• 제목/요약/키워드: Oxidized layer

검색결과 328건 처리시간 0.027초

태양전지용 규소 기판에 존재하는 기계적 손상의 gettering 공정에의 활용 (Utilization of the surface damage as gettering sink in the silicon wafers useful for the solar cell fabrication)

  • 김대일;김영관
    • 한국결정성장학회지
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    • 제16권2호
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    • pp.66-70
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    • 2006
  • 실리콘웨이퍼 표면에 기계적인 손상을 가한 후 산화 열처리 공정을 실시하면 온도와 기계적인 손상의 크기에 따라 여러 가지 결정 결함이 발생된다. 기계적인 손상이 크고 열처리 온도가 증가함에 따라 dislocation loop 등의 대형 결함들이 발생되고 열처리 온도가 낮거나 손상의 크기가 작을수록 OISF(Oxidation Induced Stacking Faults)등의 소형 결함들이 많이 발생된다. Minority carrier lifetime을 측정하여본 결과 결함의 크기가 작을수록 minority carrier lifetime이 높은 것으로 밝혀졌다. 더욱이 dislocation loop 등의 결정 결함보다는 결함 발생 이전 단계인 strained layer등이 금속불순물에 대한 gettering의 효과가 더욱 높음을 알 수 있었다.

와이어 공급에 의한 Inconel의 Nd:YAG 레이저 클래딩 (Nd:YAG Laser Cladding of Inconel with Wire Feeding)

  • 김재도;배민종;팽윤
    • Journal of Welding and Joining
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    • 제18권3호
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    • pp.83-88
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    • 2000
  • Laser cladding processing allows rapid transfer of heat to the material being processed with minimum conduction into base metal, resulting in low total heat input. The effects of Nd:YAG laser cladding with wire feeding on the mechanical properties of Inconel alloy were investigated. inconel alloy is used as the material of nuclear steam generator tubing because of its mechanical properties and corrosion resistance properties. The device for Nd:YAG laser cladding with wire feeding was designed. It consists of the wire feeding system, the wire cladding system and the shielding gas system which prevents the clad layer from being oxidized. Experimental as results indicated that the wire feeding direction and position were important for laser cladding with wire feeding. The wire feeding speed should be adapted according to cladding speed for good shaping of clad layer. The effect of heat on the HAZ size can be limited and the growth of grain size of HAZ size was not serious. The hardness of clad layer and heat affected zone increased with increasing of cladding speed.

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가습된 $N_2$/H$_2$혼합가스 분위기에서의 Kovar 산화 거동 (The Oxidation of Kovar in Humidified $N_2$/H$_2$ Atmosphere)

  • 김병수;김민호;김상우;최덕균;손용배
    • 마이크로전자및패키징학회지
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    • 제8권2호
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    • pp.1-7
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    • 2001
  • 저열팽창성 금속인 Kovar표면을 유리와 접합하기에 적합한 spinel을 주상으로 하는 균일한 산화막을 형성할 수 있도록 $N_2/H_2$$H_2O$가 첨가된 분위기에서의 산화 거동에 대하여 조사하였다. Kovar 산화는 확산에 의해 지배되는 공정이며, 이때 산화 활성화 에너지는 31.61 kacl/mol 이었다. $600^{\circ}C$에서 열처리한 결과 spinel을 주상으로 하는 0.5 $mu extrm{m}$ 이하의 연속적이고 균일한 외부 산화막을 얻을 수 있었다. TEM 분석 결과 격자 상수가 7.9 $\AA$인 spinel 임을 확인할 수 있었다. 그러므로, 가습된 $N_2/H_2$분위기에서 산화한 Kovar는 유리와 접합에 적용 가능할 것으로 판단된다.

