• Bulletin of the Korean Chemical Society
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• v.32 no.11
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• pp.4011-4015
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• 2011

We explored the interpretation of the well-accepted correlation between the apparent peak maximum position shift and extent of molecular interactions, like hydrogen bonding and dipole-dipole interactions, based on the overlapped multiple band model. The simulation of two overlapped Lorentzian bands was carried out to interpret how the maximum position of a composite peak relates to the relative contributions of two species representing the different levels of molecular interactions, i.e., free (or very weekly bound) vs. strongly bound. To demonstrate the validity of our interpretation of the origin of the peak position shift, the temperaturedependent IR spectra of ethylene glycol were also analyzed. It was found through the analysis of simulated and experimental spectra that the apparent peak shift in certain case can be safely interpreted as the measure of the strength of hydrogen bonding. The result of this study gives a new insight to interpret molecular interactions probed by vibrational spectroscopy.

• Journal of the Korean Society of Surveying, Geodesy, Photogrammetry and Cartography
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• v.36 no.5
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• pp.371-379
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• 2018

Unlike general VHR (Very-High-Resolution) satellite sensors that are mainly for panchromatic and MS (Multispectral) imaging, Worldview-3 sensor additionally provides eight SWIR (Short Wavelength Infrared) bands in wavelength range from 1198 nm to 2365 nm. This study investigates the effect of informative Worldview-3 SWIR bands for wetland classification performance. Worldview-3 imagery acquired over Sunchon Bay, which is a coastal wetland located in South Korea, is used to implement the classification. Land-cover classes for the scene are determined by referring to national land-cover maps, which are provided by the Ministry of Environment, overlapped with the scene. After that, training data for each determined class are collected. In order to analyze the effect of SWIR bands, classifications with and without SWIR bands are carried out and the results are then compared. In this regard, a SVM (Support Vector Machine) is utilized as their classifier. As a result of the accuracy assessments performed by test data that are independently extracted from training data, it was confirmed that classification performance was improved when the SWIR bands are included as input features for SVM-based classification.

• Rapid Communication in Photoscience
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• v.4 no.2
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• pp.34-36
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• 2015

New spectroscopic characteristics of amorphous ferric hydroxide ($Fe(OH)_3$), interestingly in the near infrared (NIR) region, are presented in this study. The absorption spectrum of ferric hydroxide covers wide spectral regions from ultraviolet to NIR (200~900 nm). Unique emission bands were newly observed in the NIR regions (800~1400 nm). Several bands of this NIR emission are quiet well overlapped with the combinational vibrational absorption bands of water. From photothermal conversion study, very interestingly, temperature of aqueous mixture solution including the amorphous ferric hydroxide was significantly increased from ambient temperature to $38^{\circ}C$ for 30 minutes under irradiation of a standard helium lamp.

• YAKHAK HOEJI
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• v.48 no.3
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• pp.171-176
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• 2004

This study was described for measuring clinically relevant levels of glucose in undiluted plasma and whole blood by near-infrared (NIR) spectroscopy. Result from an initial measurement of major blood components powder was over-lapped the absorption bands of glucose at 1500-1600 nm. However, the NIR data of blood components were clearly separated by principle component analysis (PCA) space. By the use of partial least squares (PLS) regression, glucose concentrations in undiluted plasma and whole blood could be determined with standard errors of prediction (SEP) of 15 mg/dl and 76 mg/dl, respectively. Although these blood components possessed strong absorption bands that overlapped with the absorption bands of glucose, successful calibration models could be carried out.

• ETRI Journal
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• v.23 no.4
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• pp.177-189
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• 2001

Multicarrier DS-CDMA is an effective approach to combat fading and various kinds of interference. In this paper, we present an overlapped multicarrier DS-CDMA system, wherein each of the rate 1/M convolutionally-encoded symbols is also repetition coded and transmitted using overlapped multicarriers. However, since the frequency spectrums of successive carriers are allowed to overlap, the transmission bandwidth is more efficiently utilized. The effect of the overlapping percentage between successive carriers of a multicarrier DS-CDMA system on the performance is investigated to determine the overlapping percentage showing the best performance. We suggest two methods for sub-band overlapping variation. One is to allow variation of sub-band overlapping percentage when the total number of subcarriers is fixed. The other is to increase the number of sub-bands (the number of repetitions R) with fixed sub-band bandwidth. Given a total number of subcarriers MR, we show that the BER variation is highly dependent on the roll-off factor ${\beta}$ of a raised-cosine chip wave-shaping filter irrespective of convolutional encoding rate 1/M and repetition coding rate 1/R. We also analyze the possibility of reduction in total multi-user interference by considering the variation of both the roll-off factor ($0<{\beta}{\leq}1$) and the sub-band overlapping factor ($0<{\lambda}{\leq}2$), and show that the proposed system may outperform the multicarrier DS-CDMA system in [3].

