• Title/Summary/Keyword: Oxygen Flow Rate

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Characterization of $SnO_2$ Thin Films Prepared by Thermal-CVD (열화학증착법으로 제조된 $SnO_2$박막의 특성)

  • Ryu, Deuk-Bae;Lee, Su-Wan
    • Korean Journal of Materials Research
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    • v.11 no.1
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    • pp.15-19
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    • 2001
  • Transparent and conducting tin oxide thin films were prepared on soda lime silicate glass by thermal chemical vapour deposition. Thin films were fabricated from mixtures of tetramethyltin (TMT) as a precursor, oxygen or oxygen containing ozone as an oxidant. The properties of fabricated tin oxide films are highly changed with variations of substrate temperature. Optimized thin films could be prepared on TMT, which flow rate of 8 sccm, oxygen flow rate of 150 sccm and substrate temperature of 38$0^{\circ}C$. We reduced deposition temperature about$ 180^{\circ}C$ by using of oxygen containing ozone instead of pure oxygen and resistivity of thin films was decreased from ~ ${\times}10^{-2}{\Omega}cm$ to ~${\times}10^{-3}{\Omega}cm$.

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Effect of the Steam Flow Rate on Syngas Productivity in IGCC Gasifier for a Power Generation (IGCC 발전용 가스화기에서 증기 주입량이 합성가스 생산량에 미치는 영향)

  • Keum, Kyung-Nam;Yoo, Ho-Seon
    • Plant Journal
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    • v.15 no.3
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    • pp.29-34
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    • 2019
  • In the study, the effect of steam injection on syngas productivity was investigated under the constant operating conditions of gasifier oxygen load while the coal feed was fixed and the steam injection flow rate is changed in Taean IGCC plant. The maximum syngas average productivity was found to be at 80 % and 90 % of gasifier oxygen loads with the steam injection flow rate of 0.14 kg/s and 0.15 kg/s per coal burner. Through this study, the syngas productivity was changed by adjusting the steam injection amount and as the steam injection flow rate increased, the syngas productivity increased and then decreased again. The syngas productivity can be increased only by steam injection without supplying additional coal and it is considered that the syngas productivity has different characteristics depending on coal type. Thus it is recommended to operate the gasifier using Carbo-One coal with the steam injection flow rate of about 0.14 kg/s per coal burner when the gasifier oxygen load is 80 % ~ 90 %.

La0.7Sr0.3MnO3 CMR thin film resistor deposited on SiO2/Si and Si substrates by rf magnetron sputtering for infrared sensor (SiO2/Si 및 Si 기판에 rf magnetron sputtering법으로 증착된 적외선 센서용 La0.7Sr0.3MnO3 CMR 박막 저항체 특성연구)

  • Choi, Sun-Gyu;Reddy, A. Sivasankar;Yu, Byoung-Gon;Ryu, Ho-Jun;Park, Hyung-Ho
    • Journal of the Korean Vacuum Society
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    • v.17 no.2
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    • pp.130-137
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    • 2008
  • $La_{0.7}Sr_{0.3}MnO_3$ films were deposited on $SiO_2$/Si and Si substrates annealed at $350^{\circ}C$ by rf magnetron sputtering. The oxygen gas flow rates were varied as 0, 40, and 80 sccm. Without post annealing process, $La_{0.7}Sr_{0.3}MnO_3$ thin films on $SiO_2$/Si and Si substrates were polycrystalline with (100), (110), and (200) growth planes. The grain size of $La_{0.7}Sr_{0.3}MnO_3$ thin films was increased with increasing oxygen gas flow rate. The sheet resistance of $La_{0.7}Sr_{0.3}MnO_3$ thin films was decreased with oxygen flow rate due to the increased grain size which induced a reduction of grain boundary. TCR (temperature coefficient of resistance) values of $La_{0.7}Sr_{0.3}MnO_3$ thin films were obtained from -2.0% to -2.2%.

