• 한국지구과학회지
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• 제24권8호
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• pp.657-667
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• 2003

현세-후기 플라이스토세의 부정합적 경계면을 조사하기 위하여 한국 서해 경기만 조간대에서 심부시추와 탄성파 탐사를 실시하였다. 분석된 모든 시추 퇴적물에서 현세 퇴적층(Unit I) 하부에 놓이는 최대 4m두께의 산화되고, 반고화된 특징을 보이는 황갈색의 산화대층(oxidized-sedimentary layer)이 발견되었다. 이 세립질의 산화대층에서 나타나는 황갈색의 퇴적물 색, 높은 N 값과 낮은 함수율의 준고화된 상태, 동토구조, 스멕타이트 광물의 부재 그리고 높은 퇴적물 화학적 풍화지수(Ba/Sr 비) 등의 다양한 특성은 퇴적물의 대기중 노출과 풍화의 중요한 증거로 제시된다. 탄소동위원소 연대와 함께 이러한 여러 증거들을 고려할 때, Unit II의 상부 산화대층은 초기 현세까지 계속되는 저해수면 동안 대기중에 노출되어 풍화 및 산화작용으로 인하여 퇴적물의 특성이 변질되어 형성된 것으로 해석된다. 따라서 산화대층의 상부 경계면은 현세와 선현세(후기 플라이스토세) 퇴적층을 구분하는 부정합면으로 제시되며, 탄성파 자료에서 나타나는 강한 반사면(prominent near-surface reflector)과 잘 일치한다.

• 한국세라믹학회지
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• 제47권3호
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• pp.256-261
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• 2010

Physical properties of Plasma electrolytic oxidized 8 different types of Al alloys, A-1100, A-2024, A-5052, A-6061, A-6063, A-7075, ACD-7B and ACD-12 were investigated. The electrolyte for PEO was $Na_2SiO_3$ solutions with NaOH and some alkali earthen metal salts. Porous layer near the surface of PEO coating was not found, and surface roughness Ra50 was below 2.5 ${\mu}m$. Surface roughness was affected by growth rate of plasma electrolytic oxidized layer, not by Si content in Al alloy.

• 한국전기전자재료학회논문지
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• 제19권9호
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• pp.868-872
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• 2006

In this work, the effects of the corona treatment on surface properties of semiconducting silicone rubber were investigated in terms of contact angles, ATR-FTIR(Attenuated total reflection fourier transform infrared spectroscopy) and XPS(X-ray photoelectron spectroscopy). And the adhesive characteristics were studied by measuring the T-peel strengths. Based on chemical analysis, the surface modification can be mainly ascribed to the creation of chemically active functional groups such as C-O, C=O and C-OH on semiconducting silicone surface. This oxidized rubber layer is inorganic silica-like structure of Si bound with three to four oxygen atoms ($SiOx,\;x=3{\sim}4$. The Corona treatment produces an increase in joint strength that is maximum for 10 min treatment. However, due to brittle property of this oxidized layer, the highly oxidized layer from too much extended treatment could be act as a weak point, decreasing the adhesion strength.

• 한국표면공학회지
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• 제44권4호
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• pp.125-130
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• 2011

$Cr_2AlC$ compounds were synthesized by hot pressing, and oxidized between 900 and $1200^{\circ}C$ in air for up to 50 hours. They oxidized to a thin $Al_2O_3$ layer containing a small amount of $Cr_2O_3$with the liberation of carbon as CO or $CO_2$ gases. The consumption of Al to form the $Al_2O_3$ layer led to the depletion of Al and enrichment of Cr just below the $Al_2O_3$ layer, resulting in the formation of an underlying $Cr_7C_3$ layer. As the oxidation temperature and time increased, the $Cr_7C_3$ oxide layer and the underlying $Cr_7C_3$ layer thickened. The oxidation resistance of $Cr_2AlC$ was generally good due to the formation of the $Al_2O_3$ barrier layer.

• 한국자기학회지
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• 제12권3호
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• pp.99-102
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• 2002

기존 절연막보다 균일한 AlO 절연막을 형성하기 위해 플라즈마 산화법을 이용하여 이중 연속 절연막을 형성한 TMR소자를 제작하였다. 10 $\AA$의 Al 하부 절연막의 산화시간을 10sec로 우선 완성하고 그 위에 13 $\AA$의 Al을 성막하고 50, 80, 120sec간 산화시켜 완성한 절연막의 특성을 알아본 결과 산화시간이 증가할수록 전기저항은 500 $\Omega$에서 2000 $\Omega$까지 크게 변화하며 80sec 에서 가장 작았고, MR비는 27~31 %로 큰 변화가 없었으나, 단일산화 절연막을 가진 시편(24%)보다는 모두 높은 자기저항비를 보였다. I-V측정을 통해 간접적으로 유효 장벽 높이와 장벽 폭을 계산한 결과 장벽 높이는 1.3~1.8eV로 터널링 장벽으로서 충분한 크기를 보였으며 장벽 폭의 경우에는 15.0 $\AA$ 이하로 실제 물리적으로 측정한 값보다 작음을 알 수 있었다. 이는 Al금속이 완전히 안정한 A1$_2$O$_3$로 산화되지 않았기 때문으로 생각되었으며, 그럼에도 불구하고 단일 AlO 절연막 시편보다는 균일하고 치밀한 절연막을 형성하였음을 확인하였다. 이러한 결과는 이중절연층 산화공정이 기존 공정보다 절연장벽을 우수하게 하여 MR비를 향상시키고 기준저항을 조절하는데 유리한 공정임을 의미하였다.

