• Title/Summary/Keyword: Oscillator strengths

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ON THE SOLAR OSCILLATOR STRENGTH OF SiH+

  • TRIVEDI CHETNA;SINHA K.
    • Journal of The Korean Astronomical Society
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    • v.29 no.spc1
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    • pp.345-346
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    • 1996
  • The contrasting values of the oscillator strengths for the (0,0) band of SiH+ molecules for the $A\;^1II-X\;^1{\sum}+$ transition reported in literature, motivated us to reinvestigate the same with the help of a new set of well accepted solar photospheric models, elemental abundances and dissociation energy.

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Optical Properties of an Exciton in Quantum Well Structures

  • Lee, Jong-Chul
    • Journal of Electrical Engineering and information Science
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    • v.3 no.3
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    • pp.385-390
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    • 1998
  • In this paper, the oscillator strengths of both the heavy-hole and the light-hole excitons in GaAs-A\ulcornerGa\ulcornerAs and In\ulcornerGa\ulcornerAs-InP quantum wells with the effect of a magnetic field applied along the growth axis are studied. The calculation is carried out usig a variational approach, based on a simple trial exction wave function. The exciton oscillator strengths are found to decrease with increasing well width and to increase with the applied magnetic fields which lead to additional quantum confinement for moderately wide well sizes. Also, the oscillator strengths for the heavy-hole exciton are found to be large than those of the light-hole exciton in these quantum well structures.

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Absorption and Fluorescence Spectra of Dy(Ⅲ) Complexes with Some Terdentate Ligands

  • Jung Seung Hee;Yoon Soo Kyung;Kim Jong Goo;Kang Jun-Gill
    • Bulletin of the Korean Chemical Society
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    • v.13 no.6
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    • pp.650-654
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    • 1992
  • Absorption and fluorescence spectra are reported for four different 1 : 3 $Dy^{3+}$ : ligand systems in aqueous solution under mild alkaline pH conditions. The ligands included in this study are oxidiacetate, dipicolinate, iminodiacetate and methyliminodiacetate. The oscillator strengths for the 4f→4f multiplet-to-multiplet transitions are empirically determined from the absorption spectra and the intensity parameters ${\Omega}_{\lambda}$}(${\lambda}$ = 2, 4, 6) for the systems are also obtained by applying the Judd-Ofelt theorem to the observed oscillator strengths. The values of the intensity parameters for the systems are compared and discussed in terms of ligand structural properties to investigate how the intensity parameters can response to the minor changes in the ligand environment. In addition, the relative oscillator strengths for fluorescence are evaluated and compared to the results obtained from absorption spectra.

Oscillator Strengths and Intensity Parameters of Ln(III) Complexes with 12-Crown-4 and 15-Crown-5 Ethers in Acetonitrile (Ln = Ho and Er)

  • 강준길;윤수경;김은정;김종구;김윤두
    • Bulletin of the Korean Chemical Society
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    • v.16 no.3
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    • pp.232-237
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    • 1995
  • The absorption spectra of holmium nitrate and erbium nitrate and the difference absorption spectra of their complexes with crown ethers were measured in acetonitrile. The crown ethers used in this study are 12-crown-4 and 15-crown-5. The oscillator strengths for the 4f→4f multiplet-to-multiplet transitions are empirically determined from the absorption spectra in combination with the difference spectra. The intensity parameters Ωλ (λ=2, 4, 6) for the systems are also evaluated by applying the Judd-Ofelt theorem to the observed oscillator strengths. The values of the intensity parameters are compared and discussed to investigate the sensitivity of the intensity parameters to the ligand environment.

The Hypersensitive Transitions of Nd(III) and Ho(III) Complexes in Aqueous Solution (수용액중에서의 Nd(III) 및 Ho(III)의 Hypersensitive Transition에 관한 연구)

  • Dae Hyun Shin;Chong Hyeak Kim;Sock Sung Yun
    • Journal of the Korean Chemical Society
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    • v.26 no.3
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    • pp.148-154
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    • 1982
  • The effects of the various ligands on the oscillator strengths of the hypersensitive transitions of Nd(III) and Ho(III) have been studied in aqueous solution. The ligands used in the study are furoate, anthranilate, and squarate. The covalent character of the metal-ligand bond in the complex is discussed on the basis of the correlation diagram between pKa of the ligands and the oscillator strengths of the complexes previously reported.

