• 제목/요약/키워드: Oxide loss

검색결과 481건 처리시간 0.026초

희토류가 첨가된 Mn-Zn ferrite의 복소투자율 분석 (An analysis of complex permeability of Mn-Zn ferrite doped with rare earth oxide)

  • 김성수;최우성
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2000년도 추계학술대회 논문집
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    • pp.93-96
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    • 2000
  • In this study, we investigated the electromagnetic properties of Mn-Zn ferrite doped with rare earth oxide (Dy$_2$O$_3$, Er$_2$O$_3$). The main composition is 52mo1% ${\alpha}$-Fe$_2$O$_3$, 25mol% Mn$_3$O$_4$ 23mo1% ZnO and doped with them(0.05wt% ∼ 0.25wt%, step:0.05wt%). An experimental process has advanced by conventional ferrimagnetism manufacturing that was prepared by standard ceramic techniques. The XRD pattern of all doped sample were observed spinel and secondary phase. The density of sample were measured nearly constant value. As increased the additive, resistivity, initial permeability and real component of the series complex permeability increased with setting limits each other. In case of Mn-Zn ferrite excess doped with them, resistivity, initial permeability and real component of the series complex permeability decreased and magnetic loss increased in proportion to increasing the additive.

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FAST (floating absorber for safety at transient) for the improved safety of sodium-cooled burner fast reactors

  • Kim, Chihyung;Jang, Seongdong;Kim, Yonghee
    • Nuclear Engineering and Technology
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    • 제53권6호
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    • pp.1747-1755
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    • 2021
  • This paper presents floating absorber for safety at transient (FAST) which is a passive safety device for sodium-cooled fast reactors with a positive coolant temperature coefficient. Working principle of the FAST makes it possible to insert negative reactivity passively in case of temperature rise or voiding of coolant. Behaviors of the FAST in conventional oxide fuel-loaded and metallic fuel-loaded SFRs are investigated assuming anticipated transients without scram (ATWS) scenarios. Unprotected loss of flow (ULOF), unprotected loss of heat sink (ULOHS), unprotected transient overpower (UTOP) and unprotected chilled inlet temperature (UCIT) scenarios are simulated at end of life (EOL) conditions of the oxide and the metallic SFR cores, and performance of the FAST to improve the reactor safety is analyzed in terms of reactivity feedback components, reactor power and maximum temperatures of fuel and coolant. It is shown that FAST is able to improve the safety margin of conventional burner-type SFRs during ULOF, ULOHS, UTOP and UCIT.

스피넬계 Mn-Zn 페라이트의 망간이온이 미치는 영향 (Behavior of Mn Ions in Spinel-type Mn-Zn-Fe Oxide System)

  • 권오흥
    • 자원리싸이클링
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    • 제9권5호
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    • pp.11-15
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    • 2000
  • The sample made of $Mn_3O_4$ indicated an excellent frequency dependency for intial permeability and core loss. Moreover the homogeneity of cation configuration in he spinel structure was confirmed by X-ray diffraction analysis. The result of homogeneity of the spinel structural coincided with the analytical results of temperature dependence of magnetization. Furthermore, the influence of manganese oxide as starting material, on homogeneity of spinel structure was examined by using thermogravimetry-differential thermal analysis. It may be concluded that the reaction between $Mn_3O_4$ and Fe-Zn oxide mixture proceeds at fist in all combination of manganese oxide and oxie mixture, and then Mn-Zn-Fe spinel was formed.

