• 제목/요약/키워드: Oxygen gas ratio

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Performance Prediction of a Gas Turbine Using CO2 as Working Fluid (CO2를 작동유체로 하는 가스터빈의 성능예측)

  • Yang, Hyun-Jun;Kang, Do-Won;Lee, Jong-Jun;Kim, Tong-Seop
    • The KSFM Journal of Fluid Machinery
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    • v.14 no.2
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    • pp.41-46
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    • 2011
  • This study investigated the changes in performance and operating characteristics of an F-class gas turbine according to the change of working fluid from air to carbon dioxide. The revised gas turbine is the topping cycle of the semi-closed oxy-fuel combustion combined cycle. With the same turbine inlet temperature, the $CO_2$ gas turbine is expected to produce about 85% more power. The main contributor is the greater compressor mass flow and the added oxygen flow for the combustion. Compressor pressure ratio increases about 50%. However, the gas turbine efficiency reduces about 10 %. Modulation of inlet guide vane to reduce the compressor inlet mass flow, the major purpose of which is to reduce the compressor inlet Mach number, was also performed.

The properties of Al-doped ZnO films deposited with RF magnetron sputtering system in various H2/(Ar + H2) gas ratios (RF 마그네트론 스퍼터링 방법을 사용해 증착된 Al이 도핑 된 ZnO 박막의 H2/(Ar + H2) 가스 비율에 따른 특성)

  • Kim, Jwa-Yeon;Han, Jung-Su
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.22 no.3
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    • pp.122-126
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    • 2012
  • The properties of Al-doped ZnO (AZO) films were investigated as a function of $H_2/(Ar+H_2)$ gas ratio using an AZO (2 wt% $Al_2O_3$) ceramic target in a radio frequency (RF) magnetron sputtering system. The deposition process was done at $200^{\circ}C$ and in $2{\times}10^{-2}$ Torr working pressure and with various ratios of $H_2/(Ar+H_2)$ gas. During the AZO film deposition process, partial $H_2$ gas affected the AZO film characteristics. The electron resistivity (${\sim}9.21{\times}10^{-4}\;{\Omega}cm$) was lowest and mobility (${\sim}17.8\;cm^2/Vs$) was highest in AZO films when the $H_2/(Ar+H_2)$ gas ratio was 2.5 %. When the $H_2/(Ar+H_2)$ gas ratio was increased above 2.5 %, the electron resistivity increased and mobility decreased with increasing $H_2/(Ar+H_2)$ gas ratio in AZO films. The carrier concentration increased with increasing $H_2/(Ar+H_2)$ gas ratio from 0 % to 7.5 %. This phenomenon was explained by reaction of hydrogen and oxygen and additional formation of oxygen vacancy. The average optical transmission in the visible light wavelength region over 90 % and an orientation of the deposition was [002] orientation for AZO films grown with all $H_2/(Ar+H_2)$ gas ratios.

The Preparation of ZnO Piezo-electric Thin Film for Surface Acoustic Wave Filter (탄성표면파 필터용 ZnO 압전 박막의 제조)

  • Lee, Dong-Yoon;Park, Jae-Jun
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2005.05b
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    • pp.10-14
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    • 2005
  • Zinc Oxide(ZnO) thin films on Si (100) substrates were deposited by RF magnetron reactive sputtering. The characteristics of zinc oxide thin films with changing sputtering conditions such as argon/oxygen gas ratios, RF power, and substrate temperature, chamber pressure and target-substrate distance were investigated. To analyze a crystallographic properties of the films, $\theta/2{\theta}$ mode X -ray diffraction, SEM, and AFM analyses. C-axis preferred orientation, resistivity, and surface roughness highly depended on Ar/$O_2$ gas ratios. The resistivity of ZnO thin films rapidly increased with increasing oxygen ratio and the resistivity value of $9{\times}10^7\;{\Omega}cm$ was obtained at a working pressure of 10 mTorr with Ar/$O_2$=50/50. The surface roughness was also improved with increasing oxygen ratio and the ZnO films deposited with Ar/$O_2$=50/50 showed the excellent roughness value of $28.7{\AA}$.

