• Title/Summary/Keyword: Oxide superconductor

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Evaluation of Ozone for Oxide Superconductor Thin Film Fabrication (산화물 초전도 박막 제작을 위한 오존의 평가)

  • Lim, Jung-Kwan;Park, Yong-Pil;Lee, Hee-Kab
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.07b
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    • pp.1230-1233
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    • 2004
  • Ozone is useful oxidizing gas for the fabrication of oxide thin films. Accordingly researching on oxidizing gas is required. In order to obtain high quality oxide thin films, higher ozone concentration is necessary. In this paper oxidation property was evaluated relation between oxide gas pressure and inverse temperature(CuO reaction). The obtained condition was formulated by the fabrication of Cu metal thin film by co-deposition using the ion Beam Sputtering method. Because the CuO phase peak appeared at the XRD evaluation of the CuO thin film using ozone gas, this study has succeeded in the fabrication of the CuO phase at $825^{\circ}C$.

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Local structural study of commercial grade MBa2Cu3O7-x (M = Y and/or Gd) coated conductors by polarized Raman spectroscopy

  • Moon, Hankyoul;Shin, Hae-Young;Jin, Hye-Jin;Jo, William;Yoon, Seokhyun
    • Progress in Superconductivity and Cryogenics
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    • v.17 no.4
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    • pp.25-29
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    • 2015
  • In 1987, M. K. Wu and Paul Chu discovered $Y_{1.2}Ba_{0.8}CuO_4$ (YBCO) with critical temperature ($T_c$) of 93 K. It has significantly lowered the cost of cooling of a material up to the point where superconductivity set in. Utilizing the cost reduction of attaining superconductivity and the vast amount of research to understand characteristics of high temperature oxide superconducting materials, there has been effort to use a high temperature superconductor as a coated conductor. It is important to characterize the materials precisely for stable performance before commercializing. We used polarized Raman scattering spectroscopy to study structural and stoichiometric information regarding $YBa_2Cu_3O_{7-x}$, $GdYBa_2Cu_3O_{7-x}$, and $GdBa_2Cu_3O_{7-x}$ produced by three leading groups of producing commercial grade high temperature superconductor coated conductors American Superconductor Corporation, Superpower, and SuNAM.

Fabrication and characterization of nickel oxide films on textured nickel substrate for a superconductor buffer layer (초전도 선재의 중간 반응 방지막으로써 Ni 기판위에 제조된 NiO 막의 특성 분석)

  • Park, Eunchul;Inki Hong;Hyunsuk Hwang;Taehyun Sung;Kwangsoo No
    • Progress in Superconductivity
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    • v.3 no.1
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    • pp.95-98
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    • 2001
  • Recently, NiO films have been studied as a buffer layer to fabricate the superconductor with preferred orientation and as a diffusion barrier to prevent the reaction between superconductor and textured nickel substrate . We fabricated NiO films on textured Ni substrate by thermal oxidation with various variables of temperature, oxidation time, atmosphere, and cooling rate. We investigated the alignment of NiO films by XRD and pole figure and the microstructures by SEM. (200) <001> alignment of NiO film was observed at the oxidation condition of $1200^{\circ}C$ far 10min and slow cooling in O2 atmosphere. During the process in Ar atmosphere, we could also observe the thermal faceting which affects the alignment of NiO alms on Ni substrate.

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Study on the preparation of BaPbO3 Additive for Improvement of YBCO Superconductor (YBCO 초전도체 특성 향상을 위한 첨가제 $BaPbO_3$ 제작에 관한 연구)

  • Cho, Yong-Joon;Soh, Dea-Wha;Park, Seong-Bum;Fan, Zhanguo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.11a
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    • pp.55-58
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    • 2003
  • [ $YBa_2Cu_3Ox$ ](YBCO) oxide superconductor was prepared by sol-gel method to improve its superconducting properties, and it was made to be a fine powder, which has the same property of solid state reacted powder. $BaPbO_3$ was synthesized with $BaCO_3$, BaO, PbO, and $PbO_2$ and analyzed by XRD. YBCO superconductor was prepared by use of sol-gelled YBCO powder and additive $BaPbO_3$ and its critical temperature and transition temperature were shown as 91.9 K, 3.7 K respectively in case 20 wt.% $BaPbO_3$ was added to pure sol-gelled YBCO powder.

