• 제목/요약/키워드: Organic-Carbon Content

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회화법으로 측정한 퇴비중 유기물 함량을 탄소 함량으로 변환하기 위한 환산계수 결정 (Conversion Factor for Determinating Carbon Contents from Organic Matter Contents in Composts by Ignition Method)

  • 남재작;조남준;정광용;이상학
    • 한국토양비료학회지
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    • 제31권4호
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    • pp.380-383
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    • 1998
  • 본 연구는 퇴비중의 유기물 함량으로부터 탄소함량을 구하기 위한 환산계수를 결정하기 위하여 수행하였다. 퇴비중의 유기물 함량은 회화법으로, 탄소함량은 원소 분석기를 사용하여 분석한 결과 유기물 함량과 탄소함량의 관계는 "탄소함량(%)=$1.995+0.484{\times}$유기물 함량(%)"의 직선 회귀식을 따랐고, 분산분석에 의한 회귀직선의 유의성 검정은 고도로 유의하게 나타났다(P < 0.001). 기존의 토양 유기물 환산계수 1.724나 1.8을 적용할 경우, 퇴비중의 유기물 함량으로부터 환산한 탄소함량은 실제보다 10% 이상 높게 평가되어 우리 나라에서 생산, 판매되는 퇴비의 탄소함량을 구할 때는 상기 회귀식을 적용하는 것이 타당하리라 생각된다.

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토양 흡착에 대한 유기탄소와 온도의 영향 (Influence of Organic Matter and Temperature on the Sorption of Volatile Organic Compounds on Soil)

  • 김희경
    • 한국지하수토양환경학회:학술대회논문집
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    • 한국지하수토양환경학회 1998년도 공동 심포지엄 및 추계학술발표회
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    • pp.57-59
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    • 1998
  • The headspace method has been acknowledged as a cost-effective and convenient method to analyze volatile organic compounds(VOCs) in soil. The headspace analysis is based on equilibrium partitioning of VOCs among water, air and soil in a closed system. However, the headspace method cannot be applied to soils where most of the VOCs remain sorbed even at high temperature. In this study, it was investigated how the sorption characteristics of VOCs varied with soil with different organic carbon contents and temperature. This study showed that all the VOCs were volatilized, not sorved, only in the soil with 5% organic carbon at 45$^{\circ}C$ or higher. Some fraction of VOCs remained in soil with 8% organic carbon at $65^{\circ}C$ of higher. Most of the VOCs remained sorbed in soil with 12% organic content even at 95$^{\circ}C$. This result suggested that the headspace method can be applied only to soils with little organic carbon content (less than 5%). In this case, 45$^{\circ}C$ seems to be high enough to volatilize all the VOCs from soil. Large particles still showed a significant sorption capacity for VOCs from soil. Large Particles still showed a significant sorption capacity for VOCs despite of their low level of organic carbon content. It was also shown that the organic carbon sorption coefficients (Koc) of VOCs varied with soils with different organic carbon content. This suggests that not only the organic matter content of soil but also the property of the organic matter in soil influence the sorption of VOCs to soil.

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Comparing Organic Carbon Storage of Upper 15-cm Soils between Different Land Use Types in Korean Inland

  • Han, Kyung-Hwa;Cho, Hee-Rae;Lee, Jeong-Tae;Lee, Gye-Jun;Hong, Suk-Young;Zhang, Yong-Seon
    • 한국토양비료학회지
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    • 제44권6호
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    • pp.1314-1319
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    • 2011
  • This study was carried out to investigate the surface soil organic carbon fractions affecting by different land use types, including needle-leaf forest (FN), broad-leaf forest (FB), pasture, annual upland cropping land (upland), and paddy rice land (paddy). We chose seven regions across Korean inland, considering sea level altitude, and measured soil organic carbon content and physico-chemical properties such as bulk density at a depth of 0~15 cm using core samples in April for the each land use type. In addition, labile organic carbon fractions in soil including light fraction and hot water extractable carbon were investigated. From this study, organic carbon storage (Mg C per ha) in the upper 15-cm soils was highest in FB (37.8), and decreased in the order of pasture (29.1), FN (28.8), paddy (21.9), and upland crop (19.9). In forest, more than 20% of soil organic carbon existed as light fraction, the free organic matter. Hot-water extractable carbon contents of soils in five land use types were lower than 7% of their soil organic carbon content.