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A measurement of the line spread function of computed radiography (Computed radiograhy의 line spread funciton(LSF) 측정)

  • Kim, Chang-Bok;Kim, Young-Keun;Kim, Keon-Jung;Lee, Kyung-Sup
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.05c
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    • pp.124-130
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    • 2003
  • Zinc Oxide(ZnO) thin films on Si (100) substrate were deposited by RF magnetron sputter with changing sputtering conditions such as argon/oxygen gas ratios, RF power, and substrate temperature, chamber pressure and target-substrate distance. To analyze a crystallographic properties of the films, $\theta/2\theta$ mode X-ray diffraction, SEM, and AFM analyses. C-axis preferred orientation, resistivity. and surface roughness highly depended on $Ar/O_2$ gas ratios. The resistivity of ZnO thin films rapidly increased with increasing oxygen ratio and the resistivity value of $9{\times}10^7{\Omega}cm$ was obtained at a working pressure of 10 mTorr with $Ar/O_2$=50/50. The surface roughness was also improved with increasing oxygen ratio and the ZnO films deposited with $Ar/O_2$=50/50 showed the excellent roughness value of $28.7{\AA}$.

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Treatment of Ar/O2 Atmospheric Pressure Plasma for Sterilization (아르곤과 산소 대기압 플라즈마 방전 효과를 이용한 살균처리)

  • Son, Hyang Ho;Lee, Won Gyu
    • Applied Chemistry for Engineering
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    • v.22 no.3
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    • pp.261-265
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    • 2011
  • The sterilization effects of atmospheric pressure plasma with the mixture of argon and oxygen were analyzed. The plasma reactor with the shape of dielectric barrier discharge produced the uniform distribution of glow discharge and generated ozone gas effectively according to the various process parameters. The sterilization for E. coli was affected by power, oxygen ratio in the mixture gas, treatment time and distance between reactor and sample. The concentration of ozone was a major source for the sterilization of E. coli, which was enhanced by the increase of power and oxygen ratio. In this study, the effect of atmospheric pressure plasma treatment for the sterilization was confirmed and its result can deliver the atmospheric pressure plasma treatment as the novel sterilization method instead of conventional methods.

The Effect of Cooled EGR and Oxygenate Fuel(EGBE) on the Diesel Engine Performance and Emissions (함산소연료(EGBE)와 Cooled EGR이 디젤기관의 성능과 배기배출물에 미치는 영향)

  • 최승훈;오영택
    • Transactions of the Korean Society of Automotive Engineers
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    • v.11 no.1
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    • pp.79-86
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    • 2003
  • In this paper, the effect of oxygen component in fuel on the exhaust emissions has been investigated fur direct injection diesel engine. It was tested to estimate change of engine performance and exhaust emission characteristics for the commercial diesel fuel and oxygenated blended fuel which has seven kinds of mixed ratio. And, the effects of exhaust gas recirculation(EGR) on the characteristics of NOx emission have been investigated. Ethylene glycol mono-n-butyl ether(EGBE) contains oxygen component 27% in itself, and it is a kind of effective oxygenated fuel of mono-ether group that the smoke emission and unburned hydrocarbons of EGBE is reduced remarkably compared with commercial diesel fuel, that is, it can supply oxygen component sufficiently at higher loads and speeds in diesel engine. It was found that simultaneous reduction of smoke and NOx was achieved with oxygenated fuel and cooled EGR method.

Simultaneous Reduction of Smoke and NOx with Oxygenated Fuel(DMC) and Cooled EGR method in Diesel Engine (디젤기관에서 함산소연료(DMC)와 Cooled EGR방법에 의한 매연과 NOx의 동시저감)

  • Oh, Y.T.;Choi, S.H.
    • Journal of Power System Engineering
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    • v.6 no.1
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    • pp.27-35
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    • 2002
  • In this paper, the effect of oxygen component in fuel on the exhaust emissions has been investigated for direct injection diesel engine. It is tested to estimate change of engine performance and exhaust emission characteristics for the commercial diesel fuel and oxygenate blended fuel which has four kinds of mixed ratio. And, the effects of exhaust gas recirculation(EGR) on the characteristics of NOx emission and brake specific fuel consumption rate have been investigated. Dimethyl carbonate(DMC) contains oxygen component 53.3% in itself, and it is a kind of effective oxygenated fuel of carbonate group that the smoke emission of DMC is reduced remarkably in comparison with commercial diesel fuel, that is, it can supply oxygen component sufficiently at higher loads and speeds in diesel engine. It was found that simultaneous reduction of smoke and NOx was achieved with oxygenated fuel and EGR method.