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메탄/순산소 혼합층에서 edge flame의 구조 (Structure of Edge Flame in a Methane-Oxygen Mixing Layer)

  • 최상규;김준홍;정석호;김종수
    • 한국연소학회:학술대회논문집
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    • 한국연소학회 2006년도 제32회 KOSCO SYMPOSIUM 논문집
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    • pp.149-156
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    • 2006
  • Structure of edge flame established in a mixing layer, formed between two uniformly flowing pure $CH_4$ and pure $O_2$ streams, is numerically investigated by employing a detailed methane-oxidation mechanism. The numerical results exhibited the most outstanding distinction of using pure oxygen in the fuel-rich premixed-flame front, through which the carbon-containing compound is found to leak mainly in the form of CO instead of HC compounds, contrary to the rich $CH_4-air$ premixed flames in which $CH_4$ as well as $C_2H_m$ leakage can occur. Moreover, while passing through the rich premixed flame, a major route for CO production, in addition to the direct $CH_4$ decomposition, is found to be $C_2H_m$ compound formation followed by their decomposition into CO. Beyond the rich premixed flame front, CO is further oxidized into $CO_2$ in a broad diffusion-flame-like reaction zone located around moderately fuel-rich side of the stoichiometric mixture by the OH radical from the fuel-lean premixed-flame front. Since the secondary CO production through $C_2H_m$ decomposition has a relatively strong reaction intensity, an additional heat-release branch appears and the resulting heat-release profile can no longer be seen as a tribrachial structure.

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$Fe/CeO_{2}Fe_{75}Co_{25}$ 터널접합의 잔기저항효과 (Magnetroresistance Effect of $Fe/CeO_{2}Fe_{75}Co_{25}$ Tunnel Junctions)

  • 이창호;김익준
    • 한국전기전자재료학회논문지
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    • 제14권8호
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    • pp.688-693
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    • 2001
  • A series of Fe/CeO$_2$/Fe$_{75}$Co$_{25}$ tunnel junctions (Magnetic Tunnel Junction, MTJ) having CeO$_2$ barrier layers from 30 to 90$\AA$ in thickness were prepared by ion beam sputtering (IBS) method. In order to compare the properties of MTJs, Fe/Al oxide/Fe-Co tunnel junctions were also prepared. Some junctions with a CeO$_2$ barrier layer showed the ferromagnetic tunneling effect and the highest MR ratio at room temperature was 5%. The electric resistance of junctions with a CeO$_2$ barrier layer was higher that that of junctions with an Al oxide barrier. On the other hand, The interface analysis of the Fe/CeO$_2$ bilayer was conducted by means of X-ray photoelectron spectroscopy (XPS). It was found that CeO$_2$ was decomposed to Ce and $O_2$ during sputtering, and Fe was oxidized with these decomposed $O_2$ molecules. The reduction of both electric resistance and MR ratio may be associated with the decomposed Ce in the barrier layer.r.r.

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메탄/순산소 혼합층에서 Edge Flame의 구조 (Structure of Edge Flame in a Methane-Oxygen Mixing Layer)

  • 최상규;김준홍;정석호;김종수
    • 한국연소학회지
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    • 제11권1호
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    • pp.19-26
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    • 2006
  • Structure of edge flame established in a mixing layer, formed between two uniformly flowing pure $CH_4$ and pure $O_2$ streams, is numerically investigated by employing a detailed methane-oxidation mechanism. The numerical results exhibited the most outstanding distinction of using pure oxygen in the fuel-rich premixed-flame front, through which the carbon-containing compound is found to leak mainly in the form of CO instead of HC compounds, contrary to the rich $CH_4-air$ premixed flames in which $CH_4$ as well as $C_2H_m$ leakage can occur. Moreover, while passing through the rich premixed flame, a major route for CO production, in addition to the direct $CH_4$ decomposition, is found to be $C_2H_m$ compound formation followed by their decomposition into CO. Beyond the rich premixed flame front, CO is further oxidized into $CO_2$ in a broad diffusion-flame-like reaction zone located around moderately fuel-rich side of the stoichiometric mixture by the OH radical from the fuel-lean premixed-flame front. Since the secondary CO production through $C_2H_m$ decomposition has a relatively strong reaction intensity, an additional heat-release branch appears and the resulting heat-release profile can no longer be seen as a tribrachial structure.