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Absorption and Fluorescence of Sm(III) Complexes with some Terdentate Ligands

  • Kim, Jong-Goo;Yoon, Soo-Kyung;Yun, Sock-Sung;Kang, Jun-Gill
    • Bulletin of the Korean Chemical Society
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    • v.13 no.1
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    • pp.54-59
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    • 1992
  • Spectroscopic measurements and theoretical calculations are performed for the four 1 : 3 Sm(III) : ligand solutions. The ligands included in this study are oxidiacetate, iminodiacetate, methyliminodiacetate and dipicolinate. The oscillator strengths for the $4f{\to}4f$ multiplet-to-multiplet transitions are empirically determined from the absorption spectra. The intensity parameters ${\Omega}_{\lambda}\;({\lambda}=2,\;4,\;6)$ of $Sm^{3+}$(aquo) and ${SmL_3}^{3-}$ complexes are also evaluated by applying the Judd-Ofelt theorem to the observed oscillator strengths. The values of the intensity parameters are compared and discussed in term of structural properties of the complexes. In addition, the fluorescence spectra are reported for the Sm(III) complex systems under mild alkaline condition. The excitation from the $^6H_{5/2}$ ground state to any excited states lying above the emitting energy level $(^4G_{5/2})$ produces four fluorescence bands, following nonradiative transitions from a certain excited state to the $^4G_{5/2}$ state. The ratios of oscillator strengths of ${SmL_3}^{3-}$ complexes to that of $Sm^{3+}$(aquo) are also evaluated from the fluorescence spectra and compared to the results obtained from the absorption bands.

Absorption and Lumiescence Spectra of Eu(Ⅲ) Complexes with Oxydiacetate and Dipicolinate in Aqueous Solution

  • 김종구;윤수경;강준길
    • Bulletin of the Korean Chemical Society
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    • v.17 no.9
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    • pp.854-857
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    • 1996
  • Absorption and luminescence spectra of Eu3+ (aquo) and the two different 1: 3 Eu3+: ligand systems in aqueous solutions are measured under mild acidic pH condition. The oxydiacetate (ODA) and dipicolinate (DPA) ligands, forming the similar geometric complexes, are used in this work. The three intensity parameters, Ωλ (λ=2, 4, and 6) are empirically determined by applying the Judd-Ofelt theorem to the oscillator strengths of the six absorption bands arising from the ground 7F0 state. Among the three intensity parameters, the Ω2 is found to response markedly to a miner change in the ligand environment via the 7F0→5D0 transition. In addition, the relative oscillator strengths of the four luminescence bands in the visible region, assigned to the 5D0→7FJ (J=1, 2, 3 and 4) transitions are obtained to investigate their sensitivity to the ligand environment. Among the four bands, the 610 nm band, attributed to the 5D0→7F2 transition, shows hypersensitivity in the luminescence.

A Study on a Linear Phase Conjugate Oscillator with Photorefractive Medium (광굴절 매질로 구성된 선형 위상 공액 발진기의 발진 조건에 관한 연구)

  • 조제황;이우상;양인응;김은수
    • Journal of the Korean Institute of Telematics and Electronics
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    • v.25 no.9
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    • pp.1108-1114
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    • 1988
  • Usng the P.Yeh's analytic method, we derive the condition for oscillation of a linear phase conjugate oscillator which consists of photorefractive medium and two conventional mirrors. From this general oscillation condition, we obtain the threshold oscillation conditon of a single phase conjugate resonator and the self-oscillation condition of photorefractive medium, then in special case (phase shift =90\ulcorner: no external dc electric field), oscillation conditions of the linear phase conjugate oscillator for any cavity length are derived. The results indicate that, unlike in a phase conjugate oscillator with Kerr-like medium, oscillation cannot occur at special cavity length for given couplinyg strengths.

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SOLAR LOG GF VALUES FOR THE SPECTRAL LINES IN THE RANGE ${\lambda}{\lambda}$ 6209 - 6273 ${\AA}$

  • STALIN C. S.;SINHA K.;SANWAL B. B.
    • Journal of The Korean Astronomical Society
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    • v.29 no.spc1
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    • pp.341-342
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    • 1996
  • We present here the solar LOG GF values obtained using the Liege solar at las and the standard solar photospheric models for the spectral lines in the wavelength range ${\lambda}{\lambda}$ 6209 - 6273 ${\AA}$. These log gf values shall be used to interpret a high resolution spectra of the star $\gamma$ Draconics.

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Excited State Absorption and Nonradiative Transition from the Lowest 5d State of $Ce^{3+}:YAlO_3$ ($Ce^{3+}:YAlO_3$ 단결정의 5d 상태 흡수 및 비발광 천이)

  • 김지병;임기수;이건준;김동호;한재민
    • Korean Journal of Optics and Photonics
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    • v.6 no.1
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    • pp.33-38
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    • 1995
  • We have measured the excited state absorption in $Ce:YAlO_{3}$, crystals for the first time and assigned it for a 5d$\rightarrow$conduction band transition. Two broad absorption bands were observed at 555 nm and 465 nm fowllowing the 308 nm XeCl laser excitation and their cross sections and oscillator strengths were calculated. We have also measured the fluorescence lifetimes in between 300 K and 700 K to study the nonradiative relaxation from the lowest 5d state of $Ce^{3+}$ ions and explained ESA and the transition process from the state in terms of a configurational coordinate.dinate.

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