• 제목/요약/키워드: Oxide nanoparticle

검색결과 244건 처리시간 0.03초

Synthesis of Zinc Oxide Nanoparticle-(C60) Fullerene Nanowhisker Composite for Catalytic Degradation of Methyl Orange under Ultraviolet and Ultrasonic Irradiation

  • Ko, Jeong Won;Son, Yeon-A;Ko, Weon Bae
    • Elastomers and Composites
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    • 제55권4호
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    • pp.321-328
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    • 2020
  • Zinc nitrate hexahydrate (Zn(NO3)2·6H2O) and sodium hydroxide (NaOH) were dissolved in distilled water and stirred for 30 min. The resulting solution was sonicated by an ultrasonic wave for 45 min. This solution was washed with distilled water and ethanol after centrifugation; next, it was placed in an electric furnace at 200℃ for 1 h under the flow of Ar gas to obtain zinc oxide nanoparticle. A zinc oxide nanoparticle-(C60) fullerene nanowhisker composite was synthesized using the zinc oxide nanoparticle solution, C60-saturated toluene, and isopropyl alcohol via the liquid-liquid interfacial precipitation method. The zinc oxide nanoparticle and zinc oxide nanoparticle-(C60) fullerene nanowhisker composite were characterized using X-ray diffraction, scanning electron microscopy, and Raman spectroscopy, and they were used for the catalytic degradation of methyl orange (MO) under ultraviolet (at 254 and 365 nm) and ultrasonic irradiation. In addition, the catalytic degradation of MO over the zinc oxide nanoparticle and zinc oxide nanoparticle-(C60) fullerene nanowhisker composite was evaluated using ultraviolet-visible spectroscopy.

금 미세 입자에 의한 그래핀 광학 특성 변화 (Gold Nanoparticle Optical Effect on Graphene)

  • 박병호;임주환;전성찬
    • 정보저장시스템학회논문집
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    • 제9권1호
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    • pp.1-4
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    • 2013
  • Graphene and Graphene oxide have intense interest in fields such as physics, chemistry, and materials science, among others. They are the promising material for solving the current limitation that organics have barely luminescence. We observed variation of photoluminescence on graphene oxide based solution with Gold nanoparticle. Gold nanoparticles lead to shift the peak wavelength of graphene oxide and to enhance the photoluminescence intensity totally. This shows the possibility that control the luminescence property of graphene oxide by adding gold nanoparticle.

Analysis of Broad-Range DNA Fragments with Yttrium Oxide or Ytterbium Oxide Nanoparticle/Polymer Sieving Matrix Using High-Performance Capillary Electrophoresis

  • Kwon, Hae-Myun;Kim, Yong-Seong
    • Bulletin of the Korean Chemical Society
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    • 제30권2호
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    • pp.297-301
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    • 2009
  • We have developed the yttrium oxide (YNP) or ytterbium oxide (YbNP) nanoparticle/polymer matrices for the size-dependent separation of DNA ranging from 100 bp to 9,000 bp. High separation efficiency (> $10^6$ plates/m) and the baseline resolution for various DNA standards (100 bp, 500 bp, and 1 kbp DNA ladder) were obtained in 10 min with these matrices. The effects of concentrations of both polyethylene oxide (PEO) and nanoparticles were investigated and the highest performance was obtained at 0.02% PEO with 0.02% YNP or YbNP. Similar sieving power for both YNP and YbNP matrices was observed probably due to the similar sizes of nanoparticles, resulting in the formation of comparable sieving networks for DNA separation. For the reduction of electrosmotic flow, either dynamic or permanent coating of the capillary inner wall was compared and it turned out that PEO was superior to polyvinylpyrrolidone (PVP) or polyacrylamide (PAA) for better separation efficiency.

Preparation of iron oxide nanoparticle combined with radioisotope for molecular imaging

  • Park, Ji Yong;Lee, Yun-Sang;Jeong, Jae Min
    • 대한방사성의약품학회지
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    • 제4권1호
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    • pp.36-42
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    • 2018
  • Molecular imaging refers to detect the biochemical process in living organisms at the cellular and molecular levels and to quantify them. Due to several advantages of nanomaterials, various molecular images using nanomaterials are being tried. Attempts have been made to combine nanoparticles, known as micro- or nanosized nanomaterials, with radioactive isotopes for molecular imaging probe. The radiolabeled nanoparticles will expend the molecular imaging due to nanoparticle's size-dependent nature. In particular, iron oxide nanoparticles can be used for magnetic resonance imaging, can be adjusted in size, easily functionalized, and biocompatible, making it a very good platform for molecular imaging. In addition, iron oxide nanoparticles may be the best example for a new approach to molecular imaging techniques. In this paper, we introduce various methods for preparation of iron oxide nanoparticle combined with radioisotope starting from various synthesis methods of iron oxide nanoparticles to utilize iron oxide nanoparticles as a platform for molecular imaging through radioactive labeling.

