• Title/Summary/Keyword: Oxygen channel

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An Experimental Study on Measurement of Oxygen Concentration in the Cathode Channel of PEMFC by Using GC (GC를 이용한 고분자전해질형 연료전지의 공기극 채널 내 산소 농도 분포에 관한 실험적 연구)

  • Ha Taehun;Kim Han-Sang;Min Kyoungdoug
    • 한국신재생에너지학회:학술대회논문집
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    • 2005.06a
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    • pp.384-387
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    • 2005
  • Fuel cell has been well known as a clean alternative power for vehicles. Recently, an experimental technique has been developed measurement of species and distributions by using gas chromatograph. In this study, cathode channel oxygen distributions as various conditions were investigated using gas chromatograph and cell visualization. And discussed relation between flooding and oxygen concentrations. As a result of experiment, oxygen consumpt ion is affected wi th flooding. Flooding is observed in channel near hydrogen inlet, and oxygen consumption is low at that region.

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Low Strain Rate Flame Extinction Characteristics of Opposed Flow Flame in a Mesoscale Channel with Variation of Oxygen Ratio (산화제의 산소농도에 따른 메소 스케일 대향류 저신장율 화염의 소멸특성)

  • Choi, Yongun;Lee, Min Jung;Jung, Yongjin;Kim, Nam Il
    • 한국연소학회:학술대회논문집
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    • 2015.12a
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    • pp.143-145
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    • 2015
  • A mesoscale channel was designed to observe the flame stabilization at low strain rate conditions (< $10s^{-1}$). At this condition, the behavior of partially premixed flame was explored by changing a channel size and the oxygen ratio in the oxidant. In this work, experiment is conducted for propane case and it was compared with methane case of previous one. Conclusively, it can be observed that the strain rate of flame extinction and starting point of oscillation were varied with oxygen ratio. Moreover we can understand the effects of enhanced oxygen ratio of oxidant and flame behavior at low strain rate conditions.

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Low Strain Rate Flame Extinction Characteristic of Oxygen Enhanced Opposed Flow Partially Premixed Flame in a Mesoscale Channel (채널 내부 대항류 산소부화 부분예혼합 화염의 저신장율 소화특성)

  • Lee, Min Jung;Kim, Nam Il
    • 한국연소학회:학술대회논문집
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    • 2014.11a
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    • pp.243-244
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    • 2014
  • The opposed flow flame in a mesoscale channel was constructed to observe the flame stabilization behaviors at low strain rate conditions (<$10s^{-1}$). The purpose of this study is to get the overall flame behaviors of partially premixed flames with oxygen enhanced conditions at low strain rates. The oxygen ratio in oxidizer was changed from 18 to 30 %. Conclusively, the flame extinction limit approached to about $1s^{-1}$, and divided into three representative regimes corresponding to self propagating flame, transitional flame, quenching flame regimes.

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Memristive Devices Based on RGO Nano-sheet Nanocomposites with an Embedded GQD Layer (저결함 그래핀 양자점 구조를 갖는 RGO 나노 복합체 기반의 저항성 메모리 특성)

  • Kim, Yongwoo;Hwang, Sung Won
    • Journal of the Semiconductor & Display Technology
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    • v.20 no.1
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    • pp.54-58
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    • 2021
  • The RGO with controllable oxygen functional groups is a novel material as the active layer of resistive switching memory through a reduction process. We designed a nanoscale conductive channel induced by local oxygen ion diffusion in an Au / RGO+GQD / Al resistive switching memory structure. A strong electric field was locally generated around the Al metal channel generated in BIL, and the local formation of a direct conductive low-dimensional channel in the complex RGO graphene quantum dot region was confirmed. The resistive memory design of the complex RGO graphene quantum dot structure can be applied as an effective structure for charge transport, and it has been shown that the resistive switching mechanism based on the movement of oxygen and metal ions is a fundamental alternative to understanding and application of next-generation intelligent semiconductor systems.