Numerical Analysis in a 1 kWe SOFC Stack for Variation of the Channel Height in Separators (분리판의 채널 높이에 따른 1 kWe 급 고체산화물 연료전지 스택 수치 해석)

  • YIN, HAOYUAN;KIM, YOUNG JIN;YI, KUNWOO;KIM, HYEON JIN;YUN, KYONG SIK;YU, JI HAENG
    • Transactions of the Korean hydrogen and new energy society
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    • v.33 no.5
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    • pp.550-556
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    • 2022
  • In this study, the flow uniformity was analyzed by performing numerical analysis on the 1 kWe internal manifold type solid oxide fuel cell stack according to the channel height of the separator. Also, it was examined by varying the fuel utilization rate and oxygen utilization rate. From the calculation results, we found that as the channel height of the separator decreased, the pressure drop increased exponentially. In addition, it was found that as the channel height of the separator decreased, the gas flow resistance inside the unit cell increased, and the flow resistance increased the pressure drop, thereby improving the flow uniformity inside the stack. Finally, the calculation results showed that as the fuel and oxygen utilization increased, the flow uniformity also improved.

A Study on the Electrical Properties of ITO Thin Films with Various Oxygen Gas Flow Rate (산소 가스 유량비 변화에 따른 ITO 박막의 전기적 특성에 관한 연구)

  • Choi, Dong-H.;Keum, Min-J.;Jean, A.R.;Han, Jean-G.
    • Journal of the Korean institute of surface engineering
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    • v.40 no.3
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    • pp.144-148
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    • 2007
  • To prepare the transparent electrode for electronic devices such as flat panel or flexible displays, solar cells, and touch panels; tin doped $In_2O_3$ (ITO) films with low resistivity and a high transparency were fabricated using a facing target sputtering (FTS) system at the various oxygen gas flow rate. The carrier concentration and mobility of ITO films were measured by Hall Effect measurement. And the transmittance was measured using the UV-VIS spectrometer. As a result, we can obtain the ITO thin films prepared at 10% oxygen gas flow ratio, thickness 150 nm with transmittance 85% and resistivity $8.1{\times}10^{-4}{\Omega}cm$ and surface roughness 5.01 nm.

The Effect of Oxygen Flow Rates on the Electrical Resistivity of MgO Thin Films in AC-PDPs

  • Chou, Hong-Chieh;Kim, Sung-O;Chen, Kuang-Lang;Chen, Samuel;Lee, Chien-Pang;Hsu, Chien-Hsing;Chou, Kuo-Ching;Huang, Chih-Ming
    • 한국정보디스플레이학회:학술대회논문집
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    • 2006.08a
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    • pp.383-386
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    • 2006
  • Magnesium oxide thin films were deposited with different thickness and oxygen flow rates for investigating the effects of the electrical resistivity of MgO thin films in AC-PDPs. The surface roughness was characterized by AFM. It reveals that higher oxygen flow rate generates higher electrical resistivity of MgO thin films.

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Effect of Variation of Substrate Temperature and Oxygen Gas Flow of the ZnO Thin Films Deposited on Sapphire (사파이어 기판 위에 증착된 ZnO 박막의 기판온도와 산소 가스량에 따른 특성)

  • Kim, Jae-Hong;Lee, Cheon
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.18 no.7
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    • pp.652-655
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    • 2005
  • ZnO thin films on (001) $Al_2O_3$ substrates have been deposited by pulsed laser deposition(PLD) technique using an Nd:YAG laser with a wavelength of 266 nm. The influence of the deposition parameters, such as oxygen gas flow, substrate temperature and laser energy density variation on the properties of the grown film, was studied. The experiments were performed for substrate temperatures in the range of $300\~450^{\circ}C$ and oxygen gas flow rate of $100\~900$ sccm. We investigated the structural and optical properties of ZnO thin films using X-ray diffraction(XRD) and photoluminescence(PL).