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Determination of Air Fuel Ratio according to Fuel Composition (I) -Eltinge Chart as a Reference Exhaust Composition- (연료 조성에 따른 공연비 산정 (I) -기준 배기 조성으로서 Eltinge 차트-)

  • Ohm, In-Yong;Park, Chan-Jun
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.27 no.11
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    • pp.1548-1562
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    • 2003
  • This paper is the first of several companion papers which compare the methods of Air-fuel ratio determination. There are many methods which calculate Air-Fuel ratio from exhaust emission. Most of them are based on the simple chemical equations, which use balance of atom, and the error of the calculation is negligible as far as the instrumentation accuracy is guaranteed. They assume homogeneous mixture and complete combustion to the extent of oxygen availability. Because of these simple assumptions, they cannot offer the information about the fuel distribution state and the malfunction of instrument. For these limitations, Eltinge offered new one based on stricter mathematical model. This result coincides with the others very well and gives more information about the mixture state and instrumentation. Consequently this might be a general solution for Air-fuel ratio determination and exhaust composition. The objects of the calculation, however, were not commercial fuels except gasoline and the compensation method of unburned hydrocarbon was not appropriate to recent analyzer. Moreover he did not consider the fuel which contains oxygen, such as methanol, ethanol and blend of gasoline-alcohol. In this paper, Eltinge chart is expanded to the arbitrary fuel composition as the reference exhaust compositions for the purpose of further discussions about Air-fuel ratio determination methods and the charts fur gasoline, diesel, methanol, M85, liquefied petroleum gas(LPG), natural gas(NG), propane, butane are illustrated.

Study on Combustion Gas Properties of a Fuel-Rich Gas Generator (연료 과농 가스발생기의 연소 가스 물성치에 관한 연구)

  • 서성현;최환석;한영민;김성구
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.34 no.10
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    • pp.56-60
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    • 2006
  • It is essential to predict thermodynamic properties of combustion gas with respect to a propellant mixture ratio for the development of a gas generator for a liquid rocket engine. The present study shows the temperature measurement of exit combustion gas as a function of a mixture ratio through the series of combustion tests of a fuel-rich gas generator with liquid oxygen and Jet A-1. The measurements of dynamic and static pressures, and combustion gas temperatures allowed the estimation of thermodynamic properties like a specific heat ratio, a gas constant, and a constant pressure specific heat of the combustion gas. The comparison of the experimental results with predictions made by interpolation parameters obtained from the modification of the chemical equilibrium code indicates that the interpolation method calibrated using the temperature measurements can be utilized as an effective tool for the initial design of a fuel-rich gas generator.

Electrical and Optical Properties of ZnO : Al Films Prepared by the DC Magnetron Sputtering System (직류 Magnetron Sputter 법으로 제막된 ZnO : Al 박막의 전기광학 특성)

  • 김의수;유세웅;유병석;이정훈
    • Journal of the Korean Ceramic Society
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    • v.32 no.7
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    • pp.799-808
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    • 1995
  • Transparent conductive films of aluminium doped zinc oxide (AZO) have been prepared by using the DC magnetron sputtering with the ZnO : Al (Al2O3 2 wt%) oxide target oriented to c-axis. Electrical and optical properties depended upon the O2/Ar gas ratio. The optical transmittance and sheet resistance of the AZO coated glass was 60~65% and 75Ω/$\square$, respectively at the O2/Ar gas ratio of 0. With the increase of the oxygen partial pressure to 2.0$\times$10-2, they were increased to the values of 81% and 1kΩ/$\square$, respectively. The films with the resistivities of 1.2~1.4$\times$10-3 Ω.cm, mobilities of 11~13 $\textrm{cm}^2$/V.sec and carrier concentrations of 3.5$\times$1020~4.0$\times$1020/㎤ were produced at the optimum O2/Ar gas ratio, which was 0.5$\times$10-2~1.0$\times$10-2. According to XRD analysis, the films have only one peak corresponding to the (002) plane, which indicates that there is a strong preferred orientation of the films. The grain size of ZnO films were calculated to 200~320 $\AA$, which was increased with the O2/Ar gas ratio and Ar gas flowrate.

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