Statistically estimated storage potential of organic carbon by its association with clay content for Korean upland subsoil

  • Han, Kyung-Hwa;Zhang, Yong-Seon;Jung, Kang-Ho;Cho, Hee-Rae;Seo, Mi-Jin;Sonn, Yeon-Kyu
    • 농업과학연구
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    • 제43권3호
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    • pp.353-359
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    • 2016
  • Soil organic carbon (SOC) retention has gradually gotten attention due to the need for mitigation of increased atmospheric carbon dioxide and the simultaneous increase in crop productivity. We estimated the statistical maximum value of soil organic carbon (SOC) fixed by clay content using the Korean detailed soil map database. Clay content is a major factor determining SOC of subsoil because it influences the vertical mobility and adsorption capacity of dissolved organic matter. We selected 1,912 soil data of B and C horizons from 13 soil series, Sangju, Jigog, Jungdong, Bonryang, Anryong, Banho, Baegsan, Daegog, Yeongog, Bugog, Weongog, Gopyeong, and Bancheon, mainly distributed in Korean upland. The ranges of SOC and clay content were $0-40g\;kg^{-1}$ and 0 - 60%, respectively. Soils having more than 25% clay content had much lower SOC in subsoil than topsoil, probably due to low vertical mobility of dissolved organic carbon. The statistical analysis of SOC storage potential of upland subsoil, performed using 90%, 95%, and 99% maximum values in cumulative SOC frequency distribution in a range of clay content, revealed that these results could be applicable to soils with 1% - 25% of clay content. The 90% SOC maximum values, closest to the inflection point, at 5%, 10%, 15%, and 25% of clay contents were $7g\;kg^{-1}$, $10g\;kg^{-1}$, $12g\;kg^{-1}$, and $13g\;kg^{-1}$, respectively. We expect that the statistical analysis of SOC maximum values for different clay contents could contribute to quantifying the soil carbon sink capacity of Korean upland soils.

Separation of soil Organic Debris using Sucrose-ZnCl2 Density Gradient Centrifugation

  • Jung, Seok-Ho;Chung, Doug-Young;Han, Gwang-Hyun
    • 한국토양비료학회지
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    • 제45권1호
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    • pp.30-36
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    • 2012
  • The active fraction of soil organic matter, which includes organic debris and light organic fraction, plays a major role in nutrient cycling. In addition, particulate organic matter is a valuable index of labile soil organic matter and can reflect differences in various soil behaviors. Since soil organic matter bound to soil mineral particles has its density lower than soil minerals, we partitioned soil organic matter into debris ($<1.5g\;cm^{-3}$), light fraction ($1.5-2.0g\;cm^{-3}$), and heavy fraction ($>2.0g\;cm^{-3}$), based on high density $ZnCl_{2-}$ sucrose solutions. Generally, partitioned organic bands were clearly separated, demonstrating that the $ZnCl_{2-}$ sucrose solutions are useful for such a density gradient centrifugation. The available gradient ranges from 1.2 to $2.0g\;cm^{-3}$. Although there was not a statistically meaningful difference in organic debris and organomineral fractions among the examined soils, there was a general trend that a higher content of organic debris resulted in a higher proportion of light organomineral fraction. In addition, high clay content was associated with increased fraction of light organomineals. Partitioning of soil organic carbon revealed that carbon content is reduced in the heavy fraction than in the light fraction, reflecting that the light fraction contains more fresh and abundant carbon than the passive resistant fraction. It was also found that carbon contents in the overall organic matter, debris, light fraction, and heavy fractions may differ considerably in response to different farming practices.

비식생 갯벌에서 퇴적물 입도에 따른 블루카본 저장 특성: 함평만과 동대만 (Characteristics of Blue Carbon Stock by Particle Size of Sediments in Unvegetated Tidal Flats : Hampyeong Bay and Dongdae Bay)

  • 박경덕;강동환;소윤환;조원기;김병우
    • 한국환경과학회지
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    • 제32권3호
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    • pp.181-189
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    • 2023
  • In this study, sediment cores from unvegetated tidal flats in the Hampyeong Bay (west coastal wetland) and Dongdae Bay (south coastal wetland) were sampled, the blue carbon stock in the sediments was calculated, and the characteristics of the blue carbon stock were analyzed based on particle size of the sediments. The sediments in the Hampyeong Bay tidal flat had large particle size and low mud content, and the Dongdae bay tidal flat had small particle size and high mud content. The organic carbon content and blue carbon stock in the sediments were higher in the Dongdae tidal flat than in the Hampyeong Bay tidal flat. As a result of the regression function, in both the Hampyeong Bay and Dongdae Bay tidal flats, the sediments had the smaller particle size and higher mud contents the higher the organic carbon content and blue carbon stock. The sediments with smaller particle size had the larger specific surface area, so were feasible to adsorb and store more organic matters.

논토양에서 퇴비시용 및 경운이 토양탄소 축적과 안정화에 미치는 영향 (Effect of Compost and Tillage on Soil Carbon Sequestration and Stability in Paddy Soil)

  • 홍창오;강점순;신현무;조재환;서정민
    • 한국환경과학회지
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    • 제22권11호
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    • pp.1509-1517
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    • 2013
  • So far, most studies associated with soil carbon sequestration have been focused on long term aspect. However, information regarding soil carbon sequestration in short term aspect is limited. This study was conducted to determine changes of soil organic carbon content and stability of carbon in response to compost application rate and tillage management during rice growing season(150 days) in short term aspect. Under pot experiment condition, compost was mixed with an arable soil at rates corresponding to 0, 6, 12, and 24 Mg/ha. To determine effect of tillage on soil carbon sequestration, till and no-till treatments were set up in soils amended with application rate of 12 Mg/ha. Compost application and tillage management did not significantly affect soil organic carbon(SOC) content in soil at harvest time. Bulk density of soil was not changed significantly with compost application and tillage management. These might result from short duration of experiment. While hot water extractable organic carbon(HWEOC) content decreased with compost application, humic substances(HS) increased. Below ground biomass of rice increased with application of compost and till operation. From the above results, continuos application of compost and reduce tillage might improve increase in soil organic carbon content and stability of carbon in long term aspect.