• 한국표면공학회지
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• 제36권2호
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• pp.128-134
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• 2003

Alloys of Ti-43%Al-2%W-0.1%Si were oxidized isothermally and cyclically between $900^{\circ}C$ and$ 1050^{\circ}C$, and their oxidation characteristics were studied. During isothermal tests, the alloys oxidized slowly up to 100$0^{\circ}C$, but fast at $1050^{\circ}C$. Though the scale adherence was not good above $900^{\circ}C$, the alloys displayed better oxidation behavior than unalloyed TiAl alloys. The oxide scales consisted primarily of an outer $TiO_2$ layer, intermediate $Al_2$$O_3$-rich layer, and an inner mixed layer of (TiO$_2$ $+Al_2$$O_3$). Tungsten was present mainly at the lower part of the oxide scale, while Si over the whole oxide scale.

• 미생물학회지
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• 제21권4호
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• pp.185-190
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• 1983

Twelve Microorganisms capable of utilizing diaminododecane were isolated from the soil by enrichment culture technique. Seven strains of these were identified as Corynebacterium. The isolated strains were tested for the ability to utilize as carbon source, 10 different kind of alkane derivatives containing CN, $NH_2$, Cl, and SH groups. Laurylcyanide, dicyanooetane, chlorodecane, and dichlorodecane were not utilized by any of the isolated strains; putrescine dihydrochloride, cadaverine dihydrochloride, diaminododecane, and n-dodecane were utilized by all of the isolated strains; and all of the isolated strains except DAD 2-3 could utilize dodecylmercaptan. The alkane derivatives that did not serve as ,growth substrates were tested further in oxidation tests using resting cell preparation. Alkane derivatives that are being oxidized by all of the isolated strains are laurylcyanide and dichlorodecane. Dicyanooctane was also oxidized by all of the isolated strains except DAD 30L, chlorodecane was the only oxidized by the three isolated strains. The most remarkable substrate that is being oxidized is dichlorodecane containing CN groups diterminally. Evidence obtained with thin layer chromatography of ,ethyl acetate extracts of culture broth of isolated strains grown in some alkane derivatives shows that these alkane derivatives are degraded.

• Nuclear Engineering and Technology
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• 제54권4호
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• pp.1185-1194
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• 2022

The maintenance of condenser main pipe is the key to achieve film-forming amine maintenance effectiveness. In this work, oxygen content, pH and temperature of the solution were controlled to simulate the condition of condenser main pipe, and magnetite coated carbon steel sample was prepared by pre-oxidization. CAM was used to characterize the hydrophobicity of film formed samples. Hydrophobic film was formed on pre-oxidized carbon steel samples when octadecylamine concentration reaches 20 mg/kg. SEM, EDS, EIS, and PD were used to characterize the influence of octadecylamine concentration on maintenance effectiveness. It was found that the maintenance effectiveness was enhanced and the corrosion rate was suppressed with the increase of octadecylamine concentration. FIB and TEM were used to detect the adsorbed octadecylamine film thickness founding that octadecylamine adsorbed onto the surface of pre-oxidized carbon steel by multi-layer adsorption mechanism.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2013년도 제45회 하계 정기학술대회 초록집
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• pp.144.1-144.1
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• 2013

Recently, we have developed the local oxidization and hydrogenization method for graphene layer using atomic force microscope(AFM) tip at room temperature and ambient pressure. With this method we could create locally oxidized or hydrogenized area on the graphene layer with various size from nanometer to micrometer scale, by controlling the amplitude and polarity of the voltage supplied between conducting AFM tip and the graphene layer. We investigated the chemical states of functionalized C atoms in the graphene layer using scanning photoelectron microscopy. By measuring C 1s core level X-ray Photoemission Spectra of the C atoms and suitable fitting process carried on the measured spectra, we could obtain the fraction of oxidization and hydrogenization under various condition, and the evolution of each chemical state during thermal annealing process.

• 대한금속재료학회지
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• 제49권2호
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• pp.153-160
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• 2011

The AISI 216L stainless steel with a composition of Fe-16Cr-6Ni-6Mn-1.7Mo (wt.%) was oxidized at $700{\sim}900^{\circ}C$ in air for 100 h. At $700^{\circ}C$, a thin $Mn_{1.5}Cr_{1.5}O_4$ oxide layer with a thickness of $0.4{\mu}m$ formed. At $800^{\circ}C$, an outer thin $Fe_2O_3$ oxide layer and a thick inner $FeCr_2O_4$ oxide layer with a total thickness of $30{\mu}m$ formed. The non-adherent scale formed at $800^{\circ}C$ was susceptible to cracking. At $900^{\circ}C$, an outer thin $Fe_2O_3$ oxide layer and a thick inner $Mn_{1.5}Cr_{1.5}O_4$ oxide layer formed, whose total thickness was $10{\sim}15{\mu}m$. The scales formed at $900^{\circ}C$ were non-adherent and susceptible to cracking. 216 L stainless steel oxidized faster than 316 L stainless steel, owing to the increment of the Mn content and the decrement of Ni content.