate the oxygen transfer characteristics of an ejector aeration system. In order to evaluate the oxygen transfer performance of the ejector aeration system, a comparative experiment was conducted on a conventional blower aeration system. The effect of entrained air flow rate and aerating water temperature on the oxygen transfer efficiency was investigated. The dissolved oxygen concentration increased with increasing entrained air flow rate, but decreased with increasing aerating water temperature for two aeration systems. The volumetric mass transfer coefficient increased with increasing entrained air flow rate and with increasing aerating water temperature for both aeration systems. The average mass transfer coefficient for the ejector aeration system was about 20% and 42% higher than that of the blower aeration system within the experimental range of entrained air flow rates and aerating water temperatures.

산소전달량 및 마모손실 측정에 의한 매체순환연소용 산소전달입자 후보 선정 (Selection of Oxygen Carrier Candidates for Chemical Looping Combustion by Measurement of Oxygen Transfer Capacity and Attrition Loss)

  • 김하나;박재현;백점인;류호정
    • 한국수소및신에너지학회논문집
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    • 제27권4호
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    • pp.404-411
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    • 2016
  • To select appropriate oxygen carrier candidates for chemical looping combustion, reduction characteristics of seven oxygen carriers were measured and discussed using three different reduction gases, such as $H_2$, CO, and $CH_4$. Moreover, attrition losses of those oxygen carriers also measured and compared. Among seven oxygen carrier particles, OCN703-1100 and NiO/bentonite particles showed higher oxygen transfer capacity than other particles, but these particles showed more attrition loss than other particles. C14 and C28 particles which used as cheap oxygen carriers in European country showed lower oxygen transfer capacity and less attrition loss. Based on the experimental results, we could select OCN717-R1SU, NC001, and N002 particles as candidates for future works because these oxygen carriers showed enough oxygen transfer capacity and good attrition resistance.

미생물 배양 시스템에서의 산소 전달 (Oxygen Transfer in Microbial System)

  • 최동원
    • 한국식품영양학회지
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    • 제7권4호
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    • pp.399-405
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    • 1994
  • Some method was introduced to explain oxygen transfer from broth to cell during aerobic microbe cultivation. It is explained by 5 steps that how desolved oxygen can reach to cell. Among these steps film resistance was the most important factor to describe oxygen transfer. Lumped model and distributed model was introduced to explain oxygen diffusion rate and oxygen consumption rate which occurs in the microbe pellet.

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Numerical study of oxygen transport characteristics in lead-bismuth eutectic for gas-phase oxygen control

  • Wang, Chenglong;Zhang, Yan;Zhang, Dalin;Lan, Zhike;Tian, Wenxi;Su, Guanghui;Qiu, Suizheng
    • Nuclear Engineering and Technology
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    • 제53권7호
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    • pp.2221-2228
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    • 2021
  • One-dimensional oxygen transport relation is indispensable to study the oxygen distribution in the LBE-cooled system with an oxygen control device. In this paper, a numerical research is carried out to study the oxygen transport characteristics in a gas-phase oxygen control device, including the static case and dynamic case. The model of static oxygen control is based on the two-phase VOF model and the results agree well with the theoretical expectation. The model of dynamic oxygen control is simplified and the gas-liquid interface is treated as a free surface boundary with a constant oxygen concentration. The influences of the inlet and interface oxygen concentration, mass flow rate, temperature, and the inlet pipe location on the mass transfer characteristics are discussed. Based on the results, an oxygen mass transport relation considering the temperature dependence and velocity dependence separately is obtained. The relation can be used in a one-dimensional system analysis code to predict the oxygen provided by the oxygen control device, which is an important part of the integral oxygen mass transfer models.

항생물질발효에서의 산소전달 및 흡수속도에 관한 연구 (The Oxygen Transfer and Oxygen Uptake in Antibiotic Fermentation using Streptomyces kanamyceticus)

  • Lee, Kye-Joon;Moo Bae
    • 한국미생물·생명공학회지
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    • 제10권3호
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    • pp.223-226
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    • 1982
  • 통기발효에서 중요한 통기 및 진탕효과를 측정함에 있어 공기로부터 물속으로 용존해 가는 산소의 전달속도와, 용존된 산소가 미생물에 의해 흡수되는 속도를 산출하였다. 항생물질발효에서 통기효과는 현저하였으며, 배양시간에 따른 산소흡수 속도와 비산소흡수 속도가 변화하는 것을 알았다. 이러한 변화는 대사이차 산물인 항생물질생합성의 생화학적인 전환에 기인하는 것으로 판단된다.

