• Title/Summary/Keyword: Organic-inorganic

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Influence of Orgnainc Pigment Addition on Surface Properties of Coating Layer (유기안료의 첨가가 도공층의 표면특성에 미치는 영향)

  • 정경모;이용규
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.36 no.2
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    • pp.47-53
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    • 2004
  • In this experiment the effects of the packing structure of pigment on the surface characteristics (smoothness and gloss) of coated paper are studied. Four different kinds of inorganic pigments(clay), ground calcium carbonate(GCC), two of precipitated calcium carbonates(PCC), and two organic pigments(solid bead and hollow type) were used. The method of measuring the relative sediment volume(RSV) was used to analyze the packing structure of coating layer. The relative sediment volume was measured, using the pressure dewatering dry-cake method(PDDM) and centrifuge method. Also, the particle size distribution of coating pigment was determined. The results showed that small amount of organic pigment, added to inorganic pigment, improved smoothness and its effect was greater when GCC was used as inorganic pigment. The efficiency of organic pigment depended upon the inorganic pigment since the organic pigment is packed in the pores formed by the inorganic pigment.

Study on the Performance Characteristics of Organic-Inorganic Hybrid Flame Retardants (유-무기 하이브리드 방염제의 성능특성에 관한 연구)

  • Cho, Kyeong-Rae;Kim, Si-Kuk
    • Fire Science and Engineering
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    • v.31 no.4
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    • pp.12-19
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    • 2017
  • The present paper is a study on the performance characteristics of organic-inorganic hybrid flame retardants. MDF plywood has been used, that are being used for the interior decoration of building structures, to make the samples for experiment according to the existing or non-existing treatment of organic-inorganic hybrid flame resistants. Later, the experiment on the measurement of flame retardant performance using a $45^{\circ}$ flammability tester and the experiment on the measurement of combustion characteristic using a cone calorimeter have been proceeded to confirm the performance characteristic of organic-inorganic hybrid flame retardants. From the result of experiments, it has been confirmed that both organic-inorganic hybrid flame retardants have merits of inorganic and organic substances, and that heat resistance, durability and adhesiveness have been largely improved. The performance on the flame retardant has also appeared with excellent effect such as the reduced generation of combustion gas and the decreased generation of smoke.

Preparation and Characterization of a Layered Organic-inorganic Composite by the Electrophoretic Deposition of Plate-shaped Al2O3 Particles and Electrophoretic Resin (전기영동적층법을 통한 판상 알루미나 입자와 전기영동 수지의 배향 유무기 복합체 제조 및 물성평가)

  • Park, Hee Jeong;Lim, Hyung Mi;Choi, Sung-Churl;Kim, Younghee
    • Journal of the Korean Ceramic Society
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    • v.50 no.6
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    • pp.460-465
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    • 2013
  • Plate-shaped inorganic particles are coated onto a stainless steel substrate by the electrophoretic deposition of a precursor slurry which includes the inorganic particles of $Al_2O_3$ and polymer resin in mixed solvents to mimic the abalone shell structure, which is a composite of plate-shaped inorganic particles and organic interlayer binding materials with a layered orientation. The process parameters of the electrophoretic deposition include the voltage, coating time, and conductivity of the substrate. In addition, the suspension parameters are the particle size, concentration, viscosity, conductivity, and stability. We prepared an organic-inorganic composite coating with a high inorganic solid content by arraying the plate-shaped $Al_2O_3$ particles and electrophoretic resin via an electrophoretic deposition method. We analyzed the effect of the slurry composition and the electrophoretic deposition process parameters on the physical, mechanical and thermal properties of the coating layer, i.e., the thickness, density, particle orientation, Young's modulus and thermogravimetric analysis results.

