• Title/Summary/Keyword: Oxidizing gas

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Reconstruction and Elimination of Optical Microscopic Background Using Surface Fitting Method

  • Kim Hak-Kyeong;Kim Dong-Kyu;Jeong Nam-Soo;Lee Myung-Suk;Kim Sang-Bong
    • Fisheries and Aquatic Sciences
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    • v.4 no.1
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    • pp.10-17
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    • 2001
  • One serious problem among the troubles to identify objects in an optical microscopic image is contour background due to non-uniform light source and various transparency of samples. To solve this problem, this paper proposed an elimination method of the contour background and compensation technique as follows. First, Otsu's optimal thresholding method extracts pixels representing background. Second, bilinear interpolation finds non-deterministic background pixels among the sampled pixels. Third, the 2D cubic fitting method composes surface function from pivoted background pixels. Fourth, reconstruction procedure makes a contour image from the surface function. Finally, elimination procedure subtracts the approximated background from the original image. To prove the effectiveness of the proposed algorithm, this algorithm is applied to the yeast Zygosaccharomyces rouxii and ammonia-oxidizing bacteria Acinetobacter sp. Labeling by this proposed method can remove some noise and is more exact than labeling by only Otsu's method. Futhermore, we show that it is more effective for the reduction of noise.

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Low Temperature Deposition and Characteristics of ATO Thin Films by Ion Beam Sputtering (이온빔 스퍼터링법에 의한 ATO박막의 저온 증착 특성)

  • Koo, Chang-Young;Lee, Hee-Young;Hong, Min-Ki;Kim, Kyung-Joong;Kim, Kwang-Ho
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.05b
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    • pp.307-310
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    • 2000
  • Antimony doped tin oxide (ATO) thin films were deposited at room temperature by ion-beam sputter deposition (IBSD) technique in oxidizing atmosphere utilizing Sb and Sn metal targets. Effect of Sb doping concentration, film thickness and heat treatment on electrical and optical properties was investigated. The thickness of as-deposited films was controlled approximately to $1500{\AA}$ or $2000{\AA}$, and Sb concentration to 10.8 and 14.9 wt%, as determined by SEM and XPS analyses. Heat treatment was performed at the temperature from $400^{\circ}C$ to $600^{\circ}C$ in flowing $O_2$ or forming gas. The resulting ATO films showed widely changing electrical resistivity and optical transmittance values in the visible spectrum depending on the composition, thickness and firing condition.

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A Numerical Study on the Slab Heating Characteristics in a Reheating Furnace with the Formation and Growth of Scale on the Slab Surface (스케일 층의 생성 및 성장을 고려한 가열로 내 슬랩의 승온 특성 해석에 관한 연구)

  • Lee, Dong-Eun;Jang, Jung-Hyun;Kim, Chong-Min;Hong, Dong-Jin;Park, Hae-Doo;Park, Yun-Beom;Kim, Man-Young
    • 한국전산유체공학회:학술대회논문집
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    • 2008.03b
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    • pp.109-112
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    • 2008
  • In this work, a mathematical heat transfer model of a walking-beam type reheating furnace that can predict the formation and growth of the scale layer, which is produced due to oxidative reaction between the furnace oxidizing atmosphere and the steel surface in the reheating furnace, has been developed. The model can also predict the heat flux distribution within the furnace and the temperature distribution in the slab and scale throughout the reheating furnace process by considering the heat exchange between the slab and its surroundings in the furnace, including radiant heat transfer among the slabs, the skids, the hot gases and the furnace wall as well as the gas convection heat transfer in the furnace. Using the model developed in this work, the effects of the scale layer on the heat transfer characteristics and temperature behavior of the slab is investigated. A comparison is also made between the predictions of the present model and the data from an in situ measurement in the furnace, and a reasonable agreement is founded.

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EFFECT OF ETHENE $(C_2 H_4)$ ON THE PLASMA $DeNO_X$ PROCESS FROM DIESEL ENGINE EXHAUST

  • Park, Kwang-Seo;Kim, Dong-Inn;Lee, Hyeong-Sang;Chun, Bae-Hyeock;Yoon, Woong-Sup;Chun, Kwang-Min
    • International Journal of Automotive Technology
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    • v.2 no.2
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    • pp.77-83
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    • 2001
  • Effect of ethene on the $DeNO_X$ conversion process in a simulated diesel engine operating conditions was investigated experimentally and theoretically. With the addition of even a small amount of ethene the NO to $NO_2$ conversion enhances greatly. The energy required to convert one NO molecule is 27 eV with 250 ppm ethene added, while 137 eV without ethene at 473 K. The effect of energy density, temperature, and the initial concentrations of ethene and oxygen are also discussed and the results show that the increase of the mentioned parameters lead to the promotion of NO oxidation. A kinetic model used in this study shows good agreement with the experimental result. Byproducts like formaldehyde ($CH_2$ 0) and methyl nitrite ($CH_3$ ONO) predicted by model calculation are broken up into CO and $H_2O$ eventually when high energy is delivered to the gas mixture. Sensitivity analysis shows that the main reactions of NO oxidation when ethene is added we: $HO_2+ NO \arrow NO_2 + OH, RO_2 + NO \arrow NO_2 + RO$, where R is a hydrocarbon radical. Also the direct oxidizing reaction of NO with O cannot be neglected.