• Journal of information and communication convergence engineering
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• v.9 no.2
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• pp.220-223
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• 2011

Respiration signal of the vital signs is an important parameter in clinical parts. To extract the respiration signal from PPG signal for mobile healthcare system is difficult because the bands of the motion artifacts and respiration in the frequency domain are overlapped. This study to improve this problem suggested a respiration extraction method using the independent component analysis and evaluated its performances. In results of evaluation, the ICA method showed better performance than LPF suggested recently.

• Bulletin of the Korean Chemical Society
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• v.20 no.2
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• pp.159-162
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• 1999

Three different chemical compositions of total paraffin, total naphthene, total aromatic content in naphtha have been successfully analyzed using FT-Raman spectroscopy. Partial least squares (PLS) regression has been utilized to develop calibration models for each composition from Raman spectral bands. The PLS calibration results showed Blood correlation with those of gas chromatography (GC). Using PLS regression, the spectral information related to each composition has been successfully extracted from highly overlapped Raman spectra of naphtha.

• Proceedings of the Korean Society of Near Infrared Spectroscopy Conference
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• 2001.06a
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• pp.1283-1283
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• 2001

NIR spectroscopy has been used extensively to investigate the structure of water, alcohol and other self-associate molecules because the frequencies of NIR bands due to OH and NH groups strength of hydrogen bonds. We have studied the structure of water -methanol mixtures by use of NIR spectroscopy. Strong features in the 7200-6300 $cm^{-1}$ / region consist of a number of overlapped bands due to the combination of OH antisymmetric and symmetric stretching modes of water and the first overtone of the OH stretching modes of free and hydrogen bonded methanol, while weak fratures in the 6000-5800 cm-1 region are ascribed to the first overtones of $CH_3$ stretching modes of methanol. We will focus the discussion on the $CH_3$ stretching bands. They seem to show a significant shift is not clear from the spectra shown in figure 1(a). Figure 1(b) depicts the second derivative in the 6000-5700 $cm^{-1}$ / region. Now, it is clear from the second derivative that there are two major bands near 5950 and 5900 $cm^{-1}$ / and that they do show a shift be about 30 $cm^{-1}$ / Why do the $CH_3$ bands show the shift with increasing concentration of methanol\ulcorner Probably, the CH, group interacts directly with OH groups of water. The results in figure 1(b) demonstrate the usefulness of the second derivative in resolution enhancement as well as the potential of NIR spectroscopy in the studies of molecular interactions.(Figure omitted).

• Journal of electromagnetic engineering and science
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• v.18 no.2
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• pp.78-87
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• 2018

This paper describes specular reflectance measurements of dielectric plates in three waveguide frequency bands: D-band (110-170 GHz), G-band (140-220 GHz), and J-band (220-325 GHz). The transmit (Tx) part of the proposed specular reflectance measurement system is stationary, while the receive (Rx) part and the material under test (MUT) holder are concentric-rotating with a 2:1 speed ratio for specular reflectance measurements. In specular reflectance measurements, the first step measures the specular reflection coefficients of an MUT and a metal plate on the MUT holder located at the center of the Tx and Rx parts, and the second step calculates the specular reflectance defined by the specular reflection power (i.e., intensity) of the MUT normalized to that of the metal plate. Multiple reflection effects between the Tx and Rx antennas and the MUT on the measured specular reflectance are minimized by averaging out the multiple specular reflectances measured with changing the separation distance between the two antennas by ${\lambda}/8$ intervals. Measurement results of the perpendicular-polarized specular reflectance of commonly used dielectric plates are verified by comparing those with the analytic results and show that the results measured over the overlapped frequency range of the D-/G-bands and at the boundary frequency of the G-/J-bands agree well with the results for the other band, respectively.

• Bulletin of the Korean Chemical Society
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• v.10 no.4
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• pp.368-371
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• 1989

The constrained, iterative Fourier deconvolution procedure was applied to quantitatively analyze the overlapped bands in the Raman spectra of biomolecules. When applied to Raman spectra of lysozyme and ${\alpha}$-amylase, this procedure resolved the amide Ⅰ band into five component peaks. The relative intensities of the resolved peaks can possibly provide the composition of secondary structure elements in proteins. The deconvolution procedure was also useful in monitoring the small changes in relative intensities of C-S stretching modes due to different conformers of L-methionine in aqueous solutions at different pH values. The implemented procedure is generally applicable to the problem of resolution enhancement of spectroscopic, chromatographic, and electrophoretic data.