• Title/Summary/Keyword: Oxide additives

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Determination of Liquid Paraffins in Foods by Using GC-FID (GC-FID를 이용한 식품 중 유동파라핀 함량 분석)

  • Park, Se-Jong;Choi, Jae-Chun;Lim, Ho-Soo;Jang, Su-Jin;Kim, So-Hee;Kim, Meehye
    • Korean Journal of Food Science and Technology
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    • v.45 no.5
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    • pp.545-549
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    • 2013
  • Liquid paraffin is a mixture of heavier alkanes derived from petroleum. It can be used as a lubricant in processing machinery, as a coating agent, or as a releasing agent. The purpose of this study was to analyze liquid paraffins in foods by using a gas chromatography-flame ionized detector (GC-FID). Liquid paraffin was extracted from the food samples using n-hexane. Non-polar aromatic or olefinic co-extractives were removed by alkaline permanganate oxidation followed by clean up on an aluminium oxide SPE cartridge before the GC-FID analysis. The results of recovery tests were 91.5-103.2%. Based on this optimized method, we investigated the amount of liquid paraffin in various food samples purchased from domestic markets. The levels of liquid paraffin in bread were $95.5{\pm}156.0$ mg/kg (0.008%), those in capsules were $40.2{\pm}54.5$ mg/kg (0.001%), and those in dried fruits and vegetables were $3.0{\pm}18.1$ mg/kg (0.0001%). No liquid paraffin was detected in fresh fruits and vegetables. We propose that our method can be used to monitor and detect liquid paraffin in foods for food safety management.

Preparation and Properties of Silicone Hydrogel Material Containing Silane Group with Cobalt Oxide Nanoparticles through Thermal Polymerization

  • Lee, Min-Jae;Kong, Ki-Oh;Sung, A-Young
    • Korean Journal of Materials Research
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    • v.30 no.6
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    • pp.273-278
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    • 2020
  • This research is conducted to analyze the compatibility of used monomers and produce the high functional hydrogel ophthalmic polymer containing silane and nanoparticles. VTMS (vinyltrimethoxysilane), TAVS [Triacetoxy(vinyl)silane] and cobalt oxide nanoparticles are used as additives for the basic combination of SilM (silicone monomer), MMA (methyl methacrylate) and MA (methyl acrylate). Also, the materials are copolymerized with EGDMA (ethylene glycol dimethacrylate) as cross-linking agent, AIBN (thermal polymerization initiator) as the initiator. It is judged that the lenses of all combinations are optically excellent and thus have good compatibility. Measurement of the optical and physical characteristics of the manufactured hydrophilic ophthalmic polymer are different in each case. Especially for TAVS, the addition of cobalt oxide nanoparticles increases the oxygen permeability. These materials are considered to create synergy, so they can be used in functional hydrogel ophthalmic lenses.

Design of Metal Oxide Hollow Structures Using Soft-templating Method for High-Performance Gas Sensors

  • Shim, Young-Seok;Jang, Ho Won
    • Journal of Sensor Science and Technology
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    • v.25 no.3
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    • pp.178-183
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    • 2016
  • Semiconductor gas sensors based on metal oxide are widely used in a number of applications, from health and safety to energy efficiency and emission control. Nanomaterials including nanowires, nanorods, and nanoparticles have dominated the research focus in this field owing to their large number of surface sites that facilitate surface reactions. Recently, metal oxide hollow structures using soft templates have been developed owing to their high sensing properties with large-area uniformity. Here, we provide a brief overview of metal oxide hollow structures and their gas-sensing properties from the aspects of template size, morphology, and additives. In addition, a gas-sensing mechanism and perspectives are presented.

Solution-processed indium-zinc oxide with carrier-suppressing additives

  • Kim, Dong Lim;Jeong, Woong Hee;Kim, Gun Hee;Kim, Hyun Jae
    • Journal of Information Display
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    • v.13 no.3
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    • pp.113-118
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    • 2012
  • Metal oxide semiconductors were considered promising materials as backplanes of future displays. Moreover, the adoption of carrier-suppressing metal into indium-zinc oxide (IZO) has become one of the most important themes in the metal oxide research field. In this paper, efforts to realize and optimize IZO with diverse types of carrier suppressors are summarized. Properties such as the band gap of metal in the oxidized form and its electronegativity were examined to confirm their relationship with the metal's carrier-suppressing ability. It was concluded that those two properties could be used as indicators of the carrier-suppressing ability of a material. As predicted by the properties, the alkali earth metals and early transition metals used in the research effectively suppressed the carrier and optimized the electrical properties of the metal oxide semiconductors. With the carrier-suppressing metals, IZO-based thin-film transistors with high (above $1cm^2/V{\cdot}s$) mobility, a lower than 0.6V/dec sub-threshold gate swing, and an over $3{\times}10^6$ on-to-off current ratio could be achieved.