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Jet 폭기 시스템의 순환유량에 따른 산소전달 특성 및 순산소 적용성 검토 (Oxygen Transfer Characteristics & Pure Oxygen Application Study on Circulation Flow Rate of the JLB (Jet Loop Bioreactor))

  • 박노백;송용효;박준규;전항배
    • 한국물환경학회지
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    • 제25권6호
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    • pp.896-901
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    • 2009
  • In this study, in order to apply the air and pure oxygen in the Jet Loop Reactor (JLB) in which the oxygen transfer rate is high, differentiate the operation mode according to each air flowrate and liquid flowrate and investigate the oxygen transfer characteristic, an experiment was carried out. The oxygen concentration with the air flowrate ($Q_g$) and liquid flowrate ($Q_L$) was identical but the oxygen transfer coefficient ($K_L{\cdot}a$) is linear depending on degree of two factors. The width of an increase is small in $0.1min^{-1}$ when the air flowrate is 0.2 L/min with increasing the liquid flowrate. Whereas, the increment was exposed to be very high for $1.5min^{-1}$ when the air flowrate was 5 L/min. In the experiments using the pure oxygen, it was 30 mg/L of oxygen concentration finally and it was 3.5 times than using the air. But the time reached the saturated concentration was similar to using the air, and $K_L{\cdot}a$ was similar to using the air too. Analysis between two independent variable and oxygen transfer of the correlation is the same model like $K_L{\cdot}a={0.0161Q_L}^{1.5371}{Q_g}^{0.5433}$ using with coefficient non linear regression analysis. It was resulted that the liquid flowrate were approximately three times than air flowrate on effect to oxygen transfer rate.

순산소 Jet 폭기 시스템을 이용한 음폐수 처리 특성 (Treatment of Food Waste Leachate using Pure-Oxygen Jet Loop Reactor(JLR))

  • 윤애화;박노백;배종훈;전항배;권영배
    • 상하수도학회지
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    • 제24권6호
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    • pp.763-773
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    • 2010
  • The removal efficiencies and a total oxygen transfer coefficient for food waste leachate(FWL) were estimated by using Jet Loop Reactor(JLR). Pure oxygen was used instead of air to improve oxygen concentration in the JLR for high total chemical oxygen demamd(TCOD) in FWL. In JLB, in order to examining the oxygen transfer characteristic, the circulation flowrate and oxygen flowrate were controlled with 7~10 L/min(1.5 L/min interval) and 0.2~0.5 L/min (0.1 L/min interval) and we experimented according to the each condition. As a result, Oxygen uptake rate(OUR) and oxygen transfer rate could be maximized than the oxygen flowrate to increase the circulation flowrate. In addition, it determined that JLR using the pure oxygen which can obtain the greatest oxygen transfer rate as it was the high-concentration organic wastewater like the food waste leachate through the continuous experiment was appropriate.

수직 오리피스 이젝터의 혼합유동 및 산소전달 특성 (Mixed Flow and Oxygen Transfer Characteristics of Vertical Orifice Ejector)

  • 김동준;박상규;양희천
    • 대한기계학회논문집B
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    • 제39권1호
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    • pp.61-69
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    • 2015
  • 본 논문은 수직 오리피스 이젝터의 혼합유동 및 산소전달 특성에 대한 실험적 연구를 목적으로 한다. 실험장치는 전동 모터-펌프, 오리피스 이젝터, 순환 수조, 공기압축기, 고속 카메라 시스템 그리고 제어 및 측정기기로 구성하였다. 측정된 구동유체 및 유입공기의 유량을 이용하여 유량비를 도출하였다. 이적터에서 분출된 혼합유동의 가시화를 통해 정성적 거동을 고찰하였으며, 용존산소 농도를 측정하여 총괄 산소전달계수를 도출하였다. 구동유체의 유량이 일정하고 압축기의 공기압이 높아지면 유량비와 산소전달계수는 증가하며, 압축기의 공기압이 일정하고 구동유체의 유량이 증가하면 유량비는 감소하지만 산소전달계수는 증가하였다. 기포의 크기에 따른 체류시간 및 확산도와 수직 혼합유동의 도달거리는 2 상의 접촉면적과 시간에 크게 영향을 미치기 때문에 산소전달율의 중요한 변수임을 유추할 수 있다.