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Fabrication of Etched Graphene/CuO Nanowires as Field Effect Transistors

  • Hien, Vu Xuan;Kim, Se-Yun;Kim, MyeongEon;Lee, Joon-Hyung;Kim, Jeong-Joo;Heo, Young-Woo
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.02a
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    • pp.430-430
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    • 2013
  • Field effect transistor based on semiconductor nanowires has been attracting lots of concerns and studies of scientists because of its different characteristic comparing with other morphology like thin film. Nowadays, graphene is introducing a great promise as an active layer in field effect transistor due to its unique electronic and optoelectronic properties. Thus, a mix structure between etched graphene and semiconductor nanowires is believed to expose novel electrical characteristics. In this study, CuO nanowires (20~80 nm in diameter and $1{\sim}10{\mu}m$ length) were grown during oxidizing Cu foil at $450^{\circ}C$ for 24 h. Besides, 3-layersetched graphene was deposited on Cu foil at $1,000^{\circ}C$ using a feedstock of $CH_4$/$H_2$ mixed gas in CVD system. A structure of Ni/Au electrode + CuO nanowires + etched graphene was fabricated, afterward. Finally, field effect properties of the device was revealed and compared with individual devices of just nanowires and just graphene.

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Phase formation and microstructural characteristics of ytterbium silicates coatings fabricated by plasma spraying with Ar/He gas compositions for environmental barrier coating applications (플라즈마용사로 증착된 환경차폐코팅 이터븀 실리케이트의 Ar/He 가스 조성에 따른 상형성 및 미세구조 특성)

  • Choi, Jae-Hyeong;Kim, Seongwon;Kim, Ji-Yoo;Moon, Hung Soo
    • Journal of Surface Science and Engineering
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    • v.55 no.6
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    • pp.376-382
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    • 2022
  • Yb2Si2O7 has a coefficient of thermal expansion similar to that of the base material of SiC and has excellent corrosion resistance in a high-temperature oxidizing atmosphere including water vapor, so it is being studied as one of the materials for environmental barrier coatings (EBCs). In this study, Yb2Si2O7 powder granule is deposited using atmospheric plasma spraying (APS) with different Ar/He ratios. Phase formation and microstructural characteristics are investigated with the coated specimens. In the coating layer, the crystallinity decreased, and the amorphous content increased from an increase in the ratio of Ar. In addition, the various types of particles involved by local volatilization of Si according to the Ar/He ratios were identified.

Acute methemoglobinemia after a normal diet (일상적인 음식 섭취 후 발생한 급성 메트헤모글로빈혈증)

  • Lee, Sung Kgun;Kang, Jeong Ho
    • Journal of Medicine and Life Science
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    • v.18 no.1
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    • pp.20-23
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    • 2021
  • Methemoglobin is generated by the oxidation of ferrous iron to ferric iron within a hemoglobin molecule. Methemoglobin is unable to bind and transport oxygen, resulting in methemoglobinemia, which can lead to fatal tissue hypoxia. The most common cause of methemoglobinemia is poisoning by oxidizing agents such as dapsone, benzocaine, and primaquine. However, methemoglobinemia can also be caused by normal dietary sources. We present two cases of methemoglobinemia that developed after a normal diet in two male patients. In this case report, the patients suddenly developed dyspnea and cyanosis after eating the same meal. They had no history of suspected poisoning, such as the use of drugs, exposure to chemicals, or gas inhalation. Their symptoms did not improve even after a high dose of oxygen was administered; further, an abnormal 'oxygen saturation gap' was observed. Because of CO-oximetry, the methemoglobin levels of the patients were 50.0% and 46.6%, respectively. We administered methylene blue (1 mg/kg), and the patients recovered completely without any complications. Emergency physicians should, therefore, be aware that methemoglobinemia can also be caused by normal dietary sources. In addition, if the source and route of contamination are unclear, an epidemiological investigation should be conducted.