Au/Titania Composite Nanoparticle Arrays with Controlled Size and Spacing by Organic-Inorganic Nanohybridization in Thin Film Block Copolymer Templates

  • Li, Xue;Fu, Jun;Steinhart, Martin;Kim, Dong-Ha;Knoll, Wolfgang
    • Bulletin of the Korean Chemical Society
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    • v.28 no.6
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    • pp.1015-1020
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    • 2007
  • A simple approach to prepare arrays of Au/TiO2 composite nanoparticles by using Au-loaded block copolymers as templates combined with a sol-gel process is described. The organic-inorganic hybrid films with closely packed inorganic nanodomains in organic matrix are produced by spin coating the mixtures of polystyrene-block-poly(ethylene oxide) (PS-b-PEO)/HAuCl4 solution and sol-gel precursor solution. After removal of the organic matrix with deep UV irradiation, arrays of Au/TiO2 composite nanoparticles with different compositions or particle sizes can be easily produced. Different photoluminescence (PL) emission spectra from an organic-inorganic hybrid film and arrays of Au/TiO2 composite nanoparticles indicate that TiO2 and Au components exist as separate state in the initial hybrid film and form composite nanoparticles after the removal of the block copolymer matrix.

Effects of the Contaminants in Papermaking Process Water on Physical Properties of Paper (공정수 내의 오염물질이 종이의 물성에 미치는 영향)

  • 이학래;함충현;이지영
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.36 no.1
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    • pp.16-23
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    • 2004
  • Recently the increased concerns about the cost reduction and environmental protection make the paper industry increase the closure level of papermaking system, which results in the buildup of organic and inorganic materials in the papermaking process water. Increase of the system closure causes deterioration of additive performance and provokes diverse problems in papermaking process and product quality. To investigate the effects of process water quality on the physical properties of fine papers handsheets were prepared with process water containing various amounts of inorganic and organic contaminants including calcium or sodium ions and oxidized or cationic starches. Inorgainc and organic materials did not show any significant effect on the physical properties of handsheets. Recycled GCC showed the same trends as inorganic and organic materials. The performance of cationic starch was deteriorated, however, in the recycled white water, which resulted in the reduction of tensile index of handsheets.

Preparation process of functional particles : I. Preparation of microcapsule by spray drying (기능성 미분말의 제조공정에 관한 연구 : I. 분무건조법에 의한 microcapsule 제조)

  • 정철원;허화범;박종현;신건철
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.6 no.4
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    • pp.521-531
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    • 1996
  • Inorganic and inorganic/organic microcapsules were prepared by spray drying. $K_{4}SO$ and clay were used as the core and colloidal silica as the shell for the inoroganic microcapsules. Forthe inorganic/organic microcapsules were used the inorganic microcapsule which were mentioned above (core) and ethyl cellulose (shell). To characterize the prepared microcapsule for the practical use, the homogenity of surface and pore volume are the dominent factors. At the volume ratio of 0.3/0.7 of core/shell, the spherical and homogeneous surfaces of inorganic microcapsule could be synthesized. In the case of inorganic/organic microcapsules, the weitht ratio was 0.76/0.24. The pore volume of inorganic/organic microcapsules decreases more than that of inorganic microcapsule. The more the amount of shell (ethyl cellulose) in inorganic/organic microcapsules increases, the more the coating became homogeneous and the pore volume decreased.

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Removal of Volatile Organic Compounds with Organic-Inorganic Hybrid Mesoporous Materials (유·무기 혼성 메조포러스 물질의 휘발성 유기화합물 제거능)

  • Jeong, Han Mo;La, Young Soo;An, Jin Hee;Jo, Ah Young;Choi, Mi Yeon;Kim, Suck Man;Moon, Nam Gu;Yoon, Young Ho
    • Applied Chemistry for Engineering
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    • v.16 no.5
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    • pp.719-723
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    • 2005
  • Organic-inorganic hybrid mesoporous materials were prepared by co-condensation of organosilanes with tetraethyl orthosilicate (TEOS) or 1,2-bis(triethoxysilyl) ethane (BTSE). Their removal capability of volatile organic compounds (VOCs) in the air was evaluated and compared with that of inorganic hydrophilic mesoporous material, SBA-15 that was prepared with TEOS only. It was found that the increased hydrophobicity of mesoporous materials due to the presence of organic group, could enhance the VOCs removal by adsorption in the air. An organic-inorganic hybrid material prepared by the co-condensation of BTSE/phenyl triethoxysilane (90/10 by weight) was a typical example of superior adsorbent. It was also observed that these organic-inorganic hybrid materials can be utilized as absorbents for the removal of oil dispersed in water.