Effect of $V_2O_5$ and $H_3BO_3$ Additives on Sintering of Magnesium Oxide (Magnesia 소결에 미치는 $V_2O_5$$H_3BO_3$ 첨가의 영향)

  • 이종권;박철원
    • Journal of the Korean Ceramic Society
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    • v.20 no.3
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    • pp.193-198
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    • 1983
  • This experiment has been carried out for the purpose of investigating the effect of $V_2O_5$ and $H_3BO_3$ additives on sintering of magnesium oxide over the temperature range of 1300-150$0^{\circ}C$ MgO powder has been obtained by calcin-ing extra reagent grade magnesium carbonate(basic) at 90$0^{\circ}C$ for 30 minutes. The specimens were prepared by compression with pressure of 700Kg/cm2 then fired at 1300-150$0^{\circ}C$ for 0-5hrs. Sintering behaviour and microstructure of fired specimens were examined. Densification rates obeyed the equation D=K 1n t+C. The ratio of density in case of addition of $V_2O_5$ to theoretical density of pure periclase was 95-99% Activation energy of densification in case of $V_2O_5$ addition was 30.15 Kcal/mole. The range of average grain size in case of addition of $V_2O_5$ was 40-50$\mu\textrm{m}$. $H_3BO_3$ addtivie had not an effect on densification of MgO.

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Effect of Alkaline-Earth Oxide Additives on Flexural Strength of Clay-Based Membrane Supports

  • Lee, Young-Il;Eom, Jung-Hye;Kim, Young-Wook;Song, In-Hyuck
    • Journal of the Korean Ceramic Society
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    • v.52 no.3
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    • pp.180-185
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    • 2015
  • Low-cost ceramic membrane supports with pore sizes in the range of $0.52-0.62{\mu}m$ were successfully prepared by uniaxial dry compaction method using inexpensive raw materials including kaolin, bentonite, talc, sodium borate, and alkaline-earth oxides in carbonate forms (e.g., $MgCO_3$, $CaCO_3$, and $SrCO_3$). The prepared green supports were sintered at $1000^{\circ}C$ for 8 hr in air. The effect of alkaline-earth oxide additives on the flexural strength of clay-based membrane supports was investigated. The porosity of the clay-based membrane supports was found to be in the range of 33-34%. The flexural strength of the clay-based membrane supports with 1% alkaline-earth carbonates was found to be in the range of 42.8-52.7 MPa. The addition of alkaline-earth carbonates to clay-based membrane supports resulted in large increases (47-80%) in the flexural strength of the membrane supports, compared to that of membrane supports without alkaline-earth carbonates. The typical flexural strength of the clay-based membrane support with 1% $SrCO_3$ was 52.7 MPa at 33.8% porosity.

Sintering agents with 2-dimensional layered structure and the enhancement of sinterability of cerium oxide using them (2차원 층상구조를 갖는 소결조제와 이를 활용한 세륨산화물 소결성 향상)

  • Park, Ji Young;Oh, Jae Myoung;Park, Hee Jung
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.29 no.1
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    • pp.1-5
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    • 2019
  • The physical properties of ceramic materials including oxides are greatly influenced by the material density. Therefore, various efforts have been made to increase the material density. One of the most popular strategies is to use sintering additives in sintering materials. The conventional sintering additive was a spherical powder having a three-dimensional structure. In this study, sintering additive with 2-dimensional (2D) layer structure was used to increase the sintering density of cerium oxide and its effect was confirmed. In this study, 1 nm-thick $TiO_x$ and $MnO_x$ nanosheets were used as sintering additives.

Effect of Storage Temperature, Time and Natural Additives on the Changes in Flavor of Lentinus edodes (저장온도, 시간 및 천연첨가제가 표고버섯의 향 변화에 미치는 영향)

  • Han, Kee-Young
    • Culinary science and hospitality research
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    • v.21 no.1
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    • pp.235-249
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    • 2015
  • This study was carried out to investigate the flavor changes of Lentinus edodes at different storage temperatures, time and natural additives using an electronic nose with six metal oxide sensors. To preserve good quality of modified atmosphere packaged Lentinus edodes, Four natural additives(Artemisia princeps, Artemisia capillaries, green tea, and activated charcoal) were used. The mushrooms were packaged in polyethylene films with each treatment and were stored at 5, 10 and $20^{\circ}C$. Increase in storage temperature and storage time decreased the ratio of resistance in the electronic nose as well as first principal component scores. In addition, indicating quality of mushroom reduced at high temperature and long storage time. The results of the electronic nose and the principal component analysis(PCA) in the mushrooms with Artemisia princeps and Artemisia capillaries that were stored at $5^{\circ}C$, and green tea and activated charcoal which were stored at $10^{\circ}C$ showed the good effects to maintain the freshness along with reducing off-flavor. However, there were no differences between control and treatment groups at $20^{\circ}C$.

Preparation of oxide barrier on Ag-sheathed Bi2223 tape for the reduction of AC loss (Ag-sheathed Bi2223 tape의 교류손실 저감을 위한 oxide barrier의 형성에 관한 연구)

  • 이세종;이득용;배성규;예경환;송요승
    • Proceedings of the Korea Institute of Applied Superconductivity and Cryogenics Conference
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    • 2002.02a
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    • pp.149-152
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    • 2002
  • SrZrO3 resistive oxide barriers on Ag sheathed Bi2223 tapes prepared by the sol-gel and dip coating method were evaluated with an aid of Taguchi method and orthogonal arrays to elucidate the effects of experimental parameters, such as ratio of starting solution, amount of additives, and heat treatment temperature and time on the properties of the thin films. Six experimental parameters were selected and then Ll8(21x37) orthogonal arrays were constructed. Finally, SEM and XRD results were related to signal to noise (S/N) ratio to evaluate the optimized experimental condition.

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