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이산화탄소를 이용한 생분해성 고분자의 합성 (Synthesis of Biodegradable Polymers with Carbon Dioixde)

  • 신상철;신재식;이윤배
    • 한국산학기술학회논문지
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    • 제5권6호
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    • pp.521-525
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    • 2004
  • Poly(ethylene carbonate)(PEC)와 유사한 카보네이트 삼원공중합체의 생분해성이 시험관(in vitro)에서 연구 되었다. PEC는 온실가스 가운데 하나인 이산화 탄소와 ethylene oxide(EO)를 zinc glutarate 촉매로 이용하여 합성되었고, 삼원공중합체는 EO, cyclohexene oxide(CHO)와 이산화 탄소로 만들었다. PEC와 EO를 포함하는 삼원공중합체는 생분해성을 보였으나 poly(propylene carbonate)(PPC)와 poly(cyclohexene carbonate)(PCHC)는 거의 분해되지 않았다. 생분해성은 무게 감소, FT-IR, SEM 등으로 확인하였다.

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Surface modification of graphene oxide by citric acid and its application as a heterogeneous nanocatalyst in organic condensation reaction

  • Maleki, Ali;Hajizadeh, Zoleikha;Abbasi, Hamid
    • Carbon letters
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    • 제27권
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    • pp.42-49
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    • 2018
  • A citric acid functionalized graphene oxide nanocomposite was successfully synthesized and the structure and morphology of the nanocatalyst were comprehensively characterized by Fourier transform infrared spectroscopy, energy-dispersive X-ray analysis, X-ray diffraction patterns, atomic force microscopy images, scanning electron microscopy images, transmission electron microscopy images, and thermogravimetric analysis. The application of this nanocatalyst was exemplified in an important condensation reaction to give imidazole derivatives in high yields and short reaction times at room temperature. The catalyst shows high catalytic activity and could be reused after simple work up and easy purification for at least six cycles without significant loss of activity, which indicates efficient immobilizing of citrate groups on the surface of graphene oxide sheets.

Trench구조와 산화물 고유전체에 따른 Trench MIM Capacitor S-Parameter 해석 (S-Parameter Simulation for Trench Structure and Oxide High Dielectric of Trench MIM Capacitor)

  • 박정래;김구성
    • 반도체디스플레이기술학회지
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    • 제20권4호
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    • pp.167-170
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    • 2021
  • Integrated passive device (IPD) technology has emerged with the need for 5G. In order to integrate and miniaturize capacitors inside IPD, various studies are actively performed using high-k materials and trench structures. In this paper, an EM(Electromagnetic) simulation study was performed by applying an oxide dielectric to the capacitors having a various trench type structures. Commercially available materials HfO2, Al2O3, and Ta2O5 are applied to non, circle, trefoil, and quatrefoil type trench structures to confirm changes in each material or structure. As a result, the bigger the capacitor area and the higher dielectric constant of the oxide dielectric, the insertion loss tended to decrease.

Effects of Test Temperature on the Reciprocating Wear of Steam Generator Tubes

  • Hong, J.K.;Kim, I.S.
    • 한국윤활학회:학술대회논문집
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    • 한국윤활학회 2002년도 proceedings of the second asia international conference on tribology
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    • pp.379-380
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    • 2002
  • Steam generators (S/G) of pressurized water reactors are large heat exchangers that use the heat from the primary reactor coolant to make steam in the secondary side for driving turbine generators. Reciprocating sliding wear experiments have been performed to examine the wear properties of Incoloy 800 and Inconel 690 steam generator tubes in high temperature water. In present study, the test rig was designed to examine the reciprocating and rolling wear properties in high temperature (room temperature - $300^{\circ}C$) water. The test was performed at constant applied load and sliding distance to investigate the effect of test temperature on wear properties of steam generator tube materials. To investigate the wear mechanism of material, the worn surfaces were observed using scanning electron microscopy. At $290^{\circ}C$, wear rate of Inconel 690 was higher than that of Incoloy 800. It was assumed to be resulted from the oxide layer property difference due to the a\loy composition difference. Between 25 and $150^{\circ}C$ the wear loss increased with increasing temperature. Beyond $150^{\circ}C$, the wear loss decreased with increasing temperature. The wear loss change with temperature were due to the formation of wear protective oxide layer. From the worn surface observation, texture patterns and wear particle layers were found. As test temperature increased, the proportion of particle layer increased.