Distribution Characteristics of Organic Carbon and Nutrient in Effluent of Land-based Aquaculture Farms around Wando in Korea (하계 완도 주변 육상 양식장 배출수 중 유기탄소 및 영양염의 분포 특성)

  • GyuRi Kim;Yujeong Choi;Tae–Hoon Kim
    • Ocean and Polar Research
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    • v.45 no.3
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    • pp.103-111
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    • 2023
  • To evaluate the impact of effluents from land-based fish farms on the coastal ocean of Wando, Korea, we analyzed inorganic nutrients, particulate organic carbon (POC), dissolved organic carbon (DOC), and colored dissolved organic matter (CDOM) in the effluent and influent of land-based fish farms during the summer (July) of 2021. The average concentrations of nutrients (Dissolved inorganic nitrogen, phosphorus, and silicate; DIN, DIP, and DSi, respectively) in the effluents of this study area were 17±3.7 μM, 1.4±0.7 μM, and 14±1.6 μM, respectively. The average concentrations of POC and DOC were 37±22 μM and 81±13 μM, respectively, with POC accounting for about 30% for total organic carbon in effluents. The Reduced Dissolved Inorganic Nitrogen/Total Dissolved Inorganic Nitrogen ratio (0.7), potential short-period index, indicates that the discharge of nutrients excreted by the fish and unconsumed feed into coastal water results in such nutrients being deposited and accumulated in the sediment. Subsequently, this continuous accumulation triggers the release of ammonium ions during organic matter decomposition, and the ammonium-enriched waters that encroach on fish farms as influent seem to be due to the diffusion of high concentrations of ammonium from bottom sediment. Furthermore, we used fluorescence indices to examine the characteristics of organic matter sources, obtaining mean values of 1.54±0.19, 1.06±0.06, and 1.56±0.06 for the humification index, biological index, and fluorescence index, respectively, in the effluent. These results indicate that the organic matters had an autochthonous origin that resulted from microbial decomposition, and such organic matters were rapidly generated and removed by biological activity, likely supplied from the sediment. Our results suggest that the effluent from land-based fish farms could be a potential source of deoxygenation occurrence in coastal areas.

Soil Organic Carbon Determination for Calcareous Soils (석회암 유래 토양의 토양유기탄소 분석법 연구)

  • Jung, Won-Kyo;Kim, Yoo-Hak
    • Korean Journal of Soil Science and Fertilizer
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    • v.39 no.6
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    • pp.396-402
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    • 2006
  • Soil organic carbon has long been considered as the most critical factor to evaluate the soil quality, fertility, and fertilizer prescription. In addition, soil organic carbon may impact on greenhouse gas effects and global warming. Because of that, the management of soil organic carbon is increasingly important not only for improving soil quality but also for managing soil as a greenhouse gas source. Both wet and dry combustion have been used to determine soil organic carbon. Many benefits, such as automation and less labor, could the dry combustion method become more popular. Inorganic form of carbon could overestimate soil organic carbon when the dry combustion method was applied. Determination of soil inorganic carbon may contribute to the improved accuracy of soil organic carbon analysis using dry combustion method. Objectives of this research were 1) to develop soil inorganic carbon determination method using modified digital pressure calcimeter and 2) to evaluate soil organic carbon from calcareous soils using the dry and wet combustion method. Results showed that the significant linear relationship was found between soil inorganic carbon content and pressure calcimeter output. Inorganic carbon ranged from 22% to 28% of total carbon in the calcareous soil samples. Soil organic carbon content by dry combustion for calcareous soil was determined by subtracting inorganic carbon measured by the digital pressure calcimeter from total carbon. Soil organic carbon determined by dry combustion method was significantly correlated with that by wet combustion method. In conclusion, the digital pressure calcimeter may use to improve soil organic carbon determination for the calcareous soils by subtracting of soil inorganic carbon from total carbon determined by dry combustion method.