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Preparation of YBa2Cu3O7-y Superconductor Using Melt Method (용융법에 의한 YBa2Cu3O7-y 초전도체 제작)

  • Lee, Sang Heon
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.35 no.6
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    • pp.622-625
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    • 2022
  • YBa2Cu3O7-y bulk as a high temperature oxide superconducting conductor has the high critical temperature of 92 K. YBa2Cu3O7-y bulk superconductors have been fabricated by a seeded melting growth. Magnetic properties were studied by using superconductor of melted YBa2Cu3O7-y oxides. It was demonstrated that Y2BaCuO5 particles acts as a pinning center which plays an important role on the magnetic properties. The thickness of the upper and lower pellets of the YBa2Cu3O7-y bulk was formed at 40 mm with 55 g of the composition, and the YBa2Cu3O7-y superconductor was manufactured through a heat treatment process. Manufacturing the superconducting bulk, it is possible to improve the pore density of the superconducting bulk by providing a path through which oxygen could be emitted.

Magnetic Properties of Oxide Superconducting Material (산화물 초전도체의 자기적 특성)

  • Lee, Sang-Heon
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.07a
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    • pp.115-118
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    • 2003
  • The sensor at liquid nitrogen temperature showed the increase of electrical resistance by applying magnetic field. Actually, the voltage drop across the sensor was changed from zero to a value more than $100\;{\mu}V$ by the applied magnetic field. The change of electrical resistance depended on magnetic field. The sensitivity of this sensor was $2.9\;{\Omega}/T$. The sensing limit was about $1.5{\times}10^{-5}\;T$. The increase of electrical resistance by the magnetic field was ascribed to a modification of the Josephson junctions due to the penetrating magnetic flux into the superconducting material. Considering the observed properties of the superconductor with trapped magnetic flux, a magnetic sensor was fabricated to detect simultaneously both the intensity and the direction of the magnetic field.

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Formation of $YBa_2Cu_3O_x$ and the microstructure of melt infiltration processed YBCO superconductors

  • Kim, C.J.;Lee, D.M.;Park, H.S.;Jee, Y.A.;Hong, G.W.
    • Progress in Superconductivity
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    • v.1 no.2
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    • pp.89-94
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    • 2000
  • A YBCO superconductor was prepared in a short time by a melt infiltration process that utilizes meting of $Ba_3Cu5O_8$ powder and the infiltration into a porous $Y_2BaCuO_5$ compact. The processing parameters such as a reaction temperature and time, and atmosphere (air and $O_2$) were controlled to establish the fabrication condition. The formation of a $YBa_2Cu_3O_x$, phase and the developed microstructure are reported.

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Magnetic Characteristics of BiPbSrCaCuO Oxide Superconductor (BPSCCO 자기 효과)

  • Lee, Sangl-Heon;Lee, Sung-Gap;Lee, Young-Hie
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.11a
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    • pp.252-254
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    • 2003
  • A magnetic field sensor is fabricated with superconducting ceramics system. The sensor at liquid nitrogen temperature shows the increase in electrical resistance by applying magnetic field. Actually, the voltage drop across the sensor is changed from zero to a value more than $100{\mu}V$ by the applied magnetic field. The change in electrical resistance depends on magnetic field. The sensitivity of this sensor is 2.9 ohm/T. The increase in electrical resistance by the magnetic field is ascribed to a modification of the Josephson junctions due to the penetrating magnetic flux into the superconducting material.

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Peculiarities of SHS and solid state synthesis of $ReBa_{2}Cu_{3}O_{7-x}$ materials

  • Sho, Dea-Wha;Li, Yingmei;Cho, Yong-Joon;Kim, Tae-Wan;Korobova, N.;Isaikina, O.;Mansurov, Z.;Baydeldinova, A.;Ksandopoulo, G.
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.07a
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    • pp.620-623
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    • 2001
  • The peculiarities of using Self-propagating High-temperature Synthesis (SHS) and solid state phase synthesis for production of high temperature superconductor materials are discussed. Oxide superconductors with general formula $ReBa_2$$Cu_3$$O_{7-x}$ (Re= Y, Yb, Sm, Nd) have been made with using barium oxide initial powder instead of traditional barium carbonate. X-ray powder diffraction showed a single phase orthorhombic perovskite structure was produced in all reactions. Phenomena observed during the grinding of the reactant mixture are presented. Mechano-chemical activation - as a pretreatment of the reactant mixture - strongly influences the kinetic parameters, the reaction mechanism, and the composition and structure of the final product.

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Peculiarities of SHS and Solid State Synthesis of ReBa2Cu3O7-x Materials

  • Soh, Deawha;Natalya, Korobova
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.15 no.3
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    • pp.275-280
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    • 2002
  • The peculiarities of using Self-propagating High-temperature Synthesis (SHS) and solid-stave chase synthesis for production of high temperature superconductor materials were discussed. Oxide superconductors with general formula of $ReBa_2Cu_3O_{7-x}$ (Re=Y, Sm) haute been made by using barium oxide initial powder instead of traditional barium carbonate. Phenomena observed during the grinding of the reactants mixture are presented. Mechano-chemical activation - as a pre-treatment of the reactants mixture - strongly influences the kinetic parameters, the reaction mechanism, and the composition and structure of the final product.