고흥만 인공습지의 토양유기탄소와 이산화탄소 변동 관측 (Observations of Variations in Soil Organic Carbon and Carbon Dioxide in the Constructed Wetland at Goheung Bay)

  • 강동환;김성수;권병혁;김일규
    • 수산해양교육연구
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    • 제20권1호
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    • pp.58-67
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    • 2008
  • Seasonal variations in carbon dioxide in the air and soil organic carbon in the sediments were monitored at the constructed wetland formed by reclamation work at Goheung Bay. Sediment sampling in the constructed wetland and carbon dioxide measurement in the air were conducted on June 16 and August 23, 2007. Sediments in the constructed wetland were sampled at 11 different points (June 16) and 14 points (August 23), while carbon dioxide in the air was measured at 13 points (June 16) and 15 points (August 23). Water content and organic carbon in the sampled sediments were analyzed in the laboratory. Water content of the sediments was higher than that of general soil, and the variation between June and August was not evident. The amounts of organic carbons in the sediments sampled on August 23 were higher than those sampled on June 16. Also, there was more organic carbon in the sediments sampled at the field of reeds than in the pure wetland area. Daily maximum variation in carbon dioxide in the air was higher on June 16, but the amount of carbon dioxide in the air was greater on August 23. The results of the study suggest that organic carbon in the sediments and carbon dioxide in the air were greater in summer (August 23) than in spring season (June 16) in the constructed wetland at Goheung Bay.

농경지 토양탄소량 결정모형 추정 및 요인별 영향력 계측 (Estimation in a Model for Determining the Amount of Carbon in Soil and Measurement of the Influences of the Specific Factors)

  • 서정민;조재환;손병구;강점순;홍창오;김운원;박정호;임우택;진경호
    • 한국환경과학회지
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    • 제23권11호
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    • pp.1827-1833
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    • 2014
  • This study has been carried out to present the valuation system of soil carbon sequestration potentials of soil in accordance with the new climate change scenarios(RCP). For that, by analyzing variation of soil carbon of the each type of agricultural land use, it aims to develop technology to increase the amount of carbon emissions and sequestration. Among the factors which affects the estimation of determining the soil carbon model and influence power after the measurement on soil organic carbon, under the center of a causal relationship between the explanatory variables this study were investigated. Chemical fertilizers (NPK) decreased with increasing the amount of soil organic carbon and as with the first experimental results, when cultivating rice than pepper, the fact that soil organic carbon content increased has been found out. The higher the carbon dioxide concentration, the higher the amount of organic carbon in the soil and this result is reliable under a 10% significance level. On the other hand, soil organic carbon, humus carbon and hot water extractable carbon has been found out that was not affected the soils depth, sames as the result of the first year. The higher concentration of carbon dioxide, the higher carbon content of humus and hot water extractable carbon content. According to IPCC 2006 Guidelines and the new climate change scenario RCP 4.5 and the measurement results of the total amount of soil organic carbon to the crops due to abnormal climate weather, 1% increase in atmospheric carbon dioxide concentration was found to be small when compared to the growing rate of increasing 0.01058% of organic carbon in the soil.

서울시 PM10 내의 수용성 유기탄소와 수분함량과의 상관성 분석 (The Relationship between the Estimated Water Content and Water Soluble Organic Carbon in PM10 at Seoul, Korea)

  • 이승하;김용표;이지이;이승묵
    • 한국대기환경학회지
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    • 제33권1호
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    • pp.64-74
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    • 2017
  • In this study, we have analyzed relationship between the measured Water Soluble Organic Carbon (WSOC) concentrations and the estimated aerosol water content of $PM_{10}$ (particulate matter with an aerodynamic diameter of less than or equal to $10{\mu}m$) for the period between September 2006 and August 2007 at Seoul, Korea. Water content of $PM_{10}$ was estimated by using a gas/particle equilibrium model, Simulating composition of Atmospheric Particles at Equilibrium 2 (SCAPE2). The WSOC concentrations showed low correlation with Elemental Carbon (EC), but Water Insoluble Organic Carbon (WISOC) were highly correlated with EC. It seemed that hydrophilic groups were produced by secondary formation rather than primary formation. As with the previous studies, WSOC showed good correlation with secondary ions ($NO_3{^-}$, $SO_4{^{2-}}$, $NH_4{^+}$), especially WSOC was highly correlated with $NO_3{^-}$ that is a secondary ion formed by photochemical oxidation from more local sources than $SO_4{^{2-}}$. No apparent correlation between the measured WSOC and estimated water content was observed. However, WSOC showed good correlation with estimated water content when it was assumed that relative humidity was higher than the deliquescence relative humidity of the system. In conclusion, WSOC is correlated with water content by hygroscopic ions and it is expected that nitrate play an important role among the water content and WSOC.