OXYGEN CONCENTRATION IN THE CATHODE CHANNEL OF PEM FUEL CELL USING GAS CHROMATOGRAPH

  • Ha, T.H.;Kim, H.S.;Min, K.D.
    • International Journal of Automotive Technology
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    • v.8 no.1
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    • pp.119-126
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    • 2007
  • Because of the low temperature operation, proton exchange membrane (PEM) fuel cell has a water phase transition. Therefore, water management is an important operation issue in a PEM fuel cell because the liquid water in the fuel cell causes electrode flooding that can lower the cell performance under high current density conditions. In this study, in order to understand the reactant distributions in the cathode channels of the PEM fuel cell, an experimental technique that can measure the species concentrations of reactant gases by using gas chromatograph (GC) is applied for an operating PEM fuel cell. The oxygen distribution along the cathode flow channels of PEM fuel cell is mainly investigated with various operating conditions. Also, the relations between cathode flooding and oxygen concentrations and oxygen consumption pattern along the cathode channel configurations of the unit cell adopted for this study are discussed using GC measurement and visualization experiment of cathode flooding. It is found that the amount of oxygen consumption is very sensitive to various operating conditions of the fuel cell and was much affected by the flooding occurrence in cathode channels.

Quantitative Visualization of Oxygen Transfer in Micro-channel using Micro-LIF Technique (마이크로 레이저 형광 여기법을 이용한 미세채널 내부에서의 산소 확산에 대한 정량적 가시화)

  • Chen, Juan;Kim, Hyun-Dong;Kim, Kyung-Chun
    • Journal of the Korean Society of Visualization
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    • v.10 no.1
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    • pp.34-39
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    • 2012
  • In the present study, oxygen transfer process across gas-liquid interface in a Y-shape micro-channel is quantitatively visualized using the micro laser induced fluorescence (${\mu}$-LIF) technique. Diffusion coefficient of Oxygen ($D_L$) is estimated based on the experimental results and compared to its theoretical value. Tris ruthenium (II) chloride hexahydrate was used as the oxygen quenchable fluorescent dye. A light-emitting diode (LED) with wavelength of 450 nm was used as the light source and phosphorescence images of fluorescent dye were captured by a CMOS high speed camera installed on the microscope system. Water having dissolved oxygen (DO) value of 0% and pure oxygen gas were injected into the Y-shaped microchannel by using a double loading syringe pump. In-situ pixel-by-pixel calibration was carried out to obtain Stern-Volmer plots over whole flow field. Instantaneous DO concentration fields were successfully mapped according to Stern-Volmer plots and DL was calculated as $2.0675{\times}10^{-9}\;m^2/s$.

Design of Cooling Channels of Preburners for Small Liquid Rocket Engines with Computational Flow and Heat Transfer Analysis

  • Moon, In-Sang;Lee, Seon-Mi;Moon, Il-Yoon;Yoo, Jae-Han;Lee, Soo-Yong
    • Journal of Astronomy and Space Sciences
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    • v.28 no.3
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    • pp.233-239
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    • 2011
  • A series of computational analyses was performed to predict the cooling process by the cooling channel of preburners used for kerosene-liquid oxygen staged combustion cycle rocket engines. As an oxygen-rich combustion occurs in the kerosene fueled preburner, it is of great importance to control the wall temperature so that it does not exceed the critical temperature. However, since the heat transfer is proportional to the speed of fluid running inside the channel, the high heat transfer leads to a trade-off of pressure loss. For this reason, it is necessary to establish a certain criteria between the pressure loss and the heat transfer or the wall surface temperature. The design factors of the cooling channel were determined by the computational research, and a test model was manufactured. The test model was used for the hot fire tests to prove the function of the cooling mechanism, among other purposes.

Numerical analysis of the shape effect on PEMFC's Performace (연료전지 성능에 영향을 미치는 채널형상에 대한 연구)

  • Kim, K.J.;Jeon, Yu-Taek;Kim, Hyo-Gyun
    • 한국신재생에너지학회:학술대회논문집
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    • 2006.06a
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    • pp.59-62
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    • 2006
  • Formability is requested to successfully develop of a metal bipolar plate for mass production. From this point of view, wider channel and land width is more helpful to improve formability. But the performance of the fuel cell can be affected by its channel and land shape. So it is very important to select proper channel and land shape not to deteriorate the fuel cell performance. In this work, 3-dimensional, non-isothermal numerical simulation was performed to analyse the effects of channel and land width on the fuel cell performance. 3 types of straight channel were selected for the numerical simulation. The simulation results reveal that wide channel and land width lower fuel cell performance and decrease voltage at a high current density region. Water activity, temperature, oxygen concentration distributions were investigated to find the reasons of performance degradation. The results show that wide channel and land width give an bad effect on fuel cell performance because of low cool ins efficiency and lack of oxygen gas under the land.

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Numerical Study on Performance of PEMFC with Block and Sub-channel of Cathode Flow Field (캐소드 유로에서 블록과 서브 채널의 고분자전해질 연료전지의 성능에 관한 전산해석 연구)

  • Jo, Seonghun;Kim, Junbom
    • Applied Chemistry for Engineering
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    • v.32 no.6
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    • pp.613-620
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    • 2021
  • A flow channel shape of PEMFC has an influence on the internal flow uniformity. If the reactant distribution in a flow path is not uniform during operation, both catalyst deactivation and mechanical damage of membrane could occur resulting in decreasing the membrane electrode assembly (MEA) durability. Numerous studies concerning flow design have been conducted to make smooth supply and uniform distribution of reactants in fuel cells. The baffle of flow path could improve fuel cell performance through the forced convection effect. A sub-channel, as an additional air flow path, could increase the reactant concentration and reduce the mass transfer loss via a smooth water discharge. In this study, computational fluid dynamics (CFD) was used to analyze the effect of blocks and sub-channels on the current density and oxygen concentration of the fuel cell. As a result, the limit current density and oxygen concentration at a rear block increased when using blocks and sub-channels in a flow channel. In particular, the current density increased significantly when the sub-channel was placed between two blocks. Also, the sub-channel position was optimized by analyzing the oxygen concentration, and the oxygen concentration was recovered at a rear block in the fuel cell.

Characteristics of a-IGZO TFTs with Oxygen Ratio

  • Lee, Cho;Park, Ji-Yong;Mun, Je-Yong;Kim, Bo-Seok
    • Proceedings of the Korean Vacuum Society Conference
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    • 2014.02a
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    • pp.341.1-341.1
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    • 2014
  • In the advanced material for the next generation display device, transparent amorphous oxide semiconductors (TAOS) are promising materials as a channel layer in thin film transistor (TFT). The TAOS have many advantages for large-area application compared with hydrogenated amorphous silicon TFT (a-Si:H) and organic semiconductor TFT. For the reasonable characteristics of TAOS, The a-IGZO has the excellent performances such as low temperature fabrication (R.T~), high mobility, visible region transparent, and reasonable on-off ratio. In this study, we investigated how the electric characteristics and physical properties are changed as various oxygen ratio when magnetron sputtering. we analysis a-IGZO film by AFM, EDS and I-V measurement. decreasing the oxygen ratio, the threshold voltage is shifted negatively and mobility is increasing. Through this correlation, we confirm the effect of oxygen ratio. We fabricated the bottom-gate a-IGZO TFTs. The gate insulator, SiO2 film was grown on heavily doped silicon wafer by thermal oxidation method. a-IGZO channel layer was deposited by RF magnetron sputtering. and the annealing condition is $350^{\circ}C$. Electrode were patterned Al deposition through a shadow mask(160/1000 um).

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