• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
• /
• 2001.07a
• /
• pp.435-438
• /
• 2001

Thin films of vanadium oxide(VO$\sub$x/) have been deposited by r.f. magnetron sputtering from V$_2$O$\sub$5/ target in gas mixture of argon and oxygen. The oxygen/(oxygen+argon) partial pressure ratio is changed from 0% to 8%. Crystal structure, chemical composition and bonding properties of films sputter-deposited under different oxygen gas pressures are characterized through XRO, XPS, RBS and FTIR measurements. All the films prepared below 8% O$_2$ are amorphous, and those prepared without oxygen are gray indicating the presence of V$_2$O$\sub$$_4$/ phase in the films. V$_2$O$\sub$5/ and lower oxides co-exist in sputter-deposited films and as the oxygen partial pressure is increased the films become more stoichiometric V$_2$O$\sub$5/. The increase of O/V ratio with increasing oxygen gas pressure is attributed to the partial filling of oxygen vacancies through diffusion. It is observed that the oxygen atoms. located on the V-O plane of V$_2$O$\sub$5/ layer participate more readily in the oxidation process.

• Transactions of the Korean Society of Automotive Engineers
• /
• v.6 no.6
• /
• pp.142-154
• /
• 1998

The effects of recirculated exhaust gas on the characteristic of soot emissions have been investigated by using an eight-cylinder, four-stroke, direct injection and water-cooled diesel engine operating at several loads and speeds. The experiments in this study are carried out at the fixed fuel injection timing of $38^{\circ}$ BTDC regardless of experimental conditions. The intake oxygen concentration and the mean equivalence ratio calculated by the intake air flow and fuel consumption rate are used to analyze and discuss the influences of EGR rate on soot emissions. Results of this study indicate that soot emissions increase owing to the drop of intake oxygen concentration and the rise of equivalence ratio as the EGR rate increases at a given engine load and speed, especially the high load.

• Proceedings of the Korean Vacuum Society Conference
• /
• 2016.02a
• /
• pp.306.2-306.2
• /
• 2016

Niobium oxide thin films were synthesized by reactive rf magnetron sputtering. The target was metallic niobium with 2 inch in diameter and the substrate was n-type Si wafer. To control the surface properties of the films, Nb oxide thin films were obtained at various mixing ratios of argon and oxygen gases. Nb oxide thin films were analyzed with alpha step, scanning electron microscopy (SEM), X-ray diffraction (XRD), and X-ray photoelectron spectroscopy (XPS). The result of alpha step showed that the thickness of Nb oxide thin films were decreased with increasing the oxygen gas ratios. SEM images showed that the granular morphology was formed at 0% of oxygen gas ratio and then disappeared at 20 and 75% of oxygen gas ratio. The amorphous Nb oxide was observed by XRD at all films. The oxidation state of Nb and O were studied with high resolution Ni 2p and O 1s XPS spectra. And the change in the chemical environment of Nb oxide thin films was investigated by XPS with Ar+ sputtering.

• Journal of the Korean Society of Manufacturing Technology Engineers
• /
• v.19 no.2
• /
• pp.230-234
• /
• 2010

Hydrox gas which is the mixed gas of hydrogen and oxygen gained fromwater electrolysis is one of the new clean energy sources and thus is researched and commercialized actively. Especially, it can be replaced the fossil energy and shows the better quality compared to the conventional energy such as LPG or acetylene gas. The mixed gas of hydrogen and oxygen is gained from water electrolysis reaction. It has constant volume ratio 2:1 of hydrogen and oxygen, and it is used as a source of thermal energy by combustion reaction. Further, hydrox gas is nearly a mixed ideal gas combusting itself completely and its combustion shows anunique characteristics of implosion. In this study, temperature rise effects on hydrox gas content through mixed combustion test of kerosene and hydrox gas and LPG and hydrox gas are investigated. it is also confirmed that economy of mixed combustion of hydrox gas as effective energy is fairly probable.

• Transactions of the Korean Society of Mechanical Engineers B
• /
• v.31 no.5
• /
• pp.405-415
• /
• 2007

The effects of recirculated exhaust gas on exhaust emissions under four kinds of nozzle tip with the different fuel consumption rates are experimentally investigated by using an once-through boiler with a FGR system. The purpose of this study is to develop the FGR control system for reducing $NO_x$ emissions in boilers. Intake and exhaust oxygen concentrations, and equivalence ratio are considered to figure out the effect of FGR rate on exhaust emissions at various fuel consumption rates. It is found that $NO_x$ emissions are markedly decreased, while soot emissions are increased owing to the drop of intake and exhaust oxygen concentrations, and the rise of equivalence ratio as FGR rates are elevated. One can also conclude that the reduction in $NO_x$ emissions is more considerably influenced by the variation of equivalence ratio due to the FGR rate than the fuel consumption rate.