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Nanoparticle Ferrite Multilayers Prepared by New Self-Assembling Sequential Adsorption Method

  • Kim, Yeong-Il;Kang, Ho-Jun;Kim, Don;Lee, Choong-Sub
    • Bulletin of the Korean Chemical Society
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    • 제24권5호
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    • pp.593-599
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    • 2003
  • The nanoparticle magnetite of which diameter was about 3 nm was synthesized in a homogeneous aqueous solution without a template. The synthesized magnetite nanoparticle was easily oxidized to maghemite in an ambient condition. The magnetic properties of the ferrite nanoparticle show superparamagnetism at room temperature and its blocking temperature is around 93 K. Modifying the sequential adsorption method of metal bisphosphonate, we have prepared a multilayer thin film of the ferrite nanoparticle on planar substrates such as glass, quartz and Si wafer. In this multilayer the ferrite nanoparticle layer and an alkylbisphosphonate layer are alternately placed on the substrates by simple immersion in the solutions of the ferrite nanoparticle and 1, 10-decanediylbis (phosphonic acid) (DBPA), alternately. This is the first example, as far as we know, of nanoparticle/alkyl-bisphosphonate multilayer which is an analogy of metal bisphosphonate multilayer. UV-visible absorption and infrared reflection-absorption studies show that the growth of each layer is very systematic and the film is considerably optically transparent to visible light of 400-700 nm. Atomic force microscopic images of the film show that the surface morphology of the film follows that of the substrate in μm-scale image and the nanoparticle-terminated surface is differentiated from the DBPA-terminated one in nm-scale image. The magnetic properties of this ferrite/DBPA thin film are almost the same as those of the ferrite nanoparticle powder only.

산화처리 탄소 및 이를 이용한 EDLC 특성 (Oxidation-treated of Oxidized Carbons and its Electrochemical Performances for Electric Double Layer Capacitor)

  • 양선혜;김익준;전민제;문성인;김현수;안계혁;이윤표
    • 한국전기전자재료학회논문지
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    • 제20권6호
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    • pp.502-507
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    • 2007
  • The oxidation treatment of several carbon materials with a sodium chlorate and 70 wt.% of nitric acid, combined with heat treatment, were attempted to achieve an electrochemical active material with a larger capacitance. Among pitch, needle coke, calcinated needle coke and natural graphite, the structure of needle coke and calacinated needle coke were changed to the graphite oxide structure with the expansion of the inter-layer. On the other hand, the calcinated needle coke after oxidation and heating at $200^{\circ}C$ has exhibited largest capacitance per weight and volume of 29.5 F/g and 24.5 F/ml at the two-electrode system in the potential range of 0 to 2.5 V. The electrochemical performance of the calcinated needle coke was discussed with the phenomenon of the electric field activation and the formation of new pores between the expanded inter-layer at first charge.

산화 그래핀을 절연층으로 사용한 유연한 ReRAM과 다층 절연층 ReRAM의 제작 방법 및 결과 비교 (A Review: Comparison of Fabrication and Characteristics of Flexible ReRAM and Multi-Insulating Graphene Oxide Layer ReRAM)

  • 김동균;김태헌;윤태환;박정호
    • 전기학회논문지
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    • 제65권8호
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    • pp.1369-1375
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    • 2016
  • A rapid progress of the next-generation non-volatile memory device has been made in recent years. Metal/insulator/Metal multi-layer structure resistive RAM(ReRAM) has attracted a great deal of attention because it has advantages of simple fabrication, low cost, low power consumption, and low operating voltage. This paper describes the working principle of the ReRAM device, a review of fabrication techniques, and characteristics of flexible ReRAM devices using graphene oxide as an insulating layer and ReRAM devices using multi-layered insulator. The switching characteristics of the above ReRAM devices have been compared. The oxidized graphene could be employed as an insulator of next generation ReRAM devices.

전분 함량 보정을 통한 판지류의 가용성 잔류물질 정량 분석 (Quantitative Analysis of Soluble Residues by Correction of Starch Content in Paperboard Grade)

  • 임채훈;박정윤;이태주;엄기증;김형진
    • 펄프종이기술
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    • 제45권6호
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    • pp.78-87
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    • 2013
  • Even though the notice No. 2010-11 of the Ministry of Food and Drug Safety Administration that has been applied to analyze the content of the water soluble residue eluted from multi-layer paperboard was abolished in 2011, its application for the analysis on evaporation residue is still valid. There are very high possibilities that the noticed existing method gives the misleading result on the evaporation residue due to the water soluble starch eluted from the multi-layer paperboard. The quantitative analysis on water-soluble residue with starch content correction has been carried in the study using UV/Vis spectroscopy and HPLC. The UV/Vis spectroscopy absorbance analysis showed the large amount of the oxidized starch obtained from the aqueous residue eluted out of the multi-layer paperboard after the iodine, ${\alpha}$-amylase reaction, and starch hydrolysis. The residual content decreased by the correction through the enzyme hydrolysis.