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$Ga_2O_3$ 첨가에 따른 $SiO_2-PbO-K_2O-Al_2O_ 3$계 적외선 센서용 glass fiber의 특성 (Properties of glass fiber by adding $Ga_2O_3$ in the $SiO_2-PbO-K_2O-Al_2O_ 3$ system for infrared sensor)

  • 이명원;윤상하;강원호
    • E2M - 전기 전자와 첨단 소재
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    • 제9권10호
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    • pp.1047-1052
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    • 1996
  • In this study, the thermal and optical proper-ties of multicomponent oxide glass fiber for IR sensor by adding heavy metal oxide Ga$_{2}$O$_{3}$ were investigated. The fiber samples were made by rod-in tube method. The optical loss of fiber was measured in 0.3-1.8/M wavelength region. As Ga$_{2}$O$_{3}$ increased up to 12wt%, the transition and softening temperature of bulk glass were increased from 495.deg. C to 564.deg. C and from 548.deg. C to 612.deg. C respectively. Whereas the thermal expansion coefficient was decreased from 102 to 88.2*10$^{-7}$ /.deg. C. The refractive index was increased from 1.621 to 1.662, and IR cut-off wavelength was enlarged from 4.64.mu.m to 5.22.mu.m. The optical loss of fiber was decreased and more remarkably decreased in 1.146.mu.m-1.8.mu.m wavelength region.

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텅스텐 폴리사이드 게이트 구조에서의 열처리 효과 (Effect of Heat Treatments on Tungsten Polycide Gate Structures)

  • 고재석;천희곤;조동율;구경완;홍봉식
    • 한국진공학회지
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    • 제1권3호
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    • pp.376-381
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    • 1992
  • Tungsten silicide films were deposited on the highly phosphorus-doped poly Si/SiO2/Si substrates by Low Pressure Chemical Vapor Deposition. They were heat treated in different conditions. XTEM, SIMS and high frequency C-V analysis were conducted for characterization. It can be concluded that outdiffusion of phosphours impurity throught the silicide films lead to its depletion in the poly-Si gate region near the gate oxide, resulting in loss of capacitance and increase of effective gate oxide thickness.

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Ni계 합금으로 브레이징된 Fe-Cr-Al 합금 접합부의 주기산화거동 (Cyclic Oxidation Behavior of Fe-Cr-Al Joint Brazed with Nickel-Base Filler Metal)

  • 문병기;최철진;박원욱
    • 연구논문집
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    • 통권29호
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    • pp.141-149
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    • 1999
  • Brazing of Fe-Cr-Al alloy was carried out at $1200^{\circ}C$ in vacuum furnace using nickel-based filler metals : BNi-5 powder(Ni-Cr-Si-Fe base alloy} and MBF-50 foil (Ni-Cr-Si-B). The effect of boron content on the stability of oxide scale on the brazed joint was investigated by means of cyclic oxidation test performed at $1050^{\circ}C$ and $1200^{\circ}C$. Apparently, the joints brazed with MBF-50 containing boron showed relatively stable oxidation rates compared to boron-free BNi-5 at both temperatures. However, it was considered that the slower weight loss of MBF-50 brazed specimen wasn’t resulted from the low oxidation rate but from the spallation of oxide layer. The oxide layer consisted of thick spinel oxide on the surface and $Al_2 O_3$ internal oxide layer along the interface between mother alloy and braze, the mother alloy was also eroded seriously by the formation of spinel oxides such as $FeCr_2 O_4$ and $NiCr_2 O_4$ on the surface, likely to be induced by the change of oxide forming mechanism due to diffusion of boron from the braze. On the contrary, the joint brazed with BNi-5 showed the good oxidation resistance during the cyclic oxidation test. It seems that the oxidation can be retarded by the formation of stable $Al_2 O_3$ layer at the surface.

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