• Proceedings of the KWS Conference
• /
• 2007.11a
• /
• pp.8-10
• /
• 2007

In recent years, hydrogen-oxygen mixed gas generated by electrically dissociating water has been proposed as alternative cutting fuel. The mixed gas consists of a hydrogen-oxygen mixed gas in the mixture ratio of 2:1. And gas has some merits as cutting quality and speed compared with existing gas cutting process. Because main source of mixed gas is water, mixed gas is environmental-friendly clean fuel. The purpose of the present paper is to investigate cutting characteristics and optimum cutting parameters of mixed gas, The effect of cutting parameter on the cutting characteristics of mixed gas is also investigated as compared to existing gas cutting process.

• Proceedings of the KIPE Conference
• /
• 2001.10a
• /
• pp.109-112
• /
• 2001

Water-Electrolyzed gas is a mixed gas of the constant volume ratio 2:1 of Hydrogen and Oxygen gained from electrolyzed water, and it has better characteristics in the field of economy, efficiency of energy, and environmental intimacy than acetylene gas and LPG (Liquefied Petroleum Gas) used for existing gas welding equipment. So studies of Water-Electrolyzed gas are activity in progress nowaday, and commercially used as a source of thermal energy for gas welding in the industry. The object of this paper is getting a V-I characteristic of Hydrogen-Oxygen Gas Generator using DC source. First, chemical analysis of electrolysis is conducted and the relation of electrical energy and then chemical energy is investigated through the faraday's laws.

• Transactions of the Korean Society of Mechanical Engineers B
• /
• v.24 no.9
• /
• pp.1247-1254
• /
• 2000

The effects of recirculated exhaust gas on the characteristics of $NO_x$ and soot emissions under a wide range of engine load have been experimentally investigated by a water-cooled, four-cylinder, indirect injection, four cycle and marine diesel engine operating at two kinds of engine speeds. The simultaneous control of $NO_x$ and soot emissions in diesel engines is targeted in this study. The EGR system is used to reduce $NO_x$ emissions, and a novel diesel soot removal device with a cylinder-type scrubber for the experiment system which has 6 water injectors(A water injector has 144 nozzles in 1.0 mm diameter) is specially designed and manufactured to reduce the soot contents in the recirculated exhaust gas to intake system of the engines. The intake oxygen concentration and the mean equivalence ratio calculated by the intake air flow and fuel consumption rate, and the exhaust oxygen concentration measured are used to analyse and discuss the influences of EGR rate on $NO_x$ and soot emissions. The experiments are performed at the fixed fuel injection timing of $15.3^{\circ}$ BTDC regardless of experimental conditions. It is found that $NO_x$ emissions are decreased and soot emissions are increased owing to the drop of intake oxygen concentration and exhaust oxygen concentration, and the rise of equivalence ratio as the EGR rate rises.

• Proceedings of the KIPE Conference
• /
• 2001.07a
• /
• pp.312-315
• /
• 2001

Water-Electrolyzed gas is a mixed gas of the constant volume ratio 2:1 Hydrogen and Oxygen gained from electrolyzed water, and it has better characteristics in the field of economy, efficiency of energy, and environmental intimacy than acetylene gas and LPG used for existing gas welding equipment. So studies of Water-Electrolyzed gas are activity in progress nowadays, and commercially used as a source of thermal energy for gas welding in the industry. The object of this paper is V-I feature of Hydrogen -Oxygen Gas Generator using DC source

• 한국연소학회:학술대회논문집
• /
• 2001.06a
• /
• pp.75-81
• /
• 2001

MCVD(modified chemical vapor deposition) used in making optical-fiber currently utilizes the hydrogen-oxygen burner as a energy supply source. To improve the productivity and to reduce the manufacturing cost of optical-fiber, a natural gas-oxygen burner has been developed. The manufacturing processes of optical-fiber consist of vapor deposition, collapse and drawing processes. Among these processes, the vapor deposition and the collapse processes are important in terms of improving the productivity and saving the production cost. The vapor deposition and collapse processes are performed by combustion heat and flame force supplied by a burner. So the flame force of the burner used in these processes is required to have an optimal and consistent value in order to allow uniform heating and collapse of quartz tube. In this regard, the momentum ratio of natural gas and oxygen has been optimally determined by modification of a burner and the inlet flow pass also has been modified.