Synthesis of Hybrid Fullerene Oxide[C60(O)n, (n≥1)] - Silver Nanoparticle Composites and Their Catalytic Activity for Reduction of 2-, 3-, 4-Nitroaniline

  • Park, Jeong Hoon;Ko, Jeong Won;Ko, Weon Bae
    • Elastomers and Composites
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    • 제54권3호
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    • pp.252-256
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    • 2019
  • Fullerene oxide[$C_{60}(O)_n$, ($n{\geq}1$)] was synthesized by dissolving fullerene[$C_{60}$] and 3-chloroperoxybenzoic acid in toluene under refluxing condition for 5 h. Hybrid fullerene oxide-silver nanoparticle composites were synthesized by dissolving fullerene oxide and silver nitrate[$AgNO_3$] in diethylene glycol under ultrasonic irradiation for 3 h. The synthesized hybrid nanocomposites were characterized by X-ray diffraction, scanning electron microscopy, and ultraviolet-visible[UV-vis] spectroscopy. The catalytic activity for the reduction of various nitroanilines[NAs] was identified by UV-vis spectrophotometer. The efficiency of the catalytic reduction by the synthesized hybrid nanocomposites has an order of 4-NA > 2-NA > 3-NA.

Indium Tin Oxide (ITO) Thin Film Fabricated by Indium-Tin-Organic sol with ITO Nanoparticle at Low Temperture

  • Hong, Sung-Jei;Chang, Sang-Gweon;Han, Jeong-In
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2006년도 6th International Meeting on Information Display
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    • pp.1334-1338
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    • 2006
  • In this work, indium tin oxide (ITO) thin film was fabricated by indium-tin-organic sol including ITO nanoparticle. ITO nanoparticle showed ultrafine size about 5 nm and (222) preferred crystal structure. Also, ITO sol-gel thin film showed good optical transmittance over 83% and electrical resistance less than $7\;{\times}\;10^3\;{\Omega}$.

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Expanded Graphite 산화물과 자성 나노입자의 복합화와 자기적 특성 (Synthesis and Magnetic Properties of Expanded Graphite Oxide/Magnetic Nanoparticle Composite)

  • 노일표;임현준;강명철;이찬혁;심인보
    • 한국자기학회지
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    • 제22권1호
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    • pp.11-14
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    • 2012
  • Expanded graphite 산화물과 자성 나노입자의 복합화는 화학적 방법을 이용하였으며, Ni과 Co 나노입자를 사용하여 간단한 방법으로 자기적 특성을 가지는 graphite 산화물을 합성하였다. $H_2SO_4$$(NH_4)SO_4$을 첨가한 혼합 용액을 제조하여, natural graphite와 반응시키고, 1차 열처리하여 expanded graphite를 제조하였다. $1050^{\circ}C$에서 30초간 급속 2차 열처리와 화학적 산화 과정을 거쳐 expanded graphite oxide로 변화시킨 뒤에 $Ni(acac)_2$, $Co(acac)_3$과 화학적 반응을 통하여 Expanded graphite 산화물자성 나노입자 복합체를 제조하였다. 결정 구조 분석을 위하여 x-선 회절 측정을 수행하였으며, Raman 분광 측정으로 graphite 산화물의 층상 구조를 분석하였다. 미세구조 분석을 위하여 투과전자현미경 측정을 수행하였으며, 진동시료형 자화율측정기를 이용하여 복합체의 자기적 특성을 연구하였다. 이러한 연구 결과는 graphite 화합물과 자성 물질의 복합화를 위한 기저 기술로 활용될 수 있을 것이다.

Ultrafine ITO Nanoparticle for Ink Jet Printing

  • Hong, Sung-Jei;Kim, Yong-Hoon;Han, Jeong-In
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2007년도 7th International Meeting on Information Display 제7권1호
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    • pp.467-470
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    • 2007
  • Ultrafine Indium tin oxide (ITO) nanoparticle was successfully fabricated by low temperature synthetic method (LTSM). Mean size of ITO nanoparticle is 5 nm, and uniformly dispersed with (222) orientated cubic structure. Using the nanoparticle, ITO thin film with good optical and electrical properties was fabricated by inkjet printing.

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Post-buckling analysis of geometrically imperfect nanoparticle reinforced annular sector plates under radial compression

  • Mirjavadi, Seyed Sajad;Forsat, Masoud;Mollaee, Saeed;Barati, Mohammad Reza;Afshari, Behzad Mohasel;Hamouda, A.M.S.
    • Computers and Concrete
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    • 제26권1호
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    • pp.21-30
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    • 2020
  • Buckling and post-buckling behaviors of geometrically imperfect annular sector plates made from nanoparticle reinforced composites have been investigated. Two types of nanoparticles are considered including graphene oxide powders (GOPs) and silicone oxide (SiO2). Nanoparticles are considered to have uniform and functionally graded distributions within the matrix and the material properties are derived using Halpin-Tsai procedure. Annular sector plate is formulated based upon thin shell theory considering geometric nonlinearity and imperfectness. After solving the governing equations via Galerkin's technique, it is showed that the post-buckling curves of annular sector plates rely on the geometric imperfection, nanoparticle type, amount of nanoparticles, sector inner/outer radius and sector open angle.