Two Cases of Inhalation Injury Caused by An Explosion of Two Different Chemical Disinfectants(Sodium Dichloroiso Cyanurate & Calcium Hypochlorite) in a Swimming Pool (수영장에서 소독제 분말 가스 폭발에 의한 흡입화상 2례)

  • Lee, Su Jin;Park, Eun Young;Kim, Mi Ran;Lee, Kon Hee;Kim, Kwang Nam
    • Clinical and Experimental Pediatrics
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    • v.46 no.2
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    • pp.198-202
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    • 2003
  • Of all toxic inhalant exposures, chlorine is one of the most common toxic chemical inhalants. When acutely inhaled, it can be responsible for symptoms ranging from upper air way irritation to more serious respiratory effects. It can also deteriorate lung function and lead to death. Chlorine and its compounds such as chlorinated cyanurates and hypochlorites are commonly used in water disinfection. The chemical agents discussed in this article are sodium dichloroiso cyanurate and calcium hypochlorite which are the two most popular products for swimming pool chlorination. They are both strong oxidizing agents which are soluble in water. Between the above two alkali agents, acid-base interaction occurred and generated heat. And the acid drove the combination of hypochlorous and chloride ions to form chlorine gas. We have experienced, two boys who had inhalation injuries caused by an accidental explosion which occurred in a swimming pool by mixing two different chlorinating agents : sodium dichloroiso cyanurate and calcium hypochlorite. The children suffered from respiratory difficulties after the exposure. They both required intensive care management and one needed the support of mechanical ventilation.

Characteristics of Bio-filter Support Media for the Odor Control (악취가스 제어를 위한 Bio-filter 담체의 특성 비교)

  • Lee, Hye-Sung;Chu, Duk-Sung;Jung, Joon-Oh
    • Journal of Environmental Health Sciences
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    • v.34 no.1
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    • pp.101-107
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    • 2008
  • Bio-filtration utilizes microorganisms fixed to a porous medium to metabolize pollutants present in an air stream. The microorganisms grow in a bio-film on the surface of a medium or are suspended in the water phase surrounding the medium particles. Therefore, bio-filter support media play one of the most important key roles in bio-filtration of gas phase pollutants. To characterize and select the appropriate support media, gas adsorption capacity and microorganism immobilization were investigated in lab-scale experiments for the selected target support media which were compost I (compost from lab-scale process), compost II (compost from municipal facility), bark, wood chip, orchid stone and vermiculite. As odor materials, ammonia and trimethylamine were utilized. From the result of experiments, bark was superior to any other support media tested in adsorption capacity as much as 12.5 mg ammonia per 1 g bark. In trimethylamine adsorption, bark and wood chip showed a remarkable results of 21.1 and 14.1 mg/g respectively. On the other hand, microorganism fixation test determined by the count of nitrogen oxidizing microbes population, the compost II and wood chips showed the best results. Considering the characteristics of materials and the operating condition of the bio-filter, bark, wood chip, and compost II are applicable to the support media of bio-filter when they are appropriately blended on the basis of studying the media pH, packing porosity and moisture contents.

Total Organic Carbon Analysis Chip Based on Photocatalytic Reaction (광촉매 반응을 이용한 총유기탄소 분석 칩)

  • Kim, Seung Deok;Jung, Dong Geon;Kwon, Soon Yeol;Choi, Young Chan;Lee, Jae Yong;Koo, Seong Mo;Kong, Seong Ho
    • Journal of Sensor Science and Technology
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    • v.29 no.2
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    • pp.128-132
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    • 2020
  • Total organic carbon (TOC) analysis equipment, which was previously used to prevent eutrophication in advance, is heavy, bulky, and expensive; therefore, so it is difficult to be carried and has been used as an experimental unit. In this study, a through-carbon analysis chip that integrates pretreatment through photocatalytic oxidation and carbon dioxide measurement using a pH indicator was investigated. Both the total carbon - inorganic carbon method and the nonpurgeable organic carbon (NPOC) measurement method require an acidification part for injecting an acid solution for inorganic carbon measurement and removal, an oxidation part for total carbon or NPOC oxidation and a measurement part for Carbon dioxide (CO2) measurement. Among them, the measurement of oxidation and CO2 requires physical technology. The proposed TOC analysis chip decomposed into CO2 as a result of the oxidizing of organic carbon using a photocatalyst, and the pH indicator that was changed by the generated CO2 was optically measured. Although the area of the sample of the oxidation part and the pH indicator of the measurement part were distinguished in an enclosed space, CO2 was quantified by producing an oxidation part and a measurement part that shared the same air in one chip. The proposed TOC analysis chip is less expensive and smaller, cost and size are disadvantages of existing organic carbon analysis equipment, because it does not require a separate carrier gas to transport the CO2 gas in the oxidation part to the measurement part.