A Study on the Pollutant Reduction by Venturi Type After-burner (벤츄리형 후연소기의 오염물질 저감에 관한 연구)

  • Lee, Hwa-Sin;Lee, Yong-Hoo;Lee, Jin-Seok;Kwon, Oh-Boong;Lee, Do-Hyung
    • Proceedings of the Korean Society of Marine Engineers Conference
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    • 2005.06a
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    • pp.81-86
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    • 2005
  • The purpose of this study is to develop venturi type after-burner in order to obtain pollutant reduction effect and find the best stable combustion condition. For this purpose, through a flow analysis, the shape of venturi type was made and flame holder locations were also decided by measuring chemical species at before and after the after-burner. Also, various chemical species concentration were measured at changing the induced air rates and the oxygen for oxygen enrichment for the solution the problems of much oxygen flow rate and the flame stability range. As results of this study, a flow distribution and the purification effect was excellent at venturi contraction 0.5 and flame holder location 12mm below the center of Venturi throat. On the purification characteristics, we found that pollutants reduction was effective when area ratio and oxygen are increased. But there are suitable quantities due to the flame shape change and combustion efficiency.

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The Process Simulation of Entrained Flow Coal Gasification in Dynamic State for 300MW IGCC (300MW급 IGCC를 위한 건식 분류층 석탄 가스화 공정의 동적 상태 모사)

  • Kim, Mi-Yeong;Joo, Yong-Jin;Choi, In-Kyu;Lee, Joong-Won
    • Transactions of the Korean hydrogen and new energy society
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    • v.21 no.5
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    • pp.460-469
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    • 2010
  • To develop coal gasfication system, many studies have been actively conducted to describe the simulation of steady state. Now, it is necessary to study the gasification system not only in steady state but also in dynamic state to elucidate abnormal condition such as start-up, shut-down, disturbance, and develop control logic. In this study, a model was proposed with process simulation in dynamic state being conducted using a chemical process simulation tool, where a heat and mass transfer model in the gasifier is incorporated, The proposed model was verified by comparison of the results of the simulation with those available from NETL (National Energy Technology Laboratory) report under steady state condition. The simulation results were that the coal gas efficiency was 80.7%, gas thermal efficiency was 95.4%, which indicated the error was under 1 %. Also, the compositions of syngas were similar to those of the NETL report. Controlled variables of the proposed model was verified by increasing oxygen flow rate to gasifier in order to validate the dynamic state of the system. As a result, trends of major process variables were resonable when oxygen flow rate increased by 5% from the steady state value. Coal flow rate to gasifier and quench gas flow rate were increased, and flow rate of liquid slag was also increased. The proposed model in this study is able to be used for the prediction of gasification of various coals and dynamic analysis of coal gasification.

Characterization of Fuel Cell Stack Using Hydrocarbon Polymer-Silica Composite Membranes (탄화수소계 고분자-실리카 복합막이 적용된 연료전지 스택 성능평가)

  • Hyun Woo Kang;Doo Sung Hwang;Chi Hoon Park;Young Moo Lee
    • Membrane Journal
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    • v.33 no.3
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    • pp.127-136
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    • 2023
  • In this study, the electrochemical performance of a 5-layer fuel cell stack using silica composite membranes as polymer electrolyte membranes was evaluated. It was observed that the flow rate of the fuel gases plays a crucial role in stack performance, particularly being mainly dependent on the flow rate of hydrogen. Increasing the flow rate of oxygen resulted in negligible changes in performance, whereas an increase in the flow rate of hydrogen demonstrated performance improvements. However, this led to an imbalance in the ratio of hydrogen to oxygen flow rates, causing significant degradation in stack performance and durability. A decline in stack performance was also observed over time due to the degradation of stack components. This phenomenon was consistently observed in individual unit cells. Based on these findings, it was emphasized that, in addition to optimizing the performance of each component during stack operation, it is important to optimize design and operating conditions for uniform flow rate control. Lastly, the developed silica composite membrane was assessed to have sufficient performance for application in actual fuel cell systems, exhibiting a performance of over